CN107915928A - A kind of ship Fire-proofing Fabric and preparation method thereof - Google Patents

A kind of ship Fire-proofing Fabric and preparation method thereof Download PDF

Info

Publication number
CN107915928A
CN107915928A CN201711248671.XA CN201711248671A CN107915928A CN 107915928 A CN107915928 A CN 107915928A CN 201711248671 A CN201711248671 A CN 201711248671A CN 107915928 A CN107915928 A CN 107915928A
Authority
CN
China
Prior art keywords
fire
roller
mixing
proofing fabric
plasticizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711248671.XA
Other languages
Chinese (zh)
Inventor
翁明仁
王瑞林
毛志柏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
South Asia Plastic Industry (nantong) Co Ltd
Original Assignee
South Asia Plastic Industry (nantong) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by South Asia Plastic Industry (nantong) Co Ltd filed Critical South Asia Plastic Industry (nantong) Co Ltd
Priority to CN201711248671.XA priority Critical patent/CN107915928A/en
Publication of CN107915928A publication Critical patent/CN107915928A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/002—Methods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001—Combinations of extrusion moulding with other shaping operations
    • B29C48/0011—Combinations of extrusion moulding with other shaping operations combined with compression moulding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07—Flat, e.g. panels
    • B29C48/08—Flat, e.g. panels flexible, e.g. films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/9258—Velocity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00—Flat articles, e.g. films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Fireproofing Substances (AREA)

Abstract

The invention discloses a kind of ship Fire-proofing Fabric and preparation method thereof, it is formulated by the raw material of following weight ratio：Corvic 100phr, 20 ~ 30phr of plasticizer, 4 ~ 6phr of liquid stabilizer, 3 ~ 5phr of epoxidized soybean oil, 20 ~ 30phr of calcium carbonate, metal hydroxides 5 ~ 15phr of smoke suppressant, 5 ~ 15phr of metal Sb system fire retardant.A kind of disclosed ship Fire-proofing Fabric, passes through the adjustment to formula and processing technology so that Fire-proofing Fabric plasticizing is uniform, excellent fireproof performance, and flame propagation velocity is low.

Description

A kind of ship Fire-proofing Fabric and preparation method thereof
Technical field
The present invention relates to a kind of PVC adhesive plasters, and in particular to a kind of ship Fire-proofing Fabric and preparation method thereof.
Background technology
With the rise of Chinese vessel industry, ship inner compartment decoration new technology is all to use PVC decorative Film clad steel plate, But because once fire occurs on ship, its escape is extremely difficult, so SOLAS<<International Convention for the Safety of Life at Sea>>In It is required that the fire resistance of PVC film will meet the requirement of the low burn property broadcast, and its fire retardancy test will pass through International Maritime Organization<<2010 International fire resistance test application rule>>Part5 is tested.
Although PVC has good fire resistance in itself, a large amount of plasticizer are with the addition of in existing PVC product, are caused PVC product is easily burnt, and when PVC product is burnt can produce a large amount of smog, for this problem Application No. A kind of flame-proof PVC artificial leather and its preparation process are mentioned in 201410192430.8, finds that it still has following deficiency through analysis Part：1. plasticizer DOP has played very big impetus to the burning of PVC in itself, plasticizer DOP, DBP dosages are set in this formula 45 ~ 75 parts fixed, plasticizer consumption is excessive, must add a large amount of fire-retardant modification agents to make up this defect；2. the PVC powder of the degree of polymerization 1800 Processing temperature is higher, is not suitable for foaming product processing, easily foams in advance if temperature is excessive during actual production, there are larger safety Hidden danger；3. a large amount of fire-retardant modification agents of addition, total addition level have exceeded the amount of PVC, cost is higher；4. blended it is a variety of it is fire-retardant into Part, and dosage is larger, these compositions are not as that calcium carbonate is so good, and processing is extremely difficult with PVC compatibility, product gelatinization, respectively The stock dispersion uniformity, product surface presentation quality are difficult to ensure that；5. fire-retardant modification agent dosage is larger, PVC systems can be seriously affected The physical property intensity of product, limits its use scope；6. it adds 20 ~ 30 parts of antimony oxide in being formulated, and has research to think, and three Saturation can be reached more than its flame retardant effect after 8PHR by aoxidizing two antimony dosages, be further added by dosage and do not had too big flame retardant effect substantially, The increase of smoke amount can conversely be caused；7. zinc borate and phosphate and aluminium hydroxide share can effective flame-retardant smoke inhibition, it is but actual Dosage, which reaches about 20 parts or so, can cause color change in PVC product process, and processability is unstable.
The content of the invention
Goal of the invention：The purpose of the invention is to make up the deficiencies in the prior art, meeting client's items quality requirement On the premise of limit the dosage of plasticizer, greatly control the facilitation that plasticizer burns PVC, while to processing work Skill is adjusted, and takes into account each side such as formulation cost, processing stability, product appearance quality, the physical property of product intensity, flame-proof smoke-suppressing Face factor, there is provided one kind plasticizing is excellent, and appearance uniform is smooth, meets the ship of the flame retardant test requirement of Far East fire prevention inspection center Use Fire-proofing Fabric.
Technical solution：A kind of ship Fire-proofing Fabric, is formulated by the raw material of following weight ratio：Corvic 100phr, 20 ~ 30phr of plasticizer, 4 ~ 6phr of liquid stabilizer, 3 ~ 5phr of epoxidized soybean oil, 20 ~ 30phr of calcium carbonate, metallic hydrogen Oxide 5 ~ 15phr of smoke suppressant, 5 ~ 15phr of metal Sb system fire retardant.
Preferably, it is formulated by the raw material of following weight ratio：Corvic 100phr, plasticizer 25phr, Liquid stabilizer 5phr, epoxidized soybean oil 4.5phr, calcium carbonate 26phr, metal hydroxides smoke suppressant 8phr, the resistance of metallic antimony system Fire agent 12phr.
Preferably, the plasticizer is phthalate.
Preferably, the liquid stabilizer barium zinc composite thermal stabilizer.
A kind of preparation method of ship Fire-proofing Fabric, includes the following steps：
A, according to mass parts, with Corvic → liquid stabilizer → epoxidized soybean oil → plasticizer → calcium carbonate → metal The order of hydroxide smoke suppressant → metal Sb system fire retardant puts into raw material in mixer successively, in the 30s for the process of feeding intake First mixed at a slow speed, 400 ~ 500r/min of mixing velocity, carry out mixed at high speed after the completion of feeding intake again, mixing velocity 900 ~ 1000r/min, mixer electric current constantly change with the uniformity coefficient and material temperature of mixing, and initial stage, electric current can gradually rise 300A, with the raising of mixed effect, electric current is gradually decrease to 260 ~ 280A, and overall incorporation time is 300 ~ 320s, material temperature Spend for 100 ~ 120 DEG C；
B, the mixed material of step a is discharged into mixer automatically, add colorant be kneaded it is agglomerating, according to mixer current control Mixing time, with the reduction of mixing electric current, mixing gelatinization degree is higher, and when mixing electric current reaches 230 ~ 240A, material is substantially close Type, mixing time about 300 ~ 350s are smelt, material temperature then drains into two roller open mills up to 160 ~ 170 DEG C；
C, material carries out mill on two roller open mills, 135 ~ 145 DEG C of wheel face temperature, two roller gap 2mm, keep material temperature 165 ~ 175 DEG C, material is further plasticized；
D, and then the material after mill is sent into and filters extruder, 70 ~ 80 DEG C of extruder hot water cavity temperature, Mo temperature 155 ~ 165 DEG C, material passes through 16 mesh filter screens successively, and 60 ~ 80 mesh filter screens and 100 ~ 150 mesh filter screens carry out filtering extrusion；
E, and then using four-roll calender to material carry out calendering process, four roll temperatures are distinguished, speed be respectively the first roller 188 ~ 192℃、15m/min；Second 188 ~ 192 DEG C of roller, 20m/min；3rd 182 ~ 187 DEG C of roller, 50m/min；Four-roller 160 ~ 165 ℃、60m/min；
F, the material after rolling is embossed by 70 ~ 80 DEG C of embossed wheels, is cooled and shaped by 25 ~ 30 DEG C of multigroup cooling wheels, final volume Obtain Fire-proofing Fabric finished product.
A kind of disclosed ship Fire-proofing Fabric, its（Since being referred to some shortcomings in background technology, that please Its fire resistance is illustrated from itself formula and technological principle）
Beneficial effect：Disclosed a kind of ship Fire-proofing Fabric, by increasing metal hydroxides smoke suppressant and gold Belong to Sb system fire retardant to limit the dosage of plasticizer, greatly control the facilitation that plasticizer burns PVC, lead at the same time Cross the control to metal hydroxides smoke suppressant and metal Sb system fire retardant dosage so that it is before possessing excellent flame retardant performance Put, finished surface flatness will not be impacted, by being adjusted to technique so that whole processing stability, product The each side factors such as presentation quality, the physical property of product intensity, flame-proof smoke-suppressing are improved.
Embodiment
With reference to specific embodiment, the invention will be further described：
A kind of disclosed ship Fire-proofing Fabric, is formulated by the raw material of following weight ratio：Corvic 100phr, 20 ~ 30phr of plasticizer, 4 ~ 6phr of liquid stabilizer, 3 ~ 5phr of epoxidized soybean oil, 20 ~ 30phr of calcium carbonate, metallic hydrogen Oxide 5 ~ 15phr of smoke suppressant, 5 ~ 15phr of metal Sb system fire retardant.
Wherein, the plasticizer is phthalate, and the liquid stabilizer is xx.
The preparation method of the ship Fire-proofing Fabric includes the following steps：
A, according to mass parts, with Corvic → liquid stabilizer → epoxidized soybean oil → plasticizer → calcium carbonate → metal The order of hydroxide smoke suppressant → metal Sb system fire retardant puts into raw material in mixer successively, in the 30s for the process of feeding intake First mixed at a slow speed, 400 ~ 500r/min of mixing velocity, carry out mixed at high speed after the completion of feeding intake again, mixing velocity 900 ~ 1000r/min, mixer electric current constantly change with the uniformity coefficient and material temperature of mixing, and initial stage, electric current can gradually rise 300A, with the raising of mixed effect, electric current is gradually decrease to 260 ~ 280A, and overall incorporation time is 300 ~ 320s, material temperature Spend for 100 ~ 120 DEG C；
B, the mixed material of step a is discharged into mixer automatically, add colorant be kneaded it is agglomerating, according to mixer current control Mixing time, with the reduction of mixing electric current, mixing gelatinization degree is higher, and when mixing electric current reaches 230 ~ 240A, material is substantially close Type, mixing time about 300 ~ 350s are smelt, material temperature then drains into two roller open mills up to 160 ~ 170 DEG C；
C, material carries out mill on two roller open mills, 135 ~ 145 DEG C of wheel face temperature, two roller gap 2mm, keep material temperature 165 ~ 175 DEG C, material is further plasticized；
D, and then the material after mill is sent into and filters extruder, 70 ~ 80 DEG C of extruder hot water cavity temperature, Mo temperature 155 ~ 165 DEG C, material passes through 16 mesh filter screens successively, and 60 ~ 80 mesh filter screens and 100 ~ 150 mesh filter screens carry out filtering extrusion；
E, and then using four-roll calender to material calendering process is carried out, four roll temperatures, speed are respectively the first roller 188 ~ 192 ℃、15m/min；Second 188 ~ 192 DEG C of roller, 20m/min；3rd 182 ~ 187 DEG C of roller, 50m/min；160 ~ 165 DEG C of four-roller, 60m/min；
F, the material after rolling is embossed by 70 ~ 80 DEG C of embossed wheels, is cooled and shaped by 25 ~ 30 DEG C of multigroup cooling wheels, final volume Obtain Fire-proofing Fabric finished product.
Embodiment one
A kind of ship Fire-proofing Fabric, is formulated by the raw material of following weight ratio：Corvic 100phr, plasticizer 25phr, liquid stabilizer 5phr, epoxidized soybean oil 4.5phr, calcium carbonate 26phr, metal hydroxides smoke suppressant 8phr, metal Sb system fire retardant 12phr.
Embodiment two
A kind of ship Fire-proofing Fabric, is formulated by the raw material of following weight ratio：Corvic 100phr, plasticizer 20phr, liquid stabilizer 4phr, epoxidized soybean oil 3phr, calcium carbonate 20phr, metal hydroxides smoke suppressant 5phr, metallic antimony Flame retardant 5phr.
Embodiment three
A kind of ship Fire-proofing Fabric, is formulated by the raw material of following weight ratio：Corvic 100phr, plasticizer 30phr, liquid stabilizer 6phr, epoxidized soybean oil 5phr, calcium carbonate 30phr, metal hydroxides smoke suppressant 15phr, metal Sb system fire retardant 15phr.
For above three embodiment, the performance parameters of its PVC rubber prepared are referring to table 1 below
Table 1
Note：Critical heat flux when CFE is extinguishes；Qsb is sustained combustion heat；Qt is hot total volume；Qp is heat release rate peak Value.
There is above-mentioned 1 content of table to can be seen that the present invention and pass through its flammability of the Fire-proofing Fabric of rational proportion acquisition of formula Each parameter of energy not only conforms with standard requirement, also considerably beyond mark permissible value, it is ensured that fire resistance.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, some improvements and modifications can also be made, these improvements and modifications Also it should be regarded as protection scope of the present invention.

Claims (5)

  1. A kind of 1. ship Fire-proofing Fabric, it is characterised in that：It is formulated by the raw material of following weight ratio：Corvic 100phr, 20 ~ 30phr of plasticizer, 4 ~ 6phr of liquid stabilizer, 3 ~ 5phr of epoxidized soybean oil, 20 ~ 30phr of calcium carbonate, metallic hydrogen Oxide 5 ~ 14phr of smoke suppressant, metal 5 ~ 10phr of Sb system fire retardant, 5 ~ 10PHR of zinc borate.
  2. A kind of 2. ship Fire-proofing Fabric according to claim 1, it is characterised in that：Matched somebody with somebody by the raw material of following weight ratio System forms：Corvic 100phr, plasticizer 25phr, liquid stabilizer 5phr, epoxidized soybean oil 4.5phr, calcium carbonate 26phr, metal hydroxides smoke suppressant 8phr, metal Sb system fire retardant 8phr.
  3. A kind of 3. ship Fire-proofing Fabric according to claim 1 or 2, it is characterised in that：The plasticizer is adjacent benzene two Formate ester.
  4. A kind of 4. ship Fire-proofing Fabric according to claim 1 or 2, it is characterised in that：The liquid stabilizer is barium Zn composite heat stabilizer.
  5. 5. a kind of preparation method for preparing ship Fire-proofing Fabric in claim 1, it is characterised in that include the following steps：
    A, according to mass parts, with Corvic → liquid stabilizer → epoxidized soybean oil → plasticizer → calcium carbonate → metal The order of hydroxide smoke suppressant → metal Sb system fire retardant puts into raw material in mixer successively, in the 30s for the process of feeding intake First mixed at a slow speed, 400 ~ 500r/min of mixing velocity, carry out mixed at high speed after the completion of feeding intake again, mixing velocity 900 ~ 1000r/min, mixer electric current constantly change with the uniformity coefficient and material temperature of mixing, and initial stage, electric current can gradually rise 300A, with the raising of mixed effect, electric current is gradually decrease to 260 ~ 280A, and overall incorporation time is 300 ~ 320s, material temperature Spend for 100 ~ 120 DEG C；
    B, the mixed material of step a is discharged into mixer automatically, add colorant be kneaded it is agglomerating, according to mixer current control Mixing time, with the reduction of mixing electric current, mixing gelatinization degree is higher, and when mixing electric current reaches 230 ~ 240A, material is substantially close Type, mixing time about 300 ~ 350s are smelt, material temperature then drains into two roller open mills up to 160 ~ 170 DEG C；
    C, material carries out mill on two roller open mills, 135 ~ 145 DEG C of wheel face temperature, two roller gap 2mm, keep material temperature 165 ~ 175 DEG C, material is further plasticized；
    D, and then the material after mill is sent into and filters extruder, 70 ~ 80 DEG C of extruder hot water cavity temperature, Mo temperature 155 ~ 165 DEG C, material passes through 16 mesh filter screens successively, and 60 ~ 80 mesh filter screens and 100 ~ 150 mesh filter screens carry out filtering extrusion；
    E, and then using four-roll calender to material carry out calendering process, four roll temperatures are distinguished, speed be respectively the first roller 188 ~ 192℃、15m/min；Second 188 ~ 192 DEG C of roller, 20m/min；3rd 182 ~ 187 DEG C of roller, 50m/min；Four-roller 160 ~ 165 ℃、60m/min；
    F, the material after rolling is embossed by 70 ~ 80 DEG C of embossed wheels, is cooled and shaped by 25 ~ 30 DEG C of multigroup cooling wheels, final volume Obtain Fire-proofing Fabric finished product.
CN201711248671.XA 2017-12-01 2017-12-01 A kind of ship Fire-proofing Fabric and preparation method thereof Pending CN107915928A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711248671.XA CN107915928A (en) 2017-12-01 2017-12-01 A kind of ship Fire-proofing Fabric and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711248671.XA CN107915928A (en) 2017-12-01 2017-12-01 A kind of ship Fire-proofing Fabric and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107915928A true CN107915928A (en) 2018-04-17

Family

ID=61898274

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711248671.XA Pending CN107915928A (en) 2017-12-01 2017-12-01 A kind of ship Fire-proofing Fabric and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107915928A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112677595A (en) * 2020-12-23 2021-04-20 浙江路联装饰材料有限公司 Slightly-antimony soft B1-grade flame-retardant decorative material and preparation process thereof
CN114181476A (en) * 2021-12-20 2022-03-15 昆山东士隆电子材料有限公司 Preparation method of high-temperature-resistant layer of insulating tape

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101497727A (en) * 2009-03-04 2009-08-05 南亚塑胶工业股份有限公司 PVC resin composition and product thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101497727A (en) * 2009-03-04 2009-08-05 南亚塑胶工业股份有限公司 PVC resin composition and product thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112677595A (en) * 2020-12-23 2021-04-20 浙江路联装饰材料有限公司 Slightly-antimony soft B1-grade flame-retardant decorative material and preparation process thereof
CN114181476A (en) * 2021-12-20 2022-03-15 昆山东士隆电子材料有限公司 Preparation method of high-temperature-resistant layer of insulating tape

Similar Documents

Publication Publication Date Title
CN103044804B (en) A kind of Flame-retardant transparent floor film and production technique thereof
CN101698748B (en) Method for preparing flame-retardant low-smoke halogen-free hot-vulcanized silicone rubber compounds for metro vehicles
CN105255016B (en) A kind of polypropylene special efficient halogen-free flame retardants master batch and its preparation method and application
CN103992588B (en) A kind of formula of polychrome cupboard board and preparation technology thereof
TWI577863B (en) A halogen-free plastic floor tiles and its composition
CN107915928A (en) A kind of ship Fire-proofing Fabric and preparation method thereof
CN102108145A (en) Halogen-free inflaming retarding polymer core material for fireproof aluminum plastic plate and preparation method of core material
CN107151398A (en) A kind of low temperature resistant PVC film and preparation method thereof
CN106750855A (en) Fire resisting expansion low-smoke halogen-free flame-retardant sheath material and preparation method thereof
CN106065109B (en) Halogen-free cable jacket rubber material and preparation method thereof
CN108912444A (en) A kind of environment friendly halogen-free fireproof master batch and preparation method thereof
CN109354804B (en) Super-strong wear-resistant PVC floor film and preparation method thereof
CN105315625B (en) A kind of Halogen free flame-retardant polyester film and preparation method thereof
CN104262875B (en) Intumescent flame-retardant cable material taking plant-based active carbon as synergist and preparation method thereof
CN103788431B (en) The rubber-plastic foamed lagging material of a kind of halogen
CN105542431A (en) Thermal insulation material for 3D (Three Dimensional) printing and preparation method thereof
CN107841117A (en) A kind of Flame retardant environment-friendlyplastic plastic material and preparation method thereof
CN102359239A (en) Environment-friendly and flame-retardant decorative plate and production method thereof
WO2014169454A1 (en) Environmentally friendly stone paper as furniture veneer, and preparation method therefor
CN106833259B (en) A kind of frosting flame retardant coating and preparation method thereof
CN102558652A (en) Method for preparing fireproof aluminum-plastic composite board core by utilizing brucite
CN107164973A (en) A kind of preparation method of environmental-protection flame-retardant uvioresistant TPU synthetic leather
CN104861249A (en) Polyethylene wholly plastic wood-imitating material and preparation method thereof
CN112677595A (en) Slightly-antimony soft B1-grade flame-retardant decorative material and preparation process thereof
CN105860204A (en) Novel halogen-free flame-retardant PE foam material and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180417