CN107880534A - One kind is packed for wear-resistant rubber-plastic material - Google Patents
One kind is packed for wear-resistant rubber-plastic material Download PDFInfo
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- CN107880534A CN107880534A CN201711051125.7A CN201711051125A CN107880534A CN 107880534 A CN107880534 A CN 107880534A CN 201711051125 A CN201711051125 A CN 201711051125A CN 107880534 A CN107880534 A CN 107880534A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/004—Additives being defined by their length
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Polymers & Plastics (AREA)
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides one kind and is packed for wear-resistant rubber-plastic material, includes the component of following parts by weight；16 29 parts of tetraethylene-glycol dimethylacrylate；Low floating fibre cuts 11 19 parts of glass fibre without alkalescence length；49 parts of polyolefin elastomer；9 16 parts of composite plant dyestuff；16 23 parts of soybean fiber；17 21 parts of Cyanuric Chloride；7 15 parts of polyhexamethylene guanidine propionate；11 26 parts of chitosan quaternary ammonium salt；13 25 parts of triethanolamine；39 parts of gallic acid.The present invention is environmentally friendly, and the excellent performance such as anti-aging, heat endurance, antifatigue, anti-oxidant is packed for wear-resistant rubber-plastic material.
Description
Technical field
Present invention relates particularly to one kind to be packed for wear-resistant rubber-plastic material.
Background technology
Save the energy and refuse reclamation to ensure the fast development of China's economy, increase economic efficiency, Push Technology is entered
Step, rationally using resource, reduce environmental pollution, uplifting the people's living standard etc. plays an important role, and realize that China passes through
The important channel and the requisite measure of implementation " strategy of sustainable development " that Ji growth pattern changes from extensive style to intensive style.
In the recent period, it is national《Rubber emission of industrial pollutants standard》Appearance, will be to dirty in rubber production process
Contaminate thing emission control, detection etc. and propose specific requirement, promote transition of the Rubber Industry to energy-conserving and environment-protective direction.Manufacturer in order to
Guarantee the profit, the reclaimed rubber of low price low-quality is mixed in selection, and the even material such as clay, calcium carbonate constantly compresses production cost but
Do not take the quality problems of product into account, so only can form vicious circle.Rubber industry must walk the road of benign development it is necessary to from
Starting with adjustment of industrial structure, it is selectively inexpensive using some that technological level is improved on the basis of product quality is ensured
Raw material.Described plasticizer, also known as plasticiser.It is the high polymer material auxiliary agent being industrially widely used, in plastic processing
Middle this material of addition, can strengthen its pliability, be easily worked, legal can be used for industrial use.China from May, 2011
6 kinds of phthalate plasticiser compositions such as DEHP, DINP, DNOP, DBP, DMP, DEP are successively detected in Taiwan Province's food,
DIDP is detected in medicine.
Therefore, it is badly in need of a kind of new rubber-plastics material, had both met the requirement of environmental protection, while there is certain functional characteristic,
With the requirement for meeting the modern life, producing.
The content of the invention
In view of this, a kind of cost of present invention offer is cheap, refuse reclamation and environmentally friendly, anti-aging, thermostabilization
The excellent performance such as property, antifatigue, anti-oxidant is packed for wear-resistant rubber-plastic material.
The technical scheme is that：One kind is packed for wear-resistant rubber-plastic material, includes the component of following parts by weight：
Urethane acrylate 22-34 parts；
Tetraethylene-glycol dimethylacrylate 16-29 parts；
Low floating fibre cuts glass fibre 11-19 parts without alkalescence length；
Polyolefin elastomer 4-9 parts；
Composite plant dyestuff 9-16 parts；
Soybean fiber 16-23 parts；
Cyanuric Chloride 17-21 parts；
Polyhexamethylene guanidine propionate 7-15 parts；
Chitosan quaternary ammonium salt 11-26 parts；
Triethanolamine 13-25 parts；
Gallic acid 3-9 parts；
The granularity size of the soybean fiber is 250-400 microns；
Further, the component of following parts by weight is included：
Urethane acrylate 25-28 parts；
Tetraethylene-glycol dimethylacrylate 18-22 parts；
Low floating fibre cuts glass fibre 13-16 parts without alkalescence length；
Polyolefin elastomer 5-7 parts；
Composite plant dyestuff 11-14 parts；
Soybean fiber 19-21 parts；
Cyanuric Chloride 17-20 parts；
Polyhexamethylene guanidine propionate 9-11 parts；
Chitosan quaternary ammonium salt 15-23 parts；
Triethanolamine 16-21 parts；
Gallic acid 4-7 parts；
The granularity size of the soybean fiber is 280-350 microns；
Further, the component of following parts by weight is included：
27 parts of urethane acrylate；
20 parts of tetraethylene-glycol dimethylacrylate；
Low floating fibre cuts 15 parts of glass fibre without alkalescence length；
6 parts of polyolefin elastomer；
12 parts of composite plant dyestuff；
20 parts of soybean fiber；
19 parts of Cyanuric Chloride；
10 parts of polyhexamethylene guanidine propionate；
19 parts of chitosan quaternary ammonium salt；
18 parts of triethanolamine；
6 parts of gallic acid；
The granularity size of the soybean fiber is 320 microns；
In the present invention, the polyolefin elastomer of use（POE）Molecular structure is similar to ethylene propylene diene rubber (EPDM), therefore POE
Also can have the excellent properties such as ageing-resistant, resistance to ozone, resistant to chemical media, by being crosslinked to POE, the heat resisting temperature quilt of material
Improve, permanent deformation reduces, and the Main Mechanical such as tensile strength, tearing strength all has significant improvement.It is multiduty
POE elastomers can exceed PVC, EVA, SBR, EMA and EPDM, and POE may substitute traditional EPDM from now on.It is excellent due to POE
The opposite sex can be such that it is all applied widely in automobile industry, electric wire and cable jacket, plastics toughening agent etc..
Further, the low floating fine length that glass fibre is cut without alkalescence length is 9-16mm, a diameter of 13-18um.
Further, the low floating fine preparation method that glass fibre is cut without alkalescence length is to be heated to alkali-free continuous glass-fiber
140-150 DEG C, input temperature is in 2-3 DEG C of hydrogen peroxide, adds potassium chloride, is incubated 2-5min, is obtained after drying described low
Floating fibre cuts glass fibre without alkalescence length.
Further, the composite plant dyestuff forms pomegranate pigment 9-18 parts, wormwood by following parts by weight component
It is pigment 15-26 parts, coptis root pigment 16-28 parts, alkannin 6-17 parts, hematoxylin 28-38 parts, curcumin 33-51 parts, big
Nettle pigment 11-19 parts.Particularly, heretofore described pomegranate pigment, wormwood pigment, coptis root pigment, alkannin, bush color
Element, curcumin, stinging nettle pigment are the natural pigment extracted by prior art from plant.
In the present invention, chitosan quaternary ammonium salt, triethanolamine, gallic acid can synergistic compounding and the cross-linking reactions of fiber molecule
The amorphous region of fiber is occurred mainly in, reaches fixation lock color and acts on, the creasy recovery angle of fiber is significantly increased after fixation, from
And make fabric that there is certain anti-wrinkle effect.
Composite plant dyestuff is with the addition of in the present invention, has invested multiple color, while color and luster is vivider, texture third dimension is more
By force, pattern more innervation and vigor.And consolidated by chitosan quaternary ammonium salt, triethanolamine, the further lock color of gallic acid compounding
Color, fully meet the selection of people's diversification of demand and the realization of personalized consumption psychology.
The present invention is cut by urethane acrylate, tetraethylene-glycol dimethylacrylate, low floating fibre without alkalescence length
The synergistic complex role of glass fibre, the spatial arrangement structure of high intensity and regular layer structure are formed, then pass through three polychlorostyrene
The effect of cyanogen, polyhexamethylene guanidine propionate, gallic acid strengthens its bonding strength.By the observation to cross-section morphology of the present invention,
The boundary of each component obscures, and parcel and wrapped connected mode be present, while some perforations also be present, illustrates three polychlorostyrene
The common synergistic of cyanogen, polyhexamethylene guanidine propionate, gallic acid can be effectively improved urethane acrylate and tetraethylene-glycol two
It is methacrylate, low floating fine without the long interface cohesion cut between glass fibre of alkalescence, but between the larger fiber of particle diameter easily
Put up a bridge so that hole is also easy to produce between fiber and fiber and between fiber and matrix, and then reduces the effect of adhesion, because
Arranged in pairs or groups in this present invention by using the fiber of different-grain diameter, avoid material from producing the phenomenon of stress concentration in stress.
Particularly, the present invention can be prepared by this area any prior art.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example only part of the embodiment of the present invention, rather than whole embodiments.It is common based on the embodiment in the present invention, this area
The every other embodiment that technical staff is obtained under the premise of creative work is not made, belong to the model that the present invention protects
Enclose.
Embodiment 1
One kind is packed for wear-resistant rubber-plastic material, including core plate 1, and the raw material of the core plate 1 and the parts by weight of each raw material are
27 parts of urethane acrylate；
20 parts of tetraethylene-glycol dimethylacrylate；
Low floating fibre cuts 15 parts of glass fibre without alkalescence length；
6 parts of polyolefin elastomer；
12 parts of composite plant dyestuff；
20 parts of soybean fiber；
19 parts of Cyanuric Chloride；
10 parts of polyhexamethylene guanidine propionate；
19 parts of chitosan quaternary ammonium salt；
18 parts of triethanolamine；
6 parts of gallic acid；
The granularity size of the soybean fiber is 320 microns；
Further, the low floating fine length that glass fibre is cut without alkalescence length is 14mm, a diameter of 15um.
The calcined temperature of the further bamboo is 480 DEG C, time 1.2h；Pickling is to be soaked using acetic acid；Calcining
Temperature be 970 DEG C, time 62min.
Further, the low floating fine preparation method that glass fibre is cut without alkalescence length is to be heated to alkali-free continuous glass-fiber
145 DEG C, input temperature is in 2.5 DEG C of hydrogen peroxide, adds potassium chloride, is incubated 4min, and the low floating fine nothing is obtained after drying
Alkalescence length cuts glass fibre.
Further, the composite plant dyestuff is made up of following parts by weight component：13 parts of pomegranate pigment, wormwood color
19 parts of element, 21 parts of coptis root pigment, 12 parts of alkannin, 33 parts of hematoxylin, 41 parts of curcumin, 14 parts of stinging nettle pigment.
Embodiment 2
One kind is packed for wear-resistant rubber-plastic material, including core plate 1, and the raw material of the core plate 1 and the parts by weight of each raw material are
22 parts of urethane acrylate；
29 parts of tetraethylene-glycol dimethylacrylate；
Low floating fibre cuts 11 parts of glass fibre without alkalescence length；
9 parts of polyolefin elastomer；
9 parts of composite plant dyestuff；
16 parts of soybean fiber；
21 parts of Cyanuric Chloride；
7 parts of polyhexamethylene guanidine propionate；
11 parts of chitosan quaternary ammonium salt；
13 parts of triethanolamine；
3 parts of gallic acid；
The granularity size of the soybean fiber is 250 microns；
Further, the low floating fine length that glass fibre is cut without alkalescence length is 9mm, a diameter of 18um.
The calcined temperature of the further bamboo is 530 DEG C, time 1.5h；Pickling is to be soaked using acetic acid；Calcining
Temperature be 1050 DEG C, time 70min.
Further, the low floating fine preparation method that glass fibre is cut without alkalescence length is to be heated to alkali-free continuous glass-fiber
140 DEG C, input temperature is in 2 DEG C of hydrogen peroxide, adds potassium chloride, is incubated 5min, and the low floating fine alkali-free is obtained after drying
Property length cut glass fibre.
Further, the composite plant dyestuff is made up of following parts by weight component：9 parts of pomegranate pigment, wormwood color
15 parts of element, 16 parts of coptis root pigment, 6 parts of alkannin, 28 parts of hematoxylin, 33 parts of curcumin, 11 parts of stinging nettle pigment.
Embodiment 3
One kind is packed for wear-resistant rubber-plastic material, including core plate 1, and the raw material of the core plate 1 and the parts by weight of each raw material are
34 parts of urethane acrylate；
16 parts of tetraethylene-glycol dimethylacrylate；
Low floating fibre cuts 19 parts of glass fibre without alkalescence length；
4 parts of polyolefin elastomer；
16 parts of composite plant dyestuff；
16 parts of soybean fiber；
21 parts of Cyanuric Chloride；
7 parts of polyhexamethylene guanidine propionate；
26 parts of chitosan quaternary ammonium salt；
25 parts of triethanolamine；
9 parts of gallic acid；
The granularity size of the soybean fiber is 400 microns；
Further, the low floating fine length that glass fibre is cut without alkalescence length is 16mm, a diameter of 13um.
The calcined temperature of the further bamboo is 450 DEG C, time 1h；Pickling is to be soaked using acetic acid；Calcining
Temperature is 920 DEG C, time 55min.
Further, the low floating fine preparation method that glass fibre is cut without alkalescence length is to be heated to alkali-free continuous glass-fiber
150 DEG C, input temperature is in 3 DEG C of hydrogen peroxide, adds potassium chloride, is incubated 2min, and the low floating fine alkali-free is obtained after drying
Property length cut glass fibre.
Further, the composite plant dyestuff is made up of following parts by weight component：18 parts of pomegranate pigment, wormwood color
26 parts of element, 28 parts of coptis root pigment, 17 parts of alkannin, 38 parts of hematoxylin, 51 parts of curcumin, 19 parts of stinging nettle pigment.
Embodiment 4
One kind is packed for wear-resistant rubber-plastic material, including core plate 1, and the raw material of the core plate 1 and the parts by weight of each raw material are
25 parts of urethane acrylate；
18 parts of tetraethylene-glycol dimethylacrylate；
Low floating fibre cuts 13 parts of glass fibre without alkalescence length；
5 parts of polyolefin elastomer；
11 parts of composite plant dyestuff；
19 parts of soybean fiber；
17 parts of Cyanuric Chloride；
9 parts of polyhexamethylene guanidine propionate；
21 parts of chitosan quaternary ammonium salt；
17 parts of triethanolamine；
7 parts of gallic acid
The granularity size of the soybean fiber is 280 microns；
Further, the low floating fine length that glass fibre is cut without alkalescence length is 15mm, a diameter of 18um.
The calcined temperature of the further bamboo is 490 DEG C, time 1.2h；Pickling is to be soaked using acetic acid；Calcining
Temperature be 1000 DEG C, time 68min.
Further, the low floating fine preparation method that glass fibre is cut without alkalescence length is to be heated to alkali-free continuous glass-fiber
148 DEG C, input temperature is in 2.2 DEG C of hydrogen peroxide, adds potassium chloride, is incubated 3.5min, and the low floating fibre is obtained after drying
Glass fibre is cut without alkalescence length.
Further, the composite plant dyestuff is made up of following parts by weight component：12 parts of pomegranate pigment, wormwood color
17 parts of element, 19 parts of coptis root pigment, 8 parts of alkannin, 35 parts of hematoxylin, 48 parts of curcumin, 12 parts of stinging nettle pigment.
Embodiment 5
One kind is packed for wear-resistant rubber-plastic material, including core plate 1, and the raw material of the core plate 1 and the parts by weight of each raw material are
28 parts of urethane acrylate；
22 parts of tetraethylene-glycol dimethylacrylate；
Low floating fibre cuts 16 parts of glass fibre without alkalescence length；
7 parts of polyolefin elastomer；
14 parts of composite plant dyestuff；
21 parts of soybean fiber；
20 parts of Cyanuric Chloride；
11 parts of polyhexamethylene guanidine propionate；
16 parts of chitosan quaternary ammonium salt；
20 parts of triethanolamine；
4 parts of gallic acid
The granularity size of the soybean fiber is 350 microns；
Further, the low floating fine length that glass fibre is cut without alkalescence length is 10mm, a diameter of 13um.
The calcined temperature of the further bamboo is 490 DEG C, time 1.2h；Pickling is to be soaked using acetic acid；Calcining
Temperature be 1000 DEG C, time 68min.
Further, the low floating fine preparation method that glass fibre is cut without alkalescence length is to be heated to alkali-free continuous glass-fiber
142 DEG C, input temperature is in 2.7 DEG C of hydrogen peroxide, adds potassium chloride, is incubated 4.5min, and the low floating fibre is obtained after drying
Glass fibre is cut without alkalescence length.
Further, the composite plant dyestuff is made up of following parts by weight component：17 parts of pomegranate pigment, wormwood color
26 parts of element, 17 parts of coptis root pigment, 14 parts of alkannin, 30 parts of hematoxylin, 38 parts of curcumin, 13 parts of stinging nettle pigment.
Comparative example 1
One kind is packed for wear-resistant rubber-plastic material, including core plate 1, and the raw material of the core plate 1 and the parts by weight of each raw material are
25 parts of urethane acrylate；
18 parts of tetraethylene-glycol dimethylacrylate；
Low floating fibre cuts 13 parts of glass fibre without alkalescence length；
11 parts of composite plant dyestuff；
19 parts of soybean fiber；
17 parts of Cyanuric Chloride；
9 parts of polyhexamethylene guanidine propionate；
21 parts of chitosan quaternary ammonium salt；
17 parts of triethanolamine；
7 parts of gallic acid
The granularity size of the soybean fiber is 280 microns；
Further, the low floating fine length that glass fibre is cut without alkalescence length is 15mm, a diameter of 18um.
The calcined temperature of the further bamboo is 490 DEG C, time 1.2h；Pickling is to be soaked using acetic acid；Calcining
Temperature be 1000 DEG C, time 68min.
Further, the low floating fine preparation method that glass fibre is cut without alkalescence length is to be heated to alkali-free continuous glass-fiber
148 DEG C, input temperature is in 2.2 DEG C of hydrogen peroxide, adds potassium chloride, is incubated 3.5min, and the low floating fibre is obtained after drying
Glass fibre is cut without alkalescence length.
Further, the composite plant dyestuff is made up of following parts by weight component：12 parts of pomegranate pigment, wormwood color
17 parts of element, 19 parts of coptis root pigment, 8 parts of alkannin, 35 parts of hematoxylin, 48 parts of curcumin, 12 parts of stinging nettle pigment.
Comparative example 2
One kind is packed for wear-resistant rubber-plastic material, including core plate 1, and the raw material of the core plate 1 and the parts by weight of each raw material are
25 parts of urethane acrylate；
18 parts of tetraethylene-glycol dimethylacrylate；
5 parts of polyolefin elastomer；
11 parts of composite plant dyestuff；
19 parts of soybean fiber；
17 parts of Cyanuric Chloride；
9 parts of polyhexamethylene guanidine propionate；
21 parts of chitosan quaternary ammonium salt；
17 parts of triethanolamine；
7 parts of gallic acid
The granularity size of the soybean fiber is 280 microns；
The calcined temperature of the further bamboo is 490 DEG C, time 1.2h；Pickling is to be soaked using acetic acid；The temperature of calcining
Spend for 1000 DEG C, time 68min.
Further, the composite plant dyestuff is made up of following parts by weight component：12 parts of pomegranate pigment, wormwood color
17 parts of element, 19 parts of coptis root pigment, 8 parts of alkannin, 35 parts of hematoxylin, 48 parts of curcumin, 12 parts of stinging nettle pigment.
Comparative example 3
One kind is packed for wear-resistant rubber-plastic material, including core plate 1, and the raw material of the core plate 1 and the parts by weight of each raw material are
25 parts of urethane acrylate；
18 parts of tetraethylene-glycol dimethylacrylate；
Low floating fibre cuts 13 parts of glass fibre without alkalescence length；
5 parts of polyolefin elastomer；
11 parts of composite plant dyestuff；
17 parts of Cyanuric Chloride；
9 parts of polyhexamethylene guanidine propionate；
21 parts of chitosan quaternary ammonium salt；
17 parts of triethanolamine；
7 parts of gallic acid
Further, the low floating fine length that glass fibre is cut without alkalescence length is 15mm, a diameter of 18um.
The calcined temperature of the further bamboo is 490 DEG C, time 1.2h；Pickling is to be soaked using acetic acid；Calcining
Temperature be 1000 DEG C, time 68min.
Further, the low floating fine preparation method that glass fibre is cut without alkalescence length is to be heated to alkali-free continuous glass-fiber
148 DEG C, input temperature is in 2.2 DEG C of hydrogen peroxide, adds potassium chloride, is incubated 3.5min, and the low floating fibre is obtained after drying
Glass fibre is cut without alkalescence length.
Further, the composite plant dyestuff is made up of following parts by weight component：12 parts of pomegranate pigment, wormwood color
17 parts of element, 19 parts of coptis root pigment, 8 parts of alkannin, 35 parts of hematoxylin, 48 parts of curcumin, 12 parts of stinging nettle pigment.
Thermal conductivity factor and shock resistance test
Embodiment 1-5 and comparative example 1-3 thermal conductivity factor and shock resistance test result such as following table, wherein, thermal conductivity factor is surveyed
It is GB/T10294-2008 to calibrate standard, and shock resistance bioassay standard is GB/T11548-1989.
| Experimental group | Impact resistance（Sheet metal thickness is 1cm）cm·kg | Thermal conductivity factor W/ (mK) |
| Embodiment 1 | 179 | 0.027 |
| Embodiment 2 | 174 | 0.035 |
| Embodiment 3 | 216 | 0.017 |
| Embodiment 5 | 221 | 0.020 |
| Comparative example 1 | 103 | 1.099 |
| Comparative example 2 | 89 | 1.352 |
| Comparative example 3 | 85 | 1.162 |
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back
In the case of spirit or essential attributes from the present invention, the present invention can be realized in other specific forms.Therefore, no matter from which
From the point of view of a bit, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention will by appended right
Ask rather than described above limits, it is intended that all changes in the implication and scope of the equivalency of claim will be fallen
Include in the present invention.Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implement
Mode only includes an independent technical scheme, and this narrating mode of specification is only art technology for clarity
Personnel should be using specification as an entirety, and the technical solutions in the various embodiments may also be suitably combined, forms this area
The other embodiment that technical staff is appreciated that.It is noted that the technical characteristic not being described in detail in the present invention,
To be realized by any prior art.
Claims (3)
1. one kind is packed for wear-resistant rubber-plastic material, it is characterised in that includes the component of following parts by weight：
Urethane acrylate 22-34 parts；
Tetraethylene-glycol dimethylacrylate 16-29 parts；
Low floating fibre cuts glass fibre 11-19 parts without alkalescence length；
Polyolefin elastomer 4-9 parts；
Composite plant dyestuff 9-16 parts；
Soybean fiber 16-23 parts；
Cyanuric Chloride 17-21 parts；
Polyhexamethylene guanidine propionate 7-15 parts；
Chitosan quaternary ammonium salt 11-26 parts；
Triethanolamine 13-25 parts；
Gallic acid 3-9 parts；
The granularity size of the soybean fiber is 250-400 microns；
It is according to claim 1 to be packed for wear-resistant rubber-plastic material, it is characterised in that to include the component of following parts by weight：
Urethane acrylate 25-28 parts；
Tetraethylene-glycol dimethylacrylate 18-22 parts；
Low floating fibre cuts glass fibre 13-16 parts without alkalescence length；
Polyolefin elastomer 5-7 parts；
Composite plant dyestuff 11-14 parts；
Soybean fiber 19-21 parts；
Cyanuric Chloride 17-20 parts；
Polyhexamethylene guanidine propionate 9-11 parts；
Chitosan quaternary ammonium salt 15-23 parts；
Triethanolamine 16-21 parts；
Gallic acid 4-7 parts；
The granularity size of the soybean fiber is 280-350 microns；
It is according to claim 1 to be packed for wear-resistant rubber-plastic material, it is characterised in that to include the component of following parts by weight：
27 parts of urethane acrylate；
20 parts of tetraethylene-glycol dimethylacrylate；
Low floating fibre cuts 15 parts of glass fibre without alkalescence length；
6 parts of polyolefin elastomer；
12 parts of composite plant dyestuff；
20 parts of soybean fiber；
19 parts of Cyanuric Chloride；
10 parts of polyhexamethylene guanidine propionate；
19 parts of chitosan quaternary ammonium salt；
18 parts of triethanolamine；
6 parts of gallic acid；
The granularity size of the soybean fiber is 320 microns；
It is according to claim 1 to be packed for wear-resistant rubber-plastic material, it is characterised in that the low floating fibre cuts glass without alkalescence length
The length of fiber is 9-16mm, a diameter of 13-18um.
2. according to claim 1 be packed for wear-resistant rubber-plastic material, it is characterised in that the low floating fibre cuts glass without alkalescence length
The preparation method of glass fiber is that alkali-free continuous glass-fiber is heated into 140-150 DEG C, is put into the hydrogen peroxide that temperature is 2-3 DEG C,
Potassium chloride is added, is incubated 2-5min, the low floating fibre is obtained after drying and cuts glass fibre without alkalescence length.
3. according to claim 1 be packed for wear-resistant rubber-plastic material, it is characterised in that the composite plant dyestuff be by with
Lower parts by weight component composition pomegranate pigment 9-18 parts, wormwood pigment 15-26 parts, coptis root pigment 16-28 parts, alkannin 6-17
Part, hematoxylin 28-38 parts, curcumin 33-51 parts, stinging nettle pigment 11-19 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711051125.7A CN107880534A (en) | 2017-10-31 | 2017-10-31 | One kind is packed for wear-resistant rubber-plastic material |
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| Application Number | Priority Date | Filing Date | Title |
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| EP4143258A4 (en) * | 2020-05-01 | 2024-05-22 | Modern Meadow, Inc. | Protein polyurethane alloys and layered materials including the same |
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