CN107879661A - Foaming agent and application - Google Patents
Foaming agent and application Download PDFInfo
- Publication number
- CN107879661A CN107879661A CN201710957949.4A CN201710957949A CN107879661A CN 107879661 A CN107879661 A CN 107879661A CN 201710957949 A CN201710957949 A CN 201710957949A CN 107879661 A CN107879661 A CN 107879661A
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- parts
- foaming agent
- sulfate
- amide groups
- polyvinyl alcohol
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
- C04B2103/304—Air-entrainers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Foaming agent, in parts by weight, its component comprises at least 15 parts of amide groups polyoxyethylene ether sulfate, 5 10 parts of silicones polyethers emulsion, 24 parts of polyquaternium, 48 parts of cellulose ether, 15 parts of polyvinyl alcohol, 10 40 parts of foaming agent, 5 15 parts of auxiliary agent, 100 parts of water.
Description
Technical field
The invention belongs to Field of Fine Chemicals, more particularly to a kind of foaming agent and application.
Background technology
Energy-saving and emission-reduction are the fundamental state policies in China.At present, building energy consumption accounts for the 28% of Chinese society total energy consumption.Build energy
Consumption is as caused by being conducted heat inside and outside architectural exterior-protecting construction (roofing, exterior wall, door and window, ground).Architectural exterior-protecting construction power-saving technology is
One of important directions of countries in the world building energy conservation research, develop high-performance building building enclosure insulation material, product and its are
System is the key for realizing building energy conservation.Organic guarantors such as China generally uses at present polystyrene foam plate, polyurethane hard foam
Adiabator, though there is lightweight, high insulating effect, its inflammable, easy to aging, poor durability.Polystyrene steeps during fire
Foam plate will soon melt, and smog is big, it is difficult to put out a fire to save life and property, harm is serious；And for polyurethane foam, except price and fire safety problem
Outside, the problems such as shrinking big, a large amount of toxic gases of release, climate wind direction influences during construction also be present.
Foam concrete has the advantage such as fire prevention, durable, sound insulation, green compared with organic insulation material.And foam
Concrete compared with inorganic heat insulation material such as air entrained concrete, foam glass, glass bead material, low cost, it is easy for construction,
Product unit weight is low, be easy to be molded, invests that small, raw material sources are wide, the advantage such as easy to spread.
Foam concrete is one kind of lightweight concrete, has the characteristics that environmental protection, saves, be cheap, fire-retardant.Foam concrete
Making be typically that foam mechanically is made in the foaming agent aqueous solution, then foam is added in binder materials oar body, passed through
Mixing, pouring molding, maintenance contain a large amount of tiny sealed porositys, and the material with some strength into a kind of.Foaming agent
The pore structure that the foam of formation is finally formed in concrete can produce large effect to foam concrete performance.Foam coagulation
Aperture is smaller in soil and closes, and hole shape is round, and pore size distribution$ is more uniform, and obtained foam concrete performance is better.Therefore,
Higher requirement is it is also proposed to foaming agent.
The content of the invention
In order to solve prior art problem, the first aspect of the present invention provides a kind of foaming agent, in parts by weight,
Its component comprise at least amide groups polyoxyethylene ether sulfate 1-5 parts, silicones polyethers emulsion 5-10 parts, polyquaternium 2-4 parts,
Cellulose ether 4-8 parts, polyvinyl alcohol 1-5 parts, foaming agent 10-40 parts, auxiliary agent 5-15 parts, 100 parts of water.
In some embodiments, the amide groups polyoxyethylene ether sulfate is selected from amide groups APEO sulfuric acid
One in sodium, amide groups APEO potassium sulfate, amide groups APEO magnesium sulfate, amide groups polyoxyethylene ether ammonium sulfate
Kind.
In some embodiments, the polyquaternium is selected from polyquaternium -1, polyquaternium -6, polyquaternium -7, poly-
At least one of quaternary ammonium salt -10, Merquat 280.
In some embodiments, the cellulose ether is selected from methyl cellulose ether, hydroxymethyl cellulose ether, ethyl cellulose
At least one of plain ether, hydroxyethyl ether cellulose.
In some embodiments, the polyvinyl alcohol is selected from polyvinyl alcohol 1788, polyvinyl alcohol 1799, polyvinyl alcohol
2388th, at least one of polyvinyl alcohol 2399.
In some embodiments, the amide groups polyoxyethylene ether sulfate and the weight ratio of silicones polyethers emulsion are
1：3.
In some embodiments, the foaming agent is the mixed of anion surfactant and zwitterionic surfactant
Compound.
In some embodiments, the anion surfactant is selected from ethoxylated dodecyl alcohol sulfate, 12
At least one of alkyl sulfate.
In some embodiments, the zwitterionic surfactant is beet alkali surface activator.
In some embodiments, the auxiliary agent in triethanolamine, diethanol monoisopropanolamine, sodium chloride at least
It is a kind of.
The second aspect of the present invention provides a kind of preparation method of foaming agent as described above, including following step
Suddenly：At room temperature, each component is mixed, stirs 10-30min, produce.
The third aspect of the present invention provides a kind of application of foaming agent in concrete production.
Embodiment
Participate in the election of the detailed description of the invention below for being preferable to carry out method and including embodiment this hair can be more easily understood
Bright content.Unless otherwise defined, all technologies used herein and scientific terminology have common with art of the present invention
The identical implication that technical staff is generally understood that.When contradiction be present, the definition in this specification is defined.
As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " comprising ",
" having ", " containing " or its any other deformation, it is intended that cover including for non-exclusionism.For example, the combination comprising listed elements
Thing, step, method, product or device are not necessarily limited to those key elements, but can include not expressly listed other key elements or
Such a composition, step, method, product or the intrinsic key element of device.
Conjunction " Consists of " excludes any key element do not pointed out, step or component.If be used in claim, this
Phrase will make claim be closed, it is not included the material in addition to the material of those descriptions, but relative normal
Except rule impurity.When being rather than immediately following in the clause that phrase " Consists of " appears in claim main body after theme,
It is only limited to the key element described in the clause；Other key elements are not excluded outside the claim as entirety.
Equivalent, concentration or other values or parameter are excellent with scope, preferred scope or a series of upper limit preferred values and lower limit
During the Range Representation that choosing value limits, this, which is appreciated that, specifically discloses by any range limit or preferred value and any scope
All scopes that any pairing of lower limit or preferred value is formed, regardless of whether the scope separately discloses.For example, when open
During scope " 1 to 5 ", described scope should be interpreted as including scope " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to
5 ", " 1 to 3 and 5 " etc..When number range is described herein, unless otherwise indicated, otherwise the scope is intended to include its end
Value and all integers and fraction within the range.
Singulative includes plural number and object is discussed, unless the context clearly dictates otherwise." optional " or it is " any
It is a kind of " refer to that the item that describes thereafter or event may or may not occur, and the description include situation that event occurs and
The situation that event does not occur.
Approximate term in specification and claims is used for modifying quantity, and it is specific to represent that the present invention is not limited to this
Quantity, include the part of the amendment of the acceptable change without cause related basic function close to the quantity.Phase
Answer, modify a numerical value with " about ", " about " etc., mean that the invention is not restricted to the exact numerical.It is approximate in some examples
Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, scope limits can be with
Combine and/or exchange, these scopes include all subranges contained therebetween if not stated otherwise.
In addition, indefinite article " one kind " before key element of the present invention or component and "one" to key element or the quantitative requirement of component
(i.e. occurrence number) unrestriction.Therefore "one" or " one kind " should be read as including one or at least one, and odd number
The key element or component of form also include plural form, unless the obvious purport of the quantity refers to singulative.
Foam is one of foam concrete main constituents, and air is brought in the inside of concrete mortar, made by foam
It has loose structure disconnected from each other after curing, and obtaining concrete, bulk density is small, and porosity is big, and thermal insulation is good
With the premium properties such as frost resistance height.The quality of foam, such as size, shape, stability etc. directly affect foam concrete performance.Cause
This foam is the basis to form foam concrete.Foam refers to that insoluble (or slightly soluble) property gas is scattered in the multiphase formed in liquid
Dispersion, wherein gas are dispersed phase (discontinuous phases), and liquid is decentralized medium (continuous phase).Foam is gathered by a large amount of bubbles
Collection forms, and the liquid for wrapping up gas is referred to as liquid film or vacuolar membrane.
Foam is Unstable Systems thermodynamically, the system being scattered in as gas in liquid, it have than air and
The taller free energy of liquid free energy sum, therefore foam can be with time spontaneous breaking, to reduce total free energy of the system.
The main reason for causing foam to destroy is the diffusion of gas in foams drain and foam.
The first aspect of the present invention provides a kind of foaming agent, and in parts by weight, its component comprises at least amide groups
Polyoxyethylene ether sulfate 1-5 parts, silicones polyethers emulsion 5-10 parts, polyquaternium 2-4 parts, cellulose ether 4-8 parts, polyethylene
Alcohol 1-5 parts, foaming agent 10-40 parts, auxiliary agent 5-15 parts, 100 parts of water.
Surface tension can promote when relatively low foam formation (formation of foam along with surface expansion, therefore produce bubble
Foam will do work, and the size of work(is multiplied by surface tension equal to the surface area of bubble), but cannot be guaranteed the stability of foam.Only when
Skin covering of the surface has some strength, and when can form polyhedron foam, low surface tension just contributes to the stabilization of foam.Surface tension is not
The formation of foam can be only influenceed, when bubble film is by external impacts, also recovers the effect of thickness of liquid film and intensity.
In some embodiments, the amide groups polyoxyethylene ether sulfate is selected from amide groups APEO sulfuric acid
One in sodium, amide groups APEO potassium sulfate, amide groups APEO magnesium sulfate, amide groups polyoxyethylene ether ammonium sulfate
Kind.
In some embodiments, the polyquaternium is selected from polyquaternium -1, polyquaternium -6, polyquaternium -7, poly-
At least one of quaternary ammonium salt -10, Merquat 280.
In some embodiments, the cellulose ether is selected from methyl cellulose ether, hydroxymethyl cellulose ether, ethyl cellulose
At least one of plain ether, hydroxyethyl ether cellulose.
In some embodiments, the polyvinyl alcohol is selected from polyvinyl alcohol 1788, polyvinyl alcohol 1799, polyvinyl alcohol
2388th, at least one of polyvinyl alcohol 2399.
Polyvinyl alcohol is white plates, cotton-shaped or pulverulent solids, tasteless.Water is dissolved in, is slightly soluble in dimethyl sulfoxide (DMSO), it is insoluble
In gasoline, kerosene, vegetable oil, benzene, toluene, dichloroethanes, carbon tetrachloride, acetone, ethyl acetate, methanol, ethylene glycol etc..Poly- second
The degree of polymerization of enol 1788 is 1700, alcoholysis degree 88%；The degree of polymerization of polyvinyl alcohol 1799 is 1700, alcoholysis degree 99%；
The degree of polymerization of polyvinyl alcohol 2388 is 2300, alcoholysis degree 88%；The degree of polymerization of polyvinyl alcohol 2399 is 2300, and alcoholysis degree is
99%.
In some embodiments, the amide groups polyoxyethylene ether sulfate and the weight ratio of silicones polyethers emulsion are
1：3.
Inventor has found in research process, when amide groups APEO magnesium sulfate and the weight of silicones polyethers emulsion
Than for 1：When 3, synergy can be produced, hence it is evident that improve foam stabilizing effect, the half-life period of foam can be extended.Inventor's supposition,
Magnesium ion is positive divalent ion in amide groups APEO magnesium sulfate, can adsorb 2 times of anionic group, and in silicones
Under the regulation of polyethers emulsion, finer and close inner layer film can be formed, the stability of electric double layer is further improved, works as thinning of liquid film
When, the repulsive interaction between two electric double layers is bigger, so as to produce synergy, obtains unexpected technique effect.
In some embodiments, the foaming agent is the mixed of anion surfactant and zwitterionic surfactant
Compound.
In some embodiments, the anion surfactant is selected from ethoxylated dodecyl alcohol sulfate, 12
At least one of alkyl sulfate.
In some preferred embodiments, the anion surfactant is selected from ethoxylated dodecyl alcohol sodium sulphate
With the mixture of lauryl sodium sulfate.
In some embodiments, the zwitterionic surfactant is beet alkali surface activator.
In some preferred embodiments, the zwitterionic surfactant is Cocoamidopropyl betaine.
In some embodiments, the auxiliary agent in triethanolamine, diethanol monoisopropanolamine, sodium chloride at least
It is a kind of.
The second aspect of the present invention provides a kind of preparation method of foaming agent as described above, including following step
Suddenly：At room temperature, each component is mixed, stirs 10-30min, produce.
The third aspect of the present invention provides a kind of application of foaming agent in concrete production.
The present invention is expanded on further with reference to specific embodiment.
Embodiment 1
Foaming agent, in parts by weight, its component includes 3 parts of amide groups APEO magnesium sulfate, silicones gathers
9 parts of ether emulsion, 3 parts of Polyquaternium-10,6 parts of methyl cellulose ether, 2,388 4 parts of polyvinyl alcohol, ethoxylated dodecyl alcohol sulphur
Sour 10 parts of sodium, 4 parts of lauryl sodium sulfate, 6 parts of Cocoamidopropyl betaine, 4 parts of triethanolamine, diethanol monoisopropanolamine
4 parts, 2 parts of sodium chloride, 100 parts of water.
Embodiment 2
Foaming agent, in parts by weight, its component includes 4 parts of amide groups APEO magnesium sulfate, silicones gathers
8 parts of ether emulsion, 3 parts of Polyquaternium-10,6 parts of methyl cellulose ether, 2,388 4 parts of polyvinyl alcohol, ethoxylated dodecyl alcohol sulphur
Sour 10 parts of sodium, 4 parts of lauryl sodium sulfate, 6 parts of Cocoamidopropyl betaine, 4 parts of triethanolamine, diethanol monoisopropanolamine
4 parts, 2 parts of sodium chloride, 100 parts of water.
Embodiment 3
Foaming agent, in parts by weight, its component includes 2 parts of amide groups APEO magnesium sulfate, silicones gathers
10 parts of ether emulsion, 3 parts of Polyquaternium-10,6 parts of methyl cellulose ether, 2,388 4 parts of polyvinyl alcohol, ethoxylated dodecyl alcohol
10 parts of sodium sulphate, 4 parts of lauryl sodium sulfate, 6 parts of Cocoamidopropyl betaine, 4 parts of triethanolamine, diethanol list isopropanol
4 parts of amine, 2 parts of sodium chloride, 100 parts of water.
Embodiment 4
Foaming agent, in parts by weight, its component include 12 parts of amide groups APEO magnesium sulfate, polyquaternary amine
3 parts of salt -10,6 parts of methyl cellulose ether, 2,388 4 parts of polyvinyl alcohol, 10 parts of ethoxylated dodecyl alcohol sodium sulphate, dodecane
4 parts of base sodium sulphate, 6 parts of Cocoamidopropyl betaine, 4 parts of triethanolamine, 4 parts of diethanol monoisopropanolamine, 2 parts of sodium chloride,
100 parts of water.
Embodiment 5
Foaming agent, in parts by weight, its component include 12 parts of silicones polyethers emulsion, 3 parts of Polyquaternium-10,
6 parts of methyl cellulose ether, 2,388 4 parts of polyvinyl alcohol, 10 parts of ethoxylated dodecyl alcohol sodium sulphate, lauryl sodium sulfate 4
Part, 6 parts of Cocoamidopropyl betaine, 4 parts of triethanolamine, 4 parts of diethanol monoisopropanolamine, 2 parts of sodium chloride, 100 parts of water.
Embodiment 1-5 preparation method stirs 10-30min, produced at room temperature, each component is mixed.
Foam stabilizing aptitude tests
At room temperature, Example each 100mL of 1-5 respectively, are poured into in graduated measuring cup, with mixer with
9000rpm rotating speed stirring 10min, stops stirring, and record foam separates out the time required for 50mL liquid, unit min.Survey
Test result is listed in the table below.
| Time | |
| Embodiment 1 | 114 |
| Embodiment 2 | 91 |
| Embodiment 3 | 83 |
| Embodiment 4 | 67 |
| Embodiment 5 | 44 |
Foregoing example is merely illustrative, some features of the feature for explaining the disclosure.Appended claim
It is intended to require the scope as wide as possible being contemplated that, and embodiments as presented herein is only according to all possible embodiment
Combination selection embodiment explanation.Therefore, the purpose of applicant is appended claim not by the explanation present invention
Feature example selectional restriction.And the progress in science and technology will not formed due to the inaccuracy of language performance and not
The possible equivalent or son being presently considered are replaced, and these changes should also be interpreted by appended in the conceived case
Claim covers.
Claims (10)
1. foaming agent, in parts by weight, its component comprise at least amide groups polyoxyethylene ether sulfate 1-5 parts, silicon tree
Fat polyethers emulsion 5-10 parts, polyquaternium 2-4 parts, cellulose ether 4-8 parts, polyvinyl alcohol 1-5 parts, foaming agent 10-40 parts, auxiliary agent
100 parts of 5-15 parts, water.
2. foaming agent as claimed in claim 1, it is characterised in that the amide groups polyoxyethylene ether sulfate is selected from
Amide groups polyethenoxy ether sodium sulfate, amide groups APEO potassium sulfate, amide groups APEO magnesium sulfate, amide groups gather
One kind in oxygen ethene ether ammonium sulfate.
3. foaming agent as claimed in claim 1, it is characterised in that the polyquaternium is selected from polyquaternium -1, gathered
At least one of quaternary ammonium salt -6, polyquaternium -7, Polyquaternium-10, Merquat 280.
4. foaming agent as claimed in claim 1, it is characterised in that the cellulose ether be selected from methyl cellulose ether,
At least one of hydroxymethyl cellulose ether, cellulose ether, hydroxyethyl ether cellulose.
5. foaming agent as claimed in claim 1, it is characterised in that the polyvinyl alcohol be selected from polyvinyl alcohol 1788,
At least one of polyvinyl alcohol 1799, polyvinyl alcohol 2388, polyvinyl alcohol 2399.
6. foaming agent as claimed in claim 1, it is characterised in that the amide groups polyoxyethylene ether sulfate and silicon
The weight ratio of resin polyethers emulsion is 1：3.
7. foaming agent as claimed in claim 1, it is characterised in that the foaming agent be anion surfactant and
The mixture of zwitterionic surfactant.
8. foaming agent as claimed in claim 7, it is characterised in that the anion surfactant is selected from laruyl alcohol
At least one of polyoxyethylene ether sulfate, lauryl sulfate.
9. foaming agent as claimed in claim 7, it is characterised in that the zwitterionic surfactant is glycine betaine
Surfactant.
10. a kind of preparation method of foaming agent as described in any one of claim 1-9 claim, including it is as follows
Step：At room temperature, each component is mixed, stirs 10-30min, produce.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710957949.4A CN107879661B (en) | 2017-10-16 | 2017-10-16 | Foaming agent composition and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710957949.4A CN107879661B (en) | 2017-10-16 | 2017-10-16 | Foaming agent composition and application |
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| Publication Number | Publication Date |
|---|---|
| CN107879661A true CN107879661A (en) | 2018-04-06 |
| CN107879661B CN107879661B (en) | 2020-07-03 |
Family
ID=61781448
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710957949.4A Active CN107879661B (en) | 2017-10-16 | 2017-10-16 | Foaming agent composition and application |
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| Country | Link |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6197179A (en) * | 1984-10-16 | 1986-05-15 | 大成建設株式会社 | Manufacture of inorganic hydraulic substance lightweight member |
| CN105585276A (en) * | 2014-10-29 | 2016-05-18 | 西安优信机电工程有限公司 | Foam concrete block foamer |
| CN106587716A (en) * | 2017-01-06 | 2017-04-26 | 中国铁道科学研究院铁道建筑研究所 | Organosilicone modified foaming agent and application thereof in foamed light soil |
-
2017
- 2017-10-16 CN CN201710957949.4A patent/CN107879661B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6197179A (en) * | 1984-10-16 | 1986-05-15 | 大成建設株式会社 | Manufacture of inorganic hydraulic substance lightweight member |
| CN105585276A (en) * | 2014-10-29 | 2016-05-18 | 西安优信机电工程有限公司 | Foam concrete block foamer |
| CN106587716A (en) * | 2017-01-06 | 2017-04-26 | 中国铁道科学研究院铁道建筑研究所 | Organosilicone modified foaming agent and application thereof in foamed light soil |
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| Publication number | Publication date |
|---|---|
| CN107879661B (en) | 2020-07-03 |
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