CN107868505A - A kind of coating additive and preparation method thereof - Google Patents

A kind of coating additive and preparation method thereof Download PDF

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Publication number
CN107868505A
CN107868505A CN201711237018.3A CN201711237018A CN107868505A CN 107868505 A CN107868505 A CN 107868505A CN 201711237018 A CN201711237018 A CN 201711237018A CN 107868505 A CN107868505 A CN 107868505A
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CN
China
Prior art keywords
parts
coating additive
essential oil
coating
essential oils
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711237018.3A
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Chinese (zh)
Inventor
李隆福
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi Ruihang Engineering Consulting Co Ltd
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Guangxi Ruihang Engineering Consulting Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by Guangxi Ruihang Engineering Consulting Co Ltd filed Critical Guangxi Ruihang Engineering Consulting Co Ltd
Priority to CN201711237018.3A priority Critical patent/CN107868505A/en
Publication of CN107868505A publication Critical patent/CN107868505A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention belongs to building material field, more particularly to a kind of coating additive and preparation method thereof, the relatively conventional coating additive coating additive can both improve the adhesiveness and glossiness, elimination steam bubble of coating, cause coating that there is preferable mould-proof bacteria-removing simultaneously, and it greatly strengthen the sterilization of coating, fungistatic effect, and sterilization material is harmless, environmental pollution will not be also caused.

Description

A kind of coating additive and preparation method thereof
【Technical field】
The invention belongs to building material field, and in particular to a kind of coating additive and preparation method thereof.
【Background technology】
Exterior wall paint coating of the prior art is big due to coated article face rough porous, oil absorption;And the coating prepared does not have A period of time is stood, dope viscosity is high, and bubble does not eliminate;Therefore, it is necessary to toward additive is added in coating, the property of coating is improved Can, addition functional additive performance comparision is single in existing coating, when needing to improve the combination property of coating, it is necessary to add Add multiple additives, cause the waste of resource, while improve the cost used.Therefore, existing coating needs a kind of more The additive of performance, improve the performance of coating.
【The content of the invention】
In view of problem above, the invention provides a kind of coating additive and preparation method thereof, the coating additive both may be used To improve the adhesiveness of coating and glossiness, eliminate steam bubble, while cause coating that there is preferable mould-proof bacteria-removing, and Sterilization, the fungistatic effect of coating are greatly strengthen, and sterilization material is harmless, will not also cause environmental pollution.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of coating additive is mainly made by the raw material of following parts by weight:17~26 parts of polyvinyl alcohol, 6~12 parts of poly- second Alkene pyrrolidone, 50~55 parts of hydrolyzed polyacrylamides, 2~7 parts of bamboo salts, 1~4 part of sodium alginate, 5~20 nano zine oxides, 10~15 parts plus peaceful eucalyptus essential oil, 2~6 parts of galanga galangal rhizome essential oils, 10~15 parts of syringic acids, 10~12 parts of essential oils in one's early teens.
Preferably, a kind of coating additive is mainly made by the raw material of following parts by weight:17 parts of polyvinyl alcohol, 6 parts of poly- second Alkene pyrrolidone, 50 parts of hydrolyzed polyacrylamides, 2 parts of bamboo salts, 1 part of sodium alginate, 5 nano zine oxides, 10 parts plus peaceful eucalyptus essential oil, 2 parts of galanga galangal rhizome essential oils, 10 parts of syringic acids, 10 parts of essential oils in one's early teens.
Preferably, a kind of coating additive is mainly made by the raw material of following parts by weight:22 parts of polyvinyl alcohol, 7 parts of poly- second Alkene pyrrolidone, 51 parts of hydrolyzed polyacrylamides, 4 parts of bamboo salts, 2 parts of sodium alginates, 15 nano zine oxides, 12 parts plus peaceful eucalyptus essence Oil, 5 parts of galanga galangal rhizome essential oils, 12 parts of syringic acids, 11 parts of essential oils in one's early teens.
Preferably, a kind of coating additive is mainly made by the raw material of following parts by weight:26 parts of polyvinyl alcohol, 12 parts of poly- second Alkene pyrrolidone, 55 parts of hydrolyzed polyacrylamides, 7 parts of bamboo salts, 4 parts of sodium alginates, 20 nano zine oxides, 15 parts plus peaceful eucalyptus essence Oil, 6 parts of galanga galangal rhizome essential oils, 15 parts of syringic acids, 12 parts of essential oils in one's early teens.
A kind of coating additive preparation method comprises the following steps:
1) the water dilution of polyvinyl alcohol, hydrolyzed polyacrylamide, polyvinylpyrrolidone 3 times of volumes of addition is sprayed on and stirred In the nano zine oxide mixed, kept for 15~25 minutes, it is 60~65 DEG C control temperature, then with it is ultrasonic it is fully dispersed after, obtain Stoste;
2) 80~95 DEG C are heated toward the stoste input bamboo salt obtained by step 1), sodium alginate, was stirred every 10~15 minutes Once, kept for 1~2 hour, adding syringic acid mixing, be stirred for after adding 20~30 minutes, temperature control is 20 during mixing ~40 DEG C, filtering, obtain mixture;
3) sequentially added to the mixture obtained by step 2) and add peaceful eucalyptus essential oil, in one's early teens galanga galangal rhizome essential oil, essential oil, Ran Houjin Row water bath heating temperature is 70~80 DEG C, then carries out vibration mixing with high speed shaker mixer again, hunting speed is 230~ 3000 revs/min, obtain coating additive.
By adopting the above-described technical solution, the invention has the advantages that:
The coating additive of the present invention, polyvinyl alcohol, polyvinylpyrrolidone, the hydrolyzed polyacrylamide of addition can carry The adhesiveness and glossiness of high coating, eliminate steam bubble, at the same with the addition of nano zine oxide, the presence of bamboo salt cause coating have compared with The effect of good mould-proof bacteria-removing, and the presence of natural traditional Chinese medicine essential oil greatly strengthen the sterilization of coating, fungistatic effect, and sterilize Material is harmless, will not also cause environmental pollution.
【Embodiment】
The following examples can help those skilled in the art that the present invention is more fully understood, but cannot be with any Mode limits the present invention.
Embodiment 1
A kind of coating additive is mainly made by the raw material of following parts by weight:17 parts of polyvinyl alcohol, 6 parts of polyvinylpyrrolidines It is ketone, 50 parts of hydrolyzed polyacrylamides, 2 parts of bamboo salts, 1 part of sodium alginate, 5 nano zine oxides, 10 parts plus peaceful eucalyptus essential oil, 2 parts big good Ginger essential oil, 10 parts of syringic acids, 10 parts of essential oils in one's early teens.
Its preparation method comprises the following steps:
1) the water dilution of polyvinyl alcohol, hydrolyzed polyacrylamide, polyvinylpyrrolidone 3 times of volumes of addition is sprayed on and stirred In the nano zine oxide mixed, kept for 15 minutes, it is 60 DEG C control temperature, then with it is ultrasonic it is fully dispersed after, obtain stoste;
2) 80 DEG C are heated toward the stoste input bamboo salt obtained by step 1), sodium alginate, every stirring in 10 minutes once, kept 1 hour, syringic acid mixing is being added, is being stirred for after adding 20 minutes, temperature control filtering, is mixed at 20 DEG C during mixing Thing;
3) sequentially added to the mixture obtained by step 2) and add peaceful eucalyptus essential oil, in one's early teens galanga galangal rhizome essential oil, essential oil, Ran Houjin Row water bath heating temperature is 70 DEG C, then carries out vibration mixing with high speed shaker mixer again, and hunting speed is 230 revs/min, is obtained To coating additive.
Embodiment 2
A kind of coating additive is mainly made by the raw material of following parts by weight:22 parts of polyvinyl alcohol, 7 parts of polyvinylpyrrolidines It is ketone, 51 parts of hydrolyzed polyacrylamides, 4 parts of bamboo salts, 2 parts of sodium alginates, 15 nano zine oxides, 12 parts plus peaceful eucalyptus essential oil, 5 parts big good Ginger essential oil, 12 parts of syringic acids, 11 parts of essential oils in one's early teens.
Its preparation method comprises the following steps:
1) the water dilution of polyvinyl alcohol, hydrolyzed polyacrylamide, polyvinylpyrrolidone 3 times of volumes of addition is sprayed on and stirred In the nano zine oxide mixed, kept for 18 minutes, it is 62 DEG C control temperature, then with it is ultrasonic it is fully dispersed after, obtain stoste;
2) 85 DEG C are heated toward the stoste input bamboo salt obtained by step 1), sodium alginate, every stirring in 12 minutes once, kept 1.5 hours, syringic acid mixing is being added, is being stirred for after adding 25 minutes, temperature control filtering, is mixed at 25 DEG C during mixing Compound;
3) sequentially added to the mixture obtained by step 2) and add peaceful eucalyptus essential oil, in one's early teens galanga galangal rhizome essential oil, essential oil, Ran Houjin Row water bath heating temperature is 75 DEG C, then carries out vibration mixing with high speed shaker mixer again, and hunting speed is 2300 revs/min, Obtain coating additive.
Embodiment 3
A kind of coating additive is mainly made by the raw material of following parts by weight:26 parts of polyvinyl alcohol, 12 parts of polyvinyl pyrroles It is alkanone, 55 parts of hydrolyzed polyacrylamides, 7 parts of bamboo salts, 4 parts of sodium alginates, 20 nano zine oxides, 15 parts plus peaceful eucalyptus essential oil, 6 parts big Galingal essential oil, 15 parts of syringic acids, 12 parts of essential oils in one's early teens.
Its preparation method comprises the following steps:
1) the water dilution of polyvinyl alcohol, hydrolyzed polyacrylamide, polyvinylpyrrolidone 3 times of volumes of addition is sprayed on and stirred In the nano zine oxide mixed, kept for 25 minutes, it is 65 DEG C control temperature, then with it is ultrasonic it is fully dispersed after, obtain stoste;
2) 95 DEG C are heated toward the stoste input bamboo salt obtained by step 1), sodium alginate, every stirring in 15 minutes once, kept 2 hours, syringic acid mixing is being added, is being stirred for after adding 30 minutes, temperature control filtering, is mixed at 40 DEG C during mixing Thing;
3) sequentially added to the mixture obtained by step 2) and add peaceful eucalyptus essential oil, in one's early teens galanga galangal rhizome essential oil, essential oil, Ran Houjin Row water bath heating temperature is 80 DEG C, then carries out vibration mixing with high speed shaker mixer again, and hunting speed is 3000 revs/min, Obtain coating additive.
Although above the present invention is described in detail with a general description of the specific embodiments, On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause This, these modifications or improvements, belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.

Claims (5)

1. a kind of coating additive, it is characterised in that the coating additive is mainly made by the raw material of following parts by weight:17~ 26 parts of polyvinyl alcohol, 6~12 parts of polyvinylpyrrolidones, 50~55 parts of hydrolyzed polyacrylamides, 2~7 parts of bamboo salts, 1~4 part of sea Mosanom, 5~20 nano zine oxides, 10~15 parts plus peaceful eucalyptus essential oil, 2~6 parts of galanga galangal rhizome essential oils, 10~15 parts of syringic acids, 10 ~12 parts of essential oils in one's early teens.
2. coating additive as claimed in claim 1, it is characterised in that the coating additive is mainly by following parts by weight Raw material is made:17 parts of polyvinyl alcohol, 6 parts of polyvinylpyrrolidones, 50 parts of hydrolyzed polyacrylamides, 2 parts of bamboo salts, 1 part of alginic acid Sodium, 5 nano zine oxides, 10 parts plus peaceful eucalyptus essential oil, 2 parts of galanga galangal rhizome essential oils, 10 parts of syringic acids, 10 parts of essential oils in one's early teens.
3. coating additive as claimed in claim 1, it is characterised in that the coating additive is mainly by following parts by weight Raw material is made:22 parts of polyvinyl alcohol, 7 parts of polyvinylpyrrolidones, 51 parts of hydrolyzed polyacrylamides, 4 parts of bamboo salts, 2 parts of alginic acids Sodium, 15 nano zine oxides, 12 parts plus peaceful eucalyptus essential oil, 5 parts of galanga galangal rhizome essential oils, 12 parts of syringic acids, 11 parts of essential oils in one's early teens.
4. coating additive as claimed in claim 1, it is characterised in that the coating additive is mainly by following parts by weight Raw material is made:26 parts of polyvinyl alcohol, 12 parts of polyvinylpyrrolidones, 55 parts of hydrolyzed polyacrylamides, 7 parts of bamboo salts, 4 parts of alginic acids Sodium, 20 nano zine oxides, 15 parts plus peaceful eucalyptus essential oil, 6 parts of galanga galangal rhizome essential oils, 15 parts of syringic acids, 12 parts of essential oils in one's early teens.
5. the preparation method of coating additive as claimed in claim 1, it is characterised in that the preparation side of the coating additive Method comprises the following steps:
1) the water dilution that polyvinyl alcohol, hydrolyzed polyacrylamide, polyvinylpyrrolidone are added to 3 times of volumes is sprayed in stirring Nano zine oxide in, kept for 15~25 minutes, it is 60~65 DEG C control temperature, then with it is ultrasonic it is fully dispersed after, obtain stoste;
2) 80~95 DEG C are heated toward the stoste input bamboo salt obtained by step 1), sodium alginate, every stirring in 10~15 minutes once, Kept for 1~2 hour, adding syringic acid mixing, be stirred for after adding 20~30 minutes, temperature control is 20~40 during mixing DEG C, filtering, obtain mixture;
3) sequentially added to the mixture obtained by step 2) and add peaceful eucalyptus essential oil, in one's early teens galanga galangal rhizome essential oil, essential oil, then enter water-filling It is 70~80 DEG C to bathe heating-up temperature, then carries out vibration mixing with high speed shaker mixer again, and hunting speed is 230~3000 Rev/min, obtain coating additive.
CN201711237018.3A 2017-11-30 2017-11-30 A kind of coating additive and preparation method thereof Pending CN107868505A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711237018.3A CN107868505A (en) 2017-11-30 2017-11-30 A kind of coating additive and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711237018.3A CN107868505A (en) 2017-11-30 2017-11-30 A kind of coating additive and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107868505A true CN107868505A (en) 2018-04-03

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Country Status (1)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103555044A (en) * 2013-10-23 2014-02-05 三棵树涂料股份有限公司 Nano multifunctional paint additive
CN104098948A (en) * 2014-07-28 2014-10-15 广西梧州龙鱼漆业有限公司 Additive for coating used in public place
CN105802308A (en) * 2014-12-29 2016-07-27 中国科学院宁波材料技术与工程研究所 Multifunctional auxiliary agent for aqueous anticorrosion paint, anticorrosion paint and use of anticorrosion paint
CN106905741A (en) * 2017-03-29 2017-06-30 合肥天沃能源科技有限公司 A kind of coating additive and preparation method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103555044A (en) * 2013-10-23 2014-02-05 三棵树涂料股份有限公司 Nano multifunctional paint additive
CN104098948A (en) * 2014-07-28 2014-10-15 广西梧州龙鱼漆业有限公司 Additive for coating used in public place
CN105802308A (en) * 2014-12-29 2016-07-27 中国科学院宁波材料技术与工程研究所 Multifunctional auxiliary agent for aqueous anticorrosion paint, anticorrosion paint and use of anticorrosion paint
CN106905741A (en) * 2017-03-29 2017-06-30 合肥天沃能源科技有限公司 A kind of coating additive and preparation method

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