CN107903474A - A kind of environmental protection package bubble chamber film and preparation method thereof - Google Patents
A kind of environmental protection package bubble chamber film and preparation method thereof Download PDFInfo
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- CN107903474A CN107903474A CN201711274996.5A CN201711274996A CN107903474A CN 107903474 A CN107903474 A CN 107903474A CN 201711274996 A CN201711274996 A CN 201711274996A CN 107903474 A CN107903474 A CN 107903474A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
- C08J2471/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Abstract
The invention discloses a kind of environmental protection package bubble chamber film, it is made of the raw material of following weight parts：Titanium dioxide 13 20, high density polyethylene (HDPE) 110 140, butanethiol tin 0.6 1, ethylene glycol dimethacrylate 46, polybenzimidazoles 12, aminopropyl triethoxysilane 0.7 1, cetomacrogol 1000 35, aluminum stearate 24, hydroxyalkyl amide 12, dodecenylsuccinic acid 0.8 1, zinc pyrithione 12, calcium aluminate 35, the skin vacuolar membrane of the present invention is free of poisonous and hazardous volatile materials, the feature of environmental protection is good, comprehensive performance is superior, particularly suitable as packing for hospital material, packaging product will not be polluted.
Description
Technical field
The invention belongs to packaging film field, and in particular to a kind of environmental protection package bubble chamber film and preparation method thereof.
Background technology
Bubble chamber film, is using polyethylene from high pressure process as primary raw material, then adds the auxiliary materials such as brightening agent, opening agent, through 230 degree or so
High temperature extrudes plastic uptake into the product of bubble.It is the New Plastic Packing Materials that a kind of quality is light, the transparency is good, nontoxic, tasteless, can
Play damp proof, buffering, insulation etc. to product.Since air-cushion film intermediate layer is full of air, so body is light, transparent, high resilience,
With sound insulation, shockproof antiwear performance, is widely used in electronics, instrument, ceramics, craftwork, household electrical appliance, from garage, kitchen,
The shock resistance buffering packages such as furniture and paint product product, glassware and precision instrument.It can be made into bubble bags, bubble kraft envelope
Bag, automobile sun gear, heat-insulated seat cushion, heat-insulating heat-preserving material etc..But presently commercially available bubble chamber film is poor there are heat-resistant stability, hold
The defects of easily rupturable.
The content of the invention
In view of the defects and deficiencies of the prior art, the present invention intends to provide a kind of environmental protection package bubble chamber film and its system
Preparation Method.
To achieve the above object, the present invention uses following technical scheme：
A kind of environmental protection package bubble chamber film, it is made of the raw material of following weight parts：
Titanium dioxide 13-20, high density polyethylene (HDPE) 110-140, butanethiol tin 0.6-1, ethylene glycol dimethacrylate
4-6, polybenzimidazoles 1-2, aminopropyl triethoxysilane 0.7-1, cetomacrogol 1000 3-5, aluminum stearate 2-4, hydroxyalkyl
Acid amides 1-2, dodecenylsuccinic acid 0.8-1, zinc pyrithione 1-2, calcium aluminate 3-5.
A kind of preparation method of environmental protection package bubble chamber film, comprises the following steps：
(1) hydroxyalkyl amide is taken, is added in the deionized water of 17-20 times of its weight, stirs evenly, adds calcium aluminate,
It is 3-4 minutes ultrasonic, obtain amide solution；
(2) zinc pyrithione is taken, is added in the absolute ethyl alcohol of 5-9 times of its weight, stirs evenly, adds aluminum stearate,
It is 60-70 DEG C to raise temperature, and insulated and stirred 10-20 minutes, obtains alcoholic solution；
(3) above-mentioned amide solution, alcoholic solution mixing are taken, stirs evenly, obtains acid amides alcoholic solution；
(4) titanium dioxide, aminopropyl triethoxysilane mixing are taken, is added to the deionized water of 10-14 times of mixture weight
In, it is 10-15 minutes ultrasonic, obtain silane dispersion fluid；
(5) above-mentioned acid amides alcoholic solution, silane dispersion fluid mixing are taken, is stirred evenly, the insulated and stirred 20-30 at 70-75 DEG C
Minute, ethanol is distilled off, obtains compound solution of silane；
(6) dodecenylsuccinic acid is taken, is added in the deionized water of 10-15 times of its weight, stirs evenly, it is and above-mentioned multiple
Solution of silane mixing is closed, when insulated and stirred 2-3 is small at 70-80 DEG C, filtering, precipitation is washed, air drying, obtains organically-modified
Compounded mix；
(7) above-mentioned organically-modified compounded mix is taken, is mixed with remaining each raw material, is stirred evenly, be sent in reaction kettle, stir
Mix uniformly, the melting extrusion at 210-260 DEG C, blow molding, to obtain the final product.
Advantages of the present invention：
The present invention titanium dioxide is handled by organic modification after again with high density polyethylene (HDPE) matrix blending extrusion, effectively
The compatibility of titanium dioxide and base-material is improved, so as to improve the mechanical stability intensity of finished product, skin vacuolar membrane of the invention is free of
Poisonous and hazardous volatile materials, the feature of environmental protection is good, and comprehensive performance is superior, will not be to bag particularly suitable as packing for hospital material
Dress product pollutes.
Embodiment
Embodiment 1
A kind of environmental protection package bubble chamber film, it is made of the raw material of following weight parts：
Titanium dioxide 20, high density polyethylene (HDPE) 140, butanethiol tin 1, ethylene glycol dimethacrylate 6, polybenzimidazoles
2nd, aminopropyl triethoxysilane 1, cetomacrogol 1000 5, aluminum stearate 4, hydroxyalkyl amide 2, dodecenylsuccinic acid 1, pyrrole
Pyridine thioketones zinc 2, calcium aluminate 5.
A kind of preparation method of environmental protection package bubble chamber film, comprises the following steps：
(1) hydroxyalkyl amide is taken, is added in the deionized water of 20 times of its weight, stirs evenly, adds calcium aluminate, ultrasound
4 minutes, obtain amide solution；
(2) zinc pyrithione is taken, is added in the absolute ethyl alcohol of 9 times of its weight, stirs evenly, adds aluminum stearate, is risen
High-temperature is 70 DEG C, and insulated and stirred 20 minutes, obtains alcoholic solution；
(3) above-mentioned amide solution, alcoholic solution mixing are taken, stirs evenly, obtains acid amides alcoholic solution；
(4) titanium dioxide, aminopropyl triethoxysilane mixing are taken, is added in the deionized water of 14 times of mixture weight,
Ultrasound 15 minutes, obtains silane dispersion fluid；
(5) above-mentioned acid amides alcoholic solution, silane dispersion fluid mixing are taken, stirs evenly, insulated and stirred 30 minutes at 75 DEG C, steams
Ethanol is removed in distillation, obtains compound solution of silane；
(6) dodecenylsuccinic acid is taken, is added in the deionized water of 15 times of its weight, stirs evenly, it is and above-mentioned compound
Solution of silane mixes, when insulated and stirred 3 is small at 80 DEG C, filtering, will precipitation washing, air drying, obtains organically-modified compound fill out
Material；
(7) above-mentioned organically-modified compounded mix is taken, is mixed with remaining each raw material, is stirred evenly, be sent in reaction kettle, stir
Mix uniformly, the melting extrusion at 260 DEG C, blow molding, to obtain the final product.
Embodiment 2
A kind of environmental protection package bubble chamber film, it is made of the raw material of following weight parts：
Titanium dioxide 13, high density polyethylene (HDPE) 110, butanethiol tin 0.6, ethylene glycol dimethacrylate 4, polyphenyl and miaow
Azoles 1, aminopropyl triethoxysilane 0.7, cetomacrogol 1000 3, aluminum stearate 2, hydroxyalkyl amide 1, dodecenylsuccinic acid
0.8th, zinc pyrithione 1, calcium aluminate 3.
A kind of preparation method of environmental protection package bubble chamber film, comprises the following steps：
(1) hydroxyalkyl amide is taken, is added in the deionized water of 17 times of its weight, stirs evenly, adds calcium aluminate, ultrasound
3 minutes, obtain amide solution；
(2) zinc pyrithione is taken, is added in the absolute ethyl alcohol of 5 times of its weight, stirs evenly, adds aluminum stearate, is risen
High-temperature is 60 DEG C, and insulated and stirred 10 minutes, obtains alcoholic solution；
(3) above-mentioned amide solution, alcoholic solution mixing are taken, stirs evenly, obtains acid amides alcoholic solution；
(4) titanium dioxide, aminopropyl triethoxysilane mixing are taken, is added in the deionized water of 10 times of mixture weight,
It is 10-15 minutes ultrasonic, obtain silane dispersion fluid；
(5) above-mentioned acid amides alcoholic solution, silane dispersion fluid mixing are taken, is stirred evenly, insulated and stirred 20-30 points at 70 DEG C
Clock, is distilled off ethanol, obtains compound solution of silane；
(6) dodecenylsuccinic acid is taken, is added in the deionized water of 10 times of its weight, stirs evenly, it is and above-mentioned compound
Solution of silane mixes, when insulated and stirred 2 is small at 70 DEG C, filtering, will precipitation washing, air drying, obtains organically-modified compound fill out
Material；
(7) above-mentioned organically-modified compounded mix is taken, is mixed with remaining each raw material, is stirred evenly, be sent in reaction kettle, stir
Mix uniformly, the melting extrusion at 210 DEG C, blow molding, to obtain the final product.
Performance test：
Moisture-vapor transmission：0.008-0.009g/m2.h；
Flame retardant rating：VTM-0.
Claims (2)
1. a kind of environmental protection package bubble chamber film, it is characterised in that it is made of the raw material of following weight parts：
Titanium dioxide 13-20, high density polyethylene (HDPE) 110-140, butanethiol tin 0.6-1, ethylene glycol dimethacrylate 4-6,
Polybenzimidazoles 1-2, aminopropyl triethoxysilane 0.7-1, cetomacrogol 1000 3-5, aluminum stearate 2-4, hydroxyalkyl amide
1-2, dodecenylsuccinic acid 0.8-1, zinc pyrithione 1-2, calcium aluminate 3-5.
2. a kind of preparation method of environmental protection package bubble chamber film as claimed in claim 1, it is characterised in that comprise the following steps：
(1) hydroxyalkyl amide is taken, is added in the deionized water of 17-20 times of its weight, stirs evenly, adds calcium aluminate, ultrasound
3-4 minutes, obtain amide solution；
(2) zinc pyrithione is taken, is added in the absolute ethyl alcohol of 5-9 times of its weight, stirs evenly, adds aluminum stearate, rise
Temperature is 60-70 DEG C, and insulated and stirred 10-20 minutes, obtains alcoholic solution；
(3) above-mentioned amide solution, alcoholic solution mixing are taken, stirs evenly, obtains acid amides alcoholic solution；
(4) titanium dioxide, aminopropyl triethoxysilane mixing are taken, is added in the deionized water of 10-14 times of mixture weight, surpasses
Sound 10-15 minutes, obtains silane dispersion fluid；
(5) above-mentioned acid amides alcoholic solution, silane dispersion fluid mixing are taken, is stirred evenly, insulated and stirred 20-30 minutes at 70-75 DEG C,
Ethanol is distilled off, obtains compound solution of silane；
(6) dodecenylsuccinic acid is taken, is added in the deionized water of 10-15 times of its weight, stirs evenly, with above-mentioned comprehensive silicon
Alkane solution mixes, and when insulated and stirred 2-3 is small at 70-80 DEG C, filtering, precipitation is washed, air drying, obtains organically-modified compound
Filler；
(7) above-mentioned organically-modified compounded mix is taken, is mixed with remaining each raw material, stirs evenly, be sent in reaction kettle, stirring is equal
It is even, the melting extrusion at 210-260 DEG C, blow molding, to obtain the final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711274996.5A CN107903474A (en) | 2017-12-06 | 2017-12-06 | A kind of environmental protection package bubble chamber film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711274996.5A CN107903474A (en) | 2017-12-06 | 2017-12-06 | A kind of environmental protection package bubble chamber film and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN107903474A true CN107903474A (en) | 2018-04-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711274996.5A Pending CN107903474A (en) | 2017-12-06 | 2017-12-06 | A kind of environmental protection package bubble chamber film and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108485033A (en) * | 2018-04-19 | 2018-09-04 | 温州市赢创新材料技术有限公司 | A kind of insulation crosslinking packaging bubble chamber film and preparation method thereof |
| CN109206791A (en) * | 2018-09-21 | 2019-01-15 | 佛山市森昂生物科技有限公司 | A kind of preparation method of air bubble bag packing material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104448481A (en) * | 2014-11-25 | 2015-03-25 | 苏州九鼎珍珠棉有限公司 | PE air bubble film, preparation method of PE air bubble film and compound aluminum film air bubble film |
| CN104448484A (en) * | 2014-11-25 | 2015-03-25 | 苏州九鼎珍珠棉有限公司 | PE air bubble film, preparation method of PE air bubble film and air bubble film compound aluminum foil |
-
2017
- 2017-12-06 CN CN201711274996.5A patent/CN107903474A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104448481A (en) * | 2014-11-25 | 2015-03-25 | 苏州九鼎珍珠棉有限公司 | PE air bubble film, preparation method of PE air bubble film and compound aluminum film air bubble film |
| CN104448484A (en) * | 2014-11-25 | 2015-03-25 | 苏州九鼎珍珠棉有限公司 | PE air bubble film, preparation method of PE air bubble film and air bubble film compound aluminum foil |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108485033A (en) * | 2018-04-19 | 2018-09-04 | 温州市赢创新材料技术有限公司 | A kind of insulation crosslinking packaging bubble chamber film and preparation method thereof |
| CN108485033B (en) * | 2018-04-19 | 2020-12-22 | 温州市赢创新材料技术有限公司 | Insulated cross-linked packaging bubble film and preparation method thereof |
| CN109206791A (en) * | 2018-09-21 | 2019-01-15 | 佛山市森昂生物科技有限公司 | A kind of preparation method of air bubble bag packing material |
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Application publication date: 20180413 |