CN107880741A - A kind of method for preparing waterborne epoxy acrylate coating - Google Patents
A kind of method for preparing waterborne epoxy acrylate coating Download PDFInfo
- Publication number
- CN107880741A CN107880741A CN201711306478.7A CN201711306478A CN107880741A CN 107880741 A CN107880741 A CN 107880741A CN 201711306478 A CN201711306478 A CN 201711306478A CN 107880741 A CN107880741 A CN 107880741A
- Authority
- CN
- China
- Prior art keywords
- epoxy acrylate
- epoxy resin
- acrylate coating
- mixed solution
- preparing waterborne
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
- C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
- C08G59/1461—Unsaturated monoacids
- C08G59/1466—Acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Emergency Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Epoxy Resins (AREA)
Abstract
The invention discloses a kind of method for preparing waterborne epoxy acrylate coating, epoxy acrylate is by epoxy resin open loop, monoacid unsaturated with acrylic acid etc. carries out the product obtained by esterification, and the crosslinking agents such as styrene are added in epoxy acrylate, just a kind of new material system, i.e. epoxy acrylate coating are formd.Test result indicates that, the coating of synthesis can integrate the features such as high-modulus, high intensity, chemical-resistant resistance and gloss of excellent anticorrosive property and acrylic resin, richness, good weatherability of epoxy resin, can solve the problem that the corrosion and protection application technology problem under harsh conditions in industrial environment.
Description
Technical field：
The present invention relates to materials synthesis field, specifically a kind of method for preparing waterborne epoxy acrylate coating.
Background technology：
World's nuclear technology increases sharply in by leaps and bounds development and application, the nuclear power station utilization of capacity, and the peaceful utilization of atomic energy obtains
Common recognition.China's nuclear technology is quickly grown, and is referred to as China to the safe utilization night of nuclear energy and common issue that the world is faced.
Easily by the infringement and pollution of radioactive element, these places need to be with resistance to for device facility in nuclear reactor and nuclear power station
The decoration protection of nuclear radiation coating.Nuclear radiation-resistant coating formed coating should be capable of withstanding nuclear radiation, easily remove pollution, have it is excellent
Corrosion resistance, absorb nuclear radiation, prevent radioactive source ambient contamination etc..
Epocryl property and performance are because of its constitutive material, such as epoxy resin, acrylic acid and reactivity dilution
The species such as agent it is different and different.But generally there are following features：
(1) vinyl that curing rate is located at end group is the very high unsaturated group of an activity.Can be with unsaturated monomer
It is quick occur freely to gather with.It is numerical value rapid curing, obtains the good monomer ethylene base ester resin copolymer of decay resistance
Or homopolymer.
(2) hydrolytic resistance methyl can shield ester bond, improve ester bond hydrolytic resistance.
(3) chemical resistance of chemicals-resistant corrosivity thermosets depends primarily on polymer chemistry group in media as well
Inertia degree and crosslink density.It is well known that the ester bond in polymer be easiest to hydrolyze hydroxyl easily with water occur association and
Suction-operated, this just more promotes the generation of ester linkage hydrolyzing reaction.Therefore, reducing ester bond and hydroxy radical content will reduce or delay ester
The hydrolysis of key, improve a series of chemical resistances such as water-resistance, particularly alkali resistance.But hydroxyl it is existing another
Effect, it is that the affinity ability that can increase material improves bonding force.Because corrosion resistance and crosslink density are with training being distributed with for point
Close, it is necessary that hydroxy radical content, which is retained in proper proportion, carries out chemical modification to resin, isocyanates is such as added, to change
Resin crosslink density and crosslinking points, the performance of resin can be improved.Double bond content height shows crosslinking points in resinous molecular structure
Number, more crosslinking points mean higher potential curing degree.
(4) cross-linking properties makes epoxy acrylate tree due to containing hydroxyl in the product after epoxy resin and its open loop
Fat has excellent adhesive property：Monomer hydroxyl interacts on secondary hydroxyl and glass surface on molecule, can improve to glass
The wellability and cementability of glass fiber.Be advantageous to improve glass hardness of steel, the reinforced plastics high mechanical strength of making, fatigue durability
It is good.
(5) other performance epoxy resin parents can assign Epocryl toughness.Ether is good in molecular structure, can be made
Resin has excellent acid resistance.
It is demonstrated experimentally that when carrying aromatic rings on the main chain or side chain of polymer architecture, its radiation resistance is good, by nuclear radiation
Caused depolymerization is slight.
Epoxy resin is smooth for the coating that coating made from base-material is formed, and the epoxy resin that the theoretical degree of cross linking is 100% applies
Layer, radiation resistance are especially good.The higher molecular epoxy coating solidified with amine has more excellent performance of depolluting.
This paper is exactly to study the synthesis of radiation proof aluminium foil epoxy grafted acrylate ester resin, makes the resin of synthesis
Can integrate epoxy resin high-modulus, high intensity, chemical-resistant resistance and the gloss of excellent anticorrosive property and acrylic resin,
The features such as richness, good weatherability, it can solve the problem that the corrosion and protection application technology problem under harsh conditions in industrial environment.
The content of the invention：
It is an object of the invention to provide a kind of method for preparing waterborne epoxy acrylate coating, it is characterised in that bag
Include following steps：
(1) 25g epoxy resin is weighed with small beaker, then weighs 10g n-butanols and 10g butyl glycol ethers in holding asphalt mixtures modified by epoxy resin
In the beaker of fat, suitably heat and stir until epoxy resin is dissolved in the in the mixed solvent of n-butanol and butyl glycol ether, so
Above-mentioned mixed solution is added to afterwards and is equipped with oil in the four-hole boiling flask of thermometer, reflux condensing tube, stirring rod and separatory funnel
Bath heating；
(2) 30g methacrylic acids (MAA), 15g styrene (St), 21 butyl acrylates (BA), 9g acrylic acid hydroxypropyls are weighed
Ester (HPA) and a certain amount of benzoyl peroxide (BPO) are in another small beaker, stirring and dissolving；
(3) when epoxy resin mixed solution temperature is heated to 115 DEG C, with separatory funnel by acrylic monomers mixed solution
It is added in four-hole boiling flask；
(4) after acrylic monomers mixed solution drips, 130 DEG C are warming up to, 8-10 hour is incubated afterwards, has reacted
Afterwards, four-hole boiling flask cooling is taken out, product is fitted into clean plastic bottle in case performance test.
Preferably, the temperature of the oil bath heating in the step (1) is 500-600 DEG C.
Preferably, the agitating solution time in the step (2) is 0.5-1h.
Preferably, in the step (3), acrylic acid solution rate of addition is that 20s mono- drips.
As further preferably, the chilling temperature in the step (4) is 50 DEG C.
Compared with the prior art, beneficial effects of the present invention are embodied in：
(1) synthetic reaction of Epocryl is radical polymerization mechanism, and the grafting rate of polymerisation is impossible
100%, final product is the mixture of non-grafted epoxy resin, the epoxy resin being graft-polymerized and acrylic copolymer, by
The synthetic reaction of the provable Epocryl of the infrared spectrum of epoxy source material and synthesizing epoxy acrylate
Compare completely, target product has been made.
(2) with the increase of epoxy resin content, the transparency increase of Epocryl.Because work as ring
During oxygen resin content increase, active hydrogen atom number also increases therewith, this considerably increases acrylic monomers in epoxy resin master
The possibility being grafted on chain, and then cause the grafting rate increase of polymerization, the transparency increase of the Epocryl of synthesis.
(3) as the increase of polymeric reaction temperature, the transparency of Epocryl increase.Because reaction
Temperature is an important factor for influenceing graft copolymerization, and the hydrogen atom that initiator free radical is captured on methylene needs certain energy,
Energy is low when temperature is relatively low, is unfavorable for graft reaction.And high temperature is advantageous to the generation of graft reaction, so with polymerisation temperature
The raising of degree, the transparency increase of Epocryl.
(4) as the increase of initiator B PO contents, the glass transition temperature of the Epocryl of synthesis drop
It is low.Because the increase of initiator content causes the increase of free free-radical contents, and then increase the possibility of graft polymerization
Property.When grafting rate increases, side base increases, and this esters of acrylic acid side base is flexible, the presence phase of this flexible side group
When the effect of plasticizer in, so cause the glass transition temperature of Epocryl to decline.
(5) with the increase of initiator (BPO) content, number-average molecular weight, the weight average molecular weight of Epocryl
All decline therewith with Z-average molecular weight, and molecular weight distribution is totally on a declining curve, occasionally there is fluctuation.Because kinetic chain length
It is square directly proportional to initiator concentration, increase the content of initiator, the increase of free radical generating rate, chain termination speed also increases
Greatly, and the degree of polymerization then reduces, so synthetic resin adhesive force decline.It is also possible that the coupling between free radical growing chain
Terminate relevant.
(6) as the raising of drying temperature, the water resistance enhancing of film, toughness improve；And temperature it is too high when, adhesive force become
Difference；Film impact resistance change under different temperatures is little, but impact resistance is relatively preferable when temperature is 120~130 DEG C.
Brief description of the drawings：
Fig. 1 is the mechanism of polymerization of epoxy grafted acrylate of the present invention.
Fig. 2 is the glass transition temperature of different BPO contents synthesizing epoxy acrylic resins.
Below by way of embodiment, and with reference to accompanying drawing, the invention will be further described.
Embodiment：
Embodiment 1：
A kind of method for preparing waterborne epoxy acrylate coating, it is characterised in that comprise the following steps：
(1) 25g epoxy resin is weighed with small beaker, then weighs 10g n-butanols and 10g butyl glycol ethers in holding asphalt mixtures modified by epoxy resin
In the beaker of fat, suitably heat and stir until epoxy resin is dissolved in the in the mixed solvent of n-butanol and butyl glycol ether, so
Above-mentioned mixed solution is added to afterwards and is equipped with the four-hole boiling flask of thermometer, reflux condensing tube, stirring rod and separatory funnel.Oil
Bath heating.
(2) 30g methacrylic acids (MAA), 15g styrene (St), 21 butyl acrylates (BA), 9g acrylic acid hydroxypropyls are weighed
Ester (HPA) and 2g benzoyl peroxides (BPO) are in another small beaker, stirring and dissolving.
(3) when epoxy resin mixed solution temperature is heated to 115 DEG C, with separatory funnel by acrylic monomers mixed solution
It is added in four-hole boiling flask, controls solution rate of addition to be dripped for 20s mono-.
(4) after acrylic monomers mixed solution drips, 130 DEG C are warming up to, is incubated 8 hours afterwards.It is reacted
Afterwards, take out four-hole boiling flask and be cooled to 50 DEG C, product is fitted into clean plastic bottle in case performance test.
Embodiment 2：
A kind of method for preparing waterborne epoxy acrylate coating, it is characterised in that comprise the following steps：
(1) 25g epoxy resin is weighed with small beaker, then weighs 10g n-butanols and 10g butyl glycol ethers in holding asphalt mixtures modified by epoxy resin
In the beaker of fat, suitably heat and stir until epoxy resin is dissolved in the in the mixed solvent of n-butanol and butyl glycol ether, so
Above-mentioned mixed solution is added to afterwards and is equipped with the four-hole boiling flask of thermometer, reflux condensing tube, stirring rod and separatory funnel.Oil
Bath heating.
(2) 30g methacrylic acids (MAA), 15g styrene (St), 21 butyl acrylates (BA), 9g acrylic acid hydroxypropyls are weighed
Ester (HPA) and 4g benzoyl peroxides (BPO) are in another small beaker, stirring and dissolving.
(3) when epoxy resin mixed solution temperature is heated to 115 DEG C, with separatory funnel by acrylic monomers mixed solution
It is added in four-hole boiling flask, controls solution rate of addition to be dripped for 20s mono-.
(4) after acrylic monomers mixed solution drips, 130 DEG C are warming up to, is incubated 8 hours afterwards.It is reacted
Afterwards, take out four-hole boiling flask and be cooled to 50 DEG C, product is fitted into clean plastic bottle in case performance test.
Embodiment 3：
A kind of method for preparing waterborne epoxy acrylate coating, it is characterised in that comprise the following steps：
(1) 25g epoxy resin is weighed with small beaker, then weighs 10g n-butanols and 10g butyl glycol ethers in holding asphalt mixtures modified by epoxy resin
In the beaker of fat, suitably heat and stir until epoxy resin is dissolved in the in the mixed solvent of n-butanol and butyl glycol ether, so
Above-mentioned mixed solution is added to afterwards and is equipped with the four-hole boiling flask of thermometer, reflux condensing tube, stirring rod and separatory funnel.Oil
Bath heating.
(2) 30g methacrylic acids (MAA), 15g styrene (St), 21 butyl acrylates (BA), 9g acrylic acid hydroxypropyls are weighed
Ester (HPA) and 6g benzoyl peroxides (BPO) are in another small beaker, stirring and dissolving.
(3) when epoxy resin mixed solution temperature is heated to 115 DEG C, with separatory funnel by acrylic monomers mixed solution
It is added in four-hole boiling flask, controls solution rate of addition to be dripped for 20s mono-.
(4) after acrylic monomers mixed solution drips, 130 DEG C are warming up to, is incubated 8 hours afterwards.It is reacted
Afterwards, take out four-hole boiling flask and be cooled to 50 DEG C, product is fitted into clean plastic bottle in case performance test.
As seen from Figure 1, the synthetic reaction of Epocryl is radical polymerization mechanism, although epoxy resin
There is no unsaturated double-bond, but contain ehter bond, the H on A-H and tertiary carbon atom on its ortho position carbon atom is comparatively relatively active,
Free radical can be formed in the presence of initiator free radical, is triggered and acrylic acid (methacrylic acid, butyl acrylate, styrene
Deng) graft polymerization reaction of unsaturated monomer, Epocryl is made.The grafting rate of polymerisation is impossible
100%, final product is the mixture of non-grafted epoxy resin, the epoxy resin being graft-polymerized and acrylic copolymer, its
Middle epoxy grafted acrylate resin makes epoxy resin preferably mix body with acrylic resin as compatibility as bulking agent
System.Using paint and varnish epoxy acrylate made from the determination method GB 6743-1986 measure polymerisations of paint base acid number
The acid number of resin, approached with the theoretical calculation acid number of simple mixtures, it is acrylic monomers and asphalt mixtures modified by epoxy resin to illustrate the polymerisation
The graft polymerization reaction of fat aliphatic chain, without esterification.
Fig. 2 is the Tg of Epocryl that DSC methods measure, as seen from the figure with the increase of initiator B PO contents,
The glass transition temperature of the Epocryl of synthesis reduces.Because the increase of initiator content causes to dissociate certainly
By the increase of base content, the chance for capturing hydrogen atom on epoxy molecule chain is increased, it is, which increase graft polymerization
Possibility.When grafting rate increases, side base increases, and this esters of acrylic acid side base is flexible.Side base is more big then flexible
Bigger, the presence of this flexible side group is equivalent to plasticizer has been played, so causing the glass of Epocryl
Change transition temperature to decline.
Molecular weight and molecular weight distribution during 1 BPO different contents of table
Molecular weight and molecular weight distribution when table 1 is the BPO different contents that exclusion chromatography measures.As seen from table with drawing
The increase of agent (BPO) content is sent out, number-average molecular weight, weight average molecular weight and the Z-average molecular weight of Epocryl are all therewith
Decline, and molecular weight distribution is totally on a declining curve, occasionally there is fluctuation.Because square of kinetic chain length and initiator concentration
It is directly proportional, increase the content of initiator, the increase of free radical generating rate, chain termination speed also increases, and the degree of polymerization then reduces, institute
Declined with the adhesive force of synthetic resin.It is also possible that the coupling termination between free radical growing chain is relevant.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made any repaiies
Change, equivalent substitution, improvement etc., should be included in the scope of the protection.
Claims (5)
- A kind of 1. method for preparing waterborne epoxy acrylate coating, it is characterised in that comprise the following steps：(1) 25g epoxy resin is weighed with small beaker, then weighs 10g n-butanols and 10g butyl glycol ethers in holding epoxy resin In beaker, suitably heat and stir until epoxy resin is dissolved in the in the mixed solvent of n-butanol and butyl glycol ether, then will Above-mentioned mixed solution, which is added to, to be equipped with oil bath in the four-hole boiling flask of thermometer, reflux condensing tube, stirring rod and separatory funnel and adds Heat；(2) 30g methacrylic acids (MAA), 15g styrene (St), 21 butyl acrylates (BA), 9g hydroxypropyl acrylates are weighed (HPA) and a certain amount of benzoyl peroxide (BPO) is in another small beaker, stirring and dissolving；(3) when epoxy resin mixed solution temperature is heated to 115 DEG C, acrylic monomers mixed solution is added with separatory funnel Into four-hole boiling flask；(4) after acrylic monomers mixed solution drips, 130 DEG C are warming up to, 8-10 hour is incubated afterwards, has reacted it Afterwards, four-hole boiling flask cooling is taken out, product is fitted into clean plastic bottle in case performance test.
- A kind of 2. method for preparing waterborne epoxy acrylate coating according to claim 1, it is characterised in that the step Suddenly the temperature of the oil bath heating in (1) is 500-600 DEG C.
- A kind of 3. method for preparing waterborne epoxy acrylate coating according to claim 1, it is characterised in that the step Suddenly the agitating solution time in (2) is 0.5-1h.
- A kind of 4. method for preparing waterborne epoxy acrylate coating according to claim 1, it is characterised in that the step Suddenly in (3), acrylic acid solution rate of addition is that 20s mono- drips.
- A kind of 5. method for preparing waterborne epoxy acrylate coating according to claim 1, it is characterised in that the step Suddenly the chilling temperature in (4) is 50 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711306478.7A CN107880741A (en) | 2017-12-11 | 2017-12-11 | A kind of method for preparing waterborne epoxy acrylate coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711306478.7A CN107880741A (en) | 2017-12-11 | 2017-12-11 | A kind of method for preparing waterborne epoxy acrylate coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107880741A true CN107880741A (en) | 2018-04-06 |
Family
ID=61773860
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711306478.7A Pending CN107880741A (en) | 2017-12-11 | 2017-12-11 | A kind of method for preparing waterborne epoxy acrylate coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107880741A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108559090A (en) * | 2018-04-26 | 2018-09-21 | 中山大桥化工集团有限公司 | A kind of waterborne epoxy modified acrylic resin and preparation method thereof |
| CN114249879A (en) * | 2022-01-12 | 2022-03-29 | 广东美亨新材料科技有限公司 | Environment-friendly vinyl ester resin |
| CN116179021A (en) * | 2023-02-01 | 2023-05-30 | 上海攸彩新材料科技有限公司 | Water-resistant salt-fog-resistant water-based universal paint color paste and application thereof |
-
2017
- 2017-12-11 CN CN201711306478.7A patent/CN107880741A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108559090A (en) * | 2018-04-26 | 2018-09-21 | 中山大桥化工集团有限公司 | A kind of waterborne epoxy modified acrylic resin and preparation method thereof |
| CN114249879A (en) * | 2022-01-12 | 2022-03-29 | 广东美亨新材料科技有限公司 | Environment-friendly vinyl ester resin |
| CN116179021A (en) * | 2023-02-01 | 2023-05-30 | 上海攸彩新材料科技有限公司 | Water-resistant salt-fog-resistant water-based universal paint color paste and application thereof |
| CN116179021B (en) * | 2023-02-01 | 2024-02-09 | 上海攸彩新材料科技有限公司 | Water-resistant salt-fog-resistant water-based universal paint color paste and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102911540B (en) | Hydrophobic MMA (Methl Methacrylate) resin floor coating and preparation method thereof | |
| CN101555386B (en) | Epoxy organosilicone ultraviolet curing coating modified by (methyl) acrylic acid and preparation method thereof | |
| CN107880741A (en) | A kind of method for preparing waterborne epoxy acrylate coating | |
| US3361842A (en) | Liquid copolymers of ethylene, another alpha olefin and carboxylic acids and compositions thereof with polyepoxides | |
| CN107936746A (en) | A kind of organic-silicon-modified cation photocuring cycloaliphatic epoxy resin coating and its application | |
| CN104211863B (en) | The preparation method of a kind of NO free radical polymer brush polymerization inhibitor and application thereof | |
| CN100487007C (en) | Process for preparing acrylate resin for powder paint | |
| CN101967211A (en) | Preparation method of low molecular weight polyacrylic ester acrylic ester for photo-curing | |
| CN101935387B (en) | Modified UV photocuring pure acrylic resin and preparation method thereof | |
| CN106432584A (en) | Synthesis of imidazole latent epoxy curing accelerator having toughening effect and application of accelerator in epoxy modification | |
| CA1089143A (en) | Radiation curable epoxy ester resin containing a vinyl polymer | |
| CN105482342B (en) | Excellent vinyl chloride resin of cryogenic property and preparation method thereof | |
| CN102603982B (en) | Method for preparing unsaturated carboxylic acid grafted polypropylene copolymer | |
| CN106752741A (en) | Ultraviolet light polymerization alkali-resistant coating composition | |
| CN105384906B (en) | A kind of photo curable prepolymer adhesive and preparation method thereof | |
| CN103819994B (en) | A kind of polypropylene film coating UV light-cured acrylate aqueous polymer dispersion | |
| CN101967213A (en) | Preparation method of carboxyl-contained polyacrylic ester with low molecular weight | |
| CN107236440A (en) | A kind of preparation method of multiple modified high salt spray resistance acrylic acid dispersion | |
| CN108047397A (en) | A kind of method for preparing Epocryl | |
| TW201024327A (en) | Acrylic copolymers with high heat-resistance and preparation thereof | |
| Jaswal et al. | Curing and decomposition behaviour of cresol novolac based vinyl ester resin | |
| CN111072882A (en) | Modified waterborne polyurethane resin, coating and preparation method thereof | |
| CN104877055B (en) | A kind of reactivity core-shell particles and preparation method and application | |
| CN108624240A (en) | Room temperature ketone hydrazine self-crosslinking acrylic resin aqueous dispersion and its preparation method and application | |
| CN108192254A (en) | High anti-pollution acrylic entity plane materiel and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180406 |