Space lease fire-retardant double sheets and preparation method thereof
Technical field
The present invention relates to flame-proof sheet material, and in particular, to space lease fire-retardant double sheets and preparation method thereof.
Background technology
With the development of economy and society, the quickening of life and work rhythm, most of Administrative Areas are no longer fixed reinforcing bars
The house of concrete, is more the working space split in a building, these spaces are rented in the form of lease
To target customer.Since the personnel often accommodated in these spaces are very much, fire-retardant fireproof is most important to lease space
It is required that.Common anti-flaming smoke-inhibiting agent has aluminium hydroxide, cerium hydroxide, magnesium hydroxide, halogen system anti-flaming smoke-inhibiting agent, phosphinates and gathers
Cyanamide etc., although the halogen system anti-flaming smoke-inhibiting agent that generally uses still use extensively now, the problems such as producing bioxin because burning
And the meeting after fire produces the reasons such as poison gas, its harm to human health and environment is increasingly closed be subject to people
Note.At present, and phosphinates has that dosage is few, the advantages that smoke density is low, no environmental hazard, have been to be concerned by more and more people.
But disclosed in patent document US 2007/0029532, phosphonate may cause to decompose in process, and process
During can produce frangible unavailable material, therefore, limit application of the phosphonate as anti-flaming smoke-inhibiting agent.
Patent document CN107207779A, it is entitled:The flame-retardant polymer of phosphorus compound and melam comprising heat treatment
Composition discloses, by will heat the anti-flaming smoke-inhibiting agent of some phosphonates acquisitions at a temperature of 200 DEG C or higher and be used as
The melam or melam derivative of retardant synergist are attached to polymer and can be easily worked under some harsh conditions.But
Because melam or melam derivative are not readily synthesized, increase the anti-flaming smoke-inhibiting agent application cost of addition melam.
Therefore, how a kind of anti-flaming smoke-inhibiting agent is provided and the plate containing such anti-flaming smoke-inhibiting agent is ensureing its smoke density
It is low, the advantages that no environmental hazard on the basis of, reduce the production cost of material, improve its fire resistance in application material,
And fragile materials are not produced, the influence to main material matrix mechanical performance particularly toughness will not be reduced, are urgently to be resolved hurrily at present
Technical problem.
The content of the invention
The object of the present invention is to provide a kind of space lease fire-retardant double sheets and preparation method thereof, which uses
Contain a kind of anti-flaming smoke-inhibiting agent in fire-retardant double sheets, which is keeping the smoke density of phosphinates low, no environment
On the basis of the advantages that endangering, its fire resistance in application material can be improved, and does not produce fragile materials, will not be reduced
Influence to main material matrix mechanical performance, also, it is adjuvant used more economical.
To achieve these goals, the present invention provides a kind of space lease preparation method of fire-retardant double sheets to include
First material and second material are subjected to coextrusion mold;Wherein, first material and second material contain anti-flaming smoke-inhibiting agent, its
In, high 20%-200% in the weight content ratio second material of anti-flaming smoke-inhibiting agent in first material;Wherein, anti-flaming smoke-inhibiting agent is logical
Cross and prepare alkyl phosphinate, tributyl tin and the trioctylphosphine as shown in formula (I) after 200-300 DEG C of also contacts
Obtain;Wherein, in formula (I):R1For C1-C6 alkyl or phenyls;R2For C1-C6 alkyl or phenyls;M is metal, and n is from 1 to 4
Number so that Mn+It is metal cation, the electric charge of the cation is wherein assigned on n+ representations, and the number that n is 1 to 4.
The present invention also provides a kind of fire-retardant double sheets of space lease being prepared according to preparation method described previously.
The space lease of the present invention will not be lost with the anti-flaming smoke-inhibiting agent in fire-retardant double sheets in high temperature working processes
Fire resistance, does not find the generation of brittle material yet, good mechanical property in obtained fire-retardant double sheets, fire-retardant, environmental protection.This hair
Bright space lease can be used for partition space with fire-retardant double sheets, and the working space of lease is made, and will meet to rent at present significantly
Space rent to fire-retardant, environmentally friendly, durable requirement.And the present invention space lease of the invention with fire-retardant double sheets cost compared with
It is low, the cost of manufacture in lease space can be reduced indirectly, therefore, had highly application value.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Embodiment
The embodiment of the present invention is described in detail below.It is it should be appreciated that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to limit the invention.
The endpoint of disclosed scope and any value are not limited to the accurate scope or value herein, these scopes or
Value should be understood to comprising the value close to these scopes or value.For number range, between the endpoint value of each scope, respectively
It can be combined with each other between the endpoint value of a scope and single point value, and individually between point value and obtain one or more
New number range, these number ranges should be considered as specific open herein.
The present invention provides a kind of anti-flaming smoke-inhibiting agent, the anti-flaming smoke-inhibiting agent for as shown in formula (I) alkyl phosphinate,
Tributyl tin and trioctylphosphine are prepared after 200-300 DEG C of also contacts;Wherein, in formula (I):R1For C1-C6 alkane
Base or phenyl;R2For C1-C6 alkyl or phenyls;M is metal, and n is the number from 1 to 4 so that Mn+It is metal cation, wherein n+
The electric charge of the cation is assigned on representation, and the number that n is 1 to 4.
According to the selection raw material type and preparation process of above-mentioned technical proposal, those skilled in the art can obtain fire-retardant
Smoke suppressant.Anti-flaming smoke-inhibiting agent provided by the invention can keep phosphinates smoke density it is low, without environmental hazard the advantages that
On the basis of, it is possible to increase its fire resistance in application material, and fragile materials are not produced, it will not reduce to main material matrix
The influence of mechanical performance.The fire resistance of anti-flaming smoke-inhibiting agent can be improved by melamine.The system of the anti-flaming smoke-inhibiting agent of the present invention
Standby raw material is cheap and easy to get so that its application value with higher.
In the above-mentioned technical solutions, the alkyl phosphinate shown in formula (I), there is the synthetic method of comparative maturity, example at present
Such as grignard reagent method, aluminum chloride-catalyzed reaction, free radical addition method, metal coordination catalysis addition process etc., are commercially available product.This
Alkyl phosphinate in invention in following embodiment is purchased from Deqing four seas Chemical Co., Ltd..
The present invention anti-flaming smoke-inhibiting agent may be added to that it is a variety of prepare in the high molecular raw material such as plastics or rubber, so as to obtain
Target material is obtained, to improve the anti-flammability of material, for example, being added to polyolefin homopolymer and copolymer, rubber, polyester, epoxy
Resin, polyurethane, polyalkylene terephthalates, polysulfones, polyimides, polyphenylene oxide, styrene polymer and copolymer, gather
Carbonic ester, acrylate copolymer, polyamide, polyacetals, epoxy resin is in the materials of main base.It can also use different poly-
The mixture of compound, such as polyphenylene ether/styrene resin resin blends, polyvinyl chloride/ABS, containing methacrylonitrile and Alpha-Methyl benzene
The ABS of ethene, and polyester/ABS or makrolon/ABS.Above-mentioned polymer can coordinate other additives to be used together.
Prepare in target material, other additives can be added, for example, plasticizer, lubricant, emulsifying agent, pigment, dyestuff, optical brightening
Agent, fire-proofing chemical, antistatic additive, foaming agent, filler, toughener, stabilizer, toughness modifier etc., differ and enumerate.
In the process, the alkyl phosphinate in anti-flaming smoke-inhibiting agent of the invention will not lose in high temperature working processes
Fire resistance, in the material applied, does not find the generation of brittle material yet.Below, with the flame-retardant smoke inhibition of the present invention
Agent is illustrated in polyvinyl chloride for the application in the material of main body.
In the present invention, excellent with fire resistance in order to obtain, fragile materials are few in the material after processing, the material after processing
Expect the anti-flaming smoke-inhibiting agent of good mechanical property, it is preferable that the temperature of the also contacts is 240-280 DEG C.
Excellent with fire resistance in order to obtain, fragile materials are few in the material after processing, the mechanical property of materials after processing
Good anti-flaming smoke-inhibiting agent, it is highly preferred that the condition of the also contacts includes:By the alkyl phosphinate shown in formula (I), three fourths
Ji Xi and trioctylphosphine mix 20-30min in 240-250 DEG C, then keep the temperature 1.5-2.5h in 260-280 DEG C.
In the present invention, R in formula (I)1And/or R2Can be by a kind of alkyl or benzene substituted in a variety of substituents
One or more in base, such as nitro, halogen, hydroxyl, amino.
In the present invention, it is preferred to the alkyl is unsubstituted or by the one or more in halogen, hydroxyl, amino
The alkyl substituted.
In the above-mentioned technical solutions, the type of alkyl can have multiple choices, can be straight chained alkyl, or side chain
Alkyl.Alkyl is substituted the position that base is substituted can multiple choices, can be 1 substitution or 2-6 take
Generation.Also, the quantity that substituent is substituted can also have multiple choices, for example, can be monosubstituted, can also be polysubstituted,
Realize the present invention.
Phenyl, which is substituted the position that base is substituted, can a multiple choices, it is o-, m-, to substitution the present invention can be achieved.
Also, the quantity that substituent is substituted can also have multiple choices, for example, can be monosubstituted, can also be polysubstituted, it can be achieved
The present invention.
High-temp combustion is halogen to be known as the production of poisonous gas in order to reduce, it is highly preferred that halogenic substituent is not contained in alkyl,
The alkyl is by alkyl that is unsubstituted or being substituted by the one or more in hydroxyl, amino.
In the present invention, it is preferred to the phenyl is unsubstituted or by the one or more in halogen, hydroxyl, amino
The phenyl substituted.
High-temp combustion is halogen to be known as the production of poisonous gas in order to reduce, it is highly preferred that halogenic substituent is not contained in alkyl,
The phenyl is by alkyl that is unsubstituted or being substituted by the one or more in hydroxyl, amino.
Formula (I) M can be common metal element, it is preferable that in order to which the alkyl phosphinate in formula (I) is cheap and easy to get,
Preferably, M is Li, K, Na, Mg, Ca, Ba, Zn, Zr, B, Al, Si, Ti, Sn or Sb in formula (I).
In the present invention, it is highly preferred that in order to which the alkyl phosphinate in formula (I) is cheap and easy to get, M is Ca or Al.
In the present invention, the weight ratio of the alkyl phosphinate shown in formula (I), tributyl tin and trioctylphosphine can be
It is adjusted in relative broad range, can obtain the anti-flaming smoke-inhibiting agent in the application.Have fire resistance excellent in order to obtain, after processing
Material in fragile materials it is few, the good anti-flaming smoke-inhibiting agent of the mechanical property of materials after processing, the alkyl phosphinic acid shown in formula (I)
The weight ratio of salt, tributyl tin and trioctylphosphine is 10: 1-3: 8-10.
The present invention also provides a kind of anti-flaming smoke-inhibiting agent prepared according to the preparation method of previously described anti-flaming smoke-inhibiting agent.
Through the above technical solutions, anti-flaming smoke-inhibiting agent provided by the invention can keep phosphinates smoke density it is low,
On the basis of the advantages that environmental hazard, it is possible to increase its fire resistance in application material, and fragile materials are not produced,
The influence to main material matrix mechanical performance will not be reduced.The preparing raw material of anti-flaming smoke-inhibiting agent is cheap and easy to get so that it is with higher
Application value.
Present invention also offers a kind of preparation method of the fire-retardant double sheets of space lease, including by first material and
Two materials carry out coextrusion mold;Wherein, first material and second material contain anti-flaming smoke-inhibiting agent, wherein, hindered in first material
Fire high 20%-200% in the weight content ratio second material of smoke suppressant;Wherein, anti-flaming smoke-inhibiting agent is the previously described present invention
The anti-flaming smoke-inhibiting agent of offer.
In the process, space lease of the invention will not be in high temperature process with the anti-flaming smoke-inhibiting agent in fire-retardant double sheets
During lose fire resistance, do not find the generation of brittle material yet, good mechanical property in obtained fire-retardant double sheets, resistance
Combustion, environmental protection.Space lease provided by the invention is different with the content of anti-flaming smoke-inhibiting agent in two layers of fire-retardant double sheets, can save
The dosage of anti-flaming smoke-inhibiting agent, saves production cost, in use, can be using the low one side of flame-retardant smoke inhibition agent content as product
Non- everyday exposure face, and using the high one side of flame-retardant smoke inhibition agent content as outer surface so that product still have it is good
Fire resistance.
Size according to the thickness adjustment roll gap of processing request.Pass through narrow slit head co-extrusion after the abundant plasticizing of screw rod
Into doubling plate base.Can trimming receipts after the further cooling of deflector roll after being shaped again by three-roller calendar cooling by a distance
Roll forming.Plastic extruding molding machine is not particularly limited herein, and traditional plastic extruding molding machine can be used.
For present situation, space lease of the invention can be used for partition space with fire-retardant double sheets, and the office of lease is made
Space, will meet that lease space is to fire-retardant, environmentally friendly, durable requirement at present significantly.And the space of the invention of the present invention is rented
Rent relatively low with fire-retardant double sheets cost, the cost of manufacture in lease space can be reduced indirectly, therefore, have very high popularization should
With value.
Space lease of the present invention can be adjusted with the raw material in fire-retardant double sheets in relative broad range, in order to obtain mechanicalness
Good, the plate of good flame retardation effect of energy, it is preferable that in parts by weight, first material includes:75-120 parts of polyvinyl chloride, filler
100-150 parts, 2-7 parts of stabilizer, 0.5-1.2 parts of stearic acid, 15-25 parts of 2-3.5 parts of ACR modifying agent and anti-flaming smoke-inhibiting agent;The
Two materials include:75-120 parts of polyvinyl chloride, 100-150 parts of filler, 2-7 parts of stabilizer, 0.5-1.2 parts of stearic acid, ACR changes
Property 2-3.5 parts of agent and 10-12 parts of anti-flaming smoke-inhibiting agent.
First material and second material can be obtained by a variety of methods, it is preferable that first material and second material according to
Following step is prepared:The polyvinyl chloride, filler, stabilizer, stearic acid, ACR modifying agent and anti-flaming smoke-inhibiting agent is first
Mixed in 120-140 DEG C of heat, it is cold mixed then at 60-80 DEG C.
For the incorporation time of material, those skilled in the art can be adjusted in relative broad range, it is highly preferred that prior to
120-140 DEG C of heat mixes 1.5-2h, then at 60-80 DEG C of cold mixed 20-40min.
For co-extrusion condition, those skilled in the art can be adjusted in relative broad range, it is preferable that the temperature of coextrusion mold
Spend for 160-210 DEG C.
Size according to the thickness adjustment roll gap of processing request.Pass through narrow slit head co-extrusion after the abundant plasticizing of screw rod
Into doubling plate base.Can trimming receipts after the further cooling of deflector roll after being shaped again by three-roller calendar cooling by a distance
Roll forming.Plastic extruding molding machine is not particularly limited herein, and traditional plastic extruding molding machine can be used.
For the trade mark of polyvinyl chloride, those skilled in the art can be adjusted in relative broad range, in order to improve processing
Effect, it is preferable that polyvinyl chloride is PVC-SG5 types.
For filler, those skilled in the art can be adjusted in relative broad range, in order to improve processing effect, preferably
Ground, filler are the one or more in powdered whiting, nanometer grade calcium carbonate, perlite, titanium dioxide and precipitated calcium carbonate.
For stabilizer, those skilled in the art can be adjusted in relative broad range, in order to improve the thermostabilization of plate
Property, it is preferable that it is lead salt compound stabilizer, organic tin stabilizer, calcium-zinc composite stabilizing agent or potassium zinc composite stabilizer.
It is prepared into the present invention also provides a kind of according to previously described space lease with the preparation method of fire-retardant double sheets
The fire-retardant double sheets of the space lease arrived.
In the process, space lease of the invention will not be in high temperature process with the anti-flaming smoke-inhibiting agent in fire-retardant double sheets
During lose fire resistance, do not find the generation of brittle material yet, good mechanical property in obtained fire-retardant double sheets, resistance
Combustion, environmental protection.
Further, space lease of the invention can be used for partition space with fire-retardant double sheets, and the office of lease is made
Space, will meet that lease space is to fire-retardant, environmentally friendly, durable requirement at present significantly.And the space of the invention of the present invention is rented
Rent relatively low with fire-retardant double sheets cost, the cost of manufacture in lease space can be reduced indirectly, therefore, have very high popularization should
With value.
The present invention will be described in detail by way of examples below.
Embodiment 1
The preparation of the fire-retardant double sheets of space lease:
(1) anti-flaming smoke-inhibiting agent is prepared:In parts by weight, by the alkyl phosphinic acid shown in 10 parts of formulas (I), 1 part of tributyl tin
20min is mixed in 240 DEG C with 6 parts of trioctylphosphines, then keeps the temperature 1.5h in 260 DEG C, wherein, R1For methyl;R2For phenyl, M
For Al, n 3, obtains anti-flaming smoke-inhibiting agent A1;
(2) in parts by weight, first material is taken to include:75 parts of PVC-SG5 types polyvinyl chloride, 100 parts of nanometer grade calcium carbonate,
15 parts of 2 parts of dimethyl tin oxide PVC stabilizer, 0.5 part of stearic acid, 2 parts of ACR K-123 modifying agent and anti-flaming smoke-inhibiting agent A1;The
Two materials include:75 parts of PVC-SG5 types polyvinyl chloride, 100 parts of nanometer grade calcium carbonate, 2 parts of dimethyl tin oxide PVC stabilizer,
10 parts of 0.5 part of stearic acid, 2 parts of ACR K-123 modifying agent and anti-flaming smoke-inhibiting agent A1, first material and second material are each divided
Prior to 120 DEG C heat do not mix 1.5h, then at 60 DEG C of cold mixed 20min, then in 160 DEG C of coextrusion molds.In the process, according to processing
It is required that thickness adjustment roll gap size, by narrow slit head co-extrusion into doubling plate base after the abundant plasticizing of screw rod.
Embodiment 2
The preparation of the fire-retardant double sheets of space lease:
(1) anti-flaming smoke-inhibiting agent is prepared:In parts by weight, by the alkyl phosphinic acid shown in 10 parts of formulas (I), 2 parts of tributyl tins
25min is mixed in 245 DEG C with 8 parts of trioctylphosphines, then keeps the temperature 2h in 270 DEG C, wherein, R1For n-propyl;R2For on 1
The isopropyl being optionally substituted by a hydroxyl group, M Al, n 3, obtains anti-flaming smoke-inhibiting agent A2;
(2) in parts by weight, first material is taken to include:90 parts of PVC-SG5 types polyvinyl chloride, 125 parts of nanometer grade calcium carbonate,
4.5 parts of dimethyl tin oxide PVC stabilizer, 0.8 part of stearic acid, 2.8 parts of ACRK-123 modifying agent and anti-flaming smoke-inhibiting agent A2 20
Part;Second material includes:95 parts of PVC-SG5 types polyvinyl chloride, 125 parts of nanometer grade calcium carbonate, dimethyl tin oxide PVC stabilizer
4.5 parts, 0.85 part of stearic acid, 11 parts of 2.8 parts of ACR K-123 modifying agent and anti-flaming smoke-inhibiting agent A2, by first material and the second thing
Each prior to 130 DEG C heat mix 1.2h to material respectively, then at 70 DEG C of cold mixed 30min, then in 180 DEG C of extrusion moldings.In the process,
According to the size of the thickness adjustment roll gap of processing request, by narrow slit head co-extrusion into doubling plate after the abundant plasticizing of screw rod
Base.
Embodiment 3
The preparation of the fire-retardant double sheets of space lease:
(1) anti-flaming smoke-inhibiting agent is prepared:In parts by weight, by the alkyl phosphinic acid shown in 10 parts of formulas (I), 3 parts of tributyl tins
30min is mixed in 250 DEG C with 10 parts of trioctylphosphines, then keeps the temperature 2.5h in 280 DEG C, wherein, R1To be substituted by chlorine on 6
N-hexyl;R2For the methyl substituted by amino, M Al, n 3, obtains anti-flaming smoke-inhibiting agent A3;
(2) in parts by weight, first material is taken to include:120 parts of PVC-SG5 types polyvinyl chloride, nanometer grade calcium carbonate 150
Part, 7 parts of dimethyl tin oxide PVC stabilizer, 1.2 parts of stearic acid, 3.5 parts of ACR K-123 modifying agent and anti-flaming smoke-inhibiting agent A3 25
Part;Second material includes:120 parts of PVC-SG5 types polyvinyl chloride, 150 parts of nanometer grade calcium carbonate, dimethyl tin oxide PVC stablize
12 parts of 7 parts of agent, 1.2 parts of stearic acid, 3.5 parts of ACR K-123 modifying agent and anti-flaming smoke-inhibiting agent A3, by first material and the second thing
Each prior to 140 DEG C heat mix 2h to material respectively, then at 80 DEG C of cold mixed 40min, then in 210 DEG C of extrusion moldings.In the process, according to
According to the size of the thickness adjustment roll gap of processing request, by narrow slit head co-extrusion into doubling plate after the abundant plasticizing of screw rod
Base.
Embodiment 4
The preparation of the fire-retardant double sheets of space lease:
(1) anti-flaming smoke-inhibiting agent is prepared:In parts by weight, by the alkyl phosphinic acid shown in 10 parts of formulas (I), 2 parts of tributyl tins
25min is mixed in 200 DEG C with 8 parts of trioctylphosphines, then keeps the temperature 2h in 200 DEG C, wherein, R1For n-propyl;R2For on 1
The isopropyl being optionally substituted by a hydroxyl group, M Al, n 3, obtains anti-flaming smoke-inhibiting agent A4;
(2) carried out according to step (2) in embodiment 2, the difference is that anti-flaming smoke-inhibiting agent used is A4.
Embodiment 5
The preparation of the fire-retardant double sheets of space lease:
(1) anti-flaming smoke-inhibiting agent is prepared:In parts by weight, by the alkyl phosphinic acid shown in 10 parts of formulas (I), 2 parts of tributyl tins
25min is mixed in 300 DEG C with 8 parts of trioctylphosphines, then keeps the temperature 2h in 300 DEG C, wherein, R1 is n-propyl;R2 is on 1
The isopropyl being optionally substituted by a hydroxyl group, M Al, n 3, obtains anti-flaming smoke-inhibiting agent A5;
(2) carried out according to step (2) in embodiment 2, the difference is that anti-flaming smoke-inhibiting agent used is A5.
Comparative example 1
Anti-flaming smoke-inhibiting agent is prepared according to (1) the step of embodiment 2, the difference is that mixing temperature and holding temperature are 150
DEG C, obtain anti-flaming smoke-inhibiting agent B1.Anti-flaming smoke-inhibiting agent B1 is prepared into the fire-retardant bilayer of space lease according to step (2) in embodiment 2
Plate.
Comparative example 2
Anti-flaming smoke-inhibiting agent is prepared according to (1) the step of embodiment 2, the difference is that mixing temperature and holding temperature are 350
DEG C, obtain anti-flaming smoke-inhibiting agent B2.Anti-flaming smoke-inhibiting agent B2 is prepared into the fire-retardant bilayer of space lease according to step (2) in embodiment 2
Plate.
Comparative example 3
10 parts of alkyl phosphinic acids in (1) the step of embodiment 2 are kept the temperature into 2.4h in 270 DEG C, obtain anti-flaming smoke-inhibiting agent B3.Will
Anti-flaming smoke-inhibiting agent B3 prepares the fire-retardant double sheets of space lease according to step (2) in embodiment 2.
Comparative example 4
By 10 parts of alkyl phosphinic acids in (1) the step of embodiment 2, numbering is anti-flaming smoke-inhibiting agent B4.By anti-flaming smoke-inhibiting agent
B4 prepares the fire-retardant double sheets of space lease according to step (2) in embodiment 2.
Blank control
Without step (1), double sheets only are prepared according to step (2) in embodiment 2, unlike, do not add any
Anti-flaming smoke-inhibiting agent, obtains blank control polyvinyl-chloride plate material.
Detect example 1
By the space lease that embodiment 1-5 and comparative example 1-4 are obtained, with fire-retardant double sheets, reference numeral is a1-a5 respectively
And b1-b4, analyze the tensile strength of a1-a5 and b1-b4 flame-proof polyvinyl chlorides plate and blank control polyvinyl-chloride plate material
And impact flexibility, examination criteria are:According to GB/T1040.3-2006 sample preparations and tensile strength is detected, uses GB/T1043.1-2008
Detect impact flexibility.
Find after testing, the tensile strength and impact flexibility of each plate substantially do not become relative to the trend of other plates
Change, i.e., tensile strength is high, and impact flexibility is also high.Wherein, there is obvious brittle fracture in b3 and b4, cause tensile strength and
Impact flexibility is poor, wherein, b4 is worst, is only the 22% of blank control sample;Tensile strength and impact in b1 and b2 is tough
Property be superior to b3, there is not obvious brittle fracture, still, tensile strength and impact flexibility are differed compared with blank control sample
It is larger, it is only 51% or so of blank control sample.
The tensile strength of other samples and the order from excellent to bad of impact flexibility are:Blank control sample, a2, a1, a3,
A4, a5, wherein, a2 is approached with blank control, and tensile strength and impact flexibility are more than the 99% of blank control sample;A1 and
The tensile strength and impact flexibility of a3 is 96% or so of blank control sample;The tensile strength and impact flexibility of a4 and a5 is sky
More than the 88% of white control sample;Wherein the tensile strength of blank control sample is 64MPa.
Detect example 2
By the space lease that embodiment 1-5 and comparative example 1-4 are obtained, with fire-retardant double sheets, reference numeral is a1-a5 respectively
And b1-b4, analyze oxygen index (OI), the cigarette of a1-a5 and b1-b4 flame-proof polyvinyl chlorides plate and blank control polyvinyl-chloride plate material
Density, wherein, the standard of oxygen index (OI) test is GB/T2406.2-2009;The testing standard of smoke density is GB/T8627-2007.
The results show that the oxygen index (OI) of a1-a5 is all higher than 27%, belong to firing-difficult matter.Specifically, wherein, oxygen index (OI) from height to
Low is a3, a2, a4, a5, a1 successively, and the oxygen index (OI) that the oxygen index (OI) of oxygen index (OI) up to 43%, the a1 of a3 are 34%, b1-b4 differs not
Greatly, 29% or so, wherein, the oxygen index (OI) of blank control sample is 19%.
The results show that the smoke density of a1-a5 is not much different, in below 46SDR, the smoke density of b1-b4 is in 48-58SDR
Between, the smoke density of blank control sample is 68SDR.
The preferred embodiment of the present invention described in detail above, still, during present invention is not limited to the embodiments described above
Detail, in the range of the technology design of the present invention, a variety of simple variants can be carried out to technical scheme, this
A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned embodiment, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should equally be considered as content disclosed in this invention.