CN107868550A - A kind of environmentally friendly fishing net protective rubber, protective coating and its dip-coating method - Google Patents

A kind of environmentally friendly fishing net protective rubber, protective coating and its dip-coating method Download PDF

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Publication number
CN107868550A
CN107868550A CN201711042903.6A CN201711042903A CN107868550A CN 107868550 A CN107868550 A CN 107868550A CN 201711042903 A CN201711042903 A CN 201711042903A CN 107868550 A CN107868550 A CN 107868550A
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CN
China
Prior art keywords
fishing net
environmentally friendly
coating
friendly fishing
net protective
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Application number
CN201711042903.6A
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Chinese (zh)
Inventor
欧昊翔
冯侠
许爱蔡
冯启明
欧伯兴
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Jiangsu Liaoyuan Environmental Technology Co Ltd
Hainan Kovy Functional Materials Co Ltd
Original Assignee
Jiangsu Liaoyuan Environmental Technology Co Ltd
Hainan Kovy Functional Materials Co Ltd
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Application filed by Jiangsu Liaoyuan Environmental Technology Co Ltd, Hainan Kovy Functional Materials Co Ltd filed Critical Jiangsu Liaoyuan Environmental Technology Co Ltd
Priority to CN201711042903.6A priority Critical patent/CN107868550A/en
Publication of CN107868550A publication Critical patent/CN107868550A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D111/00—Coating compositions based on homopolymers or copolymers of chloroprene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612—Non-macromolecular compounds
    • C09D5/1618—Non-macromolecular compounds inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612—Non-macromolecular compounds
    • C09D5/1625—Non-macromolecular compounds organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2248—Oxides; Hydroxides of metals of copper
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0058—Biocides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0091—Complexes with metal-heteroatom-bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a kind of environmentally friendly fishing net protective rubber, including following components in percentage by weight：Resin 5% 40%, anti-fouling agent 10% 40%, modified bactericide 5% 28%, color stuffing 0.5% 3%, anti-settling agent 1% 9%, solvent 5% 30%, further discloses a kind of environmentally friendly fishing net protective coating and preparation method thereof, so that the fishing net crossed using this coating dip coating, 12 30um can be can reach to marine organisms, the antifouling removing of fouling organism, paint thickness so that increased weight after fishing net dip-coating micro-, avoid fishing net from working overloadingly, extend fishing net service life；And the coating is consistent with fishing net principle of expanding with heat and contracting with cold；Environmentally friendly fishing net protective coating dip-coating method technique is simple, and cost is cheap, easily popularizes and uses between common fisherman, has good Social benefit and economic benefit.

Description

A kind of environmentally friendly fishing net protective rubber, protective coating and its dip-coating method
Technical field
The present invention relates to chemical material field, and in particular to a kind of environmentally friendly fishing net protective rubber, protective coating and its dip-coating method.
Background technology
With the improvement of people's life quality, to the demand cumulative year after year of marine product, and caught by long-term marine product Drag for, marine product supply wretched insufficiency, and then promote the development of marine aquaculture, marine aquaculture is mainly with coastal waters at present Based on, ocean cultivation is also flourishing, and with the development of the industry, and the antifouling problem of fishing net used is then increasingly in aquaculture Protrude and aggravate, be primarily due to the leaching sea depth that marine environment is the serious environment of a burn into biodeterioration, fishing net and fishing gear Generally 0-20m, just it is the most vigorous region of marine growth, easily grows marine growth, marine algae, bryozoan Deng, after fishing net is by substantial amounts of sea organism attachment, make the weight of fishing net increase several times first, fishing net overwork, significantly Its service life is shortened, and activity also has erosion damage effect to fishing net to fouling organism in itself, blocks mesh, influences in net cage Outer seawater convection current, food supply is reduced, while water quality reduces in fishing net, adds cultivation product infection parasite and various diseases Probability, cause the yield and quality of cultivation, for marine aquaculture, fishing net is antifouling to turn into a critical problem.
Fishing net is antifouling at present is broadly divided into two major classes, first, ANTI-FOULING PAINT FOR FISHING NET containing bactericide, two are free from bactericide ANTI-FOULING PAINT FOR FISHING NET, the ANTI-FOULING PAINT FOR FISHING NET containing bactericide are that the preferable kind of more and effect is used on Vehicles Collected from Market, so And totally nontoxic, efficient, wide spectrum and stable bactericide are developed, the good resin of adhesive force, water resistance, wearability and pliability, The comprehensive anti-fouling material of less toxic, nontoxic, long-acting ANTI-FOULING PAINT FOR FISHING NET is the problem of current chemical material field is badly in need of breaking through.
The content of the invention
In order to solve above-mentioned technical problem, the present invention provides a kind of environmentally friendly fishing net protective rubber, including following weight The component of percentage：
Preferably, environmentally friendly fishing net protective rubber includes following components in percentage by weight：
Preferably, environmentally friendly fishing net protective rubber includes following components in percentage by weight：
Preferably, the resin includes at least one of acrylic resin, neoprene, chloroprene nitrile, butadiene rubber；
The modified bactericide is modified ZPT；
The color stuffing includes at least one of pigment, talcum powder, barium sulfate；
The anti-settling agent includes bentonite, dicalcium powder, polyamide wax, any in Tissuemat E；
The solvent includes at least one of toluene, isobutanol, butyl acetate, ethanol, dimethylbenzene.
Preferably, the chemical structural formula of the modified ZPT is：
By ZPT powder surface is covered by polar group, easy adsorption moisture, hydrophily is presented, easily by water institute Soak, and be not easy to be soaked with nonpolar or weaker polarity organic phase, in addition the medium such as ZPT surface adsorption water Reaction is produced, R-OH based structures is generated, adds intergranular interaction force and surface-active, while between R-OH based structures Effect causes fine particle to be more also easy to produce reunion, so needing to be modified ZPT processing.
ZPT modification theory：One layer of crosslinkable organosilicon is formed in pyridine thioketones zinc powder surface using coating method Film layer, the coating method is using small molecule silane coupler as material of main part.
Silane coupler belongs to organo silane coupling agent compound, and its main component is the alkane containing activity hydroxy/ester group The polysiloxanes of one type of silane and a small amount of active ether, its molecule is centered on silicon atom, carries hydroxyl, ether isoreactivity base Group.Due to unique texture possessed by silane coupler, inorganic material and the performance of organic material are had both, there is surface tension The excellent specific properties such as low, viscosity-temperature coefficient is small, high-low temperature resistant, resistance to oxidation stability, weatherability, fire retardant and chemical inertness, it is pyridine sulphur The optimal material selection of the organic coated processing of ketone zinc.
The processing of ZPT coating mainly dissolves in a small amount of small molecule silane coupler in appropriate solvent, adds pyrrole Pyridine thioketones zinc, sonic oscillation 2h, filter, wash, dry, the modification pyrrole that surface forms one layer of crosslinkable organosilicon film is made Pyridine thioketones zinc.
Preferably, the anti-fouling agent is cuprous oxide.
Preferably, the anti-fouling agent is cuprous sulfocyanide.
Further, there is provided a kind of environmentally friendly fishing net protective coating, be made up of above-mentioned environmentally friendly fishing net protective rubber and polar solvent, ring It is 1 that fishing net protective rubber, which is protected, with polar solvent percentage by weight:0.5∽1:5, form environmentally friendly fishing net protective coating A.Polar solvent bag Include at least one of toluene, isobutanol, butyl acetate, ethanol, dimethylbenzene.
Further, there is provided a kind of dip-coating method of environmentally friendly fishing net protective coating, comprise the following steps：
S01：Environmentally friendly fishing net protective coating A is held in container；
S02：The fishing net for needing dip-coating is immersed in the environmentally friendly fishing net protective coating A in container by lifting appliance moving；
S03：Container is rocked repeatedly by external force, realizes the abundant contact and immersion of fishing net and environmentally friendly fishing net protective coating A；
S04：Outside will be moved to by the complete fishing net of immersion to dry in equipment, the fishing net soaked will be dried.
Preferably, outside equipment of drying is to dry equipment with more rollers described in step S04, passes through the rolling between roller It is dynamic to realize that unnecessary environmentally friendly fishing net protective coating is eliminated on fishing net.
In the dip-coating method of the environmentally friendly fishing net protective coating, container is closed type or semi-open type, its shape not by Limitation, can be circular, oval, square or other irregular shapes；
In the dip-coating method of the environmentally friendly fishing net protective coating, step S03 realizes fishing net and environmentally friendly fishing net protective coating Fully contact and the mode of immersion can also be：
1) container is static condition, and the environmentally friendly fishing net protective coating in container is fully stirred using outside agitator Mix, pass through the flowing of liquid so that environmentally friendly fishing net protective coating can be penetrated into fully in fishing net；
2) container is standing or mobile status, and using external force, fishing net is pulled into the opposing party from a side of container, certainly should During, the environmentally friendly fishing net protective coating in container can constantly be stirred using external equipment, avoid coating because Own wt and rapid subsidence are to container bottom；
What the present invention was brought has the beneficial effect that：Using a kind of environmentally friendly fishing net protective rubber of the present invention, it is possible to achieve right Marine organisms, the antifouling removing of fouling organism, erosion and pollution of the marine organisms to fishing net are reduced, especially modified bactericide can be with Microbe membrane caused by surface of bottom material is removed, the hotbed of marine organisms attachment, acrylic resin, neoprene rubber can be eliminated with this Any one resin such as glue, chloroprene nitrile, butadiene rubber all has good adhesion property to fishing net, can strengthen the machine of the fishing net Tool performance, anti-fouling agent use low copper compound, on the one hand can reduce copper ion to marine organisms heavily contaminated, on the other hand can be with Suppress fouling organism and be attached to fishing net existence.A kind of environmentally friendly fishing net protective coating is further provided for, by the way that environmentally friendly fishing net is protected Mixed between glue and polar solvent, realize the dilution of environmentally friendly fishing net protective rubber, 12-30um fishing nets can be reached and apply thickness Degree so that fishing net increases weight micro- after dip-coating, avoids fishing net from working overloadingly, and extends fishing net service life, and the coating can profit With the effect of surface tension, infiltrate into the per share stock silk gap of fishing net, and stock silk table face is wrapped up, so as to reach fishing net Omnibearing stereo formula soiling protective, another aspect coating has extremely strong elongation percentage and pliability, can avoid it completely in itself Though its fishing-net composition has to fishing net compared with strong adhesive force, because fishing net is in the seawater by expanding with heat and contract with cold and transverse and longitudinal pulling force is influenceed, cause Twine extend or when stretching, because coating is thicker and elongation percentage and pliability are all smaller and caused by coating cracking situation；More Further, the dip-coating method for making environmentally friendly fishing net protective coating is disclosed, this method technique is simple, and cost is cheap, easily general Popularization and use, have good Social benefit and economic benefit between logical fisherman.
Embodiment
Embodiment one：
A kind of environmentally friendly fishing net protective rubber, including following components in percentage by weight (being shown in Table one) are provided：
(table one)
A kind of environmentally friendly fishing net protective coating is provided, the environmentally friendly fishing net protective coating is as the environmentally friendly fishing net protective rubber described in table one With ethanol according to 1:0.5 weight ratio mixes, and forms coating A1.
Further, there is provided coating A1 dip-coating method, comprise the following steps：
S01：Environmentally friendly fishing net protective coating A1 is held in container；
S02：The fishing net for needing dip-coating is immersed in the environmentally friendly fishing net protective coating A1 in container by lifting appliance moving；
S03：Container is rocked repeatedly by external force, realizes the abundant contact and immersion of fishing net and environmentally friendly fishing net protective coating；
S04：Dried the outside with more rollers is moved to by soaking complete fishing net in equipment, first pass through roller it Between scrolling realization fishing net and unnecessary environmentally friendly fishing net protective coating removing, then the fishing net to soaking dries.
Embodiment two：
A kind of environmentally friendly fishing net protective rubber, including following components in percentage by weight (being shown in Table two) are provided：
Title Concrete component Percentage by weight
Resin： Acrylic resin, chloroprene nitrile 25%
Anti-fouling agent： Cuprous oxide 22%
Modified bactericide： Modified ZPT 16%
Color stuffing： Talcum powder 2%
Anti-settling agent： Dicalcium powder 6%
Solvent： Butyl acetate and dimethylbenzene 29%
(table two)
A kind of environmentally friendly fishing net protective coating is provided, the environmentally friendly fishing net protective coating is as the environmentally friendly fishing net protective rubber described in table two With toluene according to 1:2 weight ratios mix, and form coating A2；
Further, there is provided coating A2 dip-coating method, comprise the following steps：
S01：Environmentally friendly fishing net protective coating A2 is held in container；
S02：The fishing net for needing dip-coating is immersed in the environmentally friendly fishing net protective coating A2 in container by lifting appliance moving；
S03：Container is static condition, and outside agitator is fully stirred the environmentally friendly fishing net protective coating A2 in container Mix, pass through the flowing of liquid so that environmentally friendly fishing net protective coating can be penetrated into fully in fishing net, realize fishing net and environmentally friendly fishing net The abundant contact and immersion of protective coating；
S04：Outside will be moved to by the complete fishing net of immersion to dry in equipment, the fishing net soaked will be dried.
Embodiment three：
A kind of environmentally friendly fishing net protective rubber, including following components in percentage by weight (being shown in Table three) are provided：
Title Concrete component Percentage by weight
Resin： Acrylic resin, neoprene 30%
Anti-fouling agent： Cuprous oxide 32%
Modified bactericide： Modified ZPT 12%
Color stuffing： Pigment 1%
Anti-settling agent： Polyamide wax 5%
Solvent： Dimethylbenzene and toluene 20%
(table three)
A kind of environmentally friendly fishing net protective coating is provided, the environmentally friendly fishing net protective coating is as the environmentally friendly fishing net protective rubber described in table three With isobutanol according to 1:3 weight ratios mix, and form coating A3；
Further, there is provided coating A3 dip-coating method, comprise the following steps：
S01：Environmentally friendly fishing net protective coating A3 is held in container；
S02：The fishing net for needing dip-coating is immersed in the environmentally friendly fishing net protective coating A3 in container by lifting appliance moving；
S03：Container is static condition, and using external force, fishing net is pulled into the opposing party from a side of container, is pulled in fishing net During, outside mixing plant is constantly stirred to the coating A3 in container so that coating A3 can fully penetrate into fishing In net, the abundant contact and immersion of fishing net and coating A3 are realized；
S04：Outside will be moved to by the complete fishing net of immersion to dry in equipment, the fishing net soaked will be dried.
Example IV：
A kind of environmentally friendly fishing net protective rubber, including following components in percentage by weight (being shown in Table four) are provided：
Title Concrete component Percentage by weight
Resin： Acrylic resin, butadiene rubber 40%
Anti-fouling agent： Cuprous oxide 15%
Modified bactericide： Modified ZPT 15.5%
Color stuffing： Barium sulfate 0.5%
Anti-settling agent： Tissuemat E 1%
Solvent： Ethanol and dimethylbenzene 28%
(table four)
A kind of environmentally friendly fishing net protective coating is provided, the environmentally friendly fishing net protective coating is as the environmentally friendly fishing net protective rubber described in table four With butyl acetate according to 1:5 weight ratios mix, and form coating A4；
Further, there is provided coating A4 dip-coating method, comprise the following steps：
S01：Environmentally friendly fishing net protective coating A4 is held in container；
S02：The fishing net for needing dip-coating is immersed in the environmentally friendly fishing net protective coating A4 in container by lifting appliance moving；
S03：Container is rocked repeatedly by external force, realizes the abundant contact and immersion of fishing net and environmentally friendly fishing net protective coating；
S04：Outside will be moved to by the complete fishing net of immersion to dry in equipment, the fishing net soaked will be dried.
The application test result of each embodiments of environmentally friendly fishing net protective coating A1, A2, A3, A4 of the present invention is as follows：
Visible by the contrast of above-described embodiment application test result, the viscosity of four kinds of embodiments is all very low, coating flowing Property is relatively good, is easy to be attached on fishing net, surface drying time did solid work the time in 3 hours in 30 minutes, can quickly realize fishing Net dries；The thickness coated after fishing net is very thin, and fishing net weightening is micro- so that the coating infiltrates into the per share stock silk seam of fishing net In gap, and stock silk table face is wrapped up, so as to reach the omnibearing stereo formula soiling protective of fishing net, the fishing net after coating uses Life-span can reach 2 years durations, greatly extend the durability of fishing net.
The environmentally friendly fishing net protective rubber that one group of anti-fouling agent is made up of cuprous sulfocyanide is further provided for, details are as follows：
Embodiment five：
A kind of environmentally friendly fishing net protective rubber, including following components in percentage by weight (being shown in Table five) are provided：
(table five)
A kind of environmentally friendly fishing net protective coating is provided, the environmentally friendly fishing net protective coating is as the environmentally friendly fishing net protective rubber described in table five With toluene and isobutanol according to 1:1.5 weight ratios mix, and form coating A5.
Embodiment six：
A kind of environmentally friendly fishing net protective rubber, including following components in percentage by weight (being shown in Table six) are provided：
Title Concrete component Percentage by weight
Resin： Acrylic resin, chloroprene nitrile 20%
Anti-fouling agent： Cuprous sulfocyanide 27%
Modified bactericide： Modified ZPT 16.5%
Color stuffing： Talcum powder 0.5%
Anti-settling agent： Dicalcium powder 6%
Solvent： Butyl acetate and dimethylbenzene 30%
(table six)
A kind of environmentally friendly fishing net protective coating is provided, the environmentally friendly fishing net protective coating is as the environmentally friendly fishing net protective rubber described in table six With butyl acetate according to 1:3.5 weight ratios mix, and form coating A6.
Embodiment seven：
A kind of environmentally friendly fishing net protective rubber, including following components in percentage by weight (being shown in Table seven) are provided：
Title Concrete component Percentage by weight
Resin： Acrylic resin, butadiene rubber 35%
Anti-fouling agent： Cuprous sulfocyanide 20%
Modified bactericide： Modified ZPT 21%
Color stuffing： Barium sulfate 1%
Anti-settling agent： Polyamide wax 3%
Solvent： Dimethylbenzene and toluene 20%
(table seven)
A kind of environmentally friendly fishing net protective coating is provided, the environmentally friendly fishing net protective coating is as the environmentally friendly fishing net protective rubber described in table seven With toluene and dimethylbenzene according to 1:5 weight ratios mix, and form coating A7.
The application test result of each embodiments of environmentally friendly fishing net protective coating A5, A6, A7 of the present invention is as follows：
Visible by the contrast of above-described embodiment application test result, the viscosity of three kinds of embodiments is all very low, coating flowing Property is relatively good, is easy to be attached on fishing net, surface drying time did solid work the time in 4 hours in 60 minutes, can quickly realize fishing Net dries, and for fishing net thickness in 12um-30um, the life-span up to 1-2, not only realizes that coating coats the infiltrative raising of fishing net, And the durability for extending fishing net uses.
Further, there is provided coating A5 or A6 or A7 dip-coating method, comprise the following steps：
S01：Any of environmentally friendly fishing net protective coating A5, A6, A7 are held in container；
S02：The fishing net for needing dip-coating is immersed in the environmentally friendly fishing net protective coating in container by lifting appliance moving；
S03：Container is rocked repeatedly by external force, realizes the abundant contact and leaching of fishing net and environmentally friendly fishing net protective coating Bubble；
S04：Outside will be moved to by the complete fishing net of immersion to dry in equipment, the fishing net soaked will be dried.
Wherein, it is to dry equipment with more rollers that equipment is dried outside step S04, passes through the scrolling realization between roller Unnecessary environmentally friendly fishing net protective coating is eliminated on fishing net.
Above content is to combine specific preferred embodiment further description made for the present invention, it is impossible to is assert The specific implementation of the present invention is confined to these explanations, for those skilled in the art, is not taking off On the premise of from present inventive concept, some simple deduction or replace can also be made, should all be considered as belonging to the protection of the present invention Scope.

Claims (10)

  1. A kind of 1. environmentally friendly fishing net protective rubber, it is characterised in that：Including following components in percentage by weight：
  2. A kind of 2. environmentally friendly fishing net protective rubber according to claim 1, it is characterised in that：Include the group of following percentage by weight Point：
  3. A kind of 3. environmentally friendly fishing net protective rubber according to claim 1, it is characterised in that：Include the group of following percentage by weight Point：
  4. A kind of 4. environmentally friendly fishing net protective rubber according to claim any one of 1-3, it is characterised in that：
    The resin includes at least one of acrylic resin, neoprene, chloroprene nitrile, butadiene rubber；
    The modified bactericide is modified ZPT；
    The color stuffing includes at least one of pigment, talcum powder, barium sulfate；
    The anti-settling agent includes bentonite, dicalcium powder, polyamide wax, any in Tissuemat E；
    The solvent includes at least one of toluene, isobutanol, butyl acetate, ethanol, dimethylbenzene.
  5. A kind of 5. environmentally friendly fishing net protective rubber according to claim 4, it is characterised in that：The change of the modified ZPT Learning structural formula is：
  6. A kind of 6. environmentally friendly fishing net protective rubber according to claim 1 or 2, it is characterised in that：The anti-fouling agent is sub- for oxidation Copper.
  7. A kind of 7. environmentally friendly fishing net protective rubber according to claim 1 or 3, it is characterised in that：The anti-fouling agent is thiocyanic acid It is cuprous.
  8. A kind of 8. environmentally friendly fishing net protective coating, it is characterised in that：It is molten as the environmentally friendly fishing net protective rubber described in claim 1 and polarity Agent forms, and the environmentally friendly fishing net protective rubber is 1 with polar solvent percentage by weight:0.5∽1:5, form environmentally friendly fishing net protection and apply Expect A.
  9. A kind of 9. dip-coating method of environmentally friendly fishing net protective coating, it is characterised in that：Comprise the following steps：
    S01：Environmentally friendly fishing net protective coating A is held in container；
    S02：The fishing net for needing dip-coating is immersed in the environmentally friendly fishing net protective coating A in container by lifting appliance moving；
    S03：Container is rocked repeatedly by external force, realizes the abundant contact and immersion of fishing net and environmentally friendly fishing net protective coating A；
    S04：Outside will be moved to by the complete fishing net of immersion to dry in equipment, the fishing net soaked will be dried.
  10. A kind of 10. dip-coating method of environmentally friendly fishing net protective coating according to claim 9, it is characterised in that：Step S04 institutes It is to dry equipment with more rollers to state outside equipment of drying, and passes through unnecessary environmentally friendly fishing net on the scrolling realization fishing net between roller Protective coating is eliminated.
CN201711042903.6A 2017-10-30 2017-10-30 A kind of environmentally friendly fishing net protective rubber, protective coating and its dip-coating method Pending CN107868550A (en)

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Application Number Priority Date Filing Date Title
CN201711042903.6A CN107868550A (en) 2017-10-30 2017-10-30 A kind of environmentally friendly fishing net protective rubber, protective coating and its dip-coating method

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112479385A (en) * 2020-06-10 2021-03-12 宁波绿沁生态科技有限公司 Ecological water treatment facilities

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1694931A (en) * 2002-10-24 2005-11-09 Sk化学股份有限公司 Antifouling paint composition

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1694931A (en) * 2002-10-24 2005-11-09 Sk化学股份有限公司 Antifouling paint composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112479385A (en) * 2020-06-10 2021-03-12 宁波绿沁生态科技有限公司 Ecological water treatment facilities
CN112479385B (en) * 2020-06-10 2022-12-23 宁波绿沁生态科技有限公司 Ecological water treatment device

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