CN107867814A - A kind of elastic concrete - Google Patents
A kind of elastic concrete Download PDFInfo
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- CN107867814A CN107867814A CN201711261538.8A CN201711261538A CN107867814A CN 107867814 A CN107867814 A CN 107867814A CN 201711261538 A CN201711261538 A CN 201711261538A CN 107867814 A CN107867814 A CN 107867814A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
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- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
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Abstract
The invention belongs to new material technology field, discloses a kind of elastic concrete, is made up of the raw material of following parts by weight:30 40 parts of cement, 10 20 parts of slag powders, 40 80 parts of rubber grain, 13 parts of composite fibre, 0.01 0.05 parts of polyoxyethylene sorbitan monostearate, 30 60 parts of emulsified asphalt, 10 30 parts of aqueous epoxy resins, 0.5 2 parts of polycarboxylate water-reducer, 0.01 0.05 parts of defoamer, 12 parts of calcium metaaluminate, 38 parts of modified zeolite powder, 50 60 parts of sand, 10 30 parts of water.Elastic concrete of the present invention is formed by organic-inorganic Material cladding, it is cheap, elastic it is big, pliability is good, with good resistance to frost, available for exterior components, the impulsive force that motion is brought can be effectively absorbed, improve comfort level during motion, mitigate the impulsive force injury that body is subject to, rubber grain thermal conductivity factor is low, flexible big, the freeze-thaw damage in outdoor sport place can be prevented, improves the service life in place.
Description
Technical field
The invention belongs to new material technology field, and in particular to a kind of elastic concrete.
Technical background
With the development and the improvement of people's living standards of urban construction, it is intended that the leisure such as sports ground, exhibition center is good for
The ground in body recreation place has certain elasticity and silencing function.Some paving sports field plastic cement race tracks at present, it is main
It is polyurethane material to want component, and cost is high.
At the same time, as the fast development of auto industry, the generation and accumulation of a large amount of waste and used rubber tyres have been formed
Serious " black pollution ".Waste old material is processed, is incorporated into concrete, can not only solve waste old
Pollution problem to environment, and can be very good to utilize this flexible characteristic of rubber powder, prepare with good
The concrete of elasticity.Chinese patent《A kind of special concrete using waste and old rubber particle and steel slag particle as aggregate》(application number
CN200910087111.X a kind of special concrete using waste and old rubber particle and steel slag particle as aggregate, including water) are disclosed
Mud, water reducer, mineral admixture, sand, steel slag particle, rubber grain and water, each component are by mass fraction proportioning:Cement 100
Part, 0.1~3 part of water reducer, 0~50 part of mineral admixture, 0~600 part of sand, 200~400 parts of steel slag particle, rubber grain 15
~50 parts, 20~80 parts of water.Two kinds of discarded objects of waste and old rubber particle and slag are added in concrete by the present invention simultaneously, can be with
It is a large amount of to utilize discarded object, improve natural environment, absorb free calcium oxide in steel slag using the elastic characteristic of waste and old rubber particle
Swelling stress so that slag is available without specially treated, and the volume stability of material on the whole is good;And because add
Waste and old rubber particle, its elasticity is higher than normal concrete, but the rubber grain that this method preparation uses is less, finite elastic,
And the inorganic material compatibility such as rubber grain and cement is bad, caking property is low, the intensity that influences concrete, impermeability and closely knit
Property.
The content of the invention
The present invention has the advantages that low cost, deformation characteristic are good in view of the above-mentioned problems, providing a kind of elastic concrete.
To reach above-mentioned purpose, the present invention uses following technical scheme, a kind of elastic concrete, by the raw material group of following parts by weight
Into:Cement 30-40 parts, slag powders 10-20 parts, rubber grain 40-80 parts, composite fibre 1-3 parts, polyoxyethylene sorbitol acid anhydride list
Stearate 0.01-0.05 parts, emulsified asphalt 30-60 parts, aqueous epoxy resins 10-30 parts, polycarboxylate water-reducer 0.5-2 parts,
Defoamer 0.01-0.05 parts, calcium metaaluminate 1-2 parts, modified zeolite powder 3-8 parts, sand 50-60 parts, water 10-30 parts.
The cement is PO42.5 cement.
The slag powders specific surface area is not less than 400m2/ kg, 28d activity are not less than 75%.
The rubber grain particle diameter is between 20-60 mesh.
Preferably, the rubber grain is polysulfide rubber particle.
The composite fibre by sepiolite powder, wollastonite in powder, vinal, polypropylene fibre, polyacrylonitrile fibre,
Two or more in polyurethane fiber is combined.
Preferably, the composite fibre is combined by wollastonite in powder and vinal.
Preferably, the wollastonite in powder fiber and sepiolite powder fibre diameter are between 0.1-1um, and length is in 10-20um
Between;Polypropylene fibre, vinal fiber, polyacrylonitrile fibre and polyurethane fiber diameter are long between 10-30um
Degree is between 5-15mm.
Preferably, the polyoxyethylene sorbitan monostearate is polyoxyethylene (60) sorbitol anhydride monostearate
Ester, molecular formula are:C64H126O26。
The emulsified asphalt is cationic emulsified bitumen, and solid content is not less than 50%.
The aqueous epoxy resins are nonionic curing dose of self-emulsifying type.
The defoamer is tributyl phosphate, polyoxyethylene polyoxypropylene pentaerythrite ether and heterogeneous ten alcohol polyoxyethylene ether
In one kind.
Preferably, the defoamer is heterogeneous ten alcohol polyoxyethylene ether.
The modified zeolite powder is by weight 50-200 by zeolite and n-butyl glycidyl ether:Common powder after 1 mixing
What mill obtained.
Preferably, the modified zeolite powder specific surface area is not less than 500m2/kg。
The water is running water.
Cement and slag powders can not only occur hydration reaction and produce some strength, can also be emulsified asphalt and water-base epoxy tree
Fat liquor demulsification film forming provides carrier, the pitch and epoxy resin being alternatively arranged as after connection demulsification, prevents emulsified asphalt demulsification, water
Property Curing Process of Epoxy in because of polarity difference and caused by layering.Part of cement, the slag of pitch and epoxy resin parcel
Powder particles have neither part nor lot in hydration reaction, and when pitch and epoxy resin are by destroying, it is anti-after outside moisture is run into aquation can to occur
Should, there is certain self-healing.Aqueous epoxy resins and the mercapto of polysulfide rubber end react, and both closely tie
Close, soft segment is introduced in epoxy molecule, increase base plastic deformability.Wollastonite in powder and sepiolite powder have compared with
Short fiber size, it is dispersed in system, surrounding structure tissue is more compacted, improve fracture toughness.Polypropylene fibre,
Polyacrylonitrile fibre, polyurethane fiber longer dimension and there is preferable pliability, organic and inorganic compound in elastic concrete can be connected
The dispersed phase and continuous phase of condensation material, when strained, bridge joint effect is played, prevents concrete from being destroyed.Polyoxyethylene
Sorbitan monostearate can eliminate the electrostatic of organic fiber in the present invention, and improve their flexibility, be allowed in coagulation
Preferably disperse during native stirring and processing.Water reducer can reduce system water consumption under conditions of identical service behaviour is ensured;
Defoamer can reduce bubbles volume, improve the compactness of system, reduce gross imperfection.Normal-butyl in modified zeolite powder shrinks sweet
Oily ether can promote epoxy resin cure, and with cement hydration reaction can occur for zeolite;Appropriate calcium metaaluminate can accelerate hydrated cementitious
Speed, when hydrated cementitious is accelerated, the de-emulsification speed that substantial amounts of moisture also accelerates emulsified asphalt is consumed, is allowed to and epoxy resin
Curing rate is mutually coordinated.In addition, sodium metaaluminate also can adjust system pH, the stability of system is improved.The present invention is by various
The synergy of material, aqueous epoxy resins curing reaction, hydrated reaction of cement and the cementing coordinating and unifying of pitch, form stabilization
Structure.
The invention has the advantages that:
Compared with prior art, elastic concrete provided by the present invention has advantages below:Motion band can effectively be absorbed
The impulsive force come, comfort level during motion is improved, mitigate the impulsive force injury that body is subject to, rubber grain thermal conductivity factor is low, soft
Property it is big, while the intensity of concrete is high, impervious and density is good, can prevent the freeze-thaw damage in outdoor sport place, improves
The service life in place.
Embodiment
Embodiments of the invention are described in detail below, but the present invention can be limited and covered according to claim
Multitude of different ways implement.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creative labor
The every other embodiment obtained under the premise of dynamic, belongs to the scope of protection of the invention.
Embodiment 1
A kind of elastic concrete, it is made up of the raw material of following parts by weight:30 parts of cement, 20 parts of slag powders, rubber grain
40 parts, 3 parts of composite fibre, 0.01 part of polyoxyethylene sorbitan monostearate, 60 parts of emulsified asphalt, aqueous epoxy resins 10
Part, 2 parts of polycarboxylate water-reducer, 0.01 part of defoamer, 2 parts of calcium metaaluminate, 3 parts of modified zeolite powder, 60 parts of sand, 10 parts of water.
The cement is PO42.5 cement.
The slag powders specific surface area is not less than 400m2/kg, and 28d activity is not less than 75%.
The rubber grain particle diameter is between 20-30 mesh.
The composite fibre by sepiolite powder, wollastonite in powder, vinal, polypropylene fibre, polyacrylonitrile fibre,
Polyurethane fiber is combined.
The emulsified asphalt is cationic emulsified bitumen, and solid content is not less than 50%.
The aqueous epoxy resins are nonionic curing dose of self-emulsifying type.
The defoamer is tributyl phosphate.
The modified zeolite powder is by weight 50 by zeolite and n-butyl glycidyl ether:Intergrinding obtains after 1 mixing
Arrive.
Embodiment 2
A kind of elastic concrete, it is made up of the raw material of following parts by weight:40 parts of cement, 10 parts of slag powders, rubber grain
80 parts, 1 part of composite fibre, 0.05 part of polyoxyethylene sorbitan monostearate, 30 parts of emulsified asphalt, aqueous epoxy resins 30
Part, 0.5 part of polycarboxylate water-reducer, 0.05 part of defoamer, 1 part of calcium metaaluminate, 8 parts of modified zeolite powder, 50 parts of sand, 20 parts of water.
The rubber grain is polysulfide rubber particle of the particle diameter between 20-60 mesh.
The composite fibre is combined by sepiolite powder, polypropylene fibre and polyacrylonitrile fibre.
The polyoxyethylene sorbitan monostearate is polyoxyethylene (60) sorbitan monostearate, molecular formula
For:C64H126O26。
The defoamer is polyoxyethylene polyoxypropylene pentaerythrite ether.
The modified zeolite powder is by weight 200 by zeolite and n-butyl glycidyl ether:Intergrinding obtains after 1 mixing
Arrive.
Embodiment 3
A kind of elastic concrete, it is made up of the raw material of following parts by weight:32 parts of cement, 17 parts of slag powders, rubber grain
63 parts, 2 parts of composite fibre, 0.02 part of polyoxyethylene sorbitan monostearate, 50 parts of emulsified asphalt, aqueous epoxy resins 15
Part, 1.5 parts of polycarboxylate water-reducer, 0.04 part of defoamer, 1.3 parts of calcium metaaluminate, 7 parts of modified zeolite powder, 54 parts of sand, 15 parts of water.
The cement is PO42.5 cement.
The slag powders specific surface area is not less than 400m2/kg, and 28d activity is not less than 75%.
The rubber grain is polysulfide rubber particle, and particle diameter is between 30-40 mesh.
The composite fibre is combined by wollastonite in powder and vinal, and wherein wollastonite in powder fibre diameter exists
Between 0.1-1um, length is between 10-20um;Vinal fibre diameter is between 10-30um, and length is in 5-15mm
Between.
The polyoxyethylene sorbitan monostearate is polyoxyethylene (60) sorbitan monostearate, molecular formula
For:C64H126O26。
The defoamer is heterogeneous ten alcohol polyoxyethylene ether.
The modified zeolite powder is by weight 80 by zeolite and n-butyl glycidyl ether:1 mixing after intergrinding extremely
Specific surface area is more than 500m2/ kg is obtained.
Embodiment 4
A kind of elastic concrete, it is made up of the raw material of following parts by weight:33 parts of cement, 15 parts of slag powders, rubber grain
44 parts, 2 parts of composite fibre, 0.03 part of polyoxyethylene sorbitan monostearate, 45 parts of emulsified asphalt, aqueous epoxy resins 20
Part, 1.5 parts of polycarboxylate water-reducer, 0.04 part of defoamer, 1.3 parts of calcium metaaluminate, 6 parts of modified zeolite powder, 54 parts of sand, 30 parts of water.
The rubber grain particle diameter is between 30-60 mesh.
The composite fibre is combined by wollastonite in powder, vinal polyurethane fiber.
The emulsified asphalt is cationic emulsified bitumen, and solid content is not less than 50%.
The aqueous epoxy resins are nonionic curing dose of self-emulsifying type.
The defoamer is tributyl phosphate.
The modified zeolite powder is by weight 60 by zeolite and n-butyl glycidyl ether:Intergrinding obtains after 1 mixing
Arrive.
Embodiment 5
A kind of elastic concrete, it is made up of the raw material of following parts by weight:31 parts of cement, 18 parts of slag powders, rubber grain
52 parts, 1.8 parts of composite fibre, 0.02 part of polyoxyethylene sorbitan monostearate, 45 parts of emulsified asphalt, aqueous epoxy resins
24 parts, 1.4 parts of polycarboxylate water-reducer, 0.03 part of defoamer, 1.2 parts of calcium metaaluminate, 6 parts of modified zeolite powder, 55 parts of sand, water 25
Part.
Comparative example 1
A kind of elastic concrete, it is made up of the raw material of following parts by weight:32 parts of cement, 17 parts of slag powders, rubber grain
53 parts, 50 parts of emulsified asphalt, 15 parts of aqueous epoxy resins, 1.5 parts of polycarboxylate water-reducer, 0.04 part of defoamer, calcium metaaluminate 1.3
Part, 7 parts of modified zeolite powder, 54 parts of sand, 15 parts of water.
The cement is PO42.5 cement.
The slag powders specific surface area is not less than 400m2/kg, and 28d activity is not less than 75%.
The rubber grain is polysulfide rubber particle, and particle diameter is between 20-60 mesh.
The defoamer is heterogeneous ten alcohol polyoxyethylene ether.
The modified zeolite powder is by weight 80 by zeolite and n-butyl glycidyl ether:1 mixing after intergrinding extremely
Specific surface area is more than 500m2/ kg is obtained.
Comparative example 2
A kind of elastic concrete, it is made up of the raw material of following parts by weight:32 parts of cement, 17 parts of slag powders, rubber grain
53 parts, 2 parts of composite fibre, 0.02 part of polyoxyethylene sorbitan monostearate, 50 parts of emulsified asphalt, aqueous epoxy resins 15
Part, 1.5 parts of polycarboxylate water-reducer, 0.04 part of defoamer, 7 parts of modified zeolite powder, 54 parts of sand, 15 parts of water.
The cement is PO42.5 cement.
The slag powders specific surface area is not less than 400m2/kg, and 28d activity is not less than 75%.
The rubber grain is polysulfide rubber particle, and particle diameter is between 20-60 mesh.
The composite fibre is combined by wollastonite in powder and vinal, and wherein wollastonite in powder fibre diameter exists
Between 0.1-1um, length is between 10-20um;Vinal fibre diameter is between 10-30um, and length is in 5-15mm
Between.
The polyoxyethylene sorbitan monostearate is polyoxyethylene (60) sorbitan monostearate, molecular formula
For:C64H126O26。
The defoamer is heterogeneous ten alcohol polyoxyethylene ether.
The modified zeolite powder is by weight 80 by zeolite and n-butyl glycidyl ether:1 mixing after intergrinding extremely
Specific surface area is more than 500m2/ kg is obtained.
Comparative example 3
A kind of elastic concrete, it is made up of the raw material of following parts by weight:32 parts of cement, 17 parts of slag powders, rubber grain
53 parts, 2 parts of composite fibre, 0.02 part of polyoxyethylene sorbitan monostearate, 50 parts of emulsified asphalt, aqueous epoxy resins 15
Part, 1.5 parts of polycarboxylate water-reducer, 0.04 part of defoamer, 1.3 parts of calcium metaaluminate, 54 parts of sand, 15 parts of water.
The cement is PO42.5 cement.
The slag powders specific surface area is not less than 400m2/kg, and 28d activity is not less than 75%.
The rubber grain is polysulfide rubber particle, and particle diameter is between 20-60 mesh.
The composite fibre is combined by wollastonite in powder and vinal, and wherein wollastonite in powder fibre diameter exists
Between 0.1-1um, length is between 10-20um;Vinal fibre diameter is between 10-30um, and length is in 5-15mm
Between.
The polyoxyethylene sorbitan monostearate is polyoxyethylene (60) sorbitan monostearate, molecular formula
For:C64H126O26。
The defoamer is heterogeneous ten alcohol polyoxyethylene ether.
Performance test
The 28d axial compressive strengths of elastic concrete obtained by testing example 1-5 and comparative example 1-3 and resistance to compression respectively
Modulus of elasticity.As a result it see the table below 1.
The result of the test of table 1
Sequence number | Axial compressive strength/MPa | Pressure-proof elasticity modulus/GPa |
Embodiment 1 | 20.1 | 13.7 |
Embodiment 2 | 17.8 | 10.1 |
Embodiment 3 | 23.2 | 11.4 |
Embodiment 4 | 22.1 | 12.9 |
Embodiment 5 | 24.6 | 11.8 |
Comparative example 1 | 18.2 | 12.4 |
Comparative example 2 | 20.1 | 12.1 |
Comparative example 3 | 19.5 | 13.5 |
Embodiment described above is only the preferred embodiments of the present invention, is not intended to limit the invention, for this area
For technical staff, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made is any
Modification, equivalent substitution, improvement etc., should be included in the scope of the protection.
Claims (9)
1. a kind of elastic concrete, it is made up of the raw material of following parts by weight:Cement 30-40 parts, slag powders 10-20 parts, rubber
Particle 40-80 parts, composite fibre 1-3 parts, polyoxyethylene sorbitan monostearate 0.01-0.05 parts, emulsified asphalt 30-60
Part, aqueous epoxy resins 10-30 parts, polycarboxylate water-reducer 0.5-2 parts, defoamer 0.01-0.05 parts, calcium metaaluminate 1-2 parts, change
Property zeolite powder 3-8 parts, sand 50-60 parts, water 10-30 parts.
2. elastic concrete according to claim 1, it is characterised in that the rubber grain particle diameter is between 20-60 mesh.
3. elastic concrete according to claim 1, it is characterised in that the rubber grain is polysulfide rubber particle.
4. elastic concrete according to claim 1, it is characterised in that the composite fibre is by sepiolite powder, wollastonite
Two or more in powder, vinal, polypropylene fibre, polyacrylonitrile fibre, polyurethane fiber is combined.
5. elastic concrete according to claim 1, it is characterised in that the composite fibre is by wollastonite in powder and polyethylene
Alcohol fiber composite forms.
6. elastic concrete according to claim 1, it is characterised in that the polyoxyethylene sorbitan monostearate
For polyoxyethylene (60) sorbitan monostearate, molecular formula is:C64H126O26。
7. elastic concrete according to claim 1, it is characterised in that the defoamer is tributyl phosphate, polyoxy second
One kind in alkene polyoxypropylene pentaerythrite ether and heterogeneous ten alcohol polyoxyethylene ether.
8. elastic concrete according to claim 7, it is characterised in that the defoamer is the alcohol polyoxyethylene of isomery ten
Ether.
9. elastic concrete according to claim 1, it is characterised in that the modified zeolite powder is by zeolite and normal-butyl
Glycidol ether is by weight 50-200:Intergrinding obtains after 1 mixing.
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108424057A (en) * | 2018-05-22 | 2018-08-21 | 佛山市三水万瑞达环保科技有限公司 | A kind of cement-base composite material and preparation method thereof of resistance to compression waterproof fireproofing |
CN108484060A (en) * | 2018-07-06 | 2018-09-04 | 佛山市高明区爪和新材料科技有限公司 | A kind of freeze proof rubber concrete |
CN109081642A (en) * | 2018-09-17 | 2018-12-25 | 深圳市心版图科技有限公司 | A kind of epoxy resin base concrete for building and its preparation process |
CN109265696A (en) * | 2018-09-27 | 2019-01-25 | 湖南辰砾新材料有限公司 | A kind of preparation method of ceramic water reducing agent |
CN112358252A (en) * | 2020-11-11 | 2021-02-12 | 广州市广丰混凝土有限公司 | Anti-freezing cracking concrete and preparation method thereof |
CN112592133A (en) * | 2020-12-24 | 2021-04-02 | 泰安市同达建材有限公司 | Flexible early-strength concrete and preparation method thereof |
WO2022022092A1 (en) * | 2020-07-27 | 2022-02-03 | 中铁十四局集团有限公司 | Earthquake-resistant synchronous grouting material |
CN114988775A (en) * | 2022-06-21 | 2022-09-02 | 浙江方远新材料股份有限公司 | Self-repairing high-performance concrete |
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CN108424057A (en) * | 2018-05-22 | 2018-08-21 | 佛山市三水万瑞达环保科技有限公司 | A kind of cement-base composite material and preparation method thereof of resistance to compression waterproof fireproofing |
CN108424057B (en) * | 2018-05-22 | 2020-12-15 | 珠海市振业混凝土有限公司 | Compression-resistant, waterproof and fireproof cement-based composite material and preparation method thereof |
CN108484060A (en) * | 2018-07-06 | 2018-09-04 | 佛山市高明区爪和新材料科技有限公司 | A kind of freeze proof rubber concrete |
CN109081642A (en) * | 2018-09-17 | 2018-12-25 | 深圳市心版图科技有限公司 | A kind of epoxy resin base concrete for building and its preparation process |
CN109081642B (en) * | 2018-09-17 | 2021-08-10 | 中山市粤华混凝土有限公司 | Epoxy resin-based concrete for building and preparation process thereof |
CN109081642B8 (en) * | 2018-09-17 | 2022-03-22 | 中山市粤华混凝土有限公司 | Epoxy resin-based concrete for building and preparation process thereof |
CN109265696A (en) * | 2018-09-27 | 2019-01-25 | 湖南辰砾新材料有限公司 | A kind of preparation method of ceramic water reducing agent |
WO2022022092A1 (en) * | 2020-07-27 | 2022-02-03 | 中铁十四局集团有限公司 | Earthquake-resistant synchronous grouting material |
CN112358252A (en) * | 2020-11-11 | 2021-02-12 | 广州市广丰混凝土有限公司 | Anti-freezing cracking concrete and preparation method thereof |
CN112592133A (en) * | 2020-12-24 | 2021-04-02 | 泰安市同达建材有限公司 | Flexible early-strength concrete and preparation method thereof |
CN114988775A (en) * | 2022-06-21 | 2022-09-02 | 浙江方远新材料股份有限公司 | Self-repairing high-performance concrete |
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