CN107922754A - Composition for coating thermoplastic polymer film, method for producing composition for coating thermoplastic polymer film, modified thermoplastic polymer film, and method for producing modified thermoplastic polymer film - Google Patents
Composition for coating thermoplastic polymer film, method for producing composition for coating thermoplastic polymer film, modified thermoplastic polymer film, and method for producing modified thermoplastic polymer film Download PDFInfo
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- CN107922754A CN107922754A CN201680048429.5A CN201680048429A CN107922754A CN 107922754 A CN107922754 A CN 107922754A CN 201680048429 A CN201680048429 A CN 201680048429A CN 107922754 A CN107922754 A CN 107922754A
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- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
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Abstract
The invention provides a composition for coating a thermoplastic polymer film, a method for producing a modified thermoplastic polymer film using the composition, and a modified thermoplastic polymer film obtained by the production method, wherein the composition is less in drop performance reduction due to friction during film formation or spreading, exhibits excellent drop performance from the initial stage of spreading, maintains excellent drop performance for a long period of time even after spreading, and is less sticky on the film surface coated with drop agent. A composition for coating a thermoplastic polymer film, which comprises a specific modified inorganic cationic colloidal sol obtained by hydrolyzing a specific inorganic cationic colloidal sol with a specific silanol-forming organic silane compound, wherein the specific modified inorganic cationic colloidal sol contains a polyether-modified silicone, a specific polyoxyalkylene derivative and a polyalkylene glycol having a number average molecular weight of 1500-50000 at a specific ratio.
Description
Technical field
The present invention relates to a kind of thermal plastic high polymer film coating composition, said composition manufacture method, used this
The modified thermoplastic polymeric membrane of composition and the manufacture method of the modified thermoplastic polymeric membrane, it because making in the factory
The reduction of the drip performance caused by friction during film or when spreading into agricultural booth is lacked, and has been given play to from the initial stage sprawled excellent
Anti-drop property, also maintains excellent anti-drop property for a long time after sprawling, and then is coated with obtained film surface also few stickness.
Background technology
In the past, as thermal plastic high polymer film coating composition, it is proposed that using alumina sol, acidic silicasol,
The composition of organic silane derivative and nonionic surfactant (for example, with reference to patent document 1), using colloidal alumina,
The motions such as the composition of cabosil and polyethylene glycol (for example, with reference to patent document 2).But these existing thermoplasticity
Friction when having in polymeric membrane coating composition due to being film-made in the factory or when spreading into agricultural booth and make film
The problems such as drip performance reduces or further makes the coated face stickness of film.
Prior art literature
Patent document
Patent document 1：Japanese Unexamined Patent Application 62-241984 publications
Patent document 2：Japanese Unexamined Patent Publication 2000-160146 publications
The content of the invention
Problems to be solved by the invention
Problem to be solved by this invention is to provide a kind of thermal plastic high polymer film coating composition, said composition
The manufacturer of manufacture method, the modified thermoplastic polymeric membrane for having used said composition and the modified thermoplastic polymeric membrane
Method, the reduction of its drip performance when being film-made or caused by the friction for the when of sprawling are lacked, and have been given play to from the initial stage sprawled excellent
Anti-drop property, also maintains excellent anti-drop property for a long time after sprawling, and then is coated with the film surface of drip agent also few stickness.
The means to solve the problem
The present inventor is studied in order to solve the above problems, it turns out that, the coating of following thermal plastic high polymer films
Strictly suitable with composition, which is relative to the specific silanol chemical combination of utilization
The modified inorganic cationic colloidal colloidal sol that the condensation polymer of thing is modified specific inorganic cationic colloidal colloidal sol,
Polyether modified silicone, specific polyoxyalkylene derivative and number-average molecular weight are contained as 1500~50000 using specific ratio
What ployalkylene glycol formed.
That is, the present invention relates to a kind of thermal plastic high polymer film coating composition, it is characterised in that it is relative to solid
Body component is scaled following modified inorganic cationic colloidal colloidal sols of 100 mass parts, is contained with the ratio of 10~50 mass parts poly-
Ether modified silicone, contain following polyoxyalkylene derivatives and the ratio with 45~75 mass parts with the ratio of 2~30 mass parts
Example is formed containing the ployalkylene glycol that number-average molecular weight is 1500~50000.The invention further relates to the manufacturer of said composition
The manufacture method of method, the modified thermoplastic polymeric membrane for having used said composition and the modified thermoplastic polymeric membrane.
Modified inorganic cationic colloidal colloidal sol：The condensation polymer of following silanol compounds is set to be attached to following inorganic sun
The modified inorganic cationic colloidal colloidal sol formed on the solid constituent particle of Ionic colloid colloidal sol, the ratio of attachment for inorganic sun from
Condensation polymer=100/5~100/15 (mass ratio) of solid constituent/silanol compound of sub- colloid solution.
Inorganic cationic colloidal colloidal sol：Cationic oxidation containing the ratio that 20~90 mass % are scaled with solid constituent
Aluminum sol and the ratio that 10~80 mass % (100 mass % are added up to solid constituent conversion) is scaled with solid constituent
The inorganic cationic colloidal colloidal sol that cationic colloidal silica forms.
Silanol compound：To in trialkoxysilanes, dialkoxy silicane class and monoalkoxysilane class
The compound that processing forms is hydrolyzed at least one silanol formative organic silane compound.
Polyoxyalkylene derivative：Selected from least one of following compounds：Relative to every 1 mole of following initial compounds
The compound formed using ethylene oxide as 3~100 moles of ratio progress addition；Relative to every 1 mole of following initial compounds
The compound that 3~100 moles of ratio carries out random addition and form is added up to ethylene oxide and propylene oxide；And relative to
Every 1 mole of following initial compounds with ethylene oxide and propylene oxide add up to 3~100 moles ratio carry out block addition and
Into compound.
Initial compounds：Aliphatic alcohol that carbon number is 8~22, the aliphatic acid that carbon number is 8~22, the carbon of alkyl
The monoalkylamine that the alkyl phenol or the carbon number of alkyl that atomicity is 8~22 are 8~22.
The thermal plastic high polymer film coating composition (hereinafter referred to as composition of the invention) of the present invention is carried out first
Explanation.The composition of the present invention is relative to the above-mentioned modified inorganic cationic colloidal that 100 mass parts are scaled with solid constituent
Colloidal sol, is contained polyether modified silicone with the ratio of 10~50 mass parts, is contained above-mentioned polyoxygenated with the ratio of 2~30 mass parts
Ene derivative and number-average molecular weight is contained using the ratio of 45~75 mass parts formed as 1500~50000 ployalkylene glycol
, preferably relative to the modified inorganic cationic colloidal colloidal sol that 100 mass parts are scaled with solid constituent, with 20~40 mass
The ratio of part is contained polyether modified silicone, is contained above-mentioned polyoxyalkylene derivative with the ratio of 5~20 mass parts and with 50
The ratio of~70 mass parts contains what ployalkylene glycol formed.
The modified inorganic cationic colloidal colloidal sol being provided in the composition of the present invention is to make specific silanol chemical combination
The condensation polymer of thing is attached to what is formed on the solid constituent particle of specific inorganic cationic colloidal colloidal sol, the ratio of attachment
For the condensation polymer=100/5~100/15 (quality of solid constituent/silanol compound of inorganic cationic colloidal colloidal sol
Than).
Inorganic cationic colloidal colloidal sol as the raw material of above-mentioned modified inorganic cationic colloidal colloidal sol is containing with solid
Component is scaled the cationic oxidation Aluminum sol of the ratio of 20~90 mass % and is scaled 10~80 matter with solid constituent
What the cationic colloidal silica of the ratio of amount % (adding up to 100 mass % with solid constituent conversion) formed, preferably contain with solid
Body component is scaled the cationic oxidation Aluminum sol of the ratio of 50~80 mass % and is scaled 20~50 matter with solid constituent
What the cationic colloidal silica of the ratio of amount % (adding up to 100 mass % with solid constituent conversion) formed.
Cationic oxidation Aluminum sol is so-called colloidal alumina, can directly be used with the commercially available thing of aqueous dispersion
Product.As such commercially available product, for example, alumina sol 100, alumina sol 200, alumina sol 520 (with
On be the manufacture of Nissan Chemical society trade name), Cataloid AS-1, Cataloid AS-2 (be day to wave catalyst above
Into the trade name of society's manufacture) etc..
Cationic colloidal silica can also be used directly with the commercially available article of aqueous dispersion.As such commercially available product,
For example, Snowtex AK, Snowtex AK-L (being the trade name of Nissan Chemical society manufacture above), Cataloid
SN (trade name for waving the manufacture of catalyst chemical conversion society day), Quartron PL-3-C (trade name of chemical industry society of Japan manufacture) etc..
It is attached to the table of the solid constituent particle (aluminium oxide, the colloidal solid of silica) of the inorganic cationic colloidal colloidal sol
The condensation polymer of the silanol compound in face can be by the way that silanol formative organic silane compound be hydrolyzed and to being given birth to
Into silanol compound carry out condensation polymerization and obtain.On details, as described below, in above-mentioned inorganic cation glue
Silanol formative organic silane compound is hydrolyzed in the presence of body colloidal sol, is then contracted to the silanol compound of generation
Polymerization is closed, the condensation polymer thus, it is possible to obtain silanol compound is attached to the solid constituent of inorganic cationic colloidal colloidal sol
The modified inorganic cationic colloidal colloidal sol formed on particle.
In modified inorganic cationic colloidal colloidal sol in the composition for being supplied to the present invention, the contracting of silanol compound
Close the surface of solid constituent particle of the polymer to cover inorganic cationic colloidal colloidal sol it is all or part of in the form of adhere to,
The solid constituent particle of one part and inorganic cationic colloidal colloidal sol is chemically bonded by inference.The modified inorganic cationic colloidal
In colloidal sol, the condensation polymer of silanol compound is with solid constituent/silanol compound of inorganic cationic colloidal colloidal sol
The ratio of condensation polymer=100/5~100/15 (mass ratio) is attached to the solid constituent particle of inorganic cationic colloidal colloidal sol
On, preferably with condensation polymer=100/7~100/12 of solid constituent/silanol compound of inorganic cationic colloidal colloidal sol
The ratio of (mass ratio) is attached on the particle.
As the polyether modified silicone being supplied in the composition of the present invention, commercially available product can be directly used.It is used as this
The commercially available product of sample, for example, TSF4440, TSF4441, TSF4445, TSF4446, TSF4452, TSF4460 are (above
For Japan Momentive Performance Materials societies manufacture trade name), X22-4952, X-22-4272, KF-
6123、KF-351A、KF-352A、KF-353、KF-354L、KF-355A、KF-615A、KF-945、KF-640、KF-642、KF-
643rd, KF-644, KF-6204, X-22-4515, KF-6004 trade name of manufacture (be above silicone society of SHIN-ETSU HANTOTAI), SH8700,
SH8410, SH8400, L-7002, FZ-2104, FZ-77, L-7604, FZ-2203, FZ-2208 (are Toray Dow above
The trade name of Corning societies manufacture) etc., wherein it is preferred that the HLB such as TSF4440, KF-354L, KF-945, SH8400, KF-6004 is
4~16 polyether modified silicone.
The polyoxyalkylene derivative being fed into the composition of the present invention is the addition oxygen on following initial compounds
The compound that the compound, and/or addition ethylene oxide that change ethene forms are formed with propylene oxide, in addition ethylene oxide and oxygen
Can be any of block addition or random addition structure in the case of changing propylene.In addition, on addition molal quantity, phase
For 1 mole following of initial compounds, ethylene oxide or ethylene oxide and propylene oxide add up to 3~100 moles ratio,
Preferably 5~50 moles of ratio.
Initial compounds：Aliphatic alcohol that carbon number is 8~22, the aliphatic acid that carbon number is 8~22, the carbon of alkyl
The monoalkylamine that the alkyl phenol or the carbon number of alkyl that atomicity is 8~22 are 8~22.
As the carbon number in initial compounds be 8~22 aliphatic alcohol, can enumerate octanol, 2-Ethylhexyl Alcohol,
Nonyl alcohol, decyl alcohol, undecyl alcohol, the secondary alcohol that carbon number is 9~11, laruyl alcohol, tridecyl alcohol, myristyl alcohol, pentadecane
Base alcohol, cetyl alcohol, stearyl alcohol, isooctadecanol, oleyl alcohol, ricinoleyl alcohol, docosyl alcohol etc..In addition, as carbon number for 8~
22 aliphatic acid, can enumerate octanoic acid, n-nonanoic acid, capric acid, laurate, tetradecylic acid, palmitoleic acid, stearic acid, isostearic acid, oil
Acid, linoleic acid, arachic acid, behenic acid etc..And then as alkyl carbon number be 8~22 alkyl phenol, can enumerate pungent
Base phenol, nonyl phenol, decyl phenol, dodecylphenol, octadecyl phenol etc..And then as alkyl carbon number be 8~22 list
Alkylamine, can enumerate octylame, nonyl amine, decyl amine, lauryl amine, tridecyl amine, nutmeg amine, stearylamine, oleyl amine, docosane
Base amine etc..Wherein, as initial compounds, fat that aliphatic alcohol that preferably carbon number is 8~22, carbon number are 8~22
Fat acid.
Specifically, the ethylene oxide adduct as the aliphatic alcohol that carbon number is 8~22, can enumerate octanol
5 moles of additions of ethylene oxide of 5 moles of addition products of ethylene oxide, 100 moles of addition products of ethylene oxide of 2-Ethylhexyl Alcohol, nonyl alcohol
9 moles of additions of ethylene oxide of thing, 30 moles of addition products of ethylene oxide of undecyl alcohol, the secondary alcohol that carbon number is 9~12
Thing, 10 moles of addition products of ethylene oxide of laruyl alcohol, 50 moles of addition products of ethylene oxide, the ethylene oxide of stearyl alcohol of palmityl alcohol
20 moles of addition products, 20 moles of addition products of ethylene oxide of isooctadecanol, ethylene oxide 14 moles of addition products, docosyl alcohols of oleyl alcohol
24 moles of addition products of ethylene oxide etc., share ethylene oxide and oxidation third as the aliphatic alcohol that carbon number is 8~22
The addition product of alkene, can enumerate the random addition product of 10 moles of 10 mole propylene oxide of ethylene oxide of octanol, 2-Ethylhexyl Alcohol
Ethylene oxide 30 mole propylene oxide, 20 moles of random additions of 30 mole ethylene oxide of propylene oxide, 30 moles of addition products, decyl alcohol
Thing, the random addition product of 9 moles of 9 mole propylene oxide of ethylene oxide, the ethylene oxide 10 of tridecyl alcohol of dodecyl alcohol rub
The random addition product of your 10 moles of propylene oxide, myristyl alcohol 13 mole ethylene oxide of propylene oxide, 10 moles of block addition products,
13 mole ethylene oxide of propylene oxide, 11 moles of block addition products, 13 moles of the propylene oxide of pentadecyl alcohol of myristyl alcohol
10 moles of block addition products of ethylene oxide etc..
In addition, specifically, as the ethylene oxide adduct for the aliphatic acid that carbon number is 8~22, it can enumerate pungent
10 moles of addition products of ethylene oxide, 12 moles of addition products of lauric ethylene oxide, 5 moles of the ethylene oxide of palmitic acid of acid add
Into thing, 13 moles of addition products of stearic ethylene oxide, oleic acid 13 moles of addition products of ethylene oxide etc., be as carbon number
The ethylene oxide of 8~22 aliphatic acid and the addition product of propylene oxide, can enumerate 10 moles third of ethylene oxide of octanoic acid
The random addition product of 10 moles of alkene, the random addition product of 10 moles of 40 mole propylene oxide of ethylene oxide of capric acid alcohol, bay acid alcohol
The random addition product of 10 moles of 10 mole propylene oxide of ethylene oxide, 10 moles of 13 mole ethylene oxide of propylene oxide of tetradecylic acid are embedding
Section addition product, 13 mole ethylene oxide of propylene oxide, 10 moles of block addition products, the propylene oxide 24 of oleic acid of pentadecanoic acid rub
The random addition product of 10 moles of 10 propylene oxide of ethylene oxide etc. of 24 moles of block addition products of your ethylene oxide, behenic acid.
More specifically, the ethylene oxide adduct for the alkyl phenol that the carbon number as alkyl is 8~22, can enumerate
3 moles of addition products of ethylene oxide of octyl phenol, 10 moles of addition products of ethylene oxide, the ethylene oxide 12 of decyl phenol of nonyl phenol rub
100 moles of addition products of ethylene oxide etc. of your addition product, dodecylphenol, the alkyl that the carbon number as alkyl is 8~22
The ethylene oxide of phenol and the addition product of propylene oxide, can enumerate ethylene oxide 50 mole propylene oxide, 10 moles of nothings of octyl phenol
Advise addition product, the random addition product of 35 moles of 10 mole ethylene oxide of propylene oxide, 3 moles of the propylene oxide of decyl phenol of nonyl phenol
Propylene oxide 10 mole ethylene oxide, 80 moles of random additions of 10 moles of block block addition products of ethylene oxide, octadecyl phenol
Thing etc..
More specifically, the ethylene oxide adduct for the monoalkylamine that the carbon number as alkyl is 8~22, Ke Yiju
Go out 4 moles of addition products of ethylene oxide, 10 moles of addition products of ethylene oxide, the ethylene oxide 20 of nutmeg amine of lauryl amine of octylame
45 moles of addition products of ethylene oxide etc. of mole addition product, stearylamine, the monoalkylamine that the carbon number as alkyl is 8~22
Ethylene oxide and propylene oxide addition product, can enumerate octylame 10 moles of 20 mole propylene oxide of ethylene oxide it is random plus
Into thing, the random addition product of 10 moles of 10 mole propylene oxide of ethylene oxide of lauryl amine, palmitamide 10 mole oxygen of propylene oxide
Change 20 moles of block addition products of ethene, 20 mole ethylene oxide of propylene oxide 60 moles of block addition products, 22 of stearylamine
Ethylene oxide 20 mole propylene oxide, 5 moles of block addition products of alkylamine etc..
Wherein, as polyoxyalkylene derivative, preferably carbon number is the ethylene oxide addition of 8~22 aliphatic alcohol
The fat that the ethylene oxide for the aliphatic alcohol that thing, carbon number are 8~22 and the addition product of propylene oxide, carbon number are 8~22
The ethylene oxide adduct and carbon number of fat acid are 8~22 ethylene oxide of aliphatic acid and the addition product of propylene oxide,
And relative to 1 mole of initial compounds, with ethylene oxide or ethylene oxide and propylene oxide add up to 5~50 moles of ratio into
Row addition.Specifically, as the preferable polyoxyalkylene derivative, 10 moles of additions of ethylene oxide of decyl alcohol can be enumerated
Thing, 10 moles of addition products of ethylene oxide of laruyl alcohol, the 9 moles of addition products of ethylene oxide, hard for the secondary alcohol that carbon number is 9~12
20 moles of addition products of ethylene oxide of lipidol, 14 moles of addition products of ethylene oxide, the ethylene oxide 10 of dodecyl alcohol of oleyl alcohol
Ethylene oxide 10 mole propylene oxide, 10 moles of random additions of the random addition product of 10 moles of mole propylene oxide, tridecyl alcohol
13 mole ethylene oxide of propylene oxide, 11 moles of block addition products, 12 moles of the lauric ethylene oxide of thing, myristyl alcohol
Addition product, 13 moles of addition products of stearic ethylene oxide, 13 moles of addition products of ethylene oxide of oleic acid, stearic oxidation second
Propylene oxide 24 mole ethylene oxide, 24 moles of block addition products of the random addition product of 9 moles of 9 mole propylene oxide of alkene, oleic acid
Deng.
, can as the ployalkylene glycol that the number-average molecular weight being fed into the composition of the present invention is 1500~50000
To enumerate the polyethylene glycol, polypropylene glycol, ethylene oxide-propylene oxide atactic polymerization that number-average molecular weight is 1500~50000
Thing, ethylene oxide-propylene oxide block polymer etc., wherein preferred number average molecular weight be 3000~40000 polyethylene glycol,
Polypropylene glycol, ethylene oxide-propylene oxide atactic polymer, ethylene oxide-propylene oxide block polymer, more preferably number are divided equally
The polyethylene glycol that son amount is 6000~30000.Number-average molecular weight can be calculated by hydroxyl value, and hydroxyl value can utilize to be remembered in JIS K0070
The method of load is obtained.
Then to manufacture method (the hereinafter referred to as group of the invention of thermal plastic high polymer film coating composition of the invention
The manufacture method of compound) illustrate.The manufacture method of the composition of the present invention is to undergo following 1st processes and the 2nd process
Manufacture method.
1st process：In the presence of following inorganic cationic colloidal colloidal sols, to following silanol formative organic-silylations
Processing is hydrolyzed in compound, further makes generated silanol compound condensation polymerization, obtains modified inorganic cationic colloidal
The process of colloidal sol, in hydrolysis process, relative to the solid constituent of the inorganic cationic colloidal colloidal sol of every 100 mass parts,
The amount of the silanol formative organic silane compound is 5~15 mass parts ratios.
Inorganic cationic colloidal colloidal sol：Cationic oxidation aluminium containing the ratio that 20~90 mass % are scaled with solid constituent is molten
Glue and with solid constituent be scaled 10~80 mass % (with solid constituent conversion add up to 100 mass %) ratio sun from
The inorganic cationic colloidal colloidal sol that sub- Ludox forms.
Silanol formative organic silane compound：Selected from trialkoxysilanes, dialkoxy silicane class and single alcoxyl
At least one of base silane class.
2nd process：Relative to the modified inorganic cation obtained by process 1 that 100 mass parts are scaled with solid constituent
Colloid solution, with the ratio mixture polyether modified silicone of 10~50 mass parts, the following polyoxies of ratio mixture with 2~30 mass parts
Change ene derivative and using the ratio mixture number-average molecular weight of 45~75 mass parts as 1500~50000 ployalkylene glycol, obtain
To the process of thermal plastic high polymer film coating composition.
Polyoxyalkylene derivative：Selected from least one of following compounds：Relative to every 1 mole of following initial compounds
The compound formed using ethylene oxide as 3~100 moles of ratio progress addition；Relative to every 1 mole of following initial compounds
The compound that 3~100 moles of ratio carries out random addition and form is added up to ethylene oxide and propylene oxide；And relative to
Every 1 mole of following initial compounds with ethylene oxide and propylene oxide add up to 3~100 moles ratio carry out block addition and
Into compound.
Initial compounds：Aliphatic alcohol that carbon number is 8~22, the aliphatic acid that carbon number is 8~22, the carbon of alkyl
The monoalkylamine that the alkyl phenol or the carbon number of alkyl that atomicity is 8~22 are 8~22.
In the manufacture method of the composition of the present invention, on the inorganic cationic colloidal colloidal sol that is used in the 1st process as above
It is described.As the silanol formative organic silane compound used in the 1st process, can enumerate：1) methyl trimethoxy epoxide silicon
Alkane, methyltriethoxysilane, vinyl trichlorosilane, vinyltriethoxysilane, vinyl three (methoxy ethoxy)
Silane, γ-chloropropyl tripropoxy silane, γ-Mercaptopropyltriethoxysilane, γ-glycidoxypropyl group trimethoxy
Silane, γ-methacryloxypropyl, γ-urea propyl trimethoxy silicane, phenyltrimethoxysila,e
Etc. trialkoxysilanes, 2) dimethyldimethoxysil,ne, gamma-chloropropylmethyldimethoxysilane, γ-glycidoxy
The single alcoxyl of the dialkoxy silicane such as hydroxypropyl methyl dimethoxysilane class, 3) trim,ethylchlorosilane, trimethylmethoxysilane etc.
Base silane class etc..Wherein preferred γ-glycidoxypropyltrime,hoxysilane, γ-urea propyl trimethoxy silicane, methyl three
Ethoxysilane, ethyl triethoxysilane.
In the manufacture method of the composition of the present invention, the solid of the inorganic cationic colloidal colloidal sol used in the 1st process
The mass ratio of component and silanol formative organic silane compound and the solid constituent on inorganic cationic colloidal colloidal sol with
The above situation of the mass ratio of the condensation polymer of silanol compound is identical, in addition, changing on the polyethers used in the 2nd process
Property silicone, polyoxyalkylene derivative and ployalkylene glycol, also include they ratio it is as described above.
Then the modified thermoplastic polymeric membrane (hereinafter referred to as film of the invention) of the present invention is illustrated.The present invention's
Film is to adhere to be calculated as 0.1~2.0g/m with solid constituent in the Corona discharge Treatment face of thermal plastic high polymer film2Above-mentioned hair
What bright composition formed.
As thermal plastic high polymer film, 1) polyolefin-based resins, 2) polyvinyl chloride, vinyl chloride-metering system can be enumerated
The chlorine such as sour methyl terpolymer, polyvinylidene chloride system resin, 3) polyethylene terephthalate, gather to naphthalenedicarboxylic acid ethylene glycol
Whole thermoplastic resins that polyester based resins such as ester etc. are used as plastic film for agricultural use.As polyolefin-based resins, α-alkene can be enumerated
The homopolymer of hydrocarbon, the copolymer with heterobifunctional monomer using alpha-olefin as principal component, for example, polyethylene, polypropylene, second
Ethene-alpha-olefin copolymer, the second such as alkene-butylene copolymer, ethene -4 methyl 1 pentene copolymer, ethylene-hexene co-polymers
Alkene-vinyl acetate copolymer, ethylene methyl methacrylate copolymer, ethane-acetic acid ethyenyl ester-methyl methacrylate
Copolymer, ionomer resin etc..These resins can contain usually used antioxidant, weather resisting agent, ultraviolet as needed
Absorbent, infrared absorbent, lubricant, anti-blocking agent, antifoggant, heat preserving agent, pigment etc..It is resin-molded into as by these
The method of film is not particularly limited, for example, film blowing, T mold forming methods etc..The resin used during shaping can be with
For the blend of two or more resins.In addition, film can be individual layer, can also be multilayer, group can be carried out according to purpose use
Close and be molded obtained film.
The purposes of the film of the present invention is not particularly limited, but the effect embodied in the case of for agricultural mulch films
Significantly.
Finally to manufacture method (the hereinafter referred to as manufacturer of film of the invention of modified thermoplastic polymeric membrane of the invention
Method) illustrate.The manufacture method of the film of the present invention is following 1st processes of experience and the manufacture method of following 2nd processes.
1st process：Corona discharge Treatment is carried out to thermal plastic high polymer film, the wetting tension for making Corona discharge Treatment face is
The process of more than 35mN/m.
2nd process：Corona discharge Treatment face for the thermal plastic high polymer film obtained by the 1st process, according to solid
Component is calculated as 0.1~2.0g/m2It is coated with the process of the composition of the invention described above.
It is as described above on thermal plastic high polymer film in the manufacture method of the film of the present invention.1st process is to thermoplasticity
Polymeric membrane carries out Corona discharge Treatment, the process that the wetting tension for making Corona discharge Treatment face is more than 35mN/m, but soaks
When tension force is in the range of 35~70mN/m, effect is easily shown, is preferable.In the present invention, wetting tension is basis
The value that the record measure of JIS-K6768 obtains.
In addition, the 2nd process is the Corona discharge Treatment face of the thermal plastic high polymer film for being obtained by the 1st process, according to
0.1~2.0g/m is calculated as with solid constituent2It is coated with the process of the composition of the invention described above.It is coated with by the composition of the present invention
During to thermal plastic high polymer film, known rubbing method can be used.Wherein, for example, spraying process, Dipcoat method, roller coat
Method, scraper for coating method, wire rod rubbing method, air knife coating method etc..
The effect of invention
Present invention mentioned above has following effects：The drop of drip performance when being film-made or caused by the friction for the when of sprawling
It is low few, excellent anti-drop property has been given play to from the initial stage sprawled, has also maintained excellent anti-drop property for a long time after sprawling, and then
It is coated with the film surface of drip agent also few stickness.
Embodiment
Embodiment
Hereinafter, in order to make the composition of the present invention and effect more specific, embodiment etc. has been enumerated, but the present invention is not limited to this
A little embodiments.It should be noted that in following embodiment and comparative example, part refers to mass parts, and in addition % refers to quality %.
Test classification 1 (manufacture of thermal plastic high polymer film coating composition)
Embodiment 1
By 68.1 parts of water, 341.5 parts of cationic oxidation Aluminum sol (X1-1) (solid constituent converts 70 parts) and cationic colloidal silica
(X2-1) 130.4 parts (solid constituent converts 30 parts) mixing, prepare inorganic cationic colloidal colloidal sol.In the inorganic cationic colloidal
10 parts of mixed silanes alcohol formative organic silane compound (Y-1) in colloidal sol, prepares the mixed liquor that solid component concentration is 20%,
When 50 DEG C of stirrings 5 are small, processing is hydrolyzed to silanol formative organic silane compound (Y-1), further makes to be generated
Silanol compound carry out condensation polymerization, obtained modified inorganic cationic colloidal colloidal sol (A-1).The modified inorganic cation
Colloid solution (A-1) be make silanol compound condensation polymer be attached to the solid of above-mentioned inorganic cationic colloidal colloidal sol into
Divide on particle what is formed.Next, in the modified inorganic cationic colloidal colloidal sol (A-1) 100 parts in terms of solid constituent conversion
Middle 9400 parts of water of addition, 30 parts of polyether modified silicone (B-1), 10 parts of polyoxyalkylene derivative (C-1) and ployalkylene glycol (D-1)
60 parts and it is stirred, has obtained the thermal plastic high polymer film coating composition that solid component concentration is 2%.
Embodiment 2~37 and comparative example 1~15
With the situation of embodiment 1 be prepared as modified inorganic cationic colloidal colloidal sol (A-2)~(A-12) and (AR-1)~
(AR-3), the thermal plastic high polymer film coating composition of embodiment 2~37 and comparative example 1~15 has further been obtained.Will be by
The content aggregation of modified inorganic cationic colloidal colloidal sol prepared by each example of the above is listed in table 1, and the heat that will be obtained by each example of the above
The content aggregation of plastic macromolecule film coating composition is listed in table 2 and table 3.
[table 1]
In table 1,
X1-1：The trade name Alumina Sol 520 of Nissan Chemical Industries society manufacture
X1-2：The trade name Alumina Sol 200 of Nissan Chemical Industries society manufacture
X1-3：Wave the trade name CataloidAS-1 of catalyst chemical conversion society manufacture days
X2-1：The trade name Snowtex AK of Nissan Chemical Industries society manufacture
X2-2：Wave the trade name CataloidSN of catalyst chemical conversion society manufacture days
X2-3：The trade name Quartron PL-3-C of chemical industry society of Japan manufacture
Y-1：γ-glycidoxypropyltrime,hoxysilane
Y-2：γ-urea propyl trimethoxy silicane
Y-3：Ethyl triethoxysilane
Y-4：γ-glycidoxypropyl dimethoxysilane
Y-5：Trimethylmethoxysilane
[table 2]
[table 3]
In table 2 and table 3,
A-1~A-12, AR-1~AR-3：Modified inorganic cationic colloidal colloidal sol described in table 1
B-1：Polyether modified silicone (the trade name of Japan Momentive Performance Materials societies manufacture
TSF4440, HLB=14)
B-2：Polyether modified silicone (trade name KF-354L, HLB=16 of silicone society of SHIN-ETSU HANTOTAI manufacture)
B-3：Polyether modified silicone (trade name KF-945, HLB=4 of silicone society of SHIN-ETSU HANTOTAI manufacture)
B-4：Polyether modified silicone (trade name SH8400, HLB=8 of Toray Dow Corning societies manufacture)
B-5：Polyether modified silicone (trade name KF-6004, HLB=9 of silicone society of SHIN-ETSU HANTOTAI manufacture)
BR-1：Polydimethylsiloxane (the trade name KF-96 of silicone society of SHIN-ETSU HANTOTAI manufacture)
BR-2：Long chain alkyl modified silicone (the trade name KF-412 of silicone society of SHIN-ETSU HANTOTAI manufacture)
C-1：Carbon number is 10 moles of PO (oxygen of EO (ethylene oxide, same as below) of 12~13 aliphatic mixed alcohol
Change propylene, same as below) 10 moles of random addition products
C-2：EO10 moles of addition product of lauryl alcohol
C-3：Carbon number is that 9~11 aliphatic mixes EO9 moles of addition product of secondary alcohol
C-4：EO14 moles of addition product of oleyl alcohol
C-5：EO20 moles of addition product of stearyl alcohol
C-6：Carbon number is PO13 moles of EO11 moles of block addition product of 14~15 aliphatic mixed alcohol
C-7：EO10 moles of addition product of octanoic acid
C-8：Lauric EO12 moles of addition product
C-9：Stearic EO13 moles of addition product
C-10：EO24 moles of addition product of docosyl alcohol
C-11：EO9 moles of PO9 moles of random addition product of laruyl alcohol
C-12：PO24 moles of EO24 moles of block addition product of oleic acid
C-13：EO13 moles of addition product of oleic acid
C-14：4 moles of addition products of ethylene oxide of octylame
C-15：10 moles of addition products of ethylene oxide of nonyl phenol
C-16：100 moles of addition products of ethylene oxide of 2-Ethylhexyl Alcohol
CR-1：Methanol
CR-2：Ethylene glycol
D-1：Polyethylene glycol (the trade name PEG-20000 of chemical conversion industry society of Sanyo manufacture, number-average molecular weight 20000)
D-2：Polyethylene glycol (the trade name PEG-10000 of chemical conversion industry society of Sanyo manufacture, number-average molecular weight 11000)
D-3：Polyethylene glycol (the trade name PEG-13000 of chemical conversion industry society of Sanyo manufacture, number-average molecular weight 13000)
D-4：Polyethylene glycol (the trade name PEG-6000P of chemical conversion industry society of Sanyo manufacture, number-average molecular weight 8600)
D-5：Polyethylene glycol (number-average molecular weight 28000)
D-6：Ethylene oxide-propylene oxide atactic polymer (ethylene oxide/propylene oxide=4/1 (molar ratio), number-average molecular weight
10000)
D-7：Ethylene oxide-propylene oxide block polymer ((rubs ethylene oxide/propylene oxide/ethylene oxide=141/44/141
Your ratio), trade name Pluronic F108NF of BASF societies manufacture, number-average molecular weight 14600)
D-8：Ethylene oxide-propylene oxide atactic polymer (ethylene oxide/propylene oxide=50/50 (molar ratio), the equal molecule of number
Amount is 3500)
D-9：Polyethylene glycol (number-average molecular weight 40000)
D-10：Ethylene oxide-propylene oxide block polymer (divide equally by ethylene oxide/propylene oxide=25/75 (molar ratio), number
Son amount is 1700)
D-11：Polyethylene glycol (number-average molecular weight 50000)
DR-1：Polyethylene glycol (the trade name PEG-400 of chemical conversion industry society of Sanyo manufacture, number-average molecular weight 400)
DR-2：Polyethylene glycol (bright trade name Alkox R-150 manufactured into chemical industry society, number-average molecular weight 150000)
Test classification 2 (manufacture of modified thermoplastic polymeric membrane)
By ethene butene-1 copolymer (ethylene copolymer ratio 96%, density 0.930g/cm3, MFR1.0g/10 minutes) supply
To be provided with diameter 75mm, die lip gap 3mm die head inflation forming machine in, in 200 DEG C of resin extruded temperature and BUR=
Inflation shaping is carried out under conditions of 1.8, produces the olefin polymer films that thickness is 150 μm.Next, to the olefin polymer
Film implements sided corona treatment electric discharge, after the wetting tension for making Corona discharge Treatment face is 42mN/m, will be tested using gravure coating method
The thermal plastic high polymer film coating composition prepared in classification 1 is calculated as 0.3g/m according to solid constituent2It is applied to the corona
Discharge treatment face, stops 1 minute in the hot-air drying stove that temperature is adjusted to 70 DEG C, has obtained the modified thermoplastic high score of each example
Sub- film.
Test classification 3 (evaluation of modified thermoplastic polymeric membrane)
The evaluation of anti-drop property
The modified thermoplastic polymeric membrane of each example manufactured in test classification 2 is being adjusted in greenhouse temperature outside 30 DEG C warm, greenhouse
1m is unfolded on the detection greenhouse of 15 degree of inclined planes in 10 DEG C have2, it is attached to observe water droplet (after 1 day) and for a long time (after 30 days) in the early stage
Situation, with following benchmark evaluation preventing water drops effect, i.e. anti-drop properties.Result is collected and is listed in table 4 and table 5.
The metewand of anti-drop property
5：No water droplet attachment
4：Water droplet bond area is less than 10%
3：Water droplet bond area for more than 10%~be less than 50%
2：Water droplet bond area for more than 50%~be less than 80%
1：Water droplet bond area is more than 80%
The evaluation of marresistance
In the friction of the arm of frictional testing machine (vibration shape colorfastness testing machine of Daiei science essence mechanism Zuo Suo societies manufacture)
Vinyl tape is pasted on face, applies the load of 300g, the modified thermoplastic high score of each example manufactured in test classification 2
The coated face 100cm of sub- film2After upper reciprocating friction 10 times, the part after friction is contacted with hot vapour, pass through the attachment by water droplet
And the blurred portions produced observe the extent of exfoliation of film, with peel resistant strength, the i.e. scratch resistance of following benchmark evaluation films
Property.Result is collected and is listed in table 4 and table 5.
The metewand of marresistance
5：Peeling without film
4：The peeling area of film is less than 10%
3：The peeling area of film for more than 10%~be less than 50%
2：The peeling area of film for more than 50%~be less than 80%
1：The peeling area of film is more than 80%
The evaluation of stickness
The pros of 2 20cm × 20cm are cut out in the modified thermoplastic polymeric membrane of each example produced from test classification 2
Shape coupons, the coated face of the coupons is overlapped each other, equably applies 1kg/m2Load, 50 DEG C keep 24 it is small when
Afterwards, the square for the film of overlap condition being cut into 10mm × 10mm, for the test film, is commented as test film with following benchmark
The intermembranous peeling force of valency two, i.e. stickness.Result is collected and is listed in table 4 and table 5.
Stickness metewand
5：Peeling force is less than 50mN/10mm
4：Peeling force is more than 50mN/10mm~be less than 100mN/10mm
3：Peeling force is more than 100mN/10mm~be less than 150cmN/10mm
2：Peeling force is more than 150mN/10mm~be less than 200mN/10mm
1：Peeling force is more than 200mN/10mm
The evaluation of liquid stability
By the thermal plastic high polymer film coating composition of each example prepared in test classification 1 in 20 DEG C of room temperature in closed container
Stand and preserve, observe separate condition at this time, pass through the Time evaluation liquid stability untill separation with following benchmark.Will knot
Fruit, which collects, is listed in table 4 and table 5.
The metewand of liquid stability
5：Without separation more than when 24 is small
4：More than when 12 is small~be less than 24 it is small when without separation
3：More than when 6 is small~be less than 12 it is small when without separation
2：More than when 2 is small~be less than 6 it is small when without separation
1：Separate when small less than 2
The evaluation of coating
Observed for the state of the coated face of the modified thermoplastic polymeric membrane of each example manufactured in test classification 2, below
State benchmark evaluation coating.Result is collected and is listed in table 4 and table 5.
The metewand of coating
5：Uneven, shrinkage cavity does not occur
4：Occur in a part uneven
3：It is overall that inequality occurs
2：Shrinkage cavity occurs in a part
1：It is overall that shrinkage cavity occurs
[table 4]
[table 5]
From the table 4 and the result of table 5 corresponding to table 2 and table 3, in the composition of the coating present invention, during because of film
Or the reduction of the drip performance caused by friction when sprawling is lacked, excellent anti-drop property has been given play to from the initial stage sprawled, even in
Also excellent anti-drop property is maintained after sprawling for a long time, and then coated face also few stickness.
Claims (13)
1. a kind of thermal plastic high polymer film coating composition, it is characterised in that it is to be scaled 100 relative to solid constituent
Following modified inorganic cationic colloidal colloidal sols of mass parts, with the ratio of 10~50 mass parts contain polyether modified silicone, with 2~
The ratio of 30 mass parts contains following polyoxyalkylene derivatives and contains number-average molecular weight with the ratio of 45~75 mass parts
Formed for 1500~50000 ployalkylene glycol,
Modified inorganic cationic colloidal colloidal sol：The condensation polymer of following silanol compounds is set to be attached to following inorganic cations
The modified inorganic cationic colloidal colloidal sol formed on the solid constituent particle of colloid solution, the ratio of attachment is inorganic cation glue
Condensation polymer=100/5~100/15 of solid constituent/silanol compound of body colloidal sol, the ratio are mass ratio；
Inorganic cationic colloidal colloidal sol：Cationic oxidation aluminium containing the ratio that 20~90 mass % are scaled with solid constituent is molten
Glue and be scaled with solid constituent 10~80 mass % ratio the inorganic cationic colloidal that forms of cationic colloidal silica it is molten
Glue, the ratio add up to 100 mass % with solid constituent conversion；
Silanol compound：To in trialkoxysilanes, dialkoxy silicane class and monoalkoxysilane class extremely
The compound that processing forms is hydrolyzed in a kind of few silanol formative organic silane compound；
Polyoxyalkylene derivative：Selected from least one of following compounds：Relative to every 1 mole of following initial compounds with oxygen
Change the ratio that ethene is 3~100 moles and carry out the compound that addition forms；Relative to every 1 mole of following initial compounds with oxygen
Change ethene and propylene oxide adds up to the compound that 3~100 moles of the random addition of ratio progress forms；And relative to every 1
Mole following initial compounds, which with ethylene oxide and propylene oxide add up to 3~100 moles of ratio, to carry out block addition and forms
Compound；
Initial compounds：Aliphatic alcohol that carbon number is 8~22, the aliphatic acid that carbon number is 8~22, the carbon atom of alkyl
The monoalkylamine that number is 8~22 for 8~22 alkyl phenol or the carbon number of alkyl.
2. thermal plastic high polymer film coating composition as claimed in claim 1, wherein, the HLB of polyether modified silicone for 4~
16。
3. thermal plastic high polymer film coating composition as claimed in claim 1 or 2, wherein, silanol compound is to choosing
From γ-glycidoxypropyltrime,hoxysilane, γ-urea propyl trimethoxy silicane, methyltriethoxysilane and ethyl
The compound that processing forms is hydrolyzed at least one of triethoxysilane silanol formative organic silane compound.
4. such as thermal plastic high polymer film coating composition according to any one of claims 1 to 3, wherein, polyoxyalkylene spreads out
Biology is selected from least one of following compounds：Relative to every 1 mole of following initial compounds using ethylene oxide as 5~50
Mole ratio carry out the compound that forms of addition；Relative to every 1 mole of following initial compounds with ethylene oxide and oxidation third
The ratio that alkene adds up to 5~50 moles carries out the compound that random addition forms；And relative to every 1 mole following starting chemical combination
The ratio that thing adds up to 5~50 moles with ethylene oxide and propylene oxide carries out the compound that forms of block addition,
Initial compounds：The aliphatic acid that the aliphatic alcohol or carbon number that carbon number is 8~22 are 8~22.
5. such as thermal plastic high polymer film coating composition according to any one of claims 1 to 4, wherein, ployalkylene glycol
To be 3000~40000 polyethylene glycol, polypropylene glycol, ethylene oxide-propylene oxide atactic polymerization selected from number-average molecular weight
At least one of thing and ethylene oxide-propylene oxide block polymer.
6. such as thermal plastic high polymer film coating composition according to any one of claims 1 to 4, wherein, ployalkylene glycol
It is the polyethylene glycol that number-average molecular weight is 6000~30000.
7. such as thermal plastic high polymer film coating composition according to any one of claims 1 to 6, wherein, inorganic cation
Colloid solution contain with solid constituent be scaled 50~80 mass % ratio cationic oxidation Aluminum sol and with solid into
Divide the cationic colloidal silica for the ratio for being scaled 20~50 mass %, the ratio adds up to 100 matter with solid constituent conversion
Measure %.
8. such as thermal plastic high polymer film coating composition according to any one of claims 1 to 7, wherein, modified inorganic sun
Ionic colloid colloidal sol is the solid constituent for making the condensation polymer of silanol compound be attached to inorganic cationic colloidal colloidal sol
Formed on grain, the ratio of attachment is the condensation polymer of solid constituent/silanol compound of inorganic cationic colloidal colloidal sol
=100/7~100/12, which is mass ratio.
9. such as thermal plastic high polymer film coating composition according to any one of claims 1 to 8, it is relative to solid
Component is scaled the modified inorganic cationic colloidal colloidal sol of 100 mass parts, is contained with the ratio of 20~40 mass parts polyether-modified
Silicone, contain polyoxyalkylene derivative with the ratio of 5~20 mass parts and contain poly- alkylene with the ratio of 50~70 mass parts
What glycol formed.
10. a kind of manufacture method of thermal plastic high polymer film coating composition, it is characterised in that it undergoes following 1st processes
With following 2nd processes,
1st process：In the presence of following inorganic cationic colloidal colloidal sols, to following silanol formative organic silane compounds
Processing is hydrolyzed, further makes generated silanol compound condensation polymerization, obtains modified inorganic cationic colloidal colloidal sol
Process, it is described relative to the solid constituent of the inorganic cationic colloidal colloidal sol of every 100 mass parts in hydrolysis process
The amount of silanol formative organic silane compound is the ratio of 5~15 mass parts；
Inorganic cationic colloidal colloidal sol：Cationic oxidation aluminium containing the ratio that 20~90 mass % are scaled with solid constituent is molten
Glue and be scaled with solid constituent 10~80 mass % ratio the inorganic cationic colloidal that forms of cationic colloidal silica it is molten
Glue, the ratio add up to 100 mass % with solid constituent conversion；
Silanol formative organic silane compound：Selected from trialkoxysilanes, dialkoxy silicane class and monoalkoxy silicon
At least one of alkanes；
2nd process：Relative to the modified inorganic cationic colloidal obtained by process 1 that 100 mass parts are scaled with solid constituent
Colloidal sol, with the ratio mixture polyether modified silicone of 10~50 mass parts, the following polyoxyalkylenes of ratio mixture with 2~30 mass parts
Derivative and using the ratio mixture number-average molecular weight of 45~75 mass parts as 1500~50000 ployalkylene glycol, obtains heat
The process of plastic macromolecule film coating composition；
Polyoxyalkylene derivative：Selected from least one of following compounds：Relative to every 1 mole of following initial compounds with oxygen
Change the ratio that ethene is 3~100 moles and carry out the compound that addition forms；Relative to every 1 mole of following initial compounds with oxygen
Change ethene and propylene oxide adds up to the compound that 3~100 moles of the random addition of ratio progress forms；And relative to every 1
Mole following initial compounds, which with ethylene oxide and propylene oxide add up to 3~100 moles of ratio, to carry out block addition and forms
Compound；
Initial compounds：Aliphatic alcohol that carbon number is 8~22, the aliphatic acid that carbon number is 8~22, the carbon atom of alkyl
The monoalkylamine that number is 8~22 for 8~22 alkyl phenol or the carbon number of alkyl.
11. a kind of modified thermoplastic polymeric membrane, it is characterised in that adhere in the Corona discharge Treatment face of thermal plastic high polymer film
0.1~2.0g/m is calculated as with solid constituent2Thermal plastic high polymer film coating group according to any one of claims 1 to 9
Compound.
12. modified thermoplastic polymeric membrane as claimed in claim 11, it is agricultural mulch films.
13. a kind of manufacture method of modified thermoplastic polymeric membrane, it is characterised in that it undergoes following 1st processes and the following 2nd
Process,
1st process：Corona discharge Treatment is carried out to thermal plastic high polymer film, the wetting tension for making Corona discharge Treatment face is
The process of more than 35mN/m；
2nd process：Corona discharge Treatment face for the thermal plastic high polymer film obtained by the 1st process, according to solid constituent
It is calculated as 0.1~2.0g/m2It is coated with the work of thermal plastic high polymer film coating composition according to any one of claims 1 to 10
Sequence.
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| JP2015160350A JP5963923B1 (en) | 2015-08-17 | 2015-08-17 | Composition for coating thermoplastic polymer film, method for producing composition for coating thermoplastic polymer film, modified thermoplastic polymer film, and method for producing modified thermoplastic polymer film |
| JP2015-160350 | 2015-08-17 | ||
| PCT/JP2016/067751 WO2017029867A1 (en) | 2015-08-17 | 2016-06-15 | Thermoplastic polymer film coating composition, method for preparing thermoplastic polymer film coating composition, modified thermoplastic polymer film, and method for preparing modified thermoplastic polymer film |
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| CN109153878A (en) * | 2017-02-09 | 2019-01-04 | 竹本油脂株式会社 | Composition for coating thermoplastic polymer film, method for producing same, modified thermoplastic polymer film, and method for producing same |
| CN113728058A (en) * | 2020-03-25 | 2021-11-30 | 竹本油脂株式会社 | Coating agent composition for polymer film, method for producing modified film using same, and modified film |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62241984A (en) * | 1986-04-14 | 1987-10-22 | Takemoto Oil & Fat Co Ltd | Method of surface modification |
| JPH0782398A (en) * | 1993-09-17 | 1995-03-28 | Sumitomo Chem Co Ltd | Antifogging agent composition with improved applicability and agricultural film |
| JP2003049003A (en) * | 2001-02-05 | 2003-02-21 | Sekisui Chem Co Ltd | Thermoplastic resin film, coating antifogging agent and agricultural film |
| CN102719123A (en) * | 2012-07-05 | 2012-10-10 | 上海多纶化工有限公司 | External application anti-drop antifogging agent composition of agricultural film |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2000160146A (en) * | 1998-12-01 | 2000-06-13 | Sekisui Chem Co Ltd | Anti-fogging agent and agricultural film |
| JP4944311B2 (en) * | 2001-04-27 | 2012-05-30 | 積水化学工業株式会社 | Coating anti-fogging agent and agricultural film |
| JP2011179007A (en) * | 2011-04-18 | 2011-09-15 | Fumakilla Ltd | Anti-fogging agent and treatment method therewith |
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2015
- 2015-08-17 JP JP2015160350A patent/JP5963923B1/en active Active
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62241984A (en) * | 1986-04-14 | 1987-10-22 | Takemoto Oil & Fat Co Ltd | Method of surface modification |
| JPH0782398A (en) * | 1993-09-17 | 1995-03-28 | Sumitomo Chem Co Ltd | Antifogging agent composition with improved applicability and agricultural film |
| JP2003049003A (en) * | 2001-02-05 | 2003-02-21 | Sekisui Chem Co Ltd | Thermoplastic resin film, coating antifogging agent and agricultural film |
| CN102719123A (en) * | 2012-07-05 | 2012-10-10 | 上海多纶化工有限公司 | External application anti-drop antifogging agent composition of agricultural film |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109153878A (en) * | 2017-02-09 | 2019-01-04 | 竹本油脂株式会社 | Composition for coating thermoplastic polymer film, method for producing same, modified thermoplastic polymer film, and method for producing same |
| CN109153878B (en) * | 2017-02-09 | 2020-01-21 | 竹本油脂株式会社 | Composition for coating thermoplastic polymer film, method for producing same, modified thermoplastic polymer film, and method for producing same |
| CN113728058A (en) * | 2020-03-25 | 2021-11-30 | 竹本油脂株式会社 | Coating agent composition for polymer film, method for producing modified film using same, and modified film |
| CN113728058B (en) * | 2020-03-25 | 2022-11-04 | 竹本油脂株式会社 | Coating agent composition for polymer film, method for producing modified film using same, and modified film |
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| KR101904129B1 (en) | 2018-10-04 |
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| JP5963923B1 (en) | 2016-08-03 |
| CN107922754B (en) | 2019-03-08 |
| JP2017039785A (en) | 2017-02-23 |
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