CN107868486A - Anti-static non-ignition composite and preparation method thereof - Google Patents
Anti-static non-ignition composite and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/08—Ingredients of unknown constitution and ingredients covered by the main groups C08K3/00 - C08K9/00
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K11/00—Use of ingredients of unknown constitution, e.g. undefined reaction products
- C08K11/005—Waste materials, e.g. treated or untreated sewage sludge
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/085—Copper
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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Abstract
The invention belongs to building material technical field, and in particular to a kind of anti-static non-ignition composite and preparation method thereof.Anti-static non-ignition composite is made up of the following raw material：Solid waste, alkali-free short glass fiber, resin, conducting powder, accelerator, releasing agent, curing agent, pigment.The composite acid-alkali-corrosive-resisting of the present invention, high mechanical strength, static electricity resistance and performance of misfiring meet relevant criterion requirement, are a kind of new type functional composites.Both ceramic polished waste powder, fine coal ashes comprehensive utilization of resources had been realized, environmental protection, has assigned its multi-functional, wide market again.
Description
Technical field
The invention belongs to building material technical field, and in particular to a kind of anti-static non-ignition composite and its preparation side
Method.
Background technology
With the fast development of Structural ceramics industry, the quantity of shraff, especially tile polished waste is more and more, according to
Statistics：The year output estimation of national tile polished waste is 5,000,000 tons or so (shraff total amounts estimated 10,000,000 tons), so
Substantial amounts of shraff can not solve with simple burying method, meanwhile, the shraff of bulk deposition squeezes at present
Soil is accounted for, serious pollution is caused to environment such as water, air and soil.Flyash is the coal dust and bastard coal by wearing into certain fineness
Stone flour collects after high-temp combustion the fine ash come in fluidized-bed combustion boiler, it be the larger industrial residue of the current discharge capacity in China it
One, substantial amounts of flyash is untreated, will produce airborne dust, pollutes air, river can be caused to silt up if being discharged into water system, and wherein
Toxic chemical substance human body and biology can also be damaged.Mineral have both been saved using ceramic tile polishing waste material and flyash
Raw material resources, natural environment is also protected, embody the meaning of important environmental protection and energy-saving and emission-reduction.
In industrial building, for example, military project manufacture, liquefied petroleum-gas station, Gas Production factory, oiling storehouse, petrol station harbour and its
The regions such as his inflammable and explosive engineering, warehouse, have fire-proof and explosion-proof particular/special requirement to ground or wall, especially plane materiel over the ground
The requirement of material is very tight, must have antistatic, misfiring property.Material of misfiring at present can be divided into three classes, i.e.,：Misfire metal
The non-ferrous metal such as ground, its material typically conventional copper coin, aluminium sheet makes；The ground of organic material of misfiring manufacture, such as pitch, wood
The layings such as material, plastics, rubber；Inorganic material of misfiring ground, it is using misfire cement stone sand, pea gravel concreten, water mill
The inorganic material such as stone manufacture, and aggregate can be selected lime stone, marble, dolomite etc. and misfire material.Misfire and metal and do not send out
Fiery inorganic material ground is not resistant to chemical etching；Misfire the poorly conductive of organic material, there is insulation function, therefore to guiding
Electrostatic is unfavorable, also to fire-proof and explosion-proof unfavorable.
Presently used antistatic floor has all steel antistatic raised floor, aluminium alloy antistatic floor, and chemically-resistant is not rotten
Erosion；Compounded antistatic floor, the fire-protection rating of straight paving formula pvc antistatic floors are low；Ceramic antistatic floor and static-electricity proof tile
Mohs' hardness it is too high, friction, impact when easily produce spark, to fire-proof and explosion-proof unfavorable.The work(of antistatic floor used
Energy property is all very single.
The content of the invention
It is an object of the invention to provide a kind of anti-static non-ignition composite, has permanent antistatic, misfires, resistance toization
The advantages of learning corrosion, available for military project manufacture, liquefied petroleum-gas station, Gas Production factory, oiling storehouse, petrol station harbour and other are inflammable
The regions such as explosive engineering, warehouse, there is the occasion of fire-proof and explosion-proof particular/special requirement working environment, eliminate the shadow to production environment
Ring.
Anti-static non-ignition composite of the present invention, is made up of the raw material of following percentage by weight：
The addition of accelerator is the 0.5~0.8% of resin quality, the addition of releasing agent for resin quality 1.5~
2.0%, the addition of curing agent is the 0.7~1.2% of resin quality, the addition of pigment for resin quality 0.5~
1.0%.
Described solid waste is ceramic polished waste powder or fine coal ashes, and the fineness of solid waste is 325 mesh.
Described alkali-free short glass fiber is pencil, and length is 6~10mm.
Described resin is vinyl unsaturated-resin.
Described conducting powder be superfine cupper powder, superfine aluminium power or ultrafine electricity conductive graphite in one kind, superfine cupper powder, ultra-fine aluminium
The granule size of powder or ultrafine electricity conductive graphite is uniform, and particle diameter is 8-10 microns.
Described accelerator is cobalt iso-octoate.
Described releasing agent is zinc stearate.
Described curing agent is tert-butyl peroxide benzoyl.
Described pigment is one or both of inorganic pigment or mill base.
The preparation method of anti-static non-ignition composite of the present invention, step are as follows：
(1) resin, solid waste, conducting powder, accelerator, releasing agent, curing agent and pigment are mixed with mixer in advance
Stir, obtain compound；
(2) compound to stir and alkali-free short glass fiber are put into vacuum kneader kneading, are kneaded；
(3) it will mediate, be kneaded uniform raw material feeding forming machine, be molded using die pressing；
(4) dough is put into the mould being preheated when being molded, matched moulds is compressing；
(5) curing, finished product, packaging.
The preparation method of anti-static non-ignition composite of the present invention, is comprised the following steps that：
(1) resin, solid waste, conducting powder, accelerator, releasing agent, curing agent and pigment are mixed with mixer in advance
Stir, obtain compound；
(2) compound to stir and alkali-free short glass fiber are put into vacuum kneader kneading, are kneaded；
(3) it mediating, be kneaded uniform raw material and be sent into forming machine, be molded using die pressing, pressure limit is 10~
20MPa, the shaping dwell time is different according to product thickness and changes, and is 1.0~1.5 minutes/mm of thickness；
(4) dough is put into the mould being preheated when being molded, rapid matched moulds, and it is compressing by conditions above；Mould
It is 150 ± 5 DEG C to have temperature；
(5) curing, finished product, packaging, curing time are 50~60 minutes.
The present invention compared with prior art, has the advantages that：
It is resistant to chemical etching compound for anti-static non-ignition using ceramic polished waste material, coal ash for manufacturing the invention provides one kind
The method of material.The composite is using ceramic polished waste material or flyash, alkali-free short glass fiber, conducting powder to be main former
Material, addition releasing agent, accelerator, curing agent, pigment, bonds and solidifies obtained artificial compounded product with organic resin.This hair
Bright ceramic polished waste material, coal ash for manufacturing are for anti-static non-ignition sheet material, not only with the strong function of antistatic characteristic, surface point pair
Point resistance and volume resistance are 5 × 104-1×109Ω, comply with the national standard requirements, available for living environment and special experiment
Room working environment is, it is necessary to which antistatic requires, elimination electrostatic is to life and the harmful effect of working environment electrostatic and interference；And have
Misfire function；Also there is performance resistant to chemical etching simultaneously.Formula introduces a large amount of ceramic polished waste material, flyash, utilizes
It turns waste into wealth, and mitigates environmental pollution, promotes health, and protects live and work environment.
The composite acid-alkali-corrosive-resisting of the present invention, high mechanical strength, static electricity resistance and performance of misfiring meet correlation
Standard requirement, is a kind of new type functional composite.Both ceramic polished waste powder, fine coal ashes resource comprehensive profit had been realized
With environmental protection, assigning its multi-functional, wide market again.
The key technical indexes
Embodiment
The present invention is described further with reference to embodiments.
Embodiment 1
Raw material forms, by weight percentage：Ceramic polished waste powder 35%, alkali-free short glass fiber 20%, ethene
Base unsaturated-resin 30%, conducting powder superfine cupper powder 15%；
Counted using vinyl unsaturated-resin quality as 100%, accelerator cobalt iso-octoate 0.5%, stearic acid release agent zinc
1.5%th, curing agent tert-butyl peroxide benzoyl 0.7%, pigment 0.5%.
Preparation technology comprises the following steps：
(1) by vinyl unsaturated-resin, ceramic polished waste powder, conducting powder, accelerator, releasing agent, curing agent and face
Material is mixed evenly with mixer in advance；
(2) compound to stir and alkali-free short glass fiber are put into vacuum kneader kneading in proportion, are kneaded；
(3) it will mediate, be kneaded uniform raw material feeding forming machine, be molded using die pressing, pressure 10MPa, be molded pressurize
Time is 1.0 minutes/mm of thickness；
(4) dough is put into the mould being preheated when being molded, rapid matched moulds, and it is compressing by conditions above；Mould
It is 150 ± 5 DEG C to have temperature；
(5) curing, finished product, packaging, curing time are 50 minutes.
Product index：Impact strength 22.8kJ/m2, bending strength 112.8MPa；Volume resistance is 5.3 × 107Ω；Do not send out
Fire；It is acidproof：It is unchanged that 4h is soaked in 20wt% hydrochloric acid, it is alkaline-resisting：It is unchanged that 4h is soaked in 10wt%NaOH；Fire resistance：
Oxygen index (OI) OI is 36.0；Anti-wear performance：Wear away as 65mg/cm2。
Embodiment 2
Raw material forms, by weight percentage：Fine coal ashes 33%, alkali-free short glass fiber 24%, vinyl insatiable hunger
With resin 29%, conducting powder superfine aluminium power 14%；
Counted using vinyl unsaturated-resin quality as 100%, accelerator 0.6%, stearic acid release agent zinc 1.6%, solidification
Agent tert-butyl peroxide benzoyl 0.9%, pigment 0.6%.
Preparation technology comprises the following steps：
(1) it is vinyl unsaturated-resin, fine coal ashes, conducting powder, accelerator, releasing agent, curing agent and pigment is advance
It is mixed evenly with mixer；
(2) compound to stir and alkali-free short glass fiber are put into vacuum kneader kneading in proportion, are kneaded；
(3) it will mediate, be kneaded uniform raw material feeding forming machine, be molded, pressure limit 20MPa, be molded using die pressing
Dwell time is different according to product thickness and changes, and is 1.5 minutes/mm of thickness；
(4) dough is put into the mould being preheated when being molded, rapid matched moulds, and it is compressing by conditions above；Mould
It is 150 ± 5 DEG C to have temperature；
(5) curing, finished product, packaging, curing time are 60 minutes.
Product index：Impact strength 24.3kJ/m2, bending strength 110.2MPa；Volume resistance is 6.4 × 108Ω；Do not send out
Fire；It is acidproof：It is unchanged that 4h is soaked in 20wt% hydrochloric acid, it is alkaline-resisting：It is unchanged that 4h is soaked in 10wt%NaOH；Fire resistance：
Oxygen index (OI) OI is 40.0；Anti-wear performance：Wear away as 67mg/cm2。
Embodiment 3
Raw material forms, by weight percentage：Ceramic polished waste powder 35%, alkali-free short glass fiber 25%, ethene
Base unsaturated-resin 25%, conducting powder ultrafine electricity conductive graphite 15%；
Counted using vinyl unsaturated-resin quality as 100%, accelerator cobalt iso-octoate 0.7%, stearic acid release agent zinc
1.8%th, curing agent tert-butyl peroxide benzoyl 1.0%, pigment 0.8%.
Preparation technology comprises the following steps：
(1) by vinyl unsaturated-resin, ceramic polished waste powder, conducting powder, accelerator, releasing agent, curing agent and face
Material is mixed evenly with mixer in advance；
(2) compound to stir and alkali-free short glass fiber are put into vacuum kneader kneading in proportion, are kneaded；
(3) it will mediate, be kneaded uniform raw material feeding forming machine, be molded, pressure limit 15MPa, be molded using die pressing
Dwell time is 1.2 minutes/mm of thickness；
(4) dough is put into the mould being preheated when being molded, rapid matched moulds, and it is compressing by conditions above；Mould
It is 150 ± 5 DEG C to have temperature；
(5) curing, finished product, packaging, curing time are 55 minutes.
Product index：Impact strength 25.4kJ/m2, bending strength 108.0MPa；Volume resistance is 8.2 × 108Ω；Do not send out
Fire；It is acidproof：It is unchanged that 4h is soaked in 20wt% hydrochloric acid, it is alkaline-resisting：It is unchanged that 4h is soaked in 10wt%NaOH；Fire resistance：
Oxygen index (OI) OI is 38.0；Anti-wear performance：Wear away as 64mg/cm2。
Embodiment 4
Raw material forms, by weight percentage：Fine coal ashes 35%, alkali-free short glass fiber 25%, vinyl insatiable hunger
With resin 30%, conducting powder superfine cupper powder 10%；
Counted using vinyl unsaturated-resin quality as 100%, accelerator cobalt iso-octoate 0.6%, stearic acid release agent zinc
1.9%th, curing agent tert-butyl peroxide benzoyl 0.8%, pigment 0.7%.
Preparation technology comprises the following steps：
(1) it is vinyl unsaturated-resin, fine coal ashes, conducting powder, accelerator, releasing agent, curing agent and pigment is advance
It is mixed evenly with mixer；
(2) compound to stir and alkali-free short glass fiber are put into vacuum kneader kneading in proportion, are kneaded；
(3) it will mediate, be kneaded uniform raw material feeding forming machine, be molded, pressure limit 12MPa, be molded using die pressing
Dwell time is 1.2 minutes/mm of thickness；
(4) dough is put into the mould being preheated when being molded, rapid matched moulds, and it is compressing by conditions above；Mould
It is 150 ± 5 DEG C to have temperature；
(5) curing, finished product, packaging, curing time are 52 minutes.
Product index：Impact strength 25.4kJ/m2, bending strength 108.0MPa；Volume resistance is 9.2 × 106Ω；Do not send out
Fire；It is acidproof：It is unchanged that 4h is soaked in 20wt% hydrochloric acid, it is alkaline-resisting：It is unchanged that 4h is soaked in 10wt%NaOH；Fire resistance：
Oxygen index (OI) OI is 36.5；Anti-wear performance：Wear away as 66mg/cm2。
Embodiment 5
Raw material forms, by weight percentage：Ceramic polished waste powder 34%, alkali-free short glass fiber 25%, ethene
Base unsaturated-resin 28%, conducting powder superfine aluminium power 13%；
Counted using vinyl unsaturated-resin quality as 100%, accelerator cobalt iso-octoate 0.8%, stearic acid release agent zinc
2.0%th, curing agent tert-butyl peroxide benzoyl 1.2%, pigment 1.0%.
Preparation technology comprises the following steps：
(1) by vinyl unsaturated-resin, ceramic polished waste powder, conducting powder, accelerator, releasing agent, curing agent and face
Material is mixed evenly with mixer in advance；
(2) compound to stir and alkali-free short glass fiber are put into vacuum kneader kneading in proportion, are kneaded；
(3) it will mediate, be kneaded uniform raw material feeding forming machine, be molded, pressure limit 10MPa, be molded using die pressing
Dwell time is 1.5 minutes/mm of thickness；
(4) dough is put into the mould being preheated when being molded, rapid matched moulds, and it is compressing by conditions above；Mould
It is 150 ± 5 DEG C to have temperature；
(5) curing, finished product, packaging, curing time are 53 minutes.
Product index：Impact strength 25.4kJ/m2, bending strength 108.0MPa；Volume resistance is 2.8 × 108Ω；Do not send out
Fire；It is acidproof：It is unchanged that 4h is soaked in 20wt% hydrochloric acid, it is alkaline-resisting：It is unchanged that 4h is soaked in 10wt%NaOH；Fire resistance：
Oxygen index (OI) OI is 45.5；Anti-wear performance：Wear away as 64mg/cm2。
The present invention improves its performance while anti-static non-ignition material production cost is reduced, and improves the profit of enterprise
Profit, there is the advantages of production cost is low, production efficiency is high, good economy performance.
Claims (10)
1. a kind of anti-static non-ignition composite, it is characterised in that be made up of the raw material of following percentage by weight：
The addition of accelerator is the 0.5~0.8% of resin quality, the addition of releasing agent for resin quality 1.5~
2.0%, the addition of curing agent is the 0.7~1.2% of resin quality, the addition of pigment for resin quality 0.5~
1.0%.
2. anti-static non-ignition composite according to claim 1, it is characterised in that described solid waste is ceramics
Polished waste material powder or fine coal ashes, the fineness of solid waste is 325 mesh.
3. anti-static non-ignition composite according to claim 1, it is characterised in that described alkali-free staple glass is fine
It is 6~10mm to tie up as pencil, length.
4. anti-static non-ignition composite according to claim 1, it is characterised in that described resin be vinyl not
Saturated resin.
5. anti-static non-ignition composite according to claim 1, it is characterised in that described conducting powder is ultra-fine copper
One kind in powder, superfine aluminium power or ultrafine electricity conductive graphite.
6. anti-static non-ignition composite according to claim 1, it is characterised in that described accelerator is isooctyl acid
Cobalt.
7. anti-static non-ignition composite according to claim 1, it is characterised in that described releasing agent is stearic acid
Zinc.
8. anti-static non-ignition composite according to claim 1, it is characterised in that described curing agent is peroxidating
Tert-butyl benzoyl.
9. anti-static non-ignition composite according to claim 1, it is characterised in that described pigment is inorganic pigment
Or one or both of mill base.
A kind of 10. preparation method of any described anti-static non-ignition composites of claim 1-9, it is characterised in that step
It is as follows：
(1) resin, solid waste, conducting powder, accelerator, releasing agent, curing agent and pigment are mixed with mixer in advance
Uniformly, compound is obtained；
(2) compound to stir and alkali-free short glass fiber are put into vacuum kneader kneading, are kneaded；
(3) it will mediate, be kneaded uniform raw material feeding forming machine, be molded using die pressing；
(4) dough is put into the mould being preheated when being molded, matched moulds is compressing；
(5) curing, finished product, packaging.
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| CN201711269440.7A CN107868486A (en) | 2017-12-05 | 2017-12-05 | Anti-static non-ignition composite and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711269440.7A CN107868486A (en) | 2017-12-05 | 2017-12-05 | Anti-static non-ignition composite and preparation method thereof |
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|---|---|
| CN107868486A true CN107868486A (en) | 2018-04-03 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1670086A (en) * | 2004-12-17 | 2005-09-21 | 毕舒 | Method for preparing filling for rubber plastic by using ceramic polishing tail slime or ceramic waste material |
| CN106930503A (en) * | 2017-03-16 | 2017-07-07 | 杭州电盾装饰材料有限公司 | Anti-static non-ignition ground and preparation method thereof |
| CN107226980A (en) * | 2017-06-21 | 2017-10-03 | 东莞市佳乾新材料科技有限公司 | A kind of polyvinyl chloride composite sound isolating material and preparation method thereof |
| CN107353528A (en) * | 2017-06-22 | 2017-11-17 | 山东理工大学 | A kind of anti-static non-ignition composite board and preparation method thereof |
-
2017
- 2017-12-05 CN CN201711269440.7A patent/CN107868486A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1670086A (en) * | 2004-12-17 | 2005-09-21 | 毕舒 | Method for preparing filling for rubber plastic by using ceramic polishing tail slime or ceramic waste material |
| CN106930503A (en) * | 2017-03-16 | 2017-07-07 | 杭州电盾装饰材料有限公司 | Anti-static non-ignition ground and preparation method thereof |
| CN107226980A (en) * | 2017-06-21 | 2017-10-03 | 东莞市佳乾新材料科技有限公司 | A kind of polyvinyl chloride composite sound isolating material and preparation method thereof |
| CN107353528A (en) * | 2017-06-22 | 2017-11-17 | 山东理工大学 | A kind of anti-static non-ignition composite board and preparation method thereof |
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Application publication date: 20180403 |