CN107899405A - Denitrification reducing agent energy saving and efficiency increasing system - Google Patents

Denitrification reducing agent energy saving and efficiency increasing system Download PDF

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Publication number
CN107899405A
CN107899405A CN201711260371.3A CN201711260371A CN107899405A CN 107899405 A CN107899405 A CN 107899405A CN 201711260371 A CN201711260371 A CN 201711260371A CN 107899405 A CN107899405 A CN 107899405A
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China
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reducing agent
heat exchange
boiler
energy saving
exchange pipeline
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Pending
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CN201711260371.3A
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Chinese (zh)
Inventor
贾博麟
贾增源
贾文杰
王悦豪
职启琛
张书铭
陈成蹊
寿铁锋
黄海根
赵图
冯昭阳
宋问远
王加苏
王悦熹
王景尧
贾益楚
刘子涵
刘佳萱
贾琳琳
葛君利
张玲
贾庆禄
周玉叶
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Individual
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Priority to CN201711260371.3A priority Critical patent/CN107899405A/en
Publication of CN107899405A publication Critical patent/CN107899405A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8631Processes characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/79Injecting reactants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22DPREHEATING, OR ACCUMULATING PREHEATED, FEED-WATER FOR STEAM GENERATION; FEED-WATER SUPPLY FOR STEAM GENERATION; CONTROLLING WATER LEVEL FOR STEAM GENERATION; AUXILIARY DEVICES FOR PROMOTING WATER CIRCULATION WITHIN STEAM BOILERS
    • F22D1/00Feed-water heaters, i.e. economisers or like preheaters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L15/00Heating of air supplied for combustion
    • F23L15/04Arrangements of recuperators
    • F23L15/045Arrangements of recuperators using intermediate heat-transfer fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28GCLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
    • F28G1/00Non-rotary, e.g. reciprocated, appliances
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2067Urea
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a kind of denitrification reducing agent energy saving and efficiency increasing system, including boiler and reducing agent storage tank, low-level (stack-gas) economizer and air preheater are equipped with the boiler successively, the boiler is connected with smoke pipe, the flue is equipped with electric precipitator, the reducing agent storage tank is connected with heat exchange pipeline, the heat exchange pipeline enters air preheater and by arriving at the reaction zone in boiler after low-level (stack-gas) economizer at the preceding flue of electric precipitator all along flue, and the present invention provides a kind of denitrification reducing agent energy saving and efficiency increasing system for fully making reducing agent fully be pyrolyzed beneficial to fume afterheat.

Description

Denitrification reducing agent energy saving and efficiency increasing system
Technical field
The present invention relates to denitrating flue gas field, is more particularly to denitrification reducing agent energy saving and efficiency increasing system.
Background technology
Boiler exhaust gas discharge will be controlled according to the standard of minimum discharge according to environmental requirement, all boilers at present.At present The catalyst used has liquefied ammonia, urea, ammonium hydrogen carbonate, cyanuric acid etc., at present technology due to these reducing agents enter boiler into High energy consumption when temperature during row denitration is than relatively low or cracking, influence of the reducing agent to boiler is bigger, is needed when being dissolved such as urea The energy consumptions such as steam heating, need to consume substantial amounts of electric energy when using electrical heating or steam heat resolve outside stove such as urea as ammonia Or vapor.The benefit of power plant has great loss, and power cut-off occurs or when vapor is died, cause denitration cannot be just Often carry out.The invention avoids these to heat energy consumption, improves boiler efficiency.
The content of the invention
In view of the deficiencies of the prior art, the present invention provides it is a kind of be fully beneficial to fume afterheat make reducing agent be fully pyrolyzed and Improve the energy saving and efficiency increasing system of denitrification reducing agent charging temperature.
To achieve the above object, the present invention provides following technical solution:A kind of denitrification reducing agent energy saving and efficiency increasing system, bag Boiler and reducing agent storage tank are included, is equipped with low-level (stack-gas) economizer and air preheater successively in the boiler, the boiler is connected with cigarette Pipe, the flue are equipped with electric precipitator, and the reducing agent storage tank is connected with heat exchange pipeline, and the heat exchange pipeline is from electric precipitator Preceding flue at all along flue enter air preheater and by low-level (stack-gas) economizer after, into reducing agent separation vessel, point The solution or air and reducing agent storage tank, heat exchange pipeline separated out exchanges heat, and reuses to convey denitrification reducing agent, separation Reducing agent enters reducing agent storage container afterwards, and undecomposed high temperature reduction agent and the ammonia after decomposing etc. pass through spray gun or ammonia cake Denitration reaction is carried out Deng into the reaction zone in boiler.
The further heat exchange pipeline is coiled on the outer wall of flue and boiler and is bonded with the outer wall of flue.
The further heat exchange pipeline is externally provided with external insulation system.
The further heat exchange pipeline is located in flue and in boiler.
The further reducing agent storage tank is equipped with solution delivery system in parallel and powdery fluidisation transport system.
The soot blower system for being used for clearing up heat exchange pipeline outer wall is equipped with the further flue and boiler.
If the further heat exchange pipeline is equipped with dry temperature sensor.
Further further include heat exchanger and reducing agent separator, the denitrification reducing agent after being heated by heat exchanger, Into reducing agent separator, the reducing agent or the product of reducing agent separated by reducing agent separator enter reduction all the way The storage of agent storage tank, the SNCR being directly entered all the way after the flue gas heat exchange of boiler in boiler, SCR region domain carry out denitration, from also The liquid and gas for the conveying reducing agent that former agent separator is separated enter after exchanging heat with the reducing agent in transport system The reducing agent of reducing agent tank is heated reducing agent holding vessel and dissolving.
One end that the further heat exchange pipeline enters in boiler is equipped with metering distribution system.
Heat exchanger is equipped with the further reducing agent knockout drum.
High temperature reduction agent holding vessel is equipped with after the further reducing agent knockout drum.
The reducing agent pumped (conveying) medium after reducing agent knockout drum return to reducing agent holding vessel into Enter the reducing agent in reducing agent holding vessel or in reducing agent conveyance conduit to be heated.
It is further to further include DCS system, the signal of valve and measurement in the denitrification reducing agent energy saving and efficiency increasing system It is all connected with DCS system.
In conclusion the present invention utilizes the waste heat of flue gas in flue, reducing agent is inversely gradually heated up from low temperature to high temperature, from And reducing agent is pyrolyzed into ammonia completely or bring up to the optimum temperature before stove decomposes, it ensure that the decomposition of denitrification reducing agent Efficient, having saved when the electrical heating of current denitrating system needs or steam heat resolve are ammonia needs to consume substantial amounts of electric energy Or vapor etc., boiler for producing efficiency is improved, and device structure is simple, plant maintenance is convenient.
Brief description of the drawings
Fig. 1 is the structure chart of denitrification reducing agent energy saving and efficiency increasing system of the present invention.
Mark explanation:1st, reducing agent storage tank;2nd, heat exchange pipeline;3rd, electric precipitator;4th, air preheater;5th, low temperature saves coal Device;6th, distribution system is measured;7th, boiler;8th, flue;9th, temperature sensor.
Embodiment
The embodiment of denitrification reducing agent energy saving and efficiency increasing system of the present invention is described further with reference to Fig. 1.
A kind of denitrification reducing agent energy saving and efficiency increasing system, including boiler 7 and reducing agent storage tank 1, are equipped with the boiler 7 successively Low-level (stack-gas) economizer 5 and air preheater 4, the boiler 7 are connected with smoke pipe, and the flue 8 is equipped with electric precipitator 3, described to go back Former agent storage tank 1 is connected with heat exchange pipeline 2, and the heat exchange pipeline 2 enters at the preceding flue 8 of electric precipitator 3 all along flue 8 Air preheater 4 simultaneously passes through the reaction zone after low-level (stack-gas) economizer 5 in arrival boiler 7.
Reducing agent is added in reducing agent storage tank 1, reducing agent is introduced into the front and rear cigarette of electric precipitator 3 by heat exchange pipeline 2 In road 8, by tentatively being preheated in flue 8, using the flue gas in flue 8 to and the close temperature of flue-gas temperature, it is preliminary plus Reducing agent after heat enters air preheater 4 along the flue 8 of boiler 7, is further added by the heat exchanger in air preheater 4 Heat, so that the reducing agent in heat exchange pipeline 2 gradually heats up, when temperature reaches the pyrolysis temperature of reducing agent, reducing agent pyrolysis Ammonia is produced, if urea, ammonium hydrogen carbonate then decompose completion substantially at this moment, finally by being supported after low-level (stack-gas) economizer 5 Up to the reaction zone injection in boiler 7, so using the waste heat of flue gas in flue 8, inversely it is gradually heated up reducing from low temperature to high temperature Agent, so that reducing agent can be pyrolyzed into ammonia completely, pyrolysis is efficient, when to have saved electrical heating or steam heat resolve be ammonia Need to consume substantial amounts of electric energy or vapor, improve production efficiency, and device structure is simple, plant maintenance is convenient.
Embodiment 1:The heat exchange pipeline 2 is coiled on the outer wall of flue 8 and is bonded with the outer wall of flue 8, can be abundant With the flue gas heat exchange in flue 8.
Preferably the heat exchange pipeline 2 is externally provided with external insulation system to the present embodiment, avoids heat exchange pipeline 2 and outside air Heat exchange cooling.
Embodiment 2:The heat exchange pipeline 2 is located in flue 8, and heat exchange pipeline 2 is in coil pipe in flue 8 in the present embodiment Shape, for lengthening the heat exchange stroke of heat exchange pipeline 2, so as to sufficiently exchange heat with flue gas.
Embodiment 3:Certain heat exchange pipeline 2 can also be at the same time in flue 8 and outside flue 8, and principle is with embodiment 1 and implements Example 2.
The currently preferred reducing agent storage tank 1 is equipped with solution delivery system in parallel and powdery fluidisation transport system, according to The requirement of reducing agent is different, and the reducing agent in reducing agent storage tank 1 enters transport system or direct after being dissolved respectively using water Transport system is fluidized into powdery, suitable for different reducing agents.
The soot blower system for being used for clearing up 2 outer wall of heat exchange pipeline is equipped with the currently preferred boiler 7, in the present embodiment Soot blower system can be soot blower system that boiler 7 carries, so ensure the not dust stratification dirt of heat exchange pipeline 2, ensure heat exchange efficiency.
If the currently preferred heat exchange pipeline 2 is equipped with dry temperature sensor 9, for monitoring heat exchange pipeline in real time The temperature of reducing agent in 2, so as to preferably control the input quantity and flow of reducing agent.
The reducing agent separator of the present invention is after cracking or uncracked reducing agent enters reducing agent holding vessel, if ammonia is from mixing Separated in compound and occur to be replenished in time when nitre content increases suddenly into ammonia holding vessel, guarantee;From reducing agent point The material (water or air etc.) of the conveying denitrfying agent come out from device first and into the reduction agent composition of reducing agent separator carries out Heat exchange, is back to denitrfying agent holding vessel and denitrfying agent is heated after heat exchange, improve heating efficiency.Avoid the occurrence of current each Kind denitrification reducing agent enters stokehold energy consumption, as a large amount of electric energy or fuel oil or steam of urea pyrolysis stove consume energy;It it also avoid urea The steam to aqueous solution of urea for hydrolyzing stove heats energy consumption;Equally to the energy consumption of the pyrolysis such as ammonium hydrogen carbonate;Melamine is improved to enter Furnace temperature, increase reaction time improve denitration efficiency etc..The present invention except pump, wind turbine, compressor energy consumption, there is no other steamings The auxiliary such as vapour heat energy consumption.
One end that the currently preferred heat exchange pipeline 2 enters in boiler 7 is equipped with metering distribution system 6, passes through metering Distribution system 6, which can be more actually needed, rationally controls the amount of ammonia and denitrification reducing agent penetrating reaction zone.
The above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation Example, all technical solutions belonged under thinking of the present invention belong to protection scope of the present invention.It should be pointed out that for the art Those of ordinary skill for, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications It should be regarded as protection scope of the present invention.

Claims (10)

1. a kind of denitrification reducing agent energy saving and efficiency increasing system, it is characterized in that:Including boiler and reducing agent storage tank, in the boiler successively Equipped with low-level (stack-gas) economizer and air preheater, the boiler is connected with smoke pipe, and the flue is equipped with electric precipitator, the reduction Agent storage tank is connected with heat exchange pipeline, and the heat exchange pipeline enters air preheat at the preceding flue of electric precipitator all along flue Device and by low-level (stack-gas) economizer, then arrives at the reaction zone in boiler.
2. denitrification reducing agent energy saving and efficiency increasing system according to claim 1, it is characterized in that:The heat exchange pipeline is coiled in cigarette It is bonded on the outer wall of road and boiler and with the outer wall of flue.
3. denitrification reducing agent energy saving and efficiency increasing system according to claim 2, it is characterized in that:The heat exchange pipeline is externally provided with outer Portion's heat-insulation system.
4. denitrification reducing agent energy saving and efficiency increasing system according to claim 1, it is characterized in that:The heat exchange pipeline is located at flue Interior, the heat exchange pipeline of the inside of the flue is equipped with bypass, the valve that control flows to and is flowed through according to denitrfying agent temperature control The valve control system of flow in heat exchange pipeline.
5. denitrification reducing agent energy saving and efficiency increasing system according to claim 1, it is characterized in that:The reducing agent storage tank is equipped with simultaneously Solution delivery system and powdery the fluidisation transport system of connection, solution delivery system and powdery fluidisation the transport system conveying take off Nitre reducing agent is exchanged heat by heat exchange pipeline, and the pipeline of solution delivery system and powdery the fluidisation transport system is provided with pipe Road purges cleaning equipment.
6. denitrification reducing agent energy saving and efficiency increasing system according to claim 1, it is characterized in that:It is equipped with and is used for clearly in the boiler Manage the soot blower system of heat exchange pipeline outer wall.
7. denitrification reducing agent energy saving and efficiency increasing system according to claim 1, it is characterized in that:If the heat exchange pipeline is equipped with Dry temperature sensor.
8. denitrification reducing agent energy saving and efficiency increasing system according to claim 5, it is characterized in that:Further include heat exchanger and reducing agent Separator, the denitrification reducing agent, into reducing agent separator, separate after being heated by heat exchanger by reducing agent separator Reducing agent or the product of reducing agent out enters reducing agent storage tank and stores all the way, straight after the flue gas heat exchange of boiler all the way Tap into SNCR in boiler, SCR region domain carries out denitration, the liquid for the conveying reducing agent separated from reducing agent separator and Gas by with enter reducing agent holding vessel after the reducing agent heat exchange in transport system to the reducing agent of reducing agent tank heating and molten Solution.
9. denitrification reducing agent energy saving and efficiency increasing system according to claim 1, it is characterized in that:The heat exchange pipeline enters boiler Interior one end is equipped with metering distribution system.
10. the denitrification reducing agent energy saving and efficiency increasing system according to claim 1 to 9 any one, it is characterized in that:Further include DCS system, the signal of valve and measurement in the denitrification reducing agent energy saving and efficiency increasing system are all connected with DCS system.
CN201711260371.3A 2017-12-04 2017-12-04 Denitrification reducing agent energy saving and efficiency increasing system Pending CN107899405A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711260371.3A CN107899405A (en) 2017-12-04 2017-12-04 Denitrification reducing agent energy saving and efficiency increasing system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711260371.3A CN107899405A (en) 2017-12-04 2017-12-04 Denitrification reducing agent energy saving and efficiency increasing system

Publications (1)

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CN107899405A true CN107899405A (en) 2018-04-13

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109876626A (en) * 2019-02-28 2019-06-14 华电电力科学研究院有限公司 A kind of three-stage urea pyrolysis ammonia denitrating system and its working method
CN113266839A (en) * 2021-06-02 2021-08-17 秦皇岛新特科技有限公司 Denitration treatment method for sintering flue gas

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070231232A1 (en) * 2000-12-01 2007-10-04 Fuel Tech, Inc. SELECTIVE CATALYTIC REDUCTION OF NOx ENABLED BY UREA DECOMPOSITION IN HEAT-EXCHANGER BYPASS
CN102861505A (en) * 2012-09-29 2013-01-09 贾博麟 Efficient and energy-saving denitration system
CN107261837A (en) * 2017-07-27 2017-10-20 中节环立为(武汉)能源技术有限公司 It is a kind of to quote denitrification apparatus and technique that high-temperature flue gas carries out urea pyrolysis ammonia
CN107297145A (en) * 2016-04-14 2017-10-27 昆山市三维换热器有限公司 SCR boiler flue gas denitration systems
CN207822789U (en) * 2017-12-04 2018-09-07 贾博麟 Denitrification reducing agent energy saving and efficiency increasing system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070231232A1 (en) * 2000-12-01 2007-10-04 Fuel Tech, Inc. SELECTIVE CATALYTIC REDUCTION OF NOx ENABLED BY UREA DECOMPOSITION IN HEAT-EXCHANGER BYPASS
CN102861505A (en) * 2012-09-29 2013-01-09 贾博麟 Efficient and energy-saving denitration system
CN107297145A (en) * 2016-04-14 2017-10-27 昆山市三维换热器有限公司 SCR boiler flue gas denitration systems
CN107261837A (en) * 2017-07-27 2017-10-20 中节环立为(武汉)能源技术有限公司 It is a kind of to quote denitrification apparatus and technique that high-temperature flue gas carries out urea pyrolysis ammonia
CN207822789U (en) * 2017-12-04 2018-09-07 贾博麟 Denitrification reducing agent energy saving and efficiency increasing system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109876626A (en) * 2019-02-28 2019-06-14 华电电力科学研究院有限公司 A kind of three-stage urea pyrolysis ammonia denitrating system and its working method
CN113266839A (en) * 2021-06-02 2021-08-17 秦皇岛新特科技有限公司 Denitration treatment method for sintering flue gas

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