CN107892844A - One kind spray painting material - Google Patents
One kind spray painting material Download PDFInfo
- Publication number
- CN107892844A CN107892844A CN201711102932.7A CN201711102932A CN107892844A CN 107892844 A CN107892844 A CN 107892844A CN 201711102932 A CN201711102932 A CN 201711102932A CN 107892844 A CN107892844 A CN 107892844A
- Authority
- CN
- China
- Prior art keywords
- parts
- spray painting
- acrylic resin
- painting material
- titanium oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2248—Oxides; Hydroxides of metals of copper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/325—Calcium, strontium or barium phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to one kind spray painting material, and in particular to a kind of spray painting material of strong antibacterial, belongs to paint field.The spray painting material includes the component of following parts by weight：Acrylic resin：30 50 parts, hydroxyapatite：25 parts, nano titanium oxide：5 10 parts, diopside：58 parts, polymerized tung oil：24 parts, persimmon tannin：5 10 parts, other auxiliary agents：10 12 parts.Copper silicon modification is carried out to acrylic resin in present invention spray painting material, cuprous oxide can be connected on acrylic resin with chemical bond, there is excellent anti-microbial property so as to make obtained acrylic resin；Nano titanium oxide is pre-processed in present invention spray painting material, and adds diopside and polymerized tung oil, when can be impacted obtained spray painting material, more micro-cracks and plastic deformation can be produced, so as to absorb more impact energys, toughness also improves therewith.
Description
Invention field
The present invention relates to one kind spray painting material, and in particular to a kind of spray painting material of strong antibacterial, belongs to paint field.
Background technology
The general composition of paint includes：Four parts such as film forming matter, filler (color stuffing), solvent, auxiliary agent form.China applies
Expect that boundary is more authoritative《Coating process》What one book was defined as:" coating is a kind of material, and this material can be with different
Construction technology is coated in object surface, is formed and adhered to firmly, with some strength, continuous solid film.The film so formed
It is generally called film, also known as paint film or coating.”
Paint has the effect such as anti-corrosion and waterproof, grease proofing, chemicals-resistant, fast light, heatproof.Object is exposed among air, by
To the erosion of oxygen, moisture etc., the breakoff phenomenons such as corrosion of metal, foxiness, cement weathering are caused.It is coated with object surface
Material, layer protecting film is formed, can prevent or postpone the occurrence and development of these breakoff phenomenons, make the service life of various materials
Extend.So protective effect is a main function of coating.
In practical application field, due to paint nature and its contained composition, therefore its body to the mankind is good for
Health has great threat.
The content of the invention
The present invention is in view of the above-mentioned problems existing in the prior art, it is proposed that the small spray painting material of a kind of strong antibacterial, pollution
Material.
The purpose of the present invention is realized by following technical solution：One kind spray painting material, the spray painting material include as follows
The component of parts by weight：Acrylic resin：30-50 parts, hydroxyapatite：2-5 parts, nano titanium oxide：5-10 parts, saturating brightness
Stone：5-8 parts, polymerized tung oil：2-4 parts, persimmon tannin：5-10 parts, other auxiliary agents：10-12 parts.
Present invention spray painting material is acted on by ligand exchange by adding persimmon tannin, can separating metal ions so that
To spray painting material there is fungistatic effect；Hydroxyapatite and nano titanium oxide are added simultaneously, the spray painting material enabled to
Expect that anti-microbial property is excellent.
Persimmon tannin, is a kind of natural polyphenol family macromolecule compound being widely present in immature persimmon fruit, and polyphenol leans on
After nearly protein molecule surface, hydrophobic strip is initially entered, multiple spot then, which occurs, with hydrogen bond is combined, and makes the protein in organism
Solidification, causes microorganism not survive and dead；Meanwhile persimmon tannin has good film forming, the present invention is in the material that paints
Persimmon tannin is added, one layer of good antibacterial protecting film can be formed, obtain more excellent antibacterial effect.
In the present invention paints material, the particle diameter of the nano titanium oxide is 10-20nm.
Preferably, the nano titanium oxide in present invention spray painting material is by the nano titanium oxide of pretreatment, institute
Pretreatment is stated to specifically comprise the following steps：Weigh and heat diethylene glycol (DEG) and active additive, then add nano titanium oxide, stir
Mix and filter, wash after reacting, drying, being classified.
In the present invention paints material, in the pretreatment of the titanium dioxide, heating-up temperature is 80-90 DEG C, diethylene glycol (DEG)
Content is the 45-55% of nano titanium oxide quality, and the content of active additive is the 2-3% of nano titanium oxide quality.
Because nano titanium oxide has extremely strong activity, them are made to be easy to reunite together so as to form some weak companies
The larger-size aggregate in border face, the practical application effect of nano particle can be substantially reduced or even eliminate, simultaneously because receiving
Rice titanium dioxide surface is hydrophilic and oleophobic, is difficult in organic polymer resin dispersed, and gap occurs on interface, works as air
In moisture enter in space and will cause the degrading of interface high polymer, brittle, cause obtained spray painting hydraulic performance decline.To receiving
After rice titanium dioxide is pre-processed, macromolecule resin can be made to increase with intermetallic binding site, adhesion increase；Meanwhile with
Particle size to attenuate, particle specific surface area increase, between particle and matrix contact area increase, it is obtained spray painting material by
During impact, more micro-cracks and plastic deformation can be produced, so as to absorb more impact energys, toughness also improves therewith.
In the present invention paints material, the acrylic resin is to be modified the acrylic resin pre-processed, institute by copper silicon
Pretreatment is stated to specifically comprise the following steps：By nano cupric oxide, acrylic resin, organosilicon, azodiisobutyronitrile at 80-85 DEG C
Carry out reacting acrylic resin modified, then silanization treatment is carried out to acrylic resin modified with silane coupler.As excellent
Choosing, the content of organosilicon are the 5-8% of acrylic resin content, and the content of nano cupric oxide is the 0.9- of acrylic resin content
1.2%, the content of azodiisobutyronitrile is the 0.6-0.9% of acrylic resin content.
Acrylic resin is because of the changeability of group on the special light of its carbon carbon backbone chain, heat, chemical stability and side chain so that
Acrylic resin light resistance, heat resistance, corrosion resistance, resistance to acids and bases, stain resistant etc. have uniqueness advantage, but due to
Acrylic resin sheet is as linear structure, therefore its low temperature easily becomes fragile, the easy after tack of high temperature, and the present invention carries out silicon to acrylic resin
Copper is modified pretreatment, can be connected to cuprous oxide on acrylic resin with chemical bond, so as to make obtained acrylic resin
With excellent anti-microbial property.
In a kind of above-mentioned spray painting material, by adding diopside, diopside is in temperature-rise period, no crystal transfer, nothing
Burning is lost, hot expansibility is good, can quickly promote the sintering of base substrate, serve the effect of hardening agent, obtained so as to strengthen
The intensity of spray painting material.In addition, in a kind of above-mentioned spray painting material, by adding polymerized tung oil, the main composition of tung oil is paulownia
Triglyceride oleate, i.e. 18 carbon conjugated trienes -9,11,13- acid glyceryl esters.Eleostearic acid glyceryl ester alkali, acid effect under,
Hydrolysis turns into the unsaturated eleostearic acid containing 3 conjugated double bonds.And the conjugated double bond in unsaturated eleostearic acid molecular structure is neighbouring
Hydrogen on carbon atom, in atmosphere under oxygen effect, hydrogen abstraction reaction occurring, the hydroperoxides of generation, which decompose, produces free radical,
Initiated polymerization, the product of generation have the features such as good film-forming property, fast drying, film are tough and tensile, water-fast, fast light, alkaline-resisting.This hair
Bright to use polymerized tung oil, the preparation method of the polymerized tung oil comprises the following steps：Tung oil is warming up to 45-48 DEG C, adds nitre
Hydrochlorate, normal temperature is down to after reacting 2-2.5h, adjusts pH to 7-7.2.The addition of the nitrate is the 58- of polymerized tung oil quality
62%.In the present invention, by adding polymerized tung oil, paint film adhesion can not only be increased, while strengthen the anti-impact of lacquered surface
Power, case hardness and glossiness are hit, while polymerized tung oil can make the acrylic resin and inorganic material nanometer in paint ingredient
The coupled effect increase of titanium dioxide, diopside, compatibility enhancing.
In a kind of above-mentioned spray painting material, the hydroxyapatite is load titanium zinc hydroxyapatite.Hydroxyapatite has
Good biological adsorption and ion exchangeable, and the zinc ion carried on titanium zinc hydroxyapatite is consolidated by ion exchange
Material surface is scheduled on, in the starting stage, the burst size of zinc ion is larger, killing bacterium that can be rapidly and efficiently, then zinc ion
Release reached balance, into the process slowly discharged, the release of holding zinc ion that can be permanently effective, remain permanent anti-
Bacterium property.
In a kind of above-mentioned spray painting material, other described auxiliary agents include coalescents, dispersant, curing agent and diluent.
The curing agent is the one or more in MDA, diethylenetriamine, dicyanodiamine；The diluent is methyl
One or both of methyl acrylate, styrene.
It is another object of the present invention to provide a kind of preparation method of above-mentioned spray painting material, the preparation method includes
Following steps：
Pretreatment：Acrylic resin is pre-processed；Nano titanium oxide is pre-processed；
It is scattered at a high speed：Aforesaid propylene acid resin, n-butanol, nano titanium oxide, persimmon tannin, curing agent, diluent are entered
Row is scattered at a high speed, and the material that must paint is filtered after grinding.
Compared with prior art, the invention has the advantages that：
1st, copper silicon modification is carried out to acrylic resin in present invention spray painting material, can be by cuprous oxide with chemical bond
It is connected on acrylic resin, there is excellent anti-microbial property so as to make obtained acrylic resin；
2nd, nano titanium oxide is pre-processed in present invention spray painting material, and adds diopside and polymerized tung oil, energy
When spray painting material is impacted made from making, more micro-cracks and plastic deformation can be produced, so as to absorb more impact energys,
Toughness also improves therewith；
3rd, present invention spray painting material by the rational composition of compatibility and uses specific preparation method, makes obtained spray painting material
Expect that strong antibacterial, pollution are small.
Embodiment
It is the specific embodiment of the present invention below, technical scheme is further described, but the present invention is simultaneously
It is not limited to these embodiments.
Embodiment 1
Acrylic resin pre-processes：Nano cupric oxide, acrylic resin, organosilicon, azodiisobutyronitrile are entered at 80 DEG C
Row reacts acrylic resin modified, then carries out silanization treatment to acrylic resin modified with silane coupler；Wherein, it is organic
The content of silicon is the 5% of acrylic resin content, and the content of nano cupric oxide is the 0.9% of acrylic resin content, azo two
The content of isobutyronitrile is the 0.6% of acrylic resin content；
Nano titanium oxide pre-processes：Heat diethylene glycol (DEG) and active additive and control at 80 DEG C, add nanometer titanium dioxide
Titanium, filter after stirring reaction, washing, dry, classification；Wherein, the content of diethylene glycol (DEG) is the 45% of nano titanium oxide quality, living
Property additive content be nano titanium oxide quality 2%；
It is scattered at a high speed：Acrylic resin, n-butanol, nano titanium oxide, persimmon tannin, curing agent, diluent are carried out high
Speed is scattered, and the material that must paint is filtered after grinding, wherein, acrylic resin：30 parts, hydroxyapatite：2 parts, nano titanium oxide：
5 parts, polymerized tung oil：2 parts, persimmon tannin：5 parts, diopside：5 parts, coalescents, dispersant, curing agent and diluent：10 parts.
Embodiment 2
Nano titanium oxide pre-processes：Heat diethylene glycol (DEG) and active additive and control at 82 DEG C, add nanometer titanium dioxide
Titanium, filter after stirring reaction, washing, dry, classification；Wherein, the content of diethylene glycol (DEG) is the 48% of nano titanium oxide quality, living
Property additive content be nano titanium oxide quality 2.2%；
It is scattered at a high speed：By not pretreated acrylic resin, n-butanol, nano titanium oxide, persimmon tannin, curing agent,
Diluent disperse at a high speed, and the material that must paint is filtered after grinding, wherein, acrylic resin：35 parts, hydroxyapatite：3 parts,
Nano titanium oxide:6 parts, polymerized tung oil：2 parts, 6 parts of persimmon tannin, diopside：5 parts, coalescents, dispersant, curing agent and dilute
Release agent：10 parts.
Embodiment 3
Acrylic resin pre-processes：Nano cupric oxide, acrylic resin, organosilicon, azodiisobutyronitrile are entered at 83 DEG C
Row reacts acrylic resin modified, then carries out silanization treatment to acrylic resin modified with silane coupler；Wherein, it is organic
The content of silicon is the 6.5% of acrylic resin content, and the content of nano cupric oxide is the 1.0% of acrylic resin content, azo
The content of bis-isobutyronitrile is the 0.75% of acrylic resin content；
Nano titanium oxide pre-processes：Heat diethylene glycol (DEG) and active additive and control at 85 DEG C, add nanometer titanium dioxide
Titanium, filter after stirring reaction, washing, dry, classification；Wherein, the content of diethylene glycol (DEG) is the 50% of nano titanium oxide quality, living
Property additive content be nano titanium oxide quality 2.5%；
It is scattered at a high speed：Acrylic resin, n-butanol, nano titanium oxide, persimmon tannin, curing agent, diluent are carried out high
Speed is scattered, and the material that must paint is filtered after grinding, wherein, acrylic resin：40 parts, hydroxyapatite：3 parts, nano titanium oxide:
7 parts, polymerized tung oil：3 parts, 8 parts of persimmon tannin, diopside：7 parts, coalescents, dispersant, curing agent and diluent：11 parts.
Embodiment 4
Acrylic resin pre-processes：Nano cupric oxide, acrylic resin, organosilicon, azodiisobutyronitrile are entered at 84 DEG C
Row reacts acrylic resin modified, then carries out silanization treatment to acrylic resin modified with silane coupler；Wherein, it is organic
The content of silicon is the 7% of acrylic resin content, and the content of nano cupric oxide is the 1.1% of acrylic resin content, azo two
The content of isobutyronitrile is the 0.85% of acrylic resin content；
It is scattered at a high speed：By acrylic resin, n-butanol, not pretreated nano titanium oxide, persimmon tannin, curing agent,
Diluent disperse at a high speed, and the material that must paint is filtered after grinding, wherein, acrylic resin：45 parts, hydroxyapatite：4 parts,
Nano titanium oxide:8 parts, polymerized tung oil：4 parts, 9 parts of persimmon tannin, diopside：7 parts, coalescents, dispersant, curing agent and dilute
Release agent：11 parts.
Embodiment 5
Acrylic resin pre-processes：Nano cupric oxide, acrylic resin, organosilicon, azodiisobutyronitrile are entered at 85 DEG C
Row reacts acrylic resin modified, then carries out silanization treatment to acrylic resin modified with silane coupler；Wherein, it is organic
The content of silicon is the 8% of acrylic resin content, and the content of nano cupric oxide is the 1.2% of acrylic resin content, azo two
The content of isobutyronitrile is the 0.9% of acrylic resin content；
Nano titanium oxide pre-processes：Heat diethylene glycol (DEG) and active additive and control at 90 DEG C, add nanometer titanium dioxide
Titanium, filter after stirring reaction, washing, dry, classification；Wherein, the content of diethylene glycol (DEG) is the 55% of nano titanium oxide quality, living
Property additive content be nano titanium oxide quality 3%；
It is scattered at a high speed：Acrylic resin, n-butanol, nano titanium oxide, persimmon tannin, curing agent, diluent are carried out high
Speed is scattered, and the material that must paint is filtered after grinding, wherein, acrylic resin：50 parts, hydroxyapatite：5 parts, nano titanium oxide:
10 parts, polymerized tung oil：4 parts, 10 parts of persimmon tannin, diopside：8 parts, coalescents, dispersant, curing agent and diluent：12 parts.
Comparative example 1
With differing only in for embodiment 1, the comparative example uses commercial spray lacquer material, and other are same as Example 1, herein
Repeat no more.
Comparative example 2
With differing only in for embodiment 1, persimmon tannin is not contained in comparative example spray painting material, other and the phase of embodiment 1
Together, here is omitted.
Comparative example 3
With differing only in for embodiment 1, nano titanium oxide is not contained in comparative example spray painting material, other and implementation
Example 1 is identical, and here is omitted.
Comparative example 4
With differing only in for embodiment 1, hydroxyapatite is not contained in comparative example spray painting material, other and embodiment
1 is identical, and here is omitted.
Comparative example 5
With differing only in for embodiment 1, polymerized tung oil is not contained in comparative example spray painting material, other and embodiment 1
Identical, here is omitted.
Comparative example 6
With differing only in for embodiment 1, diopside is not contained in comparative example spray painting material, other and the phase of embodiment 1
Together, here is omitted.
Spray painting material in above-described embodiment 1-5 and comparative example 1-6 is subjected to performance detection, testing result is as shown in table 1.
To sum up, copper silicon modification is carried out to acrylic resin in present invention spray painting material, cuprous oxide can changed
Key connection is learned on acrylic resin, there is excellent anti-microbial property so as to make obtained acrylic resin；Meanwhile present invention spray
Nano titanium oxide is pre-processed in paint material, and adds polymerized tung oil and diopside, can make obtained spray painting material by
To during impact, more micro-cracks and plastic deformation can be produced, so as to absorb more impact energys, toughness also improves therewith；
Specific embodiment described herein is only to spirit explanation for example of the invention.Technology belonging to the present invention is led
The technical staff in domain can be made various modifications or supplement to described specific embodiment or be substituted using similar mode, but simultaneously
Do not deviate by the spirit of the present invention or surmount scope defined in appended claims.
It is skilled to this area although having been made a detailed description to the present invention and being cited some specific embodiments
For technical staff, as long as it is obvious that can make various changes or correct without departing from the spirit and scope of the present invention.
Claims (10)
1. one kind spray painting material, it is characterised in that the spray painting material includes the component of following parts by weight：Acrylic resin：
30-50 parts, hydroxyapatite：2-5 parts, nano titanium oxide：5-10 parts, polymerized tung oil：2-4 parts, persimmon tannin：5-10 parts, thoroughly
Pyroxene：5-8 parts, other auxiliary agents：10-12 parts.
2. a kind of spray painting material according to claim 1, it is characterised in that the particle diameter of the nano titanium oxide is 10-
20nm。
3. a kind of spray painting material according to claim 1 or 2, it is characterised in that the nano titanium oxide is by pre-
The nano titanium oxide of processing.
A kind of 4. spray painting material according to claim 2, it is characterised in that the pretreatment tool of described nano titanium oxide
Body includes：Weigh and heat diethylene glycol (DEG) and active additive, then add nano titanium oxide, filter, wash after stirring reaction,
Dry, classification.
5. a kind of spray painting material according to claim 4, it is characterised in that heating-up temperature is 80-90 DEG C, and diethylene glycol (DEG) contains
It is the 2-3% of nano titanium oxide quality to measure as the 45-55% of nano titanium oxide quality, the content of active additive.
6. a kind of spray painting material according to claim 1, it is characterised in that the acrylic resin is to be modified by copper silicon
The acrylic resin of pretreatment.
A kind of 7. spray painting material according to claim 6, it is characterised in that the silicone modified pretreatment specifically include as
Lower step：Nano cupric oxide, acrylic resin, organosilicon, azodiisobutyronitrile are carried out at 80-85 DEG C to react to obtain modified propylene
Acid resin, then carry out silanization treatment to acrylic resin modified with silane coupler.
8. a kind of spray painting material according to claim 7, it is characterised in that the content of the organosilicon is acrylic resin
The 5-8% of content, the content of nano cupric oxide are the 0.9-1.2% of acrylic resin content, and the content of azodiisobutyronitrile is
The 0.6-0.9% of acrylic resin content.
9. a kind of spray painting material according to claim 1, it is characterised in that the preparation method of the polymerized tung oil is included such as
Lower step：Tung oil is warming up to 45-48 DEG C, adds nitrate, normal temperature is down to after reacting 2-2.5h, adjusts pH to 7-7.2.
10. a kind of spray painting material according to claim 1, it is characterised in that the hydroxyapatite is load titanium zinc hydroxyl
Apatite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711102932.7A CN107892844A (en) | 2017-11-10 | 2017-11-10 | One kind spray painting material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711102932.7A CN107892844A (en) | 2017-11-10 | 2017-11-10 | One kind spray painting material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107892844A true CN107892844A (en) | 2018-04-10 |
Family
ID=61804914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711102932.7A Pending CN107892844A (en) | 2017-11-10 | 2017-11-10 | One kind spray painting material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107892844A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110938302A (en) * | 2019-10-23 | 2020-03-31 | 清远高新华园科技协同创新研究院有限公司 | High-molecular light-reflecting functional material for automobile, preparation method and production equipment |
| WO2024142937A1 (en) * | 2022-12-28 | 2024-07-04 | マクセル株式会社 | Composition, coating, water-resistant base material, and method for producing water-resistant base material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103805007A (en) * | 2013-10-18 | 2014-05-21 | 中山市大田汽车护理用品有限公司 | Benzene-free spray paint and preparation method thereof |
-
2017
- 2017-11-10 CN CN201711102932.7A patent/CN107892844A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103805007A (en) * | 2013-10-18 | 2014-05-21 | 中山市大田汽车护理用品有限公司 | Benzene-free spray paint and preparation method thereof |
Non-Patent Citations (5)
| Title |
|---|
| 朱永平: "《陶瓷砖生产技术》", 28 February 2009, 天津大学出版社 * |
| 王勇等: ""天然高分子柿单宁的研究与应用"", 《材料导报》 * |
| 路国忠等: ""羟基磷灰石抗菌剂在涂料中的应用"", 《涂料工业》 * |
| 鲁黎等: ""聚合桐油—天然生漆改性涂料及其性能的研究"", 《湖北林业科技》 * |
| 黄静等: ""防污闪氟碳涂料的制备及应用研究"", 《涂料工业》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110938302A (en) * | 2019-10-23 | 2020-03-31 | 清远高新华园科技协同创新研究院有限公司 | High-molecular light-reflecting functional material for automobile, preparation method and production equipment |
| WO2024142937A1 (en) * | 2022-12-28 | 2024-07-04 | マクセル株式会社 | Composition, coating, water-resistant base material, and method for producing water-resistant base material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101775245B (en) | Multifunctional putty | |
| CA2939966C (en) | Anticorrosive coating composition | |
| CN101812156B (en) | Water-base ambient crosslinking acrylate wood paint resin and preparation method thereof | |
| CN1927968A (en) | Water industrial paint based on organosilicon acrylic acid epoxy ester water dispersion and preparation method thereof | |
| TWI301503B (en) | ||
| CN104178013A (en) | Environment-friendly water-based nano varnish and preparation method | |
| CN109517516B (en) | Certified bentonite modified waterborne polyurethane coating and preparation method thereof | |
| EP2336257A4 (en) | Coating composition, method for producing same, coating film and underwater structure | |
| CN107892844A (en) | One kind spray painting material | |
| CN104178012A (en) | High-property environment-friendly water-based activation nano metallic paint and preparation method | |
| EP1897922B1 (en) | Coating composition for a metal, and metal material having a coating of such coating composition | |
| CN1198180A (en) | Electrodeposition coating composition having electrodeposition potentiality and process for electrodeposition coating | |
| CN107974141B (en) | Nano-material modified fluorocarbon resin stone waterproof coating and preparation method thereof | |
| CN103642305A (en) | High-bonding printing ink and preparation method thereof | |
| CN110204993B (en) | Preparation method and application of carbon nanotube assembled capsaicin repellent biological antifouling marine paint | |
| CN1159399C (en) | Water-based acrylic acid modified alcoholic acid amino baking paint | |
| CN112831244A (en) | Color coating paint and preparation method of color coated sheet applying color coating paint | |
| CN115612330B (en) | Preparation and application of mercapto-modified nano silver particle dispersion liquid | |
| CN1902288A (en) | Paint composition improved far-infrared radiation, antibiosis and solvent resistance, and precoated metal sheet coated the same | |
| CN106280954A (en) | A kind of aqueous polyurethane coating of high rigidity and preparation method thereof | |
| CN114540804B (en) | Amino modified polysiloxane-based chromium-free passivation solution and preparation method thereof | |
| CN1872923A (en) | Green environmental protection polyisoprene in high elasticity | |
| CN113698823B (en) | Water-based coating special for household appliance plastics and preparation method thereof | |
| CN101403126A (en) | Surface processing technique for metal product | |
| Mao et al. | Advanced Marine Antifouling Hydrogels Based on 7-Amino-4-methylcoumarin Fluorescence Driven by Rare-Earth Phosphorescence |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180410 |