CN107877625A - A kind of compound bamboo fiberboard of thermal-insulation three-decker formula - Google Patents

A kind of compound bamboo fiberboard of thermal-insulation three-decker formula Download PDF

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Publication number
CN107877625A
CN107877625A CN201711073893.2A CN201711073893A CN107877625A CN 107877625 A CN107877625 A CN 107877625A CN 201711073893 A CN201711073893 A CN 201711073893A CN 107877625 A CN107877625 A CN 107877625A
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bamboo fibre
bamboo
insulation
thermal
hot pressing
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CN107877625B (en
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茆莉娟
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BEIJING JULONG BOFANG SCIENCE
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D1/00Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/067Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of fibres or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B19/00Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica
    • B32B19/06Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B19/00Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica
    • B32B19/08Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica comprising asbestos
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/002Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising natural stone or artificial stone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/02Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/047Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • E04C2/284Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
    • E04C2/296Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating composed of insulating material and non-metallic or unspecified sheet-material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/20All layers being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14Mixture of at least two fibres made of different materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Building Environments (AREA)

Abstract

The invention discloses a kind of compound bamboo fiberboard of thermal-insulation three-decker formula, it is related to bamboo fiberboard processing technique field, including bamboo fibre bottom plate, heat insulation layer and bamboo fibre panel, the heat insulation layer is located between bamboo fibre bottom plate and bamboo fibre panel, bamboo fibre bottom plate is made up with bamboo fibre panel of the preheated pressure technique of bamboo fibre blank, heat insulation layer is made up of heat preserving and insulating material, and compound bamboo fiberboard is made through heat pressing process again in bamboo fibre bottom plate, heat insulation layer and bamboo fibre panel.The present invention first passes through pre- heat pressing process and bamboo fibre blank is made into bamboo fibre bottom plate and bamboo fibre panel, heat preserving and insulating material is filled between bamboo fibre bottom plate and bamboo fibre panel by heat pressing process again, to assign made compound bamboo fiberboard excellent thermal and insulating performance.

Description

A kind of compound bamboo fiberboard of thermal-insulation three-decker formula
Technical field:
The present invention relates to bamboo fiberboard processing technique field, and in particular to a kind of thermal-insulation three-decker formula composite bamboo Fiberboard.
Background technology:
Fiberboard structure is uniform, and medium density, surface is smooth, has good processing characteristics, therefore used extensively In furniture manufacturing industry and construction industry.At present, the raw material for being widely used in fiberboard preparation is lignocellulosic and Lauxite.But It is the excessive felling with the forest reserves, how ensures the lignocellulosic material supply of abundance, it has also become fiberboard manufacturing industry The major issue faced.In addition, Lauxite derives from non-renewable fossil resources, easily discharged under hygrothermal environment Go out free formaldehyde, seriously pollute environment, endanger human health.
China's bamboo resource enriches, and has substantial amounts of bamboo fibre remnants to go out of use in Bamboo processing enterprise, and bamboo and timber phase Than with intensity is high, good toughness the characteristics of, be fiberboard desirable feedstock.But in fiberboard process, due to applying glue Inequality, easily cause fibrous caking and into felt, directly affect plate property.In addition, the bamboo fiberboard processed at present does not possess Thermal and insulating performance, and the thermal and insulating performance assigned by coating way is weaker, it is difficult to meet construction and decoration construction to spacing The requirement of plate thermal and insulating performance.
The content of the invention:
The technical problems to be solved by the invention are to provide a kind of physical mechanics performance excellent, strong using the feature of environmental protection And it can realize that bamboo -processing industry discards the compound bamboo fiberboard of thermal-insulation three-decker formula that bamboo fibre resource rationally recycles.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of compound bamboo fiberboard of thermal-insulation three-decker formula, including bamboo fibre bottom plate, heat insulation layer and bamboo are fine Tie up panel, the heat insulation layer is located between bamboo fibre bottom plate and bamboo fibre panel, bamboo fibre bottom plate and bamboo fibre panel by The preheated pressure technique of bamboo fibre blank is made, and heat insulation layer is made up of heat preserving and insulating material, bamboo fibre bottom plate, heat insulation layer Compound bamboo fiberboard is made through heat pressing process again with bamboo fibre panel.
The technological parameter of the pre- heat pressing process is 135-145 DEG C of hot pressing temperature, hot pressing pressure 5-5.5MPa, hot pressing time 3-5min。
The technological parameter of the heat pressing process is 165-175 DEG C of hot pressing temperature, hot pressing pressure 6.5-7MPa, hot pressing time 5- 8min。
The specific preparation method of the heat preserving and insulating material is:Magnesium ingot is first heated to molten condition insulation, treats that magnesium melts Start to stir using permanent magnetism blender when rate reaches 60%, asbestos wool, sepiolite fibre and glass are added after magnesium is completely melt Fiber, rear more than insulated and stirred 15min is added, add foaming agent and nano titanium oxide, continue insulated and stirred, infusion pending Stop stirring after being uniformly dispersed, thermal insulation foaming, foam after terminating through naturally cooling to room temperature, produce heat preserving and insulating material.
The magnesium ingot, asbestos wool, sepiolite fibre, glass fibre, the mass ratio of foaming agent and nano titanium oxide are 5- 10:10-15:5-10:1-5:0.5-2:0.5-2。
One or more of the foaming agent in dolomite, calcium carbonate, quick lime, calcium sulfate, carbon dust, titantium hydride.
The processing technology of the bamboo fibre blank includes following process:
(1) impregnation:First ethoxylated hydrogenated castor oil is added in 45-55 DEG C of warm water, is heated to reflux state insulation 5-15wt% dispersion liquid is made in stirring, adds hydrophobically modified hydroxyethyl-beta-schardinger dextrin and 5A molecular sieve activation powder, continues at Insulated and stirred under reflux state, until obtaining homogeneous paste, through naturally cooling to room temperature, produce adhesive;
(2) it is glued:The bamboo fibre of length 15-20mm, water content less than 5wt% is fitted into glue mixing roller, utilizes compression Air makes the bamboo fibre in roller be in suspended state, while using spray pattern that 5-15wt% polymeric aluminum chlorides solution is equal It is even to be sprayed on bamboo fibre, then equally above-mentioned institute's preparing adhesive is sprayed on bamboo fibre with spray pattern, it is well mixed, finally Dried at 55-65 DEG C to water content and be reduced to 20-25%, produce bamboo fibre blank.
The quality of the ethoxylated hydrogenated castor oil, hydrophobically modified hydroxyethyl-beta-schardinger dextrin and 5A molecular sieve activation powder Than for 1-5:15-25:1-5.
The bamboo fibre, polymeric aluminum chlorides solution, the mass ratio of adhesive are 100-200:1-5:15-25.
Hydrophobically modified hydroxyethyl-the beta-schardinger dextrin is made by hydroxyethyl-β-cyclodextrin is hydrophobically modified, its specific system Preparation Method is:Absolute ethyl alcohol is added dropwise until be completely dissolved into hydroxyethyl-β-cyclodextrin under stirring, and add 12 phosphotungstic acids and 16- mercaptohexadecanoics base acid, is heated to reflux state insulated and stirred 2-5h, gained mixture is concentrated under reduced pressure to reclaim ethanol, treated Gained solid is transferred in 50-60 DEG C of baking oven when ethanol recovery reaches 90-95%, is dried to constant weight, produces hydrophobically modified hydroxyl Second group-beta-cyclodextrin.
The mass ratio of the hydroxyethyl-β-cyclodextrin, 12 phosphotungstic acids and 16- mercaptohexadecanoics base acid is 15-25: 0.05-0.5:5-10。
The beneficial effects of the invention are as follows:
(1) for the present invention using heat preserving and insulating material as heat insulation layer, bamboo fiberboard is made three layers as bottom plate and panel The compound bamboo fiberboard of structural formula, first pass through pre- heat pressing process and bamboo fibre bottom plate and bamboo fibre panel is made in bamboo fibre blank, then Heat preserving and insulating material is filled between bamboo fibre bottom plate and bamboo fibre panel by heat pressing process, it is fine to assign made composite bamboo Tie up the excellent thermal and insulating performance of plate;And further enhance made composite bamboo using bamboo fibre bottom plate or bamboo fibre panel is made by oneself The thermal and insulating performance of fiberboard, while ensure the physical mechanics performance of made compound bamboo fiberboard.
(2) present invention in impregnation process with ethoxylated hydrogenated castor oil, hydrophobically modified hydroxyethyl-beta-schardinger dextrin and 5A Molecular sieve activation powder is that adhesive is made in raw material, and the adhesive is good with bamboo fibre comixing compatibility, and energy Quick uniform penetrates into bamboo In fiber, especially with the superpower permeability of 5A molecular sieve activation powder, so as to play excellent adhesive property, and made bamboo is assigned Foundation board or the certain water resistance of panel, and then reduce expansion rate of water absorption.
(3) present invention sprays adhesive to first uniformly spraying polymeric aluminum chlorides solution on bamboo fibre be glued in process again, By being used cooperatively for aluminium polychloride, to strengthen made bamboo fibre bottom plate or bamboo fibre face while expansion rate of water absorption is reduced The physical and mechanical property of plate, so as to improve the synthesis performance of made bamboo fibre bottom plate or bamboo fibre panel;And made bamboo The use feature of environmental protection of foundation board or bamboo fibre panel is strong, ensure that zero release of formaldehyde during use, will to meet environmental protection Ask;The resource for realizing the discarded bamboo fibre of bamboo -processing industry simultaneously rationally recycles, and bamboo wood is played its utilization to greatest extent Value.
Brief description of the drawings:
Fig. 1 is the structural representation of the present invention;
Wherein:1- bamboo fibre bottom plates;2- heat insulation layers;3- bamboo fibre panels.
Embodiment:
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Conjunction is specifically illustrating and embodiment, and the present invention is expanded on further.
Embodiment 1
As shown in figure 1, a kind of compound bamboo fiberboard of thermal-insulation three-decker formula, including bamboo fibre bottom plate 1, thermal insulation separation Thermosphere 2 and bamboo fibre panel 3, the heat insulation layer are located between bamboo fibre bottom plate and bamboo fibre panel, bamboo fibre bottom plate with Bamboo fibre panel is made up of the preheated pressure technique of bamboo fibre blank, and heat insulation layer is made up of heat preserving and insulating material, bamboo fibre bottom Compound bamboo fiberboard is made through heat pressing process again in plate, heat insulation layer and bamboo fibre panel.
The technological parameter of pre- heat pressing process is 135-145 DEG C of hot pressing temperature, hot pressing pressure 5-5.5MPa, hot pressing time 5min, the technological parameter of heat pressing process is 165-175 DEG C of hot pressing temperature, hot pressing pressure 6.5-7MPa, hot pressing time 8min.
Embodiment 2
As shown in figure 1, a kind of compound bamboo fiberboard of thermal-insulation three-decker formula, including bamboo fibre bottom plate 1, thermal insulation separation Thermosphere 2 and bamboo fibre panel 3, the heat insulation layer are located between bamboo fibre bottom plate and bamboo fibre panel, bamboo fibre bottom plate with Bamboo fibre panel is made up of the preheated pressure technique of bamboo fibre blank, and heat insulation layer is made up of heat preserving and insulating material, bamboo fibre bottom Compound bamboo fiberboard is made through heat pressing process again in plate, heat insulation layer and bamboo fibre panel.
The technological parameter of pre- heat pressing process is 135-145 DEG C of hot pressing temperature, hot pressing pressure 5-5.5MPa, hot pressing time 5min, the technological parameter of heat pressing process is 165-175 DEG C of hot pressing temperature, hot pressing pressure 6.5-7MPa, hot pressing time 8min.
The preparation of heat preserving and insulating material:5g magnesium ingots are first heated to molten condition insulation, when magnesium dissolution rate reaches 60% Start to stir using permanent magnetism blender, 10g asbestos wools, 5g sepiolite fibres and 2g glass fibres added after magnesium is completely melt, Rear more than insulated and stirred 15min is added, adds 0.5g foaming agents calcium carbonate and 0.5g nano titanium oxides, continues insulation and stirs Mix, infusion pending stops stirring after being uniformly dispersed, thermal insulation foaming, foam after terminating through naturally cooling to room temperature, produce thermal insulation separation Hot material.
Bamboo fibre bottom plate uses 1 made bamboo fiberboard of patent CN200710164450.4 embodiments with bamboo fibre panel.
Embodiment 3
As shown in figure 1, a kind of compound bamboo fiberboard of thermal-insulation three-decker formula, including bamboo fibre bottom plate 1, thermal insulation separation Thermosphere 2 and bamboo fibre panel 3, the heat insulation layer are located between bamboo fibre bottom plate and bamboo fibre panel, bamboo fibre bottom plate with Bamboo fibre panel is made up of the preheated pressure technique of bamboo fibre blank, and heat insulation layer is made up of heat preserving and insulating material, bamboo fibre bottom Compound bamboo fiberboard is made through heat pressing process again in plate, heat insulation layer and bamboo fibre panel.
The technological parameter of pre- heat pressing process is 135-145 DEG C of hot pressing temperature, hot pressing pressure 5-5.5MPa, hot pressing time 5min, the technological parameter of heat pressing process is 165-175 DEG C of hot pressing temperature, hot pressing pressure 6.5-7MPa, hot pressing time 8min.
The preparation of heat preserving and insulating material:10g magnesium ingots are first heated to molten condition insulation, when magnesium dissolution rate reaches 60% Start to stir using permanent magnetism blender, 15g asbestos wools, 5g sepiolite fibres and 3g glass fibres added after magnesium is completely melt, Rear more than insulated and stirred 15min is added, adds 1g foaming agents calcium carbonate and 1g nano titanium oxides, continues insulated and stirred, treats Foaming agent stops stirring after being uniformly dispersed, thermal insulation foaming, foam after terminating through naturally cooling to room temperature, produce insulation material Material.
Bamboo fibre bottom plate uses 1 made bamboo fiberboard of patent CN200710164450.4 embodiments with bamboo fibre panel.
Embodiment 4
As shown in figure 1, a kind of compound bamboo fiberboard of thermal-insulation three-decker formula, including bamboo fibre bottom plate 1, thermal insulation separation Thermosphere 2 and bamboo fibre panel 3, the heat insulation layer are located between bamboo fibre bottom plate and bamboo fibre panel, bamboo fibre bottom plate with Bamboo fibre panel is made up of the preheated pressure technique of bamboo fibre blank, and heat insulation layer is made up of heat preserving and insulating material, bamboo fibre bottom Compound bamboo fiberboard is made through heat pressing process again in plate, heat insulation layer and bamboo fibre panel.
The technological parameter of pre- heat pressing process is 135-145 DEG C of hot pressing temperature, hot pressing pressure 5-5.5MPa, hot pressing time 5min, the technological parameter of heat pressing process is 165-175 DEG C of hot pressing temperature, hot pressing pressure 6.5-7MPa, hot pressing time 8min.
The preparation of heat preserving and insulating material:5g magnesium ingots are first heated to molten condition insulation, when magnesium dissolution rate reaches 60% Start to stir using permanent magnetism blender, 10g asbestos wools, 5g sepiolite fibres and 2g glass fibres added after magnesium is completely melt, Rear more than insulated and stirred 15min is added, adds 0.5g foaming agents calcium carbonate and 0.5g nano titanium oxides, continues insulation and stirs Mix, infusion pending stops stirring after being uniformly dispersed, thermal insulation foaming, foam after terminating through naturally cooling to room temperature, produce thermal insulation separation Hot material.
The processing of bamboo fibre blank:
(1) impregnation:First 2g ethoxylated hydrogenated castor oils are added in 45-55 DEG C of warm water, are heated to reflux state guarantor 15wt% dispersion liquid is made in temperature stirring, adds 20g hydrophobically modified hydroxyethyls-beta-schardinger dextrin and 3g 5A molecular sieve activation powder, Insulated and stirred under reflux state is continued at, until obtaining homogeneous paste, through naturally cooling to room temperature, produces adhesive;
(2) it is glued:The 150g bamboo fibres of length 15-20mm, water content less than 5wt% are fitted into glue mixing roller, utilized Compressed air makes the bamboo fibre in roller be in suspended state, while uses spray pattern by 5g 10wt% aluminium polychloride Solution is uniformly sprayed on bamboo fibre, then equally above-mentioned made 25g adhesive is sprayed on bamboo fibre with spray pattern, mixing Uniformly, 20-25% most is reduced to water content after dry at 55-65 DEG C, produces bamboo fibre blank.
The preparation of hydrophobically modified hydroxyethyl-beta-schardinger dextrin:Anhydrous second is added dropwise under stirring into 15g hydroxyethyl-β-cyclodextrins Alcohol adds the phosphotungstic acids of 0.2g 12 and 5g 16- mercaptohexadecanoics base acid up to being completely dissolved, and is heated to reflux state insulation 3h is stirred, and gained mixture is concentrated under reduced pressure to reclaim ethanol, gained solid is transferred to when ethanol recovery reaches 90-95% In 50-60 DEG C of baking oven, constant weight is dried to, produces hydrophobically modified hydroxyethyl-beta-schardinger dextrin.
Embodiment 5
As shown in figure 1, a kind of compound bamboo fiberboard of thermal-insulation three-decker formula, including bamboo fibre bottom plate 1, thermal insulation separation Thermosphere 2 and bamboo fibre panel 3, the heat insulation layer are located between bamboo fibre bottom plate and bamboo fibre panel, bamboo fibre bottom plate with Bamboo fibre panel is made up of the preheated pressure technique of bamboo fibre blank, and heat insulation layer is made up of heat preserving and insulating material, bamboo fibre bottom Compound bamboo fiberboard is made through heat pressing process again in plate, heat insulation layer and bamboo fibre panel.
The technological parameter of pre- heat pressing process is 135-145 DEG C of hot pressing temperature, hot pressing pressure 5-5.5MPa, hot pressing time 5min, the technological parameter of heat pressing process is 165-175 DEG C of hot pressing temperature, hot pressing pressure 6.5-7MPa, hot pressing time 8min.
The preparation of heat preserving and insulating material:10g magnesium ingots are first heated to molten condition insulation, when magnesium dissolution rate reaches 60% Start to stir using permanent magnetism blender, 15g asbestos wools, 5g sepiolite fibres and 3g glass fibres added after magnesium is completely melt, Rear more than insulated and stirred 15min is added, adds 1g foaming agents calcium carbonate and 1g nano titanium oxides, continues insulated and stirred, treats Foaming agent stops stirring after being uniformly dispersed, thermal insulation foaming, foam after terminating through naturally cooling to room temperature, produce insulation material Material.
The processing of bamboo fibre blank:
(1) impregnation:First 3g ethoxylated hydrogenated castor oils are added in 45-55 DEG C of warm water, are heated to reflux state guarantor 15wt% dispersion liquid is made in temperature stirring, adds 25g hydrophobically modified hydroxyethyls-beta-schardinger dextrin and 5g 5A molecular sieve activation powder, Insulated and stirred under reflux state is continued at, until obtaining homogeneous paste, through naturally cooling to room temperature, produces adhesive;
(2) it is glued:The 200g bamboo fibres of length 15-20mm, water content less than 5wt% are fitted into glue mixing roller, utilized Compressed air makes the bamboo fibre in roller be in suspended state, while uses spray pattern by 5g 15wt% aluminium polychloride Solution is uniformly sprayed on bamboo fibre, then equally above-mentioned made 25g adhesive is sprayed on bamboo fibre with spray pattern, mixing Uniformly, 20-25% most is reduced to water content after dry at 55-65 DEG C, produces bamboo fibre blank.
The preparation of hydrophobically modified hydroxyethyl-beta-schardinger dextrin:Anhydrous second is added dropwise under stirring into 25g hydroxyethyl-β-cyclodextrins Alcohol adds the phosphotungstic acids of 0.5g 12 and 10g 16- mercaptohexadecanoics base acid up to being completely dissolved, and is heated to reflux state insulation 4h is stirred, and gained mixture is concentrated under reduced pressure to reclaim ethanol, gained solid is transferred to when ethanol recovery reaches 90-95% In 50-60 DEG C of baking oven, constant weight is dried to, produces hydrophobically modified hydroxyethyl-beta-schardinger dextrin.
Reference examples 1
The processing of bamboo fibre blank:
(1) impregnation:First 3g ethoxylated hydrogenated castor oils are added in 45-55 DEG C of warm water, are heated to reflux state guarantor 15wt% dispersion liquid is made in temperature stirring, adds 25g hydrophobically modified hydroxyethyls-beta-schardinger dextrin and 5g 5A molecular sieve activation powder, Insulated and stirred under reflux state is continued at, until obtaining homogeneous paste, through naturally cooling to room temperature, produces adhesive;
(2) it is glued:The 150g bamboo fibres of length 15-20mm, water content less than 5wt% are fitted into glue mixing roller, utilized Compressed air makes the bamboo fibre in roller be in suspended state, while is sprayed above-mentioned made 25g adhesive using spray pattern In on bamboo fibre, it is well mixed, is most reduced to 20-25% to water content after dry at 55-65 DEG C, produces bamboo fibre blank.
The preparation of hydrophobically modified hydroxyethyl-beta-schardinger dextrin:Anhydrous second is added dropwise under stirring into 15g hydroxyethyl-β-cyclodextrins Alcohol adds the phosphotungstic acids of 0.2g 12 and 5g 16- mercaptohexadecanoics base acid up to being completely dissolved, and is heated to reflux state insulation 3h is stirred, and gained mixture is concentrated under reduced pressure to reclaim ethanol, gained solid is transferred to when ethanol recovery reaches 90-95% In 50-60 DEG C of baking oven, constant weight is dried to, produces hydrophobically modified hydroxyethyl-beta-schardinger dextrin.
Reference examples 2
The processing of bamboo fibre blank:
(1) impregnation:First 3g ethoxylated hydrogenated castor oils are added in 45-55 DEG C of warm water, are heated to reflux state guarantor 15wt% dispersion liquid is made in temperature stirring, adds 25g hydrophobically modified hydroxyethyls-beta-schardinger dextrin, continues under reflux state and protect Temperature stirring, until obtaining homogeneous paste, through naturally cooling to room temperature, produces adhesive;
(2) it is glued:The 200g bamboo fibres of length 15-20mm, water content less than 5wt% are fitted into glue mixing roller, utilized Compressed air makes the bamboo fibre in roller be in suspended state, while uses spray pattern by 5g 15wt% aluminium polychloride Solution is uniformly sprayed on bamboo fibre, then equally above-mentioned made 25g adhesive is sprayed on bamboo fibre with spray pattern, mixing Uniformly, 20-25% most is reduced to water content after dry at 55-65 DEG C, produces bamboo fibre blank.
The preparation of hydrophobically modified hydroxyethyl-beta-schardinger dextrin:Anhydrous second is added dropwise under stirring into 15g hydroxyethyl-β-cyclodextrins Alcohol adds the phosphotungstic acids of 0.2g 12 and 5g 16- mercaptohexadecanoics base acid up to being completely dissolved, and is heated to reflux state insulation 3h is stirred, and gained mixture is concentrated under reduced pressure to reclaim ethanol, gained solid is transferred to when ethanol recovery reaches 90-95% In 50-60 DEG C of baking oven, constant weight is dried to, produces hydrophobically modified hydroxyethyl-beta-schardinger dextrin.
Reference examples 3
The processing of bamboo fibre blank:
(1) impregnation:First 3g ethoxylated hydrogenated castor oils are added in 45-55 DEG C of warm water, are heated to reflux state guarantor 15wt% dispersion liquid is made in temperature stirring, adds 25g hydroxyethyl-β-cyclodextrins and 5g 5A molecular sieve activation powder, continues at back Insulated and stirred under stream mode, until obtaining homogeneous paste, through naturally cooling to room temperature, produce adhesive;
(2) it is glued:The 200g bamboo fibres of length 15-20mm, water content less than 5wt% are fitted into glue mixing roller, utilized Compressed air makes the bamboo fibre in roller be in suspended state, while uses spray pattern by 5g 15wt% aluminium polychloride Solution is uniformly sprayed on bamboo fibre, then equally above-mentioned made 25g adhesive is sprayed on bamboo fibre with spray pattern, mixing Uniformly, 20-25% most is reduced to water content after dry at 55-65 DEG C, produces bamboo fibre blank.
Reference examples 4
Glue in reference examples 3 is replaced with 1 made modified soy protein adhesive of patent CN200710164450.4 embodiments Stick.
Embodiment 6
Thermal and insulating performance test is carried out to the compound bamboo fiberboard of the made stack piles of embodiment 2-5 respectively, as a result such as table 1 It is shown;And the individual layer bamboo fiberboard of stack pile is set the processing technology of individual layer bamboo fiberboard is the same as in embodiment 5 as reference examples 5 The processing technology of bamboo fibre blank.
The thermal and insulating performance test result of the compound bamboo fiberboard of the present invention of table 1
Group Thermal conductivity factor W/ (mK)
Embodiment 2 0.058
Embodiment 3 0.053
Embodiment 4 0.045
Embodiment 5 0.042
Reference examples 5 0.146
Embodiment 7
By made bamboo fibre blank in embodiment 4-5, reference examples 1-4 first in 135-145 DEG C of hot pressing temperature, hot pressing pressure 5- Pre- hot pressing under the conditions of 5.5MPa, hot pressing time 5min, then in 165-175 DEG C of hot pressing temperature, hot pressing pressure 6.5-7MPa, hot pressing Between hot pressing under the conditions of 8min, and the bamboo fiberboard of made stack pile is subjected to performance test by GB/T 17657-2013, surveyed Test result is as shown in table 2.
The performance test result of 2 bamboo fiberboard of the present invention of table
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (6)

  1. A kind of 1. compound bamboo fiberboard of thermal-insulation three-decker formula, it is characterised in that:Including bamboo fibre bottom plate, insulation Layer and bamboo fibre panel, the heat insulation layer are located between bamboo fibre bottom plate and bamboo fibre panel, and bamboo fibre bottom plate is fine with bamboo Dimension panel is made up of the preheated pressure technique of bamboo fibre blank, and heat insulation layer is made up of heat preserving and insulating material, bamboo fibre bottom plate, protects Compound bamboo fiberboard is made through heat pressing process again in warm thermal insulation layer and bamboo fibre panel.
  2. 2. the compound bamboo fiberboard of thermal-insulation three-decker formula according to claim 1, it is characterised in that:The preheating The technological parameter for pressing technique is 135-145 DEG C of hot pressing temperature, hot pressing pressure 5-5.5MPa, hot pressing time 3-5min.
  3. 3. the compound bamboo fiberboard of thermal-insulation three-decker formula according to claim 1, it is characterised in that:The hot pressing The technological parameter of technique is 165-175 DEG C of hot pressing temperature, hot pressing pressure 6.5-7MPa, hot pressing time 5-8min.
  4. 4. the compound bamboo fiberboard of thermal-insulation three-decker formula according to claim 1, it is characterised in that:The insulation The specific preparation method of heat-barrier material is:Magnesium ingot is first heated to molten condition insulation, utilized when magnesium dissolution rate reaches 60% Permanent magnetism blender starts to stir, and asbestos wool, sepiolite fibre and glass fibre are added after magnesium is completely melt, is incubated and stirs after adding More than 15min is mixed, adds foaming agent and nano titanium oxide, continues insulated and stirred, infusion pending stops stirring after being uniformly dispersed Mix, thermal insulation foaming, foam after terminating through naturally cooling to room temperature, produce heat preserving and insulating material.
  5. 5. the compound bamboo fiberboard of thermal-insulation three-decker formula according to claim 4, it is characterised in that:The magnesium Ingot, asbestos wool, sepiolite fibre, glass fibre, the mass ratio of foaming agent and nano titanium oxide are 5-10:10-15:5-10: 1-5:0.5-2:0.5-2。
  6. 6. the compound bamboo fiberboard of thermal-insulation three-decker formula according to claim 4, it is characterised in that:The foaming One or more of the agent in dolomite, calcium carbonate, quick lime, calcium sulfate, carbon dust, titantium hydride.
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CN114701212B (en) * 2022-03-18 2024-02-13 程海涛 Bamboo fiber composite felt, preparation method thereof and special-shaped curved surface composite felt

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