CN107902653A - For air purification and the shaddock peel activated carbon one-step preppn process of sewage disposal - Google Patents
For air purification and the shaddock peel activated carbon one-step preppn process of sewage disposal Download PDFInfo
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- CN107902653A CN107902653A CN201711177192.3A CN201711177192A CN107902653A CN 107902653 A CN107902653 A CN 107902653A CN 201711177192 A CN201711177192 A CN 201711177192A CN 107902653 A CN107902653 A CN 107902653A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 244000276331 Citrus maxima Species 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 25
- 235000001759 Citrus maxima Nutrition 0.000 title claims abstract description 19
- 239000010865 sewage Substances 0.000 title claims abstract description 15
- 238000004887 air purification Methods 0.000 title claims abstract description 14
- 239000003575 carbonaceous material Substances 0.000 claims abstract description 51
- 238000002360 preparation method Methods 0.000 claims abstract description 32
- 239000012190 activator Substances 0.000 claims abstract description 28
- 239000000843 powder Substances 0.000 claims abstract description 18
- 238000001354 calcination Methods 0.000 claims abstract description 17
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052786 argon Inorganic materials 0.000 claims abstract description 7
- 239000007789 gas Substances 0.000 claims abstract description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical group [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000002028 Biomass Substances 0.000 claims description 13
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 230000004913 activation Effects 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 239000011592 zinc chloride Substances 0.000 claims description 5
- 235000005074 zinc chloride Nutrition 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 abstract description 8
- 230000002349 favourable effect Effects 0.000 abstract description 5
- 238000001179 sorption measurement Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 5
- 238000010792 warming Methods 0.000 description 5
- 238000007598 dipping method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 2
- 239000002154 agricultural waste Substances 0.000 description 2
- 229910001437 manganese ion Inorganic materials 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 241000609240 Ambelania acida Species 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 241001464837 Viridiplantae Species 0.000 description 1
- 244000126002 Ziziphus vulgaris Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Hydrology & Water Resources (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Water Treatment By Sorption (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The present invention is a kind of preparation method of the one-step method for the shaddock peel activated carbon for being used for air purification and sewage disposal.The preparation method comprises the following steps:(1)Pomelo peel is cleaned and dry, pulverize into powder;(2)Configure the activator solution of saturation;(3)A certain amount of pomelo peel powder is put into after impregnating a few hours in the activator solution of saturation, is pulled out and dry;(4)Dried pomelo peel powder is put into the tube furnace full of argon gas and is carbonized, activated;(5)Sample after calcining is washed, is dry, obtains the pomelo peel carbon material.A kind of preparation method of the one-step method of shaddock peel activated carbon for being used for air purification and sewage disposal of the present invention, can extremely save the energy with a step into carbon;Preparation method is simple, short preparation period, favorable repeatability.
Description
Technical field
The invention belongs to carbon material preparing technical field, and in particular to a kind of preparation method of biomass carbon material.
Background technology
Traditional carbon material is prepared by coal, oil etc. for primary raw material by working process, but nowadays in global range
The deterioration of energy crisis and ecological environment, is restricted the further development of traditional carbon material, develops renewable resources
And it is translated into the energy and has important practical significance with a variety of materials.It using biomass is raw material system that biomass carbon material, which is,
Standby various carbon materials.Biomass refers to by photosynthesis the various organisms that are formed, including all animals and plants and micro-
Biology.And so-called biomass energy, it is exactly the form of energy that solar energy is stored in the form of chemical energy in biomass, i.e., with biomass
For the energy of carrier.It directly or indirectly derive from green plants photosynthesis, can be converted into conventional solid-state, liquid and
Fuel gas, it is inexhaustible, nexhaustible, it is a kind of regenerative resource, while be also a kind of unique reproducible carbon source.With life
Material prepares carbon material for raw material, can reduce the production cost of carbon material, realize the sustainable development of carbon material.
In recent years, many scientists are being directed to grinding for the preparation of novel biomass class nano-carbon material and potential application
Study carefully.It is prepared by raw material such as with using cotton stalk, bagasse, rice husk, tealeaf residue, jujube core, pomelo peel, cocoanut shell agricultural waste material
Carbon-based material.As a kind of agricultural wastes, pomelo peel yield is big, derives from a wealth of sources, and cost of material is cheap, and raw material concentrate.
At present, there is substantial amounts of pomelo peel every year as garbage disposal, cause the significant wastage of resource and pollute environment.
In view of this, our seminars propose an a kind of step of the shaddock peel activated carbon for being used for air purification and sewage disposal
The preparation method of method.
The content of the invention
It is an object of the invention to provide a kind of system of the one-step method for the shaddock peel activated carbon for being used for air purification and sewage disposal
Preparation Method, this method technique is simple, improves the performance of product.
To achieve these goals, the technical solution adopted in the present invention is:
A kind of preparation method of the one-step method for the shaddock peel activated carbon for being used for air purification and sewage disposal, comprises the following steps:
(1)Pomelo peel is cleaned and dry, pulverize into powder;
(2)Configure the activator solution of saturation:Activator is added in quantitative deionized water, stirred evenly until activator
It is not redissolved, obtains saturation activation agent solution;The activator is potassium hydroxide, one kind in sodium hydroxide, zinc chloride;
(3)By 1-20 grams of pomelo peel powder be put into the activator solution of saturation impregnate 12-48 it is small when after, pulled out and done
It is dry;
(4)Dried pomelo peel powder is put into the tube furnace full of argon gas, when 400-700 DEG C of calcining 2-5 is small, is being risen
Temperature is to 800-1000 DEG C, and when calcining 1-5 is small, cooled to room temperature, obtains carbon material at initial stage;
(5)Sample after calcining is washed, is dry:Carbon material at initial stage is first washed with deionized, then is washed with absolute ethyl alcohol
Carbon material at initial stage is washed, the carbon material at initial stage after being washed;Carbon material at initial stage after dry washing, obtains the biomass carbon
Material.
Further, the pomelo peel is dry in drying box, then crushed 100-120 mesh sieves.
Further, the step(2)In, the volume of the saturation activation agent solution configured is 250mL.
Further, the step(5)Further include:It is washed with deionized after carbon material at initial stage 5-6 times, uses again afterwards
Absolute ethyl alcohol washing carbon material at initial stage 3-4 times.
Further, the step(5)In, dry temperature is 50-80 DEG C, when drying time is 10-15 small.
Compared with prior art, the beneficial effects of the present invention are:
1st, preparation method technique of the present invention is simple, short preparation period, favorable repeatability.
2nd, the present invention is prepared using one-step method, extremely saves the energy.
Brief description of the drawings
Using attached drawing, the present invention will be further described, but the content in attached drawing does not form any limitation of the invention.
Fig. 1 is the X ray diffracting spectrum of the embodiment of the present invention 1.
Embodiment
A kind of one-step method for the shaddock peel activated carbon for being used for air purification and sewage disposal in order to which the present invention is further explained
Preparation method, reach expected goal of the invention, below in conjunction with preferred embodiment, to being used for air according to one kind proposed by the present invention
The preparation method of the one-step method of the shaddock peel activated carbon of purification and sewage disposal, its embodiment, structure, feature and work(
Effect, describes in detail as after.In the following description, what different " embodiment " or " embodiment " referred to is not necessarily same implementation
Example.In addition, the special characteristic, structure or feature in one or more embodiments can be combined by any suitable form.
Elaborating a kind of system of the one-step method for the shaddock peel activated carbon for being used for air purification and sewage disposal of the present invention
Before Preparation Method, it is necessary to the method referred in the present invention is described further, to reach more preferable effect.
The pomelo peel after dipping is put into the tube furnace full of argon gas and is first warming up to 400-700 by calcination process in the present invention
DEG C, when constant temperature 2-5 is small, activator and vapor is acutely discharged, achieve the purpose that pore-creating.Continue to be warming up to 800-1000 DEG C,
When keeping 1-5 small.On the one hand this process burns up the crystallization water in carbon, the structure of one side Stable Carbon.Then Temperature fall is
Can.
Washing, laboratory washing operation are:Precipitation is transferred to filter(By funnel, filter paper, beaker and fixing device group
Into)In, wash solution is added into funnel to not crossing and treats washings, but liquid level is less than filter paper edge, allows under liquid flows into naturally
In the undertaking beaker in face, treat that wash solution is flow to end.Period cannot be stirred with glass bar, in order to avoid scratch filter paper.Washed in the present invention
The process washed is to remove the ash content in carbon material.
Drying is to remove the wash solution in carbon material in the present invention.
After the method referred in having understood the present invention, below in conjunction with specific embodiments, to a kind of use of the invention
It is further described in detail in the preparation method of air purification and the one-step method of the shaddock peel activated carbon of sewage disposal:
Embodiment 1.
Concrete operation step is as follows:
(1)Pomelo peel is cleaned and dry, pulverize into powder;
(2)Configure the activator solution of saturation:Activator is added in quantitative deionized water, stirred evenly until activator
It is not redissolved, obtains saturation activation agent solution;The activator is potassium hydroxide, one kind in sodium hydroxide, zinc chloride;
(3)By 5 grams of pomelo peel powder be put into the activator solution of saturation dipping 12 it is small when after, pulled out and dry;
(4)Dried pomelo peel powder is put into the tube furnace full of argon gas, when 400 DEG C of calcinings 5 are small, is being warming up to
800 DEG C, when calcining 1 is small, cooled to room temperature, obtains carbon material at initial stage;
(5)Sample after calcining is washed, is dry:Carbon material at initial stage is first washed with deionized, then is washed with absolute ethyl alcohol
Carbon material at initial stage is washed, the carbon material at initial stage after being washed;By initial stage carbon material at a temperature of 50 DEG C it is dry 15 it is small when after, obtain
To the biomass carbon material.
By test it can be seen that pomelo peel, which is used as carbon material prepared by carbon source, more considerable specific surface area, reach
236.13 m2/ g, average pore volume is 0.17 cm3/ g, average pore size are respectively 2.4 nm.It is it can be seen from the above that manufactured in the present embodiment
Carbon material has good architectural feature.
From figure 1 it appears that activated carbon prepared by the present invention is carbon material.
A kind of one-step method of shaddock peel activated carbon for being used for air purification and sewage disposal described in the embodiment of the present invention
Preparation method, extremely saves the energy, can be with a step into carbon;Preparation method is simple, short preparation period, favorable repeatability.
Embodiment 2.
Concrete operation step is as follows:
(1)Pomelo peel is cleaned and dry, pulverize into powder;
(2)Configure the activator solution of saturation:Activator is added in quantitative deionized water, stirred evenly until activator
It is not redissolved, obtains saturation activation agent solution;The activator is potassium hydroxide, one kind in sodium hydroxide, zinc chloride;
(3)By 10 grams of pomelo peel powder be put into the activator solution of saturation dipping 36 it is small when after, pulled out and dry;
(4)Dried pomelo peel powder is put into the tube furnace full of argon gas, when 500 DEG C of calcinings 3 are small, is being warming up to
900 DEG C, when calcining 2 is small, cooled to room temperature, obtains carbon material at initial stage;
(5)Sample after calcining is washed, is dry:Carbon material at initial stage is first washed with deionized, then is washed with absolute ethyl alcohol
Carbon material at initial stage is washed, the carbon material at initial stage after being washed;By carbon material at initial stage when drying 12 is small at a temperature of 60 DEG C, obtain
The biomass carbon material.
The formalin for being 46 mg/mL with the shaddock peel activated carbon absorption initial concentration of preparation, shaddock foams press dosage
20 mg/mL, 313 K of adsorption temp, 5 h of adsorption time, adsorbance can reach 29.76 mg/g.
A kind of one-step method of shaddock peel activated carbon for being used for air purification and sewage disposal described in the embodiment of the present invention
Preparation method, extremely saves the energy, can be with a step into carbon;Preparation method is simple, short preparation period, favorable repeatability, PARA FORMALDEHYDE PRILLS(91,95)
There is certain adsorption effect.
Embodiment 3.
Concrete operation step is as follows:
(1)Pomelo peel is cleaned and dry, pulverize into powder;
(2)Configure the activator solution of saturation:Activator is added in quantitative deionized water, stirred evenly until activator
It is not redissolved, obtains saturation activation agent solution;The activator is potassium hydroxide, one kind in sodium hydroxide, zinc chloride;
(3)By 20 grams of pomelo peel powder be put into the activator solution of saturation dipping 48 it is small when after, pulled out and dry;
(4)Dried pomelo peel powder is put into the tube furnace full of argon gas, when 700 DEG C of calcinings 2 are small, is being warming up to
1000 DEG C, when calcining 5 is small, cooled to room temperature, obtains carbon material at initial stage;
(5)Sample after calcining is washed, is dry:Carbon material at initial stage is first washed with deionized, then is washed with absolute ethyl alcohol
Carbon material at initial stage is washed, the carbon material at initial stage after being washed;By carbon material at initial stage when drying 10 is small at a temperature of 80 DEG C, obtain
The biomass carbon material.
The waste water containing manganese ion is adsorbed with the shaddock peel activated carbon of preparation, the wherein concentration of manganese ion is 12 mg/L, is added
The amount of the shaddock peel activated carbon entered is 15 g/L, and adsorption temp is 35 DEG C, is adsorbed after 5 h and reaches balance, adsorption rate reaches 83
%。
A kind of one-step method of shaddock peel activated carbon for being used for air purification and sewage disposal described in the embodiment of the present invention
Preparation method, extremely saves the energy, can be with a step into carbon;Preparation method is simple, short preparation period, favorable repeatability, Dui Han Manganese
Waste water has certain adsorption effect.
Claims (5)
- A kind of 1. preparation method of the one-step method for the shaddock peel activated carbon for being used for air purification and sewage disposal, it is characterised in that Comprise the following steps:(1)Pomelo peel is cleaned and dry, pulverize into powder;(2)Configure the activator solution of saturation:Activator is added in quantitative deionized water, stirred evenly until activator It is not redissolved, obtains saturation activation agent solution;The activator is potassium hydroxide, one kind in sodium hydroxide, zinc chloride;(3)By 1-20 grams of pomelo peel powder be put into the activator solution of saturation impregnate 12-48 it is small when after, filtered and done It is dry;(4)Dried pomelo peel powder is put into the tube furnace full of argon gas, when 400-700 DEG C of calcining 2-5 is small, is being risen Temperature is to 800-1000 DEG C, and when calcining 1-5 is small, cooled to room temperature, obtains carbon material at initial stage;(5)Sample after calcining is washed, is dry:Carbon material at initial stage is first washed with deionized, then is washed with absolute ethyl alcohol Carbon material at initial stage is washed, the carbon material at initial stage after being washed;Carbon material at initial stage after dry washing, obtains the biomass carbon Material.
- 2. preparation method according to claim 1, it is characterised in thatThe pomelo peel is dry in drying box, then crushed 100-120 mesh sieves.
- 3. preparation method according to claim 1, it is characterised in thatThe step(2)In, the volume of the saturation activation agent solution configured is 250mL.
- 4. preparation method according to claim 1, it is characterised in thatThe step(5)Further include:It is washed with deionized after carbon material at initial stage 5-6 times, is washed again with absolute ethyl alcohol afterwards Initial stage carbon material 3-4 times.
- 5. preparation method according to claim 1, it is characterised in thatThe step(5)In, dry temperature is 50-80 DEG C, when drying time is 10-15 small.
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Cited By (9)
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CN110182803A (en) * | 2019-06-11 | 2019-08-30 | 武汉科技大学 | A kind of absorbent charcoal material and preparation method thereof |
CN110203931A (en) * | 2019-07-01 | 2019-09-06 | 湖南城市学院 | A method of high pressure water system electrode material for super capacitor is prepared using pomelo peel |
CN110550628A (en) * | 2019-10-21 | 2019-12-10 | 青岛科技大学 | Method for preparing activated carbon for industrial wastewater treatment by one-step method |
CN110559991A (en) * | 2019-09-03 | 2019-12-13 | 湖南农业大学 | Modified biochar and preparation method and application thereof |
CN111151245A (en) * | 2019-12-31 | 2020-05-15 | 南京环福新材料科技有限公司 | Gold nanoflower catalyst with biomass activated carbon as carrier and preparation method and application thereof |
CN113460992A (en) * | 2021-06-20 | 2021-10-01 | 桂林理工大学 | Method for realizing in-situ mosaic construction of cellular porous carbon and iron phosphate precursor by using waste shaddock peel |
CN114477175A (en) * | 2022-01-25 | 2022-05-13 | 南京智汇环境气象产业研究院有限公司 | Simple preparation method of carbon material by taking shaddock inner pulp as raw material |
CN114917871A (en) * | 2022-06-21 | 2022-08-19 | 徐靖才 | Photocatalytic regenerated active carbon and preparation method thereof |
CN116239117A (en) * | 2023-03-23 | 2023-06-09 | 大连理工大学 | Preparation method of shaddock peel-based activated carbon and application of shaddock peel-based activated carbon in removal of ethane in carbon dioxide |
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CN105502384A (en) * | 2015-12-14 | 2016-04-20 | 太原科技大学 | Preparation method of shaddock-peel-base activated carbon and application of shaddock-peel-base activated carbon to phenol-containing wastewater and waste gas |
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CN107159110A (en) * | 2017-05-22 | 2017-09-15 | 江苏大学 | A kind of preparation method and its usage of pomelo peel base multi-stage porous carbon material |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110182803A (en) * | 2019-06-11 | 2019-08-30 | 武汉科技大学 | A kind of absorbent charcoal material and preparation method thereof |
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