CN107892767A - A kind of antirust bag and preparation method thereof - Google Patents
A kind of antirust bag and preparation method thereof Download PDFInfo
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- CN107892767A CN107892767A CN201711390854.5A CN201711390854A CN107892767A CN 107892767 A CN107892767 A CN 107892767A CN 201711390854 A CN201711390854 A CN 201711390854A CN 107892767 A CN107892767 A CN 107892767A
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- agent
- antirust
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- antirust bag
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/267—Magnesium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The invention discloses a kind of antirust bag, include the component of following parts by weight：60 ~ 80 parts of plastics, 10 ~ 20 parts of antirust agent, 5 ~ 10 parts of modifying agent, 1 ~ 5 part of coupling agent, 1 ~ 5 part of plasticizer, 0.1 ~ 1 part of organo-silicic oil；1 ~ 3 part of 10 ~ 20 parts of halogen-free flame retardants and anti-blushing agent.The invention also discloses a kind of preparation method of antirust bag.A kind of antirust bag provided by the invention and preparation method thereof; modifying agent includes the setting of water-repelling agent and 1 ~ 3 part of anti-blushing agent; make the antirust bag of the present invention there is hydrophobic waterproof function; prevent the moisture in marine environment and salinity from entering antirust bag; the moisture and salinity for preventing the external world react with vapour phase inhibitor; so as to reduce the antirust function of vapour phase inhibitor, therefore the antirust bag of the present invention is adapted to high humidity hypersaline environment, the corrosion protection time of non-ferrous metal is 5 ~ 7 years.
Description
Technical field
The present invention relates to a kind of antirust bag and preparation method thereof, belong to High Polymer Material ＆ Porcessing technical field.
Background technology
Metal processing piece is during production and processing and transport, it is easy to gets rusty, this just needs to use antirust bag, prevents
Rust bag has good plasticity, can overcome the insufficient weakness of traditional antirust product protection；With the good transparency；Have
The product protection time of effect can reach 1-3.Contain the vapour phase inhibitor for playing anti-rust action in antirust bag, vapour phase inhibitor
Volatility increase with the rise of temperature, it is necessary to it is specifically intended that：Vapour phase inhibitor is more than 75% environment in relative humidity
In, its corrosion mitigating effect will reduce, and how prevent non-ferrous metal from transporting（Particularly transport by sea）During corrosion, be at present urgently
The technical problem of solution.
The content of the invention
The technical problem to be solved by the invention is to provide one kind can prevent non-ferrous metal from transporting（Particularly transport by sea）
During occur corrosion, the protection non-ferrous metal time is 5 ~ 7 years antirust bag and preparation method thereof.
In order to solve the above technical problems, the technical solution adopted by the present invention is：
A kind of antirust bag, include the component of following parts by weight：60 ~ 80 parts of plastics, 10 ~ 20 parts of antirust agent, 5 ~ 10 parts of modifying agent are even
Join 1 ~ 5 part of agent, 1 ~ 5 part of plasticizer, 0.1 ~ 1 part of organo-silicic oil；1 ~ 3 part of 10 ~ 20 parts of halogen-free flame retardants and anti-blushing agent.
The plastics include one or more of in polyethylene, polypropylene, polyvinyl chloride, polystyrene and polyurethane.
The antirust agent includes nitrogen heterocyclic ring class chemicals, long-chain carboxylic acid and inorganic salts, and the ratio of three is 1：（1~2）：
（0.1~0.5）.
The nitrogen heterocyclic ring class chemicals include benzotriazole；The long-chain carboxylic acid includes lauric acid/dodecanoic acid, tridecanoic acid and ten
One or more in tetracid；The inorganic salts include calcium carbonate and/or magnesium carbonate.
The modifying agent includes water-repelling agent, and the water-repelling agent includes long chain alkane or polyoxyethylene.
The anti-blushing agent includes carboxymethyl cellulose or hydroxypropyl methyl cellulose.
The coupling agent is silane coupler.
The halogen-free flame retardants includes phosphate compound；Whiteness >=95 of the phosphate compound, decompose temperature
>=350 DEG C of degree.
A kind of preparation method of antirust bag, comprises the following steps：
S01, batch mixing：Long-chain carboxylic acid is heated at least 70 °, adds nitrogen heterocyclic ring class chemicals and inorganic salts, stirring is allowed to
All dissolvings, then add plastics, modifying agent, coupling agent, plasticizer, organo-silicic oil, halogen-free flame retardants and anti-blushing agent,
Stirring makes all to be well mixed to obtain compound；
S02, above-mentioned compound is added in plastic sheet machine, is melted, extruded, be molded, cool down, handle, wind, cut out successively
The process cut, packed.
The nitrogen heterocyclic ring class chemicals and inorganic salts can be added repeatedly in batches.
A kind of antirust bag provided by the invention and preparation method thereof, modifying agent include water-repelling agent and 1 ~ 3 part of anti-blushing agent
Set, make the antirust bag of the present invention there is hydrophobic waterproof function, prevent the moisture in marine environment and salinity from entering antirust bag, prevent
Only extraneous moisture and salinity react with vapour phase inhibitor, and so as to reduce the antirust function of vapour phase inhibitor, therefore the present invention's is anti-
The bag that becomes rusty is adapted to high humidity hypersaline environment, the corrosion protection time of non-ferrous metal is 5 ~ 7 years.
Embodiment
The present invention is further described below.
Embodiment 1
A kind of antirust bag, include the component of following parts by weight：60 parts of plastics, 10 parts of antirust agent, 5 parts of modifying agent, 1 part of coupling agent,
1 part of plasticizer, 0.1 part of organo-silicic oil；1 part of 10 parts of halogen-free flame retardants and anti-blushing agent.
The plastics include one or more of in polyethylene, polypropylene, polyvinyl chloride, polystyrene and polyurethane.
The antirust agent includes nitrogen heterocyclic ring class chemicals, long-chain carboxylic acid and inorganic salts, and the ratio of three is 1：1：0.1.
The nitrogen heterocyclic ring class chemicals include benzotriazole；The long-chain carboxylic acid includes lauric acid/dodecanoic acid, tridecanoic acid and ten
One or more in tetracid；The inorganic salts include calcium carbonate and/or magnesium carbonate.
The modifying agent includes water-repelling agent, and the water-repelling agent includes long chain alkane or polyoxyethylene.
The anti-blushing agent includes carboxymethyl cellulose or hydroxypropyl methyl cellulose.
The coupling agent is silane coupler.
The halogen-free flame retardants includes phosphate compound；Whiteness >=95 of the phosphate compound, decompose temperature
>=350 DEG C of degree.
A kind of preparation method of antirust bag, comprises the following steps：
S01, batch mixing：Long-chain carboxylic acid is heated at least 70 °, adds nitrogen heterocyclic ring class chemicals and inorganic salts, stirring is allowed to
All dissolvings, then add plastics, modifying agent, coupling agent, plasticizer, organo-silicic oil, halogen-free flame retardants and anti-blushing agent,
Stirring makes all to be well mixed to obtain compound；
S02, above-mentioned compound is added in plastic sheet machine, is melted, extruded, be molded, cool down, handle, wind, cut out successively
The process cut, packed.
The nitrogen heterocyclic ring class chemicals and inorganic salts can be added repeatedly in batches.
Embodiment 2
The present embodiment differs only in embodiment 1：A kind of antirust bag, include the component of following parts by weight：80 parts of plastics, prevent
20 parts of agent of rust, 10 parts of modifying agent, 5 parts of coupling agent, 5 parts of plasticizer, 1 part of organo-silicic oil；20 parts of halogen-free flame retardants and protection against the tide
3 parts of agent.
The antirust agent includes nitrogen heterocyclic ring class chemicals, long-chain carboxylic acid and inorganic salts, and the ratio of three is 1： 2：
0.5。
Described above is only the preferred embodiment of the present invention, it should be pointed out that：For the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (10)
- A kind of 1. antirust bag, it is characterised in that：Include the component of following parts by weight：60 ~ 80 parts of plastics, 10 ~ 20 parts of antirust agent, change 5 ~ 10 parts of agent of property, 1 ~ 5 part of coupling agent, 1 ~ 5 part of plasticizer, 0.1 ~ 1 part of organo-silicic oil；10 ~ 20 parts of halogen-free flame retardants and anti- Damp 1 ~ 3 part of agent.
- A kind of 2. antirust bag according to claim 1, it is characterised in that：The plastics include polyethylene, polypropylene, polychlorostyrene It is one or more of in ethene, polystyrene and polyurethane.
- A kind of 3. antirust bag according to claim 1, it is characterised in that：The antirust agent includes nitrogen heterocyclic ring class chemistry Thing, long-chain carboxylic acid and inorganic salts, the ratio of three is 1：（1~2）：（0.1~0.5）.
- A kind of 4. antirust bag according to claim 3, it is characterised in that：The nitrogen heterocyclic ring class chemicals include benzene a pair of horses going side by side three Nitrogen azoles；The long-chain carboxylic acid includes the one or more in lauric acid/dodecanoic acid, tridecanoic acid and tetradecylic acid；The inorganic salts include calcium carbonate And/or magnesium carbonate.
- A kind of 5. antirust bag according to claim 1, it is characterised in that：The modifying agent includes water-repelling agent, described hydrophobic Agent includes long chain alkane or polyoxyethylene.
- A kind of 6. antirust bag according to claim 1, it is characterised in that：The anti-blushing agent includes carboxymethyl cellulose or hydroxyl Propyl methocel.
- A kind of 7. antirust bag according to claim 1, it is characterised in that：The coupling agent is silane coupler.
- A kind of 8. antirust bag according to claim 1, it is characterised in that：The halogen-free flame retardants includes phosphoric acid salt chemical combination Thing；Whiteness >=95 of the phosphate compound, decomposition temperature >=350 DEG C.
- A kind of 9. preparation method of antirust bag according to any one of claim 1 ~ 8, it is characterised in that：Including following step Suddenly：S01, batch mixing：Long-chain carboxylic acid is heated at least 70 °, adds nitrogen heterocyclic ring class chemicals and inorganic salts, stirring is allowed to All dissolvings, then add plastics, modifying agent, coupling agent, plasticizer, organo-silicic oil, halogen-free flame retardants and anti-blushing agent, Stirring makes all to be well mixed to obtain compound；S02, above-mentioned compound is added in plastic sheet machine, is melted, extruded, be molded, cool down, handle, wind, cut out successively The process cut, packed.
- A kind of 10. preparation method of antirust bag according to claim 9, it is characterised in that：The nitrogen heterocyclic ring class chemistry Thing and inorganic salts can be added repeatedly in batches.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711390854.5A CN107892767A (en) | 2017-12-21 | 2017-12-21 | A kind of antirust bag and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711390854.5A CN107892767A (en) | 2017-12-21 | 2017-12-21 | A kind of antirust bag and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107892767A true CN107892767A (en) | 2018-04-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711390854.5A Pending CN107892767A (en) | 2017-12-21 | 2017-12-21 | A kind of antirust bag and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1796449A (en) * | 2004-12-24 | 2006-07-05 | 李延明 | Gas phase anticorrosive thin film of thermal contraction |
| CN101323956A (en) * | 2007-06-14 | 2008-12-17 | 熊小勇 | Composite gas-phase anti-rust master batch and preparing process thereof |
| CN103992540A (en) * | 2014-04-25 | 2014-08-20 | 烟台恒迪克能源科技有限公司 | Vapor phase antirust blown polyethylene film and making method thereof |
| CN104497383A (en) * | 2014-12-16 | 2015-04-08 | 青岛海芬海洋生物科技有限公司 | Anti-electrostatic rustproof film |
-
2017
- 2017-12-21 CN CN201711390854.5A patent/CN107892767A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1796449A (en) * | 2004-12-24 | 2006-07-05 | 李延明 | Gas phase anticorrosive thin film of thermal contraction |
| CN101323956A (en) * | 2007-06-14 | 2008-12-17 | 熊小勇 | Composite gas-phase anti-rust master batch and preparing process thereof |
| CN103992540A (en) * | 2014-04-25 | 2014-08-20 | 烟台恒迪克能源科技有限公司 | Vapor phase antirust blown polyethylene film and making method thereof |
| CN104497383A (en) * | 2014-12-16 | 2015-04-08 | 青岛海芬海洋生物科技有限公司 | Anti-electrostatic rustproof film |
Non-Patent Citations (2)
| Title |
|---|
| 乐志强: "《无机精细化学品手册》", 31 January 2001 * |
| 周祥兴: "《包装用塑料制品的生产配方和生产工艺》", 31 December 2010 * |
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Application publication date: 20180410 |
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