CN107868301A - A kind of preparation method of anti-static composite material - Google Patents
A kind of preparation method of anti-static composite material Download PDFInfo
- Publication number
- CN107868301A CN107868301A CN201610852011.1A CN201610852011A CN107868301A CN 107868301 A CN107868301 A CN 107868301A CN 201610852011 A CN201610852011 A CN 201610852011A CN 107868301 A CN107868301 A CN 107868301A
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- CN
- China
- Prior art keywords
- mass parts
- composite material
- preparation
- static composite
- toughener
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of preparation method of anti-static composite material, the preparation process of this method are as follows：In parts by mass, after each component is uniformly mixed according to a ratio, extruded in addition double screw extruder after melt blending, cooling granulation, produce the anti-static composite material of the present invention.Plastics produced by the present invention have good antistatic and anti-wear performance；And the mechanical strength of plastics is not influenceed；The compatibility with resin will get well simultaneously, do not migrate, do not separate out, be not extracted in plastic products.
Description
Technical field
The invention belongs to polymeric material field, and in particular to a kind of preparation method of anti-static composite material.
Technical background
Electrostatic, (electric charge of flowing is formed immobilising electric charge exactly a kind of electric charge to remain static in other words
Electric current).Electrostatic is formed when accumulation is on some object or surface, and electric charge is divided into positive charge and negative electrical charge two
Kind, that is to say, that electrostatic phenomenon is also classified into two kinds of i.e. positive electrostatic and negative electrostatic.When positive charge is gathered on some object with regard to shape
Into positive electrostatic, negative electrostatic is formed when negative electrical charge is gathered on some object, but either positive electrostatic still bears electrostatic,
Electric charge transfer can all occur when static electrification object contacts zero potential object (ground connection object) or has the object of potential difference with it, just
Being that we are daily sees Spark Discharges.Such as northern wintry weather is dried, human body easily takes electrostatic, when contact he or gold
When belonging to electric conductor will Discharge Phenomena, these electrostatic have certain infringement to human body.
The content of the invention
For above shortcomings in the prior art, it is an object of the present invention to provide a kind of nonabradable antistatic compound
The preparation method of material.
The purpose of the present invention is achieved through the following technical solutions：A kind of preparation method of anti-static composite material, by
Following weight parts component forms：160-165 mass parts butadiene-styrene rubber, 30-35 mass parts neoprene, the poly- carbonic acid of 10-14 mass parts
Ester resin, 10-15 mass parts toughener, 10-15 mass parts plasticizer, 10-13 mass parts calcium sulfate, 6-10 mass parts are disperseed
Agent, 10-12 mass parts antistatic additive and 10-14 mass parts toughener be sufficiently mixed uniformly after, add double screw extruder in
Extruded at a temperature of 170-200 DEG C and under the conditions of screw speed 80-90r/min after melt blending, cooling granulation, produce the present invention's
Anti-static composite material.
The toughener is grafting maleic anhydride with ethylene propylene terpolymer.
The dispersant is one kind in Tissuemat E, OPE, polyamide wax.
The plasticizer is adipic acid monomethyl ester, monoethyl adipatee, sebacic acid monomethyl ester or ethyl glutarate.
The antistatic additive is graphite or conductive carbon fibre.
The device have the advantages that：Plastics produced by the present invention have good antistatic and anti-wear performance；And
The mechanical strength of plastics is not influenceed；The compatibility with resin will get well simultaneously, do not migrate, do not separate out in plastic products, not extracted
Take.
Embodiment
Embodiment 1
The preparation of anti-static composite material：By 160-165 mass parts butadiene-styrene rubber, 30-35 mass parts neoprene, 10-14
Mass parts polycarbonate resin, 10-15 mass parts toughener, 10-15 mass parts plasticizer, 10-13 mass parts calcium sulfate, 6-10
After mass parts dispersant, 10-12 mass parts antistatic additive and 10-14 mass parts toughener are sufficiently mixed uniformly, twin-screw is added
Extruded in extruder at a temperature of 170-200 DEG C and under the conditions of screw speed 80-90r/min after melt blending, cooling granulation, i.e.,
Obtain anti-static composite material of the invention.
The toughener is grafting maleic anhydride with ethylene propylene terpolymer.The dispersant is Tissuemat E, oxidic polyethylene
One kind in wax, polyamide wax.The plasticizer is adipic acid monomethyl ester, monoethyl adipatee, sebacic acid monomethyl ester or penta 2
Diethyl phthalate.The antistatic additive is graphite or conductive carbon fibre.
Embodiment 2
The preparation of anti-static composite material：By 164 mass parts butadiene-styrene rubber, 35 mass parts neoprenes, the poly- carbon of 13 mass parts
Acid ester resin, 15 mass parts toughener, 14 mass parts plasticizer, 13 mass parts calcium sulfate, 8 mass parts dispersants, 11 mass parts
Antistatic additive and 14 mass parts toughener be sufficiently mixed uniformly after, add double screw extruder at a temperature of 170-200 DEG C and
Extruded under the conditions of screw speed 80-90r/min after melt blending, cooling granulation, produce the anti-static composite material of the present invention.
The toughener is grafting maleic anhydride with ethylene propylene terpolymer.The dispersant is Tissuemat E, oxidic polyethylene
One kind in wax, polyamide wax.The plasticizer is adipic acid monomethyl ester, monoethyl adipatee, sebacic acid monomethyl ester or penta 2
Diethyl phthalate.The antistatic additive is graphite or conductive carbon fibre.
Embodiment 3
The preparation of anti-static composite material：By 162 mass parts butadiene-styrene rubber, 31 mass parts neoprenes, the poly- carbon of 11 mass parts
Acid ester resin, 11 mass parts toughener, 11 mass parts plasticizer, 11 mass parts calcium sulfate, 7 mass parts dispersants, 12 mass parts
Antistatic additive and 11 mass parts toughener be sufficiently mixed uniformly after, add double screw extruder at a temperature of 170-200 DEG C and
Extruded under the conditions of screw speed 80-90r/min after melt blending, cooling granulation, produce the anti-static composite material of the present invention.
The toughener is grafting maleic anhydride with ethylene propylene terpolymer.The dispersant is Tissuemat E, oxidic polyethylene
One kind in wax, polyamide wax.The plasticizer is adipic acid monomethyl ester, monoethyl adipatee, sebacic acid monomethyl ester or penta 2
Diethyl phthalate.The antistatic additive is graphite or conductive carbon fibre.
Claims (5)
1. a kind of preparation method of anti-static composite material, it is characterised in that the preparation process of this method is as follows：By 160-165 matter
Measure part butadiene-styrene rubber, 30-35 mass parts neoprene, 10-14 mass parts polycarbonate resin, 10-15 mass parts toughener, 10-
15 mass parts plasticizer, 10-13 mass parts calcium sulfate, 6-10 mass parts dispersant, 10-12 mass parts antistatic additive and 10-14
After mass parts toughener is sufficiently mixed uniformly, add in double screw extruder at a temperature of 170-200 DEG C and screw speed 80-
Extruded under the conditions of 90r/min after melt blending, cooling granulation, produce the anti-static composite material of the present invention.
2. the preparation method of a kind of anti-static composite material according to claim 1, it is characterised in that the toughener is
Grafting maleic anhydride with ethylene propylene terpolymer.
3. the preparation method of a kind of anti-static composite material according to claim 1, it is characterised in that the dispersant is
One kind in Tissuemat E, OPE, polyamide wax.
4. the preparation method of a kind of anti-static composite material according to claim 1, it is characterised in that the plasticizer is
Adipic acid monomethyl ester, monoethyl adipatee, sebacic acid monomethyl ester or ethyl glutarate.
A kind of 5. preparation method of anti-static composite material according to claim 1, it is characterised in that the antistatic additive
For graphite or conductive carbon fibre.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610852011.1A CN107868301A (en) | 2016-09-26 | 2016-09-26 | A kind of preparation method of anti-static composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610852011.1A CN107868301A (en) | 2016-09-26 | 2016-09-26 | A kind of preparation method of anti-static composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107868301A true CN107868301A (en) | 2018-04-03 |
Family
ID=61751918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610852011.1A Pending CN107868301A (en) | 2016-09-26 | 2016-09-26 | A kind of preparation method of anti-static composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107868301A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111500080A (en) * | 2020-05-09 | 2020-08-07 | 广东华凯科技股份有限公司 | Antistatic latex fiberboard, preparation method thereof and shoe sole |
-
2016
- 2016-09-26 CN CN201610852011.1A patent/CN107868301A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111500080A (en) * | 2020-05-09 | 2020-08-07 | 广东华凯科技股份有限公司 | Antistatic latex fiberboard, preparation method thereof and shoe sole |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180403 |
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| WD01 | Invention patent application deemed withdrawn after publication |