CN107915891A - A kind of Black stretch film and preparation method thereof - Google Patents

A kind of Black stretch film and preparation method thereof Download PDF

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Publication number
CN107915891A
CN107915891A CN201710751173.0A CN201710751173A CN107915891A CN 107915891 A CN107915891 A CN 107915891A CN 201710751173 A CN201710751173 A CN 201710751173A CN 107915891 A CN107915891 A CN 107915891A
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China
Prior art keywords
black
parts
stretch film
black stretch
preparation
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Pending
Application number
CN201710751173.0A
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Chinese (zh)
Inventor
陈建朝
杨胜利
许萍萍
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XIAMEN JUFU PLASTIC PRODUCTS CO Ltd
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XIAMEN JUFU PLASTIC PRODUCTS CO Ltd
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Priority to CN201710751173.0A priority Critical patent/CN107915891A/en
Publication of CN107915891A publication Critical patent/CN107915891A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of Black stretch film and preparation method thereof, the raw material of the Black stretch film includes 37~99.6 parts of linear low density polyethylene, 0~50 part of metallocene linear-low density polyethylene, 0.2~10 part of black master batch, 0.2~10 part of masterbatch of thickening, 0~30 part of reworked material；Wherein black master batch includes 40~70 parts of polyethylene, 20~55 parts of carbon black, 5~30 parts of the Tissuemat E of the equal relative molecular mass 1000~4000 of number；Wherein viscosify masterbatch includes 40~70 parts of polyethylene, 30~60 parts of polyisobutene according to the mass fraction；The raw material is used into tape-casting after mixing, is film-made 170~290 DEG C of temperature, 15~35 DEG C of chill-roll temperature, speed is than being 1.01~1.2, to obtain the final product.The present invention can obtain preferably viscosity with relatively little of thickening masterbatch and viscosity release is fast, and the delivery cycle shortens dramatically, while employs reworked material, and cost is lower, and environment influences smaller, and preparation method is easy, requires low, good control to production equipment, is adapted to continuous production.

Description

A kind of Black stretch film and preparation method thereof
Technical field
The present invention relates to winding technical field of membrane, and in particular to a kind of Black stretch film and preparation method thereof.
Background technology
Film is wound, is called stretched film, heat shrink films, the country is earliest with PVC (polyvinyl chloride) for base material, DOA (adipic acids two Monooctyl ester) produce PVC for plasticizer and a self-adhesion and wind film.Due to environmental issue, of high cost (with respect to PE (polyethylene) proportion Greatly, unit packaging area is few), the reason such as draftability difference, when 1994~nineteen ninety-five, the country started to produce PE stretched films progressively by Eliminate.PE stretched films are before this with EVA (ethylene-vinyl acetate copolymer) for self adhesive material, but its is of high cost, and flavoursome, after Development is self adhesive material with PIB (polyisobutene), VLDPE (very low density polyethylene), and base material is now (linear low close with LLDPE Spend polyethylene) based on, including C4, C6, C8 and metallocene PE (MPE).
Black stretch film belongs to one kind in winding film, i.e., black master batch is added during film preparation is wound and is made.At present Black stretch film need to store 30 days right and lefts mostly from producing to using can have certain viscosity, and viscosify masterbatch in producing Additive amount is also larger, causes cost accordingly to increase, and often many customer requirements shorter delivery cycle and higher cost performance. Therefore, it is necessary to the Black stretch membrane preparation method that a kind of cost is low, sticky release is fast.
The content of the invention
It is an object of the invention in place of overcome the deficiencies in the prior art, there is provided a kind of Black stretch film and its preparation side Method, has the advantage that cost is low, the sticky release of Black stretch film is fast.
One of the technical solution adopted by the present invention to solve the technical problems is：
A kind of Black stretch film, the raw material of the Black stretch film according to the mass fraction, including：Linear low density polyethylene (LLDPE) 37~99.6 parts, 0~50 part of metallocene linear-low density polyethylene (MLLDPE), 0.2~10 part of black master batch, increases Viscous 0.2~10 part of masterbatch, 0~30 part of reworked material；Wherein described black master batch according to the mass fraction, including：Polyethylene (PE) 40 ~70 parts, 20~55 parts of carbon black, 5~30 parts of the Tissuemat E of the equal relative molecular mass 1000~4000 of number；Wherein described thickening Masterbatch according to the mass fraction, including：40~70 parts of polyethylene (PE), 30~60 parts of polyisobutene (PIB).
In one embodiment：The black master batch does not contain slipping agent or opening agent.
In one embodiment：The slipping agent or opening agent are the slipping agent or opening agent of soap salt.
In one embodiment：The slipping agent or opening agent of the soap salt are zinc stearate or calcium stearate.
In one embodiment：The reworked material is to wind the leftover pieces produced during film preparation.
The two of the technical solution adopted by the present invention to solve the technical problems are：
The preparation method of above-mentioned Black stretch film, including：
1) raw material is uniformly mixed, obtains mixture；
2) mixture for obtaining step 1) uses tape-casting, is film-made 170~290 DEG C of temperature, chill-roll temperature 15 ~35 DEG C, by control speed than for 1.01~1.2 to ensure suitable winding tension, to obtain the final product the Black stretch film.
In one embodiment：In the step 2), 180~270 DEG C of temperature, 20~30 DEG C of chill-roll temperature are film-made.
Compared with background technology, it has the following advantages that the technical program：
1. black master batch is free of slipping agent or opening agent, and carrier polyethylene is homologous series, and it is female not interfere with thickening substantially The viscosity and rate of release of material, have certain viscosity after effectively ensure that winding film production, and preferably viscosity effect is can reach in 7 days Fruit, substantially reduces production and service life；
2. since the influence that black master batch is influenced to viscosity is greatly lowered, the additive amount for viscosifying masterbatch is also reduced accordingly, Coordinate the recycling of reworked material, therefore greatly reduce total cost of production, also mitigate environmental pressure；
3. preparation method of the present invention is easy, low, good control is required to production equipment, is adapted to continuous production.
Embodiment
Present disclosure is illustrated below by embodiment：
Embodiment 1
A kind of Black stretch film, its raw material by mass percentage, including：Linear low density polyethylene 82%, black masterbatch Material 2%, viscosifies masterbatch 6%, reworked material 10%；
Wherein described black master batch by mass percentage, including：Carrier polyethylene 43%, carbon black 44%, dispersant are The Tissuemat E 13% of the equal relative molecular mass 2000 of number, and do not contain the slipping agent or opening agent of soap salt；
It is wherein described to viscosify masterbatch by mass percentage, including：Polyethylene 55%, polyisobutene 45%.
Wherein described reworked material is to wind the leftover pieces produced during film preparation.
The preparation method of above-mentioned Black stretch film, including：
1) linear low density polyethylene, black master batch, thickening masterbatch, reworked material are put into blender in proportion, stirring is mixed Close uniformly, obtain mixture；
2) mixture obtained step 1) is sent into casting machine, and film temperature control is at 180~260 DEG C, chill-roll temperature Control at 20~25 DEG C, by control speed than for 1.1 to ensure suitable winding tension, to obtain the final product the Black stretch film.
Embodiment 2
A kind of Black stretch film, its raw material by mass percentage, including：Linear low density polyethylene 61%, metallocene Linear low density polyethylene 20%, black master batch 3%, viscosifies masterbatch 6%, reworked material 10%；
Wherein described black master batch by mass percentage, including：Carrier polyethylene 50%, carbon black 30%, dispersant are The Tissuemat E 20% of the equal relative molecular mass 3000 of number, and do not contain the slipping agent or opening agent of soap salt；
It is wherein described to viscosify masterbatch by mass percentage, including：Polyethylene 45%, polyisobutene 55%.
Wherein described reworked material is to wind the leftover pieces produced during film preparation.
The preparation method of above-mentioned Black stretch film, including：
1) by linear low density polyethylene, metallocene linear-low density polyethylene, black master batch, thickening masterbatch, reworked material Blender is put into proportion, is uniformly mixed, and obtains mixture；
2) mixture obtained step 1) is sent into casting machine, and film temperature control is at 180~260 DEG C, chill-roll temperature Control at 20~25 DEG C, by control speed than for 1.1 to ensure suitable winding tension, to obtain the final product the Black stretch film.
Embodiment 3
A kind of Black stretch film, its raw material by mass percentage, including：Linear low density polyethylene 83%, black masterbatch Material 8%, viscosifies masterbatch 9%；
Wherein described black master batch by mass percentage, including：Carrier polyethylene 50%, carbon black 25%, dispersant are The Tissuemat E 25% of the equal relative molecular mass 3500 of number, and do not contain the soap salt such as slipping agent such as zinc stearate, calcium stearate Or opening agent；
It is wherein described to viscosify masterbatch by mass percentage, including：Polyethylene 65%, polyisobutene 35%.
Wherein described reworked material is to wind the leftover pieces produced during film preparation.
The preparation method of above-mentioned Black stretch film, including：
1) linear low density polyethylene, black master batch, thickening masterbatch are put into blender in proportion, are uniformly mixed, Obtain mixture；
2) mixture obtained step 1) is sent into casting machine, and film temperature control is at 170~270 DEG C, chill-roll temperature Control at 20~25 DEG C, by control speed than for 1.1 to ensure suitable winding tension, to obtain the final product the Black stretch film.
Embodiment 4
A kind of Black stretch film, its raw material by mass percentage, including：Linear low density polyethylene 90%, black masterbatch Material 5%, viscosifies masterbatch 5%；
Wherein described black master batch by mass percentage, including：Carrier polyethylene 65%, carbon black 20%, dispersant are The Tissuemat E 15% of the equal relative molecular mass 1500 of number, and do not contain the slipping agent or opening agent of soap salt；
It is wherein described to viscosify masterbatch by mass percentage, including：Polyethylene 60%, polyisobutene 40%.
Wherein described reworked material is to wind the leftover pieces produced during film preparation.
The preparation method of above-mentioned Black stretch film, including：
1) linear low density polyethylene, black master batch, thickening masterbatch are put into blender in proportion, are uniformly mixed, Obtain mixture；
2) mixture obtained step 1) is sent into casting machine, and film temperature control is at 190~285 DEG C, chill-roll temperature Control at 30~35 DEG C, by control speed than for 1.1 to ensure suitable winding tension, to obtain the final product the Black stretch film.
Embodiment 5
A kind of Black stretch film, its raw material by mass percentage, including：Linear low density polyethylene 70%, black masterbatch Material 6%, viscosifies masterbatch 4%, reworked material 20%；
Wherein described black master batch by mass percentage, including：Carrier polyethylene 50%, carbon black 30%, dispersant are The Tissuemat E 20% of the equal relative molecular mass 3000 of number, and do not contain the slipping agent or opening agent of soap salt；
It is wherein described to viscosify masterbatch by mass percentage, including：Polyethylene 45%, polyisobutene 55%.
Wherein described reworked material is to wind the leftover pieces produced during film preparation.
The preparation method of above-mentioned Black stretch film, including：
1) linear low density polyethylene, black master batch, thickening masterbatch, reworked material are put into blender in proportion, stirring is mixed Close uniformly, obtain mixture；
2) mixture obtained step 1) is sent into casting machine, and film temperature control is at 190~250 DEG C, chill-roll temperature Control at 18~23 DEG C, by control speed than for 1.1 to ensure suitable winding tension, to obtain the final product the Black stretch film.
The Black stretch film product that the embodiment of the present invention 1~5 obtains is tested for the property, wherein reference examples are common city Winding film is sold, the results are shown in Table 1：
The Black stretch film product of 1 embodiment 1~5 of table and the performance of reference examples survey data
The above, is only present pre-ferred embodiments, therefore cannot limit the scope implemented of the present invention according to this, i.e., according to The equivalent changes and modifications that the scope of the claims of the present invention and description are made, all should still belong in the range of the present invention covers.

Claims (7)

  1. A kind of 1. Black stretch film, it is characterised in that：The raw material of the Black stretch film according to the mass fraction, including：It is linear low 37~99.6 parts of density polyethylene, 0~50 part of metallocene linear-low density polyethylene, 0.2~10 part of black master batch, thickening masterbatch 0.2~10 part, 0~30 part of reworked material；Wherein described black master batch according to the mass fraction, including：40~70 parts of polyethylene, carbon black 20~55 parts, 5~30 parts of the Tissuemat E of the equal relative molecular mass 1000~4000 of number；Wherein described thickening masterbatch presses mass parts Number meter, including：40~70 parts of polyethylene, 30~60 parts of polyisobutene.
  2. 2. Black stretch film according to claim 1, it is characterised in that：The black master batch does not contain slipping agent or opening Agent.
  3. 3. Black stretch film according to claim 2, it is characterised in that：The slipping agent or opening agent are the refreshing of soap salt Lubrication prescription or opening agent.
  4. 4. Black stretch film according to claim 3, it is characterised in that：The slipping agent or opening agent of the soap salt are hard Resin acid zinc or calcium stearate.
  5. 5. Black stretch film according to claim 1, it is characterised in that：The reworked material for winding film preparation during produce Raw leftover pieces.
  6. A kind of 6. preparation method of the Black stretch film any one of claim 1 to 5, it is characterised in that：Including：
    1) raw material is uniformly mixed, obtains mixture；
    2) mixture for obtaining step 1) uses tape-casting, is film-made 170~290 DEG C of temperature, chill-roll temperature 15~35 DEG C, speed is than being 1.01~1.2, up to the Black stretch film.
  7. 7. the preparation method of Black stretch film according to claim 6, it is characterised in that：In the step 2), film temperature 180~270 DEG C of degree, 20~30 DEG C of chill-roll temperature.
CN201710751173.0A 2017-08-28 2017-08-28 A kind of Black stretch film and preparation method thereof Pending CN107915891A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109535534A (en) * 2018-11-06 2019-03-29 厦门聚富塑胶制品有限公司 Viscosity discharges fast winding film and preparation method thereof under low temperature

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1966245A (en) * 2005-11-14 2007-05-23 陈建朝 Method for producing twisting film using regenerated polythene
CN102040764A (en) * 2010-12-20 2011-05-04 深圳市科聚新材料有限公司 Black master batch and preparation method thereof
CN102093622A (en) * 2009-12-09 2011-06-15 中国石油天然气股份有限公司 Preparation method of material special for transparent winding film

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1966245A (en) * 2005-11-14 2007-05-23 陈建朝 Method for producing twisting film using regenerated polythene
CN102093622A (en) * 2009-12-09 2011-06-15 中国石油天然气股份有限公司 Preparation method of material special for transparent winding film
CN102040764A (en) * 2010-12-20 2011-05-04 深圳市科聚新材料有限公司 Black master batch and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109535534A (en) * 2018-11-06 2019-03-29 厦门聚富塑胶制品有限公司 Viscosity discharges fast winding film and preparation method thereof under low temperature

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Application publication date: 20180417

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