CN107904537A - A kind of method of plastic plate plating metal on surface - Google Patents

A kind of method of plastic plate plating metal on surface Download PDF

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Publication number
CN107904537A
CN107904537A CN201711298515.4A CN201711298515A CN107904537A CN 107904537 A CN107904537 A CN 107904537A CN 201711298515 A CN201711298515 A CN 201711298515A CN 107904537 A CN107904537 A CN 107904537A
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CN
China
Prior art keywords
plastic plate
handled
metal
plating metal
annealing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711298515.4A
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Chinese (zh)
Inventor
董学汉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guizhou Yu Ring Mechanical Plastic Co Ltd
Original Assignee
Guizhou Yu Ring Mechanical Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guizhou Yu Ring Mechanical Plastic Co Ltd filed Critical Guizhou Yu Ring Mechanical Plastic Co Ltd
Priority to CN201711298515.4A priority Critical patent/CN107904537A/en
Publication of CN107904537A publication Critical patent/CN107904537A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/123Spraying molten metal

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention belongs to plastic plate technical field, more particularly to a kind of method of plastic plate plating metal on surface, comprises the following steps:Plastic plate is made annealing treatment;Oil removal treatment is carried out to the plastic plate by annealing;Plastic plate Jing Guo oil removal treatment is de-energized and dust removal process;Plastic plate surface after step 3 is handled is handled, and it is 1 ~ 6mm to make its surface smoothness;To the plastic plate surface coating epoxy resin and the mixture of curing agent after step 4 processing, coat is formed;To the coat thermal spraying on surface wire of the plastic plate after step 5 processing, metal coating is formed;Plastic plate is dried after step 6 is handled, to obtain the final product.First the surface of plastic plate is handled by annealing, dedusting, oil removing etc., is conducive to strengthen adhesive force of the metal on plastic plate, makes metal layer more stable, it is not easily to fall off.

Description

A kind of method of plastic plate plating metal on surface
Technical field
The present invention relates to plastic plate technical field technical field, it particularly relates to a kind of plastic plate surface gold-plating The method of category.
Background technology
Plastics are a kind of plastic synthesis high molecular materials of tool.It is formd now with synthetic rubber, synthetic fibers Indispensable three big synthetic material of daily life.Specifically, plastics are using natural or synthetic resin as main component, are added Various additives, can mould under the conditions of certain temperature and pressure etc. and definite shape is made, and keep shape invariance at normal temperatures Material.Plastic plate industry is the pillar industry of China's light industry.At present, the plastic plate industry faces opportunity to develop in China, But many challenges can be also run into, it is leading that this, which is needed using market, enterprise, and government is being subject to policy guide, together to plastic plate Power strides forward.The inherently simple resin of some plastics, such as polyethylene, polystyrene, are known as one-component plastics.Some Plastics, also containing other auxiliary materials, such as plasticizer, stabilizer, colouring agent, various fillers, claim in addition to synthetic resin For multi-component plastics.Plastics metalizing main purpose and advantage has:(1)Metallic luster is obtained to improve decoration performance, and more The piebald, the gas that produce in resin molding process is mended to satisfy defect.(2)The surface property of plastic plate is improved, such as wearability, heat-resisting Property, weatherability, corrosion resistance etc..(3)Improve water suction, the hygroscopicity of product.(4)Improve the mechanical property of product.(5)Have plastics There is the electric conductivity of metal.(7)Mitigate product weight, reduce cost.The method of metallization of plastic surface is divided into dry and wet Two kinds.Dry method mainly includes vacuum evaporation, gas phase spraying, coated conductive layer etc.;Wet method mainly includes liquid phase spraying and chemical plating Deng.However, these methods are all there are this insufficient shortcoming of power is combined between metal layer and base material, this is because plastics and its surface The bonding force covered between metal layer is very faint, and the bond strength between metal cladding is low, and metal layer easily peels off, shadow Using effect is rung, seriously constrains its extensive use.
The content of the invention
In view of this, the object of the present invention is to provide a kind of method of plastic plate plating metal on surface, to solve existing skill The caducous technical problem of plastic plate metal layer of art.
The present invention solves above-mentioned technical problem by the following technical programs:
A kind of method of plastic plate plating metal on surface, comprises the following steps:
S1, makes annealing treatment plastic plate;
S2, oil removal treatment is carried out to the plastic plate by annealing;
S3, is de-energized the plastic plate Jing Guo oil removal treatment and dust removal process;
S4, the plastic plate surface after step 3 is handled are handled, and it is 1 ~ 6mm to make its surface smoothness;
S5, to the plastic plate surface coating epoxy resin and the mixture of curing agent after step 4 processing, forms coat;
S6, to the coat thermal spraying on surface wire of the plastic plate after step 5 processing, forms metal coating;
S7, plastic plate is dried after step 6 is handled, to obtain the final product.
In the step 1, plastic plate is heated to 50 ~ 70 DEG C, and keep 1.5 ~ 3h.
In the step 5, the mass ratio of epoxy resin and curing agent is 2: 1.
In the step 7, by plastic plate at a temperature of 60 ~ 80 DEG C 8 ~ 10min of baking and curing, afterwards again using 30 ~ 50 DEG C of temperature is dried to moisture as 4 ~ 6%.
The beneficial effects of the present invention are:First the surface of plastic plate is handled by annealing, dedusting, oil removing etc., favorably In strengthening adhesive force of the metal on plastic plate, make metal layer more stable, it is not easily to fall off.By the surface for controlling plastic plate Roughness, be conducive to strengthen adhesive force of the metal on plastic plate, make metal layer more stable, it is not easily to fall off.
Embodiment
In order to facilitate the understanding of those skilled in the art, below in conjunction with embodiment, the present invention will be further described. Embodiment is only for example, not being limitation of the invention, the step of not illustrated in embodiment to the invention It is prior art, is not described in detail herein.
Embodiment one
A kind of method of plastic plate plating metal on surface, comprises the following steps:
S1, makes annealing treatment plastic plate;
S2, oil removal treatment is carried out to the plastic plate by annealing;
S3, is de-energized the plastic plate Jing Guo oil removal treatment and dust removal process;
S4, the plastic plate surface after step 3 is handled are handled, and it is 1mm to make its surface smoothness;
S5, to the plastic plate surface coating epoxy resin and the mixture of curing agent after step 4 processing, forms coat;
S6, to the coat thermal spraying on surface wire of the plastic plate after step 5 processing, forms metal coating;
S7, plastic plate is dried after step 6 is handled, to obtain the final product.
In the step 1, plastic plate is heated to 50 DEG C, and keep 1.5h.
In the step 5, the mass ratio of epoxy resin and curing agent is 2: 1.
In the step 7, by plastic plate at a temperature of 60 DEG C baking and curing 8min, use 30 DEG C of temperature again afterwards Moisture is dried to as 4%.
Embodiment two
A kind of method of plastic plate plating metal on surface, comprises the following steps:
S1, makes annealing treatment plastic plate;
S2, oil removal treatment is carried out to the plastic plate by annealing;
S3, is de-energized the plastic plate Jing Guo oil removal treatment and dust removal process;
S4, the plastic plate surface after step 3 is handled are handled, and it is 6mm to make its surface smoothness;
S5, to the plastic plate surface coating epoxy resin and the mixture of curing agent after step 4 processing, forms coat;
S6, to the coat thermal spraying on surface wire of the plastic plate after step 5 processing, forms metal coating;
S7, plastic plate is dried after step 6 is handled, to obtain the final product.
In the step 1, plastic plate is heated to 70 DEG C, and keep 3h.
In the step 5, the mass ratio of epoxy resin and curing agent is 2: 1.
In the step 7, by plastic plate at a temperature of 80 DEG C baking and curing 10min, use 50 DEG C of temperature again afterwards Degree is dried to moisture as 6%.
Embodiment three
A kind of method of plastic plate plating metal on surface, comprises the following steps:
S1, makes annealing treatment plastic plate;
S2, oil removal treatment is carried out to the plastic plate by annealing;
S3, is de-energized the plastic plate Jing Guo oil removal treatment and dust removal process;
S4, the plastic plate surface after step 3 is handled are handled, and it is 5mm to make its surface smoothness;
S5, to the plastic plate surface coating epoxy resin and the mixture of curing agent after step 4 processing, forms coat;
S6, to the coat thermal spraying on surface wire of the plastic plate after step 5 processing, forms metal coating;
S7, plastic plate is dried after step 6 is handled, to obtain the final product.
In the step 1, plastic plate is heated to 60 DEG C, and keep 2h.
In the step 5, the mass ratio of epoxy resin and curing agent is 2: 1.
In the step 7, by plastic plate at a temperature of 70 DEG C baking and curing 9min, use 40 DEG C of temperature again afterwards Moisture is dried to as 5%.

Claims (4)

  1. A kind of 1. method of plastic plate plating metal on surface, it is characterised in that comprise the following steps:
    S1, makes annealing treatment plastic plate;
    S2, oil removal treatment is carried out to the plastic plate by annealing;
    S3, is de-energized the plastic plate Jing Guo oil removal treatment and dust removal process;
    S4, the plastic plate surface after step 3 is handled are handled, and it is 1 ~ 6mm to make its surface smoothness;
    S5, to the plastic plate surface coating epoxy resin and the mixture of curing agent after step 4 processing, forms coat;
    S6, to the coat thermal spraying on surface wire of the plastic plate after step 5 processing, forms metal coating;
    S7, plastic plate is dried after step 6 is handled, to obtain the final product.
  2. 2. the method for plastic plate plating metal on surface as claimed in claim 1, it is characterised in that:In the step 1, by plastics Plate is heated to 50 ~ 70 DEG C, and keeps 1.5 ~ 3h.
  3. 3. the method for plastic plate plating metal on surface as claimed in claim 1, it is characterised in that:In the step 5, asphalt mixtures modified by epoxy resin The mass ratio of fat and curing agent is 2: 1.
  4. 4. the method for plastic plate plating metal on surface as claimed in claim 1, it is characterised in that:In the step 7, by plastics Plate 8 ~ 10min of baking and curing at a temperature of 60 ~ 80 DEG C, uses 30 ~ 50 DEG C of temperature to be dried to moisture as 4 again afterwards ~6%。
CN201711298515.4A 2017-12-08 2017-12-08 A kind of method of plastic plate plating metal on surface Pending CN107904537A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711298515.4A CN107904537A (en) 2017-12-08 2017-12-08 A kind of method of plastic plate plating metal on surface

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711298515.4A CN107904537A (en) 2017-12-08 2017-12-08 A kind of method of plastic plate plating metal on surface

Publications (1)

Publication Number Publication Date
CN107904537A true CN107904537A (en) 2018-04-13

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CN201711298515.4A Pending CN107904537A (en) 2017-12-08 2017-12-08 A kind of method of plastic plate plating metal on surface

Country Status (1)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109295420A (en) * 2018-09-30 2019-02-01 柳州科沃塑业有限公司 The method for plating metal on surface of plastic products
CN109402554A (en) * 2018-09-30 2019-03-01 柳州科沃塑业有限公司 A kind of method for plating metal on surface of plastic products
CN113061829A (en) * 2021-03-18 2021-07-02 东莞仁海科技股份有限公司 Preparation process of conductive silicone rubber

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109295420A (en) * 2018-09-30 2019-02-01 柳州科沃塑业有限公司 The method for plating metal on surface of plastic products
CN109402554A (en) * 2018-09-30 2019-03-01 柳州科沃塑业有限公司 A kind of method for plating metal on surface of plastic products
CN113061829A (en) * 2021-03-18 2021-07-02 东莞仁海科技股份有限公司 Preparation process of conductive silicone rubber

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Application publication date: 20180413