CN107870189B - Current compensation method of tin plating amount analyzer for tin-plated plate - Google Patents
Current compensation method of tin plating amount analyzer for tin-plated plate Download PDFInfo
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- CN107870189B CN107870189B CN201610852093.XA CN201610852093A CN107870189B CN 107870189 B CN107870189 B CN 107870189B CN 201610852093 A CN201610852093 A CN 201610852093A CN 107870189 B CN107870189 B CN 107870189B
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/416—Systems
- G01N27/42—Measuring deposition or liberation of materials from an electrolyte; Coulometry, i.e. measuring coulomb-equivalent of material in an electrolyte
- G01N27/44—Measuring deposition or liberation of materials from an electrolyte; Coulometry, i.e. measuring coulomb-equivalent of material in an electrolyte using electrolysis to generate a reagent, e.g. for titration
Abstract
The invention discloses a current compensation method of a tinning quantity analyzer of a tinning plate, which comprises the steps of carrying out 20 times of actual current measurement of a constant direct-current power supply when a tinning plate sample is subjected to electrolytic treatment, wherein the measurement time is 5s, the current sampling frequency in the measurement is 10Hz, obtaining a group of current measured values and averaging the current measured values, obtaining a ratio Q by the current measured values/a current set value, carrying out data fitting on the ratio Q to obtain a ratio Q function formula, integrating the ratio Q function in time t and dividing the time t by the ratio Q function to obtain a compensation parameter k, and multiplying the compensation parameter k by an integral value of the output current I of the constant direct-current power supply in time t to realize the compensation of the integral value. When the method is used for measuring the tin content of the tin plate by using an electrolytic method, the influence of the current setting of the constant direct current power supply is eliminated, and the integral value is corrected, so that the tin content detection precision of the tin plate is improved, and the product quality is ensured.
Description
Technical Field
The invention relates to a current compensation method of a tinning amount analyzer of a tinning plate.
Background
A tin plating amount detection and analysis instrument (instrument technology and sensor 2005, 5 th edition, written in Liu nan Hei, Liu Zi, Chi Yan Song, elegans, Meng Qingjie) introduces a tin plating amount detection and analysis method, the tin plating amount analysis instrument is used for measuring the tin component content on the surface of a tin plating plate, usually, an electrolysis method is adopted for detecting the tin content of the tin plating plate, a constant direct current power supply is required to be connected for electrolyzing the tin plating plate, a detection result is in direct proportion to an integral value of output current (I) of the constant direct current power supply on time (t), and the I x t is directly adopted to calculate the integral value J, so that the final tin plating amount of the tin plate is obtained. The above method is also described in "test method for tin plating amount of tin-plated steel sheet" (GB/T1838-2008). However, when the constant dc power supply is set, the current does not reach the set value I directly from zero, and therefore, a certain error occurs in the calculation of the integral value, which reduces the detection accuracy. Therefore, the integral value J needs to be corrected to eliminate the influence of the above factors on the final detection result.
Disclosure of Invention
The invention aims to solve the technical problem of providing a current compensation method of a tinning plate tinning amount analyzer, which eliminates the influence of constant direct current power supply current setting when measuring the tinning plate tin content by using an electrolytic method and corrects an integral value, thereby improving the detection precision of the tinning plate tin content and ensuring the product quality.
In order to solve the technical problem, the current compensation method of the tin plate tin plating quantity analyzer comprises the following steps:
firstly, carrying out electrolytic treatment on a tinned plate sample, starting a constant direct current power supply, setting an output current set value of the constant direct current power supply, and measuring the actual output current of the constant direct current power supply according to a sampling frequency of 10Hz, wherein the sampling time t is 5 seconds;
step two, repeating the measurement of the constant direct current power supply output current in the step one for 20 times to obtain a group of output current measured values, dividing the output current measured values by the output current set value and taking the average value of the 20 measurements to obtain the ratio Q of the output current measured values to the output current set value;
step three, fitting data to the value Q to obtain a ratio Q function formula,
when t is<When 5, Q (t) = 1-e(-1.5t)
When t ≧ 5, Q (t) =1
Wherein: t is the sampling time of the output current measured value;
step four, integrating the function of the comparison value Q on the time t and dividing the function by the time t to obtain a compensation parameter k,
when t is<At 5, k =2 (e)(-1.5t)-1)/3t + 1
When t is more than or equal to 5, k =1-2/3t
And step five, after the compensation parameter k is obtained, multiplying the compensation parameter k by the integral value of the output current I of the constant direct current power supply on the time t to realize the compensation of the integral value.
The current compensation method of the tinning amount analyzer of the tinning plate adopts the technical scheme, namely the method obtains a group of current measured values and takes an average value after 20 times of actual current measurement of a constant direct-current power supply when a tinning plate sample is subjected to electrolytic treatment, the measured time is 5s, the current sampling frequency in the measurement is 10Hz, the ratio Q is obtained by the current measured values/current set values, data fitting is carried out on the ratio Q to obtain a ratio Q function formula, the ratio Q function is integrated and divided by the time t over the time t to obtain a compensation parameter k, and the compensation parameter k is multiplied by the integral value of the output current I of the constant direct-current power supply over the time t to realize the compensation of the integral value. When the method is used for measuring the tin content of the tin plate by using an electrolytic method, the influence of the current setting of the constant direct current power supply is eliminated, and the integral value is corrected, so that the tin content detection precision of the tin plate is improved, and the product quality is ensured.
Drawings
The invention is described in further detail below with reference to the following figures and embodiments:
FIG. 1 is a diagram showing a ratio Q function curve of a current compensation method of an analyzer for tin plating amount of a tin plate according to the present invention.
Detailed Description
The current compensation method of the tinning quantity analyzer of the tinning plate comprises the following steps of:
firstly, carrying out electrolytic treatment on a tinned plate sample, starting a constant direct current power supply, setting an output current set value of the constant direct current power supply, and measuring the actual output current of the constant direct current power supply according to a sampling frequency of 10Hz, wherein the sampling time t is 5 seconds;
step two, repeating the measurement of the constant direct current power supply output current in the step one for 20 times to obtain a group of output current measured values, dividing the output current measured values by the output current set value and taking the average value of the 20 measurements to obtain the ratio Q of the output current measured values to the output current set value;
the specific 20 measurements of the ratio Q data are shown in the following table:
time(s) | Ratio (Q) | Time(s) | Ratio (Q) | Time(s) | Ratio (Q) |
0 | 0 | 1.7 | 0.922 | 3.4 | 0.994 |
0.1 | 0.139 | 1.8 | 0.933 | 3.5 | 0.995 |
0.2 | 0.259 | 1.9 | 0.942 | 3.6 | 0.995 |
0.3 | 0.362 | 2 | 0.950 | 3.7 | 0.996 |
0.4 | 0.451 | 2.1 | 0.957 | 3.8 | 0.997 |
0.5 | 0.528 | 2.2 | 0.963 | 3.9 | 0.997 |
0.6 | 0.593 | 2.3 | 0.968 | 4 | 0.998 |
0.7 | 0.650 | 2.4 | 0.973 | 4.1 | 0.998 |
0.8 | 0.699 | 2.5 | 0.976 | 4.2 | 0.998 |
0.9 | 0.741 | 2.6 | 0.980 | 4.3 | 0.998 |
1 | 0.777 | 2.7 | 0.983 | 4.4 | 0.999 |
1.1 | 0.808 | 2.8 | 0.985 | 4.5 | 0.999 |
1.2 | 0.835 | 2.9 | 0.987 | 4.6 | 0.999 |
1.3 | 0.858 | 3 | 0.989 | 4.7 | 0.999 |
1.4 | 0.878 | 3.1 | 0.990 | 4.8 | 0.999 |
1.5 | 0.895 | 3.2 | 0.992 | 4.9 | 0.999 |
1.6 | 0.909 | 3.3 | 0.993 | 5 | 0.999 |
Step three, fitting data to the value Q to obtain a ratio Q function formula,
when t is<When 5, Q (t) = 1-e(-1.5t)
When t ≧ 5, Q (t) =1
The ratio Q function is shown in fig. 1, where: t is the sampling time of the output current measured value;
step four, integrating the function of the comparison value Q on the time t and dividing the function by the time t to obtain a compensation parameter k,
when t is<At 5, k =2 (e)(-1.5t)-1)/3t + 1
When t is more than or equal to 5, k =1-2/3t
And step five, after the compensation parameter k is obtained, multiplying the compensation parameter k by the integral value of the output current I of the constant direct current power supply on the time t to realize the compensation of the integral value.
After a ratio Q function formula is obtained in the fourth step, according to the measurement principle, the final measurement result of the tin content of tin plate plating is in direct proportion to the integral value of the current (I) on the time (t), and the actual current is calculatedIntegral function over time tAnd the original integral functionObtaining a correction function k (t) as follows:
wherein ISIs a current set value, IA(t) is a function of the actual value of the current, Q (t) is a function of the ratio of the current (actual value/set value), and t is time.
The method obtains a data curve when the current is set by measuring the actual value of the output current of the constant direct current power supply for multiple times, obtains a compensation parameter according to the data curve, and finally multiplies the compensation parameter by the original calculation result to obtain the compensated data, thereby obtaining the accurate final measurement result of the tin content of tin plate plating, solving the influence of the transition stage of the output current of the constant direct current power supply from zero to the set value I on the final measurement result, and improving the measurement precision.
Claims (1)
1. A current compensation method of a tinning quantity analyzer of a tinning plate is characterized by comprising the following steps:
firstly, carrying out electrolytic treatment on a tinned plate sample, starting a constant direct current power supply, setting an output current set value of the constant direct current power supply, and measuring the actual output current of the constant direct current power supply according to a sampling frequency of 10Hz, wherein the sampling time t is 5 seconds;
step two, repeating the measurement of the constant direct current power supply output current in the step one for 20 times to obtain a group of output current measured values, dividing the output current measured values by the output current set value and taking the average value of the 20 measurements to obtain the ratio Q of the output current measured values to the output current set value;
step three, fitting data to the value Q to obtain a ratio Q function formula,
when t is<When 5, Q (t) = 1-e(-1.5t)
When t ≧ 5, Q (t) =1
Wherein: t is the sampling time of the output current measured value;
step four, integrating the function of the comparison value Q on the time t and dividing the function by the time t to obtain a compensation parameter k,
when t is<At 5, k =2 (e)(-1.5t)-1)/3t + 1
When t is more than or equal to 5, k =1-2/3t
And step five, after the compensation parameter k is obtained, multiplying the compensation parameter k by the integral value of the output current I of the constant direct current power supply on the time t to realize the compensation of the integral value.
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US5196096A (en) * | 1992-03-24 | 1993-03-23 | International Business Machines Corporation | Method for analyzing the addition agents in solutions for electroplating of PbSn alloys |
CN1530468A (en) * | 2003-03-17 | 2004-09-22 | 徐文星 | Electrolytic water oxidation-reduction potential positioning system and correcting compensating constant outputting method thereof |
CN101551444A (en) * | 2008-04-03 | 2009-10-07 | 现代自动车株式会社 | Method for estimating remaining capacity of battery |
CN102998470A (en) * | 2011-09-15 | 2013-03-27 | 上海宝钢工业检测公司 | Tinned plate surface coating quality full-automatic multifunctional measuring system |
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Address after: 3520 Tongji Road, Baoshan District, Shanghai 201900 Patentee after: Baowu equipment Intelligent Technology Co.,Ltd. Address before: 201900, 335, Pu Pu Road, Shanghai, Baoshan District Patentee before: SHANGHAI BAOSTEEL INDUSTRY TECHNOLOGICAL SERVICE Co.,Ltd. |