CN107916062A - A kind of solid wood dedicated transparent priming paint and preparation method thereof - Google Patents

A kind of solid wood dedicated transparent priming paint and preparation method thereof Download PDF

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Publication number
CN107916062A
CN107916062A CN201711188874.4A CN201711188874A CN107916062A CN 107916062 A CN107916062 A CN 107916062A CN 201711188874 A CN201711188874 A CN 201711188874A CN 107916062 A CN107916062 A CN 107916062A
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component
solid wood
priming paint
transparent priming
dedicated transparent
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CN201711188874.4A
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CN107916062B (en
Inventor
姜敬达
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Guangdong Huilon Coating Industrial Co Ltd
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Guangdong Huilon Coating Industrial Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/06Polyurethanes from polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4202Two or more polyesters of different physical or chemical nature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/58Epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of solid wood dedicated transparent priming paint and preparation method thereof, the solid wood dedicated transparent priming paint uses two kinds of special saturated polyester resins and epoxy resin that transparent priming is made as first component plus auxiliary raw materials such as appropriate talcum powder;Butyl acetate and polyisocyanate curing agent etc. are configured to second component;Third component is configured to butyl acetate, propylene glycol methyl ether acetate, dimethyl carbonate, dimethylbenzene etc., high-grade solid wood furniture surface is painted on after the first and second the third three components are mixed in a certain ratio uniformly during construction, forms coating;Proved after tested with practical function:Not only strong adhesive force, pliability are good, hardness is high for the coating, the transparency is good, but also it has solid muscle, filling capacity, the performance of anti-timber natural texture (clarity, three-dimensional sense) of sinking, highlight, and the texture and class of solid wood furniture is substantially improved.

Description

A kind of solid wood dedicated transparent priming paint and preparation method thereof
Technical field
The invention belongs to technical field of coatings, more particularly to a kind of solid wood dedicated transparent priming paint and preparation method thereof.
Background technology
At present, in household industry, solid wood furniture closing application uses PE/UV transparent primings, PU finishing coat techniques mostly, but The product that the technique is worked it out shows that the inadequate clear and natural of wood grain, stereovision three-dimensional sense are very poor, and color and luster is also very inflexible, not as pure PU Priming paint is worked it out fresh and alive, can not lift the class of solid wood furniture.
PU transparent primings are a kind of woodwork coatings of excellent combination property, are widely used in wood decoration, but routine PU is saturating After the construction of bright priming paint, because of common alkyd resin self-characteristic, the degree of cross linking can not design too high, and hardness is not high, and solvent easily infiltrates into Paint film, it is serious that paint film parches after-contraction, and during solid wood ground multiple tracks application (enclosed type), rear road coating solvents, which penetrate into soak into, leads Paint film in wood grain conduit is caused to send out the protuberance that rises, wood falls into or swells (cannot return abdomen) so as to influence surface effect now after paint film parches.
The content of the invention
In view of the problems of the existing technology, the object of the present invention is to provide a kind of solid wood dedicated transparent priming paint and its preparation Method.The transparent priming of the present invention has the characteristics that high rigidity, high filling power, high transparency, solid muscle are prevented falling into, and meets current market pair The application demand of high-grade solid wood furniture.
To achieve these goals, the present invention uses following technical scheme:
A kind of solid wood dedicated transparent priming paint, including first component, second component and the third component,
Wherein, the first component includes following raw material by weight percentage:
9 modified saturated polyester resin 15%--25% of carbon,
Superbrnaching end-hydroxy saturated polyester resin 30%--50%,
Dispersant 0.1%--0.2%,
Epoxy resin 3--5%,
Defoamer 0.2%--0.3%,
Anti-settling agent 1%--2%,
Zinc stearate 5%--8%,
Talcum powder 8%--20%,
Propylene glycol methyl ether acetate 3%--5%,
Butyl acetate 5%--15%;
The second component includes following raw material by weight percentage:
Dehydration acetate butyl ester 40%--45%,
TDI addition product curing agent 45%--50%,
TDI trimer curing agents 10%--15%;
Third component includes following raw material by weight percentage:
The first component, second component, the weight ratio of the third component are 1:0.5:(0.6--0.8).
Preferably, the 9 modified saturated polyester resin of carbon is the RV8660 of three chemical Science and Technology Ltd.s.
Preferably, the terminal hydroxy group surpasses cladodification saturated polyester resin for the 9875 of leaf generation Chemical Group resin prosperous greatly.
Preferably, the dispersant be Dutch Efka company EFKA4050, EFKA5065 and EFKA4010 in extremely Few one kind.
Preferably, the epoxy resin is Changxing epoxy resin DR-G908.
Preferably, the defoamer is at least one of Silok4084, BYK1788, BYK052.
Preferably, the TDI addition products curing agent is the Desmodur L-75 of Bayer Bitterfeld GmbH chemical company production, is dissociated TDI, HDI content≤0.5%.
Preferably, the TDI trimer curing agents are the Desmodur IL 1451 of Bayer Bitterfeld GmbH chemical company production, are swum From TDI, HDI content≤0.5%.
Preferably, fineness≤40 μm of the first component, its viscosity are 10000--20000mPa.s at 25 DEG C.
Preferably, the dehydration acetate butyl ester is urethane level solvent.
Preferably, the anti-settling agent is bentonite.
The preparation method of above-mentioned solid wood dedicated transparent priming paint, comprises the following steps:
(1) preparation of first component:By 9 modified saturated polyester resin of carbon, superbrnaching end-hydroxy saturated polyester resin, asphalt mixtures modified by epoxy resin Fat, dispersant, defoamer are put into dispersion machine successively, after being uniformly dispersed with the rotating speed of 600--800RPM, then in 300-- 500RPM rotating speeds disperse side and put into anti-settling agent, zinc stearate, talcum powder successively below, then high with the rotating speed of 1200--1500RPM The scattered 10--15min of speed, to fineness≤40 μm, input propylene glycol methyl ether acetate is uniformly dispersed with the rotating speed of 600--800RPM, Viscosity is adjusted with butyl acetate, it is 10000--20000mPa.s when at 25 DEG C to make it, and first component is made, spare;
(2) preparation of second component:By butyl acetate, vacuum dehydration about 20-40min, extremely dehydration are complete at 90-100 DEG C Afterwards;By dehydration acetate butyl ester, TDI addition products curing agent and TDI trimer curing agents, stir evenly rear press filtration and be transferred to storage tank and treat With;
The preparation of (3) third components:By dimethylbenzene, butyl acetate, propylene glycol methyl ether acetate, dimethyl carbonate and acetic acid second In ester input dispersion machine, disperseed 4-10 minutes with the rotating speed of 300-500RPM, it is stand-by to be sufficiently mixed uniform sealed storage;
(4) first component, second component and the third component are uniformly mixed, solid wood dedicated transparent priming paint is made.
The present invention uses two kinds of special saturated polyester resins, and permeability is extremely strong, its hydroxyl and isocyanates reaction are thorough, make It is strong to obtain high paint film crosslink density, hardness height, solvent resistance;Changxing epoxy resin DR-G908 is introduced in first component of the present invention, its The material of high molecular weight reactive can occur with isocyano group (- NCO) functional group, it has the compatibility of broadness, tool with high molecular polymer There is very high alkyl (- OH) tolerance, strengthen the toughness of paint film, wearability, moisture resistance, salt spray resistance, solvent resistant chemicals energy, And the epoxy resin has good to ground wetting function in itself, strengthen the permeability of paint.After strengthening paint film crosslink density, Solvent is less susceptible to infiltration and soaks into during multipass application, and paint film hardness in itself and solvent resistance also obtain basic reinforcement, so The bottom paint film of wooden intraocular will not be because of being caused protuberance of swelling by solvent soaking, and the present invention easily infiltration, strong muscle are so as to leading Cause wooden eye easily fill up parch after do not shrink, paint film parch after be more not in the disadvantage such as sagging.
Beneficial effects of the present invention:
The high rigidity of the present invention, high filling power, high transparency, solid muscle prevent sunken advanced solid wood dedicated transparent priming paint, after tested Proved with practical function, not only strong adhesive force, pliability are good, hardness is high for its coating, the transparency is good, but also it has solid muscle, fills out Fill ability, the performance of anti-timber natural texture (clarity, three-dimensional sense) of sinking, highlight, be substantially improved solid wood furniture texture and Class.
Embodiment
With reference to embodiment, the present invention is specifically described.
Embodiment 1
A kind of high rigidity, high filling power, high transparency, solid muscle prevent sunken high-grade solid wood dedicated transparent priming paint, and it includes first Component, second component and the third component, the first component, second component, the weight ratio of the third component are 1:0.5:0.7;
The first component includes following raw material by weight percentage:
The second component includes following raw material by weight percentage:
Dehydration acetate butyl ester 40%,
Curing agent L-75 50%,
Curing agent 1,351 10%;
Third component includes following raw material by weight percentage:
The preparation method of above-mentioned solid wood dedicated transparent priming paint, comprises the following steps:
(1) preparation of first component:By 9 modified saturated polyester resin of carbon, superbrnaching end-hydroxy saturated polyester resin, DR- G908, EFKA4010, BYK052 are put into dispersion machine successively, after being uniformly dispersed with the rotating speed of 700RPM, then in 400RPM rotating speeds Scattered side puts into bentonite, zinc stearate, talcum powder, then the rotating speed high speed dispersion 15min with 1400RPM successively below, to thin Degree≤40 μm, input propylene glycol methyl ether acetate be uniformly dispersed with the rotating speed of 7RPM, with butyl acetate adjust viscosity, make its It is 10000--20000mPa.s at 25 DEG C, first component is made, it is spare;
(2) preparation of second component:By butyl acetate at 90 DEG C vacuum dehydration about 30min, to be dehydrated completely after;Will dehydration Butyl acetate, L-75 and 1351, stir evenly rear press filtration and to be transferred to storage tank stand-by;
The preparation of (3) third components:By dimethylbenzene, butyl acetate, propylene glycol methyl ether acetate, dimethyl carbonate and acetic acid second In ester input dispersion machine, disperseed 10 minutes with the rotating speed of 400RPM, it is stand-by to be sufficiently mixed uniform sealed storage;
(4) first component, second component and the third component are uniformly mixed, solid wood dedicated transparent priming paint is made.
The solid wood dedicated transparent priming paint that embodiment 1 is prepared is tested for the property, and test result is shown in Table 1.
The performance test results of the solid wood dedicated transparent priming paint of 1 embodiment 1 of table
Embodiment 2
A kind of high rigidity, high filling power, high transparency, solid muscle prevent sunken high-grade solid wood dedicated transparent priming paint, and it includes first Component, second component and the third component, the first component, second component, the weight ratio of the third component are 1:0.5:0.6;
The first component includes following raw material by weight percentage:
The second component includes following raw material by weight percentage:
Dehydration acetate butyl ester 45%,
Curing agent L-75 45%,
Curing agent 1,351 10%;
Third component includes following raw material by weight percentage:
The preparation method of above-mentioned solid wood dedicated transparent priming paint, comprises the following steps:
(1) preparation of first component:By 9 modified saturated polyester resin of carbon, superbrnaching end-hydroxy saturated polyester resin, DR- G908, EFKA4010, BYK052 are put into dispersion machine successively, after being uniformly dispersed with the rotating speed of 700RPM, then in 400RPM rotating speeds Scattered side puts into bentonite, zinc stearate, talcum powder, then the rotating speed high speed dispersion 15min with 1400RPM successively below, to thin Degree≤40 μm, input propylene glycol methyl ether acetate be uniformly dispersed with the rotating speed of 7RPM, with butyl acetate adjust viscosity, make its It is 10000--20000mPa.s at 25 DEG C, first component is made, it is spare;
(2) preparation of second component:By butyl acetate at 90 DEG C vacuum dehydration about 30min, to be dehydrated completely after;Will dehydration Butyl acetate, L-75 and 1351, stir evenly rear press filtration and to be transferred to storage tank stand-by;
The preparation of (3) third components:By dimethylbenzene, butyl acetate, propylene glycol methyl ether acetate, dimethyl carbonate and acetic acid second In ester input dispersion machine, disperseed 10 minutes with the rotating speed of 400RPM, it is stand-by to be sufficiently mixed uniform sealed storage;
(4) first component, second component and the third component are uniformly mixed, solid wood dedicated transparent priming paint is made.
The solid wood dedicated transparent priming paint that embodiment 2 is prepared is tested for the property, and test result is shown in Table 2.
The performance test results of the solid wood dedicated transparent priming paint of 2 embodiment 2 of table
Comparative example 1
A kind of reality wood primer, including following raw material by weight:
Comparative example 2
A kind of reality wood primer, including following raw material by weight:
The transparent priming of embodiment 1-2 and comparative example 1-2 are tested for the property.Detection method:Performance indicator refers to GB/ T23997-2009, limits of harmful substances is with reference to GB18581-2009.It the results are shown in Table shown in 3.
The performance test results of the transparent priming of table 3 embodiment 1-2 and comparative example 1-2
Inspection project Embodiment 1 Embodiment 2 Comparative example 1 Comparative example 2
Surface drying (min) 35 30 35 30
Do solid work (h) 6.5 6 6.5 6
Adhesive force (level) 1 1 1 1
Pliability (mm) 1 1 1 1
Hardness 2H 2H H HB
Grinability It is good It is good It is good It is good
Gu muscle Effect is good Effect is good Wooden eye protuberance Wooden eye protuberance
Filling It is good It is good Difference It is slightly worse
The transparency It is good It is good It is good It is good
Smell Net taste Net taste Peculiar smell weight Peculiar smell
Wood is fallen into now Nothing Nothing It is obvious to sink It is obvious to sink
Show, solid wood dedicated transparent priming paint of the invention that there is high rigidity, high filling power, height thoroughly by above test data Characteristic that is bright, preventing wood from falling into now, is the preferred product of high-grade solid wood furniture closing application.

Claims (10)

  1. A kind of 1. solid wood dedicated transparent priming paint, it is characterised in that including first component, second component and the third component,
    Wherein, the first component includes following raw material by weight percentage:
    The second component includes following raw material by weight percentage:
    Urethane level butyl acetate 40%--45%,
    TDI addition product curing agent 45%--50%,
    TDI trimer curing agents 10%--15%;
    Third component includes following raw material by weight percentage:
    The first component, second component, the weight ratio of the third component are 1:0.5:(0.6--0.8).
  2. 2. solid wood dedicated transparent priming paint according to claim 1, it is characterised in that the dispersant is that Dutch Efka is public At least one of EFKA4050, EFKA5065 and EFKA4010 of department.
  3. 3. solid wood dedicated transparent priming paint according to claim 1, it is characterised in that the epoxy resin is Changxing asphalt mixtures modified by epoxy resin Fat DR-G908.
  4. 4. solid wood dedicated transparent priming paint according to claim 1, it is characterised in that the defoamer for Silok4084, At least one of BYK1788, BYK052.
  5. 5. solid wood dedicated transparent priming paint according to claim 1, it is characterised in that the TDI addition products curing agent is moral The Desmodur L-75 of Chemical Bayer Ltd. of state production, free TDI, HDI content≤0.5%.
  6. 6. solid wood dedicated transparent priming paint according to claim 1, it is characterised in that the TDI trimer curing agents are moral The Desmodur IL 1451 of Chemical Bayer Ltd. of state production, free TDI, HDI content≤0.5%.
  7. 7. solid wood dedicated transparent priming paint according to claim 1, it is characterised in that fineness≤40 μm of the first component, Its viscosity is 10000--20000mPa.s at 25 DEG C.
  8. 8. solid wood dedicated transparent priming paint according to claim 1, it is characterised in that the dehydration acetate butyl ester is urethane level Solvent.
  9. 9. solid wood dedicated transparent priming paint according to claim 1, it is characterised in that the anti-settling agent is bentonite.
  10. 10. the preparation method of the solid wood dedicated transparent priming paint according to any one of claim 1-9, it is characterised in that bag Include following steps:
    (1) preparation of first component:By 9 modified saturated polyester resin of carbon, superbrnaching end-hydroxy saturated polyester resin, epoxy resin, Dispersant, defoamer are put into dispersion machine successively, after being uniformly dispersed with the rotating speed of 600--800RPM, then at 300--500RPM turns Fast side scattered below puts into anti-settling agent, zinc stearate, talcum powder, then the rotating speed high speed dispersion with 1200--1500RPM successively 10--15min, to fineness≤40 μm, input propylene glycol methyl ether acetate is uniformly dispersed with the rotating speed of 600--800RPM, uses acetic acid Butyl ester adjusts viscosity, and it is 10000--20000mPa.s when at 25 DEG C to make it, and first component is made, spare;
    (2) preparation of second component:By butyl acetate at 90-100 DEG C vacuum dehydration about 20-40min, to be dehydrated completely after;Will Dehydration acetate butyl ester, TDI addition products curing agent and TDI trimer curing agents, stir evenly rear press filtration and to be transferred to storage tank stand-by;
    The preparation of (3) third components:Dimethylbenzene, butyl acetate, propylene glycol methyl ether acetate, dimethyl carbonate and ethyl acetate are thrown Enter in dispersion machine, disperseed 4-10 minutes with the rotating speed of 300-500RPM, it is stand-by to be sufficiently mixed uniform sealed storage;
    (4) first component, second component and the third component are uniformly mixed, solid wood dedicated transparent priming paint is made.
CN201711188874.4A 2017-11-24 2017-11-24 Special transparent primer for solid wood and preparation method thereof Active CN107916062B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108682495A (en) * 2018-04-26 2018-10-19 广东莱尔新材料科技股份有限公司 A kind of dynamic FFC wire rod hot melt adhesive films of snap connector high temperature anti-current
CN112961589A (en) * 2021-03-05 2021-06-15 广东美涂士建材股份有限公司 Wood fiber environment-friendly paint
CN112961593A (en) * 2021-03-05 2021-06-15 广东美涂士建材股份有限公司 Special primer for woodware
CN114350240A (en) * 2021-12-27 2022-04-15 澳达树熊涂料(惠州)有限公司 Solvent type skin-feel clear finishing paint and preparation method thereof
CN115785797A (en) * 2022-12-29 2023-03-14 山东巴德士新材料有限公司 Primer and preparation method and application thereof

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Publication number Priority date Publication date Assignee Title
CN102604527A (en) * 2012-03-20 2012-07-25 浙江大学 Preparation method for polyurethane paint primer
CN104087136A (en) * 2014-06-25 2014-10-08 三棵树涂料股份有限公司 High-sinking-resistance transparent primer and preparation method thereof
CN104559745A (en) * 2014-12-29 2015-04-29 上海巴德士化工新材料有限公司 Environment-friendly, odor-less and high-gloss white PU (polyurethane) primer with good sinking resistance, low odor and high whiteness
CN104559747A (en) * 2015-01-12 2015-04-29 山东巴德士化工有限公司 Subsidence-resistant PU transparent priming paint
CN106010206A (en) * 2016-08-09 2016-10-12 无锡市虎皇漆业有限公司 Full odor-free anti-expansion transparent priming paint and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102604527A (en) * 2012-03-20 2012-07-25 浙江大学 Preparation method for polyurethane paint primer
CN104087136A (en) * 2014-06-25 2014-10-08 三棵树涂料股份有限公司 High-sinking-resistance transparent primer and preparation method thereof
CN104559745A (en) * 2014-12-29 2015-04-29 上海巴德士化工新材料有限公司 Environment-friendly, odor-less and high-gloss white PU (polyurethane) primer with good sinking resistance, low odor and high whiteness
CN104559747A (en) * 2015-01-12 2015-04-29 山东巴德士化工有限公司 Subsidence-resistant PU transparent priming paint
CN106010206A (en) * 2016-08-09 2016-10-12 无锡市虎皇漆业有限公司 Full odor-free anti-expansion transparent priming paint and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108682495A (en) * 2018-04-26 2018-10-19 广东莱尔新材料科技股份有限公司 A kind of dynamic FFC wire rod hot melt adhesive films of snap connector high temperature anti-current
CN112961589A (en) * 2021-03-05 2021-06-15 广东美涂士建材股份有限公司 Wood fiber environment-friendly paint
CN112961593A (en) * 2021-03-05 2021-06-15 广东美涂士建材股份有限公司 Special primer for woodware
CN114350240A (en) * 2021-12-27 2022-04-15 澳达树熊涂料(惠州)有限公司 Solvent type skin-feel clear finishing paint and preparation method thereof
CN114350240B (en) * 2021-12-27 2023-02-03 澳达树熊涂料(惠州)有限公司 Solvent type skin-feel clear finishing paint and preparation method thereof
CN115785797A (en) * 2022-12-29 2023-03-14 山东巴德士新材料有限公司 Primer and preparation method and application thereof

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