CN107867738A - Electrolytic ionized water producing apparatus - Google Patents
Electrolytic ionized water producing apparatus Download PDFInfo
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- CN107867738A CN107867738A CN201710103831.5A CN201710103831A CN107867738A CN 107867738 A CN107867738 A CN 107867738A CN 201710103831 A CN201710103831 A CN 201710103831A CN 107867738 A CN107867738 A CN 107867738A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/46115—Electrolytic cell with membranes or diaphragms
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- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The embodiment of the present invention is related to electrolytic ionized water producing apparatus.Electrolytic ionized water producing apparatus according to involved by this embodiment, it is able to maintain that the ease of use of device and the simplification of device can be sought.Electrolytic ionized water producing apparatus involved by this embodiment possesses：Electrolytic cell；Barrier film by electrolytic cell zoning into the 2nd electrode chamber of the 1st electrode chamber and configuration polarity at least configuring the 1st electrode 2nd electrode different from the 1st electrode；Alive power supply is applied to the 1st electrode and the 2nd electrode；The feed system of water is provided to the 1st electrode chamber；From the 1st electrode chamber to the drainage system of draining；Feed system, power supply and drainage system are alternately driven, alternately continues the control unit of the generation of electrolysis water and the discharge of electrolysis water.
Description
The present patent application is enjoyed based on the Japanese patent application 2016-186827 proposed on the 26th of September in 2016
The benefit of priority of this application.The present patent application includes the entire disclosure of which by referring to this application.
Technical field
The embodiment of the present invention is related to electrolytic ionized water producing apparatus.
Background technology
If be powered to the water containing chlorion, acid water is generated in anode side, alkaline water is generated in negative electrode side.
Contain hypochlorous acid in the acid water of anode side generation, there is bactericidal action.Therefore, acid water is used to sterilize, sterilize.It is also, near
In use of the research as deodorization means over year.
As the electrolytic ionized water producing apparatus that electrolytically generated electrolysis water is carried out to the water containing chlorion, side is continuously to electrolysis
The channelling water electrolytic ionized water producing apparatus of groove water supply side generation electrolysis water, pass through the electrolytically generated rule of water progress to storage in a reservoir
The storage type electrolytic ionized water producing apparatus of quantitative electrolysis water etc. is just practical.
Channelling water electrolytic ionized water producing apparatus together can continuously provide electrolysis water with the starting of device.But it is being electrolysed
In water making device, the pressure oscillation of water or the drainpipe from electrolytic cell are produced in the water supply line towards electrolytic cell
When back-pressure surges are produced in road, it is also desirable to maintain the hypochlorous concentration contained in electrolysis water in constant scope.Therefore,
Need water, the water for the water discharged by discharge pipe line from electrolytic cell of the water for will be provided by water supply line to electrolytic cell
Amount maintains constant mechanism.Therefore, channelling water electrolytic ionized water producing apparatus is necessary in the water flowing system rich in corrosive electrolysis water
Set in system and be used for controlling control valve, sensor of water-flowing amount etc..Also, it is different according to the scale of water-flowing device, purposes, it is used for
Control the algorithm of these control valves becomes complicated sometimes.In this case, it is believed that complicatedization of device or
Larger-scale unit.
On the other hand, storage type electrolytic ionized water producing apparatus to the water being stored in hold-up vessel due to by carrying out electrolysis life
Into electrolysis water, therefore electrolytic cell is not supplied water when being electrolysed, necessity of draining.Therefore, with channelling water electrolysis water
Manufacture device is different, and storage type electrolytic ionized water producing apparatus there is no need for carrying out control valve, the sensing of the water flowing control of electrolytic cell
Device etc..Therefore, it is possible to simplify apparatus structure, as a result it is capable of miniaturization, the cost degradation of realization device.
But storage type electrolytic ionized water producing apparatus is passing through the stipulated time since starting device untill electrolysis terminates
Electrolysis water can not be obtained.Therefore, if consuming the electrolysis water of generation, the time being electrolysed again is needed.Therefore, storage type
Electrolytic ionized water producing apparatus is different according to purposes, and ease of use is poor compared with channelling water electrolytic ionized water producing apparatus.
The content of the invention
The present invention is exactly to complete in the scenario above, to maintain the letter of the ease of use of device and realization device
Turn to problem.
In order to solve above-mentioned problem, the electrolytic ionized water producing apparatus involved by this embodiment possesses electrolytic cell, barrier film, electricity
Source, feed system, drainage system and control unit.By electrolytic cell zoning at least configure the 1st electrode the 1st electrode chamber and configuration
The barrier film of 2nd electrode chamber of polarity 2nd electrode different from the 1st electrode.Power supply applies voltage to the 1st electrode and the 2nd electrode.For
To system water is provided to the 1st electrode chamber.Drainage system is from the 1st electrode chamber to storage unit draining.Control unit alternately drives
Feed system, power supply and drainage system, the generation of electrolysis water and the draining of electrolysis water is set alternately to continue.
Electrolytic ionized water producing apparatus according to involved by this embodiment, the continuous offer of the electrolysis water of high quality can be realized
With the simplification of device.
Brief description of the drawings
Fig. 1 is the figure for the schematic configuration for representing the electrolytic ionized water producing apparatus involved by the 1st embodiment.
Fig. 2 is the flow chart for representing a succession of processing that control device performs.
Fig. 3 is the figure for the schematic configuration for representing the electrolytic ionized water producing apparatus involved by the 2nd embodiment.
Fig. 4 is the flow chart for representing a succession of processing that control device performs.
Fig. 5 is the figure for the schematic configuration for representing the electrolytic ionized water producing apparatus involved by the 3rd embodiment.
Fig. 6 is the figure for the schematic configuration for representing the electrolytic ionized water producing apparatus involved by the 4th embodiment.
Fig. 7 is the figure for the schematic configuration for representing the electrolytic ionized water producing apparatus involved by the 5th embodiment.
Fig. 8 is for illustrating the figure of the electrolytic cell involved by variation.
Embodiment
The embodiment ＞ of ＜ the 1st
Below according to the 1st embodiment of brief description of the drawings.Fig. 1 is to represent the electrolytic ionized water producing apparatus involved by this embodiment
The figure of 10 schematic configuration.Electrolytic ionized water producing apparatus 10 is electrolytically generated containing acid hypochlorous acid water by being carried out to salt solution
Device.
As shown in figure 1, electrolytic ionized water producing apparatus 10 possesses electrolytic cell 11, hold-up tank 12, dc source 31 and control device
50。
Electrolytic cell 11 is the container body being made up of resin, stainless steel etc..Electrolytic cell 11 is for example including rectangular shape
The housing 11b of housing 11a and configuration inside housing 11a.Housing 11a inner space and housing 11b inner space pass through
Amberplex 21 connects.Electrolytic cell 11 makes housing 11b inner space turn into the moon by housing 11a and housing 11b combinations
Pole room S2, remaining housing 11a inner space turn into anode chamber S1.
Anode chamber S1 is connected by pipeline 110 with commercial water works, and is connected by pipeline 111 and hold-up tank 12
Connect.Also, S1 inside is configured with the electrode 23 for generating acid water in anode chamber.
Running water is supplied to anode chamber S1 from water works.From preventing using calcium carbonate as the build-up of limescale of main component
Viewpoint is set out, and the few soft water of alkaline components is preferably used as anode chamber S1 running water is supplied to.This soft water can pass through
Generated using for example make use of the water softener of ion exchange resin.Anode chamber S1 running water is supplied to by electricity from water works
Magnet valve V1 is controlled.Magnetic valve V1 is such as normally closed solenoid valve.When magnetic valve V1 becomes ON, provided certainly to anode chamber S1
Water.When magnetic valve V1 becomes OFF, stop providing running water to anode chamber S1.
Anode chamber S1 water level is detected by the level sensor W1 being arranged on housing 11a.As level sensor W1 energy
Enough using electrostatic capacitive level sensor, electrical conductivity level sensor or float type water level sensor etc..Level sensor
W1 has the contact for for example becoming ON when anode chamber S1 water level becomes suitable for the specified water level of electrolysis.
Cathode chamber S2 is the space surrounded by housing 11b, is internally configured with electrode 24.Cathode chamber S2 inside filling salt
Water.Used for example by water (H as salt solution2O the salt solution that addition sodium chloride (NaCl) generates as electrolyte in), or
By adding the salt such as chloride potassium chloride (KCl) in water the salt solution that generates.The concentration of salt solution has no particular limits, if but
Consider stability during electrolysis, the up to a certain degree of preferred concentration.Wherein, saturated sodium-chloride is preferably used as salt solution.
Amberplex 21 is with allowing such as chlorion Cl-The anion-exchange membrane of the property passed through Deng anion.Make
For anion-exchange membrane, NEOSEPTOR (the Japanese original texts of ASTOM (A Si Toms) company can be used：ネ オ セ プ タ) (note
Volume trade mark), the SELEMION (registration mark) of AGC engineering technology company (AGC ENGINEERING Co., Ltd.) etc..
Also, perforated membrane substitution ion exchange membrane 21 can also be used.As perforated membrane, it can use in polyolefin, contain
Formed on the stable high-molecular organic material film of the chemical property of fluorine compounds etc micro- porous acquisition organic micro-porous film,
Inorganic oxide perforated membrane etc..A variety of materials can be used as inorganic oxide.For example, it can use titanium oxide, oxidation
The micropowder of silicon, aluminum oxide, niobium oxide, tantalum oxide, nickel oxide etc. is coated to the material on supporting mass.Particularly preferably using oxidation
Titanium, silica and aluminum oxide.As other perforated membranes, can also use with chlorine, the porous polymer of fluorine system halogenated high-molecular-weight
Deng.
As anode electrode 23 by such as titanium (Ti), stainless steel (SUS), chromium (Cr), nickel (Ni), aluminium (Al) or they
Alloy, composite are formed.Electrode 23 is shaped as rectangle tabular, in order that raw water circulates and increases surface area, is formed
There are multiple through holes.Through hole both can be the constant straight hole of opening diameter, can also be shaped to electrode 23 side face with
The different taper of the face diameter of opposite side, can also be shaped to internal face turns into the shape of curved surface.
The shape of through hole can be the arbitrary shape such as rectangle, circle, ellipse.Also, through hole both can rule
Ground is arranged in rectangular or honeycombed, can also brokenly arrange.
The oxide catalyst such as noble metal catalyst, yttrium oxide such as platinum (Pt) is attached on the surface of electrode 23.
Also formed as the electrode 24 of negative electrode in the same manner as electrode 23.Electrode 24 does not attach catalyst, can remain untouched
Ground has the metal of corrosion resistance using titanium, stainless steel etc..
Dc source 31 is indicated to electrode 23 and the application voltage of electrode 24 according to control device 50.Manufacture and fill in electrolysis water
In putting 10, apply voltage to electrode 23,24 respectively in a manner of electrode 23 is turned into anode, electrode 24 turns into negative electrode.
Hold-up tank 12 is the tank formed such as the metal by resin, stainless steel.The volume preferred anodes room S1 of hold-up tank 12
About 5 times or more of volume.Hold-up tank 12 is arranged on the position lower than electrolytic cell 11, passes through pipeline 111 and electrolytic cell 11
Anode chamber S1 connections.Also, hold-up tank 12 is connected by pipeline 112 with external equipment.The water level such as water of hold-up tank 12
Level sensor W2 is detected.As level sensor W2, electrostatic capacitive level sensor, electrical conductivity level sensor can be used
Device or float type water level sensor etc..Level sensor W2 has the contact for for example becoming ON when hold-up tank 12 becomes full water.
As described above, the volume VOL1 [L] of hold-up tank 12 be preferably about 5 times of anode chamber S1 volume VOL2 [L] or with
Upper (VOL1 >=5 × VOL2).In electrolytic ionized water producing apparatus 10, water when making 12 full water of hold-up tank for 4 × VOL2 [L] with
Under.Thus, when the electrolysis water in by anode chamber S1 is transported in hold-up tank 12, even if level sensor W2 becomes ON, also can
Enough continue the conveying of electrolysis water untill anode chamber S1 is emptying.
The volumetric ratio anode chamber S1 for the cathode chamber S2 for making to have salt solution volume VOL2 is small, and is often repeated a number of times
The circulation of generation electrolysis water, just replaces salt solution in anode chamber S1.Salt solution displacement after, to next time replace salt solution iterative cycles by
Anode chamber S1 volume, cathode chamber S2 volume, the concentration of electrolysis water etc. of generation determine, but preferably 1~20 circulation is left
It is right.
Specifically, if hypothesis anode chamber S1 is 1L, cathode chamber S2 is 0.02L, the concentration to salt solution drops to characteristic
20 circulations are needed untill having an impact, 10 circulations are needed untill the pH of salt solution exceedes the scope of violent in toxicity.In order to generate electricity
Xie Shui, the amount for crossing the electrolyte of barrier film loss are few.Therefore, if by barrier film by salt water segregation, then the moon can be made
Pole room S2 volume is reduced to 1/10~1/100 or so of anode chamber S2 volume.Also, in anode chamber S1 it is multiple cyclically
After generating electrolysis water, by being changed to salt solution, salt solution can be effectively consumed, and the time of waste, electricity can be cut down
Power.
Also, if anode chamber S2 volume is excessive, then exists and also will not equably be mixed even if by draining, electrolysis water
The problem of.Experimental verification, if anode chamber S2 volume VOL2 is mixed within 5L by draining, the concentration of electrolysis water becomes
Uniformly, if in more than 5L, even if by draining, in the beginning and end of draining, the concentration of electrolysis water also occurs very big
Difference.Also, if anode chamber S2 volume VOL2 is too small, then supply water, the time scale increase that draining accounts for, under production efficiency
Drop.Anode chamber S2 volume VOL2 is wished in the range of 0.5~5L.
One end of pipeline 111 is connected to the housing 11a for the anode chamber S1 for forming electrolytic cell 11 bottom.Also, the other end
It is connected to the top of hold-up tank 12.The electrolysis water that S1 is generated in anode chamber is conveyed and stored to hold-up tank 12 by pipeline 111.And
And it is stored in the electrolysis water in hold-up tank 12 and is provided by pipeline 112 to external device (ED) of the point of use as electrolysis water etc..
Magnetic valve V2, V3 are respectively arranged with pipeline 111,112.Magnetic valve V2 is such as normally closed solenoid valve.In anode
The electrolysis water of room S1 generations conveys when magnetic valve V2 is ON by gravity to hold-up tank 12, stops when magnetic valve V2 is OFF
Conveying to hold-up tank 12.Also, magnetic valve V3 is to be controlled by the user or external device (ED) of electrolytic ionized water producing apparatus 10
Magnetic valve.Electrolysis water in hold-up tank 12 provides when magnetic valve V3 is opens to point of use.Stop when magnetic valve V3 is closed
There is provided to point of use.
Control device 50 for CPU (Central Processing Unit), as CPU working region main memory
The computer in the auxiliary storage portion of reservoir, storage program and/or various parameters etc..Control device 50 is according to being stored in auxiliary storage
The above-mentioned dc source 31 of driven by program and each magnetic valve V1, V2 in portion.
Then the action of electrolytic ionized water producing apparatus 10 formed in the above described manner is illustrated.Fig. 2 holds for expression control device 50
The flow chart of capable a succession of processing.Electrolytic ionized water producing apparatus 10 carries out the place of the flow chart according to Fig. 2 by control device 50
Manage and act.Illustrate the processing of the execution of control device 50 referring to Fig. 2.A succession of processing shown in Fig. 2 flow chart passes through
Such as control device 50 receives to start from the sign on of user.
Premise as explanation, it is assumed that each magnetic valve V1~V3 closures (OFF), dc source 31 stop.And, it is assumed that sun
Pole room S1 and hold-up tank 12 are all empty state, it is assumed that automatic in advance in cathode chamber S2 or be filled with salt by user
Water.
First, control device 50 judges whether level sensor W2 is ON (step S101).When hold-up tank 12 is full water,
Level sensor W2 becomes ON, and when hold-up tank 12 is not full water, level sensor W2 becomes OFF.Control device 50 is judging
In the case of being ON for level sensor W2 (being Yes in step S101), wait the electrolysis water in hold-up tank 12 by user or
External device (ED) draining.
On the other hand, control device 50 be determined as level sensor W2 be OFF in the case of (being No in step S101),
Magnetic valve V1 is set to become ON (step S102).Thus, running water provides to the anode chamber S1 of electrolytic cell 11.
Then, control device 50 judges whether level sensor W1 is ON (step S103).When anode chamber S1 is full water,
Level sensor W1 becomes ON；When anode chamber S1 is not full water, level sensor W1 becomes OFF.Control device 50 is judging
In the case of being OFF for level sensor W1 (being No in step S103), magnetic valve V1 is set to continue as ON.On the other hand, control
Device 50 be determined as level sensor W1 be ON in the case of (being Yes in step S103), make magnetic valve V1 become OFF (step
Rapid S104).Thus, stop running water providing to anode chamber S1.
Then, control device 50 makes dc source 31 run (step S105).Thus, electrode 23,24 is by dc source 31
Apply voltage.When electrode 23,24 is applied in voltage, the chlorion Cl that is stored in the salt solution in cathode chamber S2-Pass through ion
Exchange membrane 21 moves to anode chamber S1.The chlorion Cl moved to anode chamber S1-Be oxidized, and with anode chamber S1 water
(H2O) reacted.Thus, as shown in following formula (1), generated in anode chamber S1 comprising hypochlorous acid and hydrochloric acid, the acid in acidity
Property water.
2Cl-+H2O→HClO+HCl+2e-…………(1)
Also, sodium ion Na is generated in cathode chamber S2+.Sodium ion Na+With the hydroxyl ion OH in cathode chamber S2-Carry out
Reaction.Thus, sodium hydroxide is generated.Also, in cathode chamber S2, hydroxyl ion OH-Counter ion counterionsl gegenions be hydrogen ion H+Gone back
Original, generate hydrogen.As shown in following formula (2), generated in cathode chamber S2 comprising sodium hydroxide, in the alkaline water and hydrogen of acidity.
2Na++2e-+2H2O→2NaOH+H2………(2)
Then, control device 50 judges whether to have passed through defined time (step after the operation for starting dc source 31
S106).The run time DT of dc source 31 each time by electrode 23 and anode chamber S1 etc. size, be stored in cathode chamber S2's
The concentration of salt solution, output current of dc source 31 etc. determine.Control device 50 is being determined as from the fortune for starting dc source 31
Without by (being No in step S106) in the case of run time DT after row, continue to run with dc source 31.
On the other hand, control device 50 is being judged to have passed through run time DT's after the operation for starting dc source 31
In the case of (step S106 is Yes), make dc source 31 operation stop (step S107).Thus, anode chamber S1 is in generation
The state of the hypochloric acid water of normal concentration.
Then, control device 50 makes magnetic valve V2 become ON (step S108).Thus, the electrolysis generated in anode chamber S1
Water conveys to hold-up tank 12.
Then, control device 50 judges whether to have passed through defined time (step after magnetic valve V2 to be become to ON
S109).To hold-up tank 12 convey electrolysis water required for time of delivery TT by anode chamber S1 size, the internal diameter of pipeline 111 and
Length etc. determines.(the step in the case where judgement is after the conveying for starting electrolysis water without time of delivery TT is passed through of control device 50
It is No in rapid S109), magnetic valve V2 ON is maintained, continues to convey electrolysis water.
On the other hand, control device 50 is in the case where being judged to have passed through time of delivery TT after conveying electrolysis water is started
(being Yes in step S109), makes magnetic valve V2 become OFF.Thus, conveying of the electrolysis water to hold-up tank 12 stops.After, control
Device 50 performs step S101~S110 processing repeatedly.
As described above, sun of the electrolytic ionized water producing apparatus 10 involved by this embodiment to generation electrolysis water
Pole room S1 provides the water of ormal weight, is electrolysed after anode chamber S1 is become the hydrostatic state of no water discrepancy.Also, generate
Temporarily stop electrolysis after electrolysis water, the electrolysis water in anode chamber S1 is conveyed to hold-up tank 12.So, by alternately entering repeatedly
The conveying of the electrolysis water of electrolysis and generation of the row to the water of ormal weight, the constant electrolysis water of stock concentration in hold-up tank 12.Cause
This, can carry out the offer both sides of the offer of continuous electrolysis water and the electrolysis water of high quality.
For example, the channelling water electrolysis water manufacture dress of offer and the discharge of the raw waters such as running water is continuously carried out to anode chamber S1
Put and constantly generate electrolysis water.Therefore, it is possible to continuously provide electrolysis water.But channelling water electrolytic ionized water producing apparatus is sometimes difficult
So that the concentration of electrolysis water is maintained into constant.
Also, it is right that the storage type electrolytic ionized water producing apparatus for making anode chamber S1 water become to be electrolysed after hydrostatic state passes through
The water of fixed amount, which is powered, generates electrolysis water.Therefore, it is possible to easily produce the electrolysis water of constant concentration.But in order that electricity consumption
Xie Shui is, it is necessary to wait until the electrolysis in anode chamber terminates.Therefore, using up in the case of the electrolysis water of anode chamber's generation,
Before electrolysis water is generated next time, it is necessary to control the use of electrolysis water.Also, once electrolytic obtain electrolysis water amount by
The capacity of anode chamber determines.But if the capacity of increase electrode chamber, the time to the generation end of electrolysis water is extended
, therefore excessively increase the capacity of electrode chamber and unrealistic.It is used to connect as described above, storage type electrolytic ionized water producing apparatus is present
The problem of electrolysis water is provided continuously.
Electrolytic ionized water producing apparatus 10 involved by this embodiment can make as the excellent of channelling water electrolytic ionized water producing apparatus
Point continuously provides the electrolysis water of electrolysis water and offer high quality the advantages of as storage type electrolytic ionized water producing apparatus and deposited.
Also, the electrolytic ionized water producing apparatus 10 involved by this embodiment can realize the electrolysis for continuously providing high quality
The simplification of water and device.
The concentration of the hypochlorous acid included in electrolysis water etc. with current value during electrolysis, the electrolytic efficiency of electrolytic cell except becoming
It is outside the pale of civilization, also change with the output for the raw water for being supplied to electrolytic cell.It is easy that current value when being electrolysed, which is controlled in setting,
, the electrolytic efficiency of electrolytic cell can be obtained in advance.But the water-flowing amount of raw water is arranged by the pressure oscillation of raw water, electrolysis water
The influence of the back-pressure surges of water destination and change.Thus, for example channelling water electrolytic ionized water producing apparatus 10 is pacified in pipeline path
Dress is used for the concentration of electrolysis water maintaining constant constant flow rate valve, or quantity delivered, the electrolysis of raw water are monitored using flowmeter
The displacement of water, be adjusted the feeding pipe for being arranged on raw water, electrolysis water discharge pipe line in control valve control.
But constant flow rate valve, in addition to the range hydraulic pressure in constant flow rate can be controlled to exist and restricted, precision is not also high.
Although also, by using flowmeter and control valve can precision be advantageously controlled the displacement of the quantity delivered of raw water, electrolysis water,
But the size of flowmeter, control valve is bigger, price is high.Therefore, it is difficult to be applicable in small electrolytic water making device.
Electrolytic ionized water producing apparatus 10 involved by this embodiment does not need constant flow rate valve, flowmeter and control valve etc..
Therefore, the continuous offer of electrolysis water can not only be realized, additionally it is possible to simplify device miniaturization of the apparatus.As a result, it is possible to reduce dress
Manufacturing cost, the operating cost put.
Also, the electrolytic ionized water producing apparatus 10 involved by this embodiment possesses the hold-up tank 12 of storage electrolysis water.Therefore,
Regardless of the working condition of electrolytic ionized water producing apparatus 10, electrolysis water can be provided.
The variation of channelling water electrolytic ionized water producing apparatus demand is unrelated, can only provide the electrolysis water of fixed amount, but electrolysis water system
Allow as long as making the capacity of the hold-up tank 12 of device 10, even if the quantity delivered of electrolysis water changes, also can stably provide.Also,
The generation of electrolysis water, the offer for the electrolysis water that can be stablized need not be provided as storage type electrolytic ionized water producing apparatus.
Although electrolytic ionized water producing apparatus itself possesses hold-up tank 12 in this embodiment, hold-up tank 12 can also be with electrolysis
Water making device separates.
Also, level sensor W2 can also be integrally installed at the top of pipeline 111.For example, using existing tank
In the case of as hold-up tank, if the top of pipeline 111 is provided with level sensor W2, then by by pipeline 111
It is suitably attached on existing tank, electrolytic ionized water producing apparatus can carry out above-mentioned action.
In the case where using the container of bucket etc as existing tank, it is believed that level sensor W2 is installed to
It is difficult on tank.In this case, the processing as the step S101 in control flow, as long as receiving the amount of electrolysis water, by being
The no value received that exceedes judges whether to be electrolysed can.For example, manufactured by the bucket configuration that capacity is 7L in electrolysis water
Below device, provide it with electrolysis water in the case of, if anode chamber S2 volume VOL2 is that 1L, user etc. will for example
In the 6L input electrolytic ionized water producing apparatus of its multiple.The electrolytic ionized water producing apparatus for receiving the quantity delivered of 6L electrolysis waters is carried out 6 times
The generation and draining of electrolysis water.Thus, water supply bucket provides 6L electrolysis waters.Even if in this case, if electrode chamber S1 appearance
Product VOL2 is excessive, then for the container typically used, each growing amount excessively falls into disuse.Therefore, as described above, electrode chamber
S1 volume VOL2 is wished for 0.5~5L.
Although this embodiment illustrates not replace salt solution in cathode chamber S2, multiple acid water is generated in anode chamber S1
Situation.But it is not limited thereto, can also suitably carries out the displacement of the salt solution in cathode chamber S2.For example, possessing to the moon
Pole room S2 is automatically in the case of the device of the mechanism of supply and discharge salt solution, when making cathode chamber due to carrying out generating the electrolysis of acid water
When the concentration of S2 salt solution reduces, the replacing of salt solution can also be suitably carried out.
Specifically, 5 anode chamber S1 electrolysis processing and water supply and sewage is often carried out, with regard to automatically carrying out once being used for changing the moon
The draining and water supply of the salt solution of pole room S2 salt solution.As the mechanism for the salt solution automatically changed in cathode chamber S2, and to anode
Room S1 provide raw water mechanism it is same, can by possess magnetic valve, with the feeding pipe of the cathode chamber S1 salt solution being connected and draining
Pipeline etc. is formed.
The embodiment ＞ of ＜ the 2nd
Below according to the 2nd embodiment of brief description of the drawings.For the structure with the 1st embodiment identically or comparably, use
Suitable mark, while its explanation is omitted or simplified.
Fig. 3 is the figure for the schematic configuration for representing the electrolytic ionized water producing apparatus 10A involved by the 2nd embodiment.Electrolysis water system
It is by carrying out the electrolytically generated hypochlorous acid water comprising acidity to salt solution and including the sodium hydroxide of alkalescence to make device 10A
Alkaline water device.Electrolytic ionized water producing apparatus 10A is in electrolytic cell 11 by zoning into anode chamber S1, cathode chamber S2 and medial compartment S3
It is different from the electrolytic ionized water producing apparatus 10 involved by the 1st embodiment on this aspect.
As shown in figure 3, electrolytic ionized water producing apparatus 10A possesses electrolytic cell 11, hold-up tank 12A, 12B, dc source 31 and control
Device 50 processed.
Electrolytic cell 11 is the container body being made up of resin, stainless steel etc..The inside of electrolytic cell 11 is by 1 group of amberplex
21st, 22 zonings are into anode chamber S1, cathode chamber S2 and medial compartment S3.Amberplex 21 is with allowing such as chlorion Cl-Deng the moon
The anion-exchange membrane for the property that ion passes through.Also, amberplex 22 is with allowing such as sodium ion Na+Lead to Deng cation
The cation-exchange membrane for the property crossed.
As anion-exchange membrane, NEOSEPTOR (the Japanese original texts of ASTOM (A Si Toms) company can be used：ネオセ
プ タ) (registration mark), the SELEMION (registration mark) of AGC engineering technology company (AGCENGINEERING Co., Ltd.)
Deng.As cation-exchange membrane, such as the NAFION (registration mark) 112 of usable E.I. Du Ponts (E.I.du Pont) company,
115th, 117, the FLEMION (registration mark) of Asahi Glass Co., Ltd, the ACIPLEX (registration mark) of Asahi Kasei Corporation
Deng.Also, it can also use perforated membrane substitution ion exchange membrane 21,22 both sides or a wherein side.
Medial compartment S3 is the space clipped by 2 amberplexes 21,22.Filling chlorinated sodium (NaCl) is made in medial compartment S3
For the water of electrolyte.
Anode chamber S1 is to pass through the space adjacent with medial compartment S3 of amberplex 21.In anode chamber, S1 is configured to generate
The electrode 23 of acid water.Also, cathode chamber S2 is to pass through the space adjacent with medial compartment S3 of amberplex 22.In cathode chamber S2
It is configured to generate the electrode 24 of alkaline water.
Anode chamber S1 and cathode chamber S2 is connected by pipeline 110 with the water works of commercialization.Also, anode chamber S1 passes through
Pipeline 111A is connected with hold-up tank 12A, and cathode chamber S2 is connected by pipeline 111B with hold-up tank 12B.
Running water is supplied to anode chamber S1 and cathode chamber S2 from water works.Anode chamber S1 is supplied to from water works
Running water controlled by magnetic valve V11, the running water for being supplied to cathode chamber S2 from water works is controlled by magnetic valve V12.Electricity
Magnet valve V11, V12 are, for example, normally closed solenoid valve.Anode chamber S1 water level is detected with level sensor W1.Also, cathode chamber S2's
Water level is detected with level sensor W3.
Hold-up tank 12A, 12B are mutually of equal structure, are arranged on the position lower than electrolytic cell 11.Hold-up tank 12A leads to
Pipeline 111A is crossed to be connected with the anode chamber S1 of electrolytic cell 11.Also, hold-up tank 12B passes through pipeline 111B and the negative electrode of electrolytic cell 11
Room S2 connections.Hold-up tank 12A, 12B water level are for example detected with level sensor W2, W4.Also, in hold-up tank 12A, 12B
Overflow pipe 120 is provided with, it is specified that the water level upper limit of the electrolysis water of storage.
Pipeline 111A one end is connected with anode chamber S1 bottom, and the other end is connected with hold-up tank 12A top.In anode
The electrolysis water of generation is conveyed and stored to hold-up tank 12A by pipeline 111A in the S1 of room.Also, it is stored in hold-up tank 12A electricity
Xie Shui is provided by pipeline 112A to external device (ED) of the point of use as electrolysis water etc..
Pipeline 111B one end is connected with cathode chamber S2 bottom, and the other end is connected with hold-up tank 12B top.In negative electrode
The electrolysis water of room S2 generations is conveyed and stored to hold-up tank 12B by pipeline 111B.Also, the electricity being stored in hold-up tank 12B
Xie Shui is provided by pipeline 112B to external device (ED) of the point of use as electrolysis water etc..
Magnetic valve V21, V31 are respectively arranged with pipeline 111A, 112A.Magnetic valve V21 is, for example, normally closed solenoid valve.Sun
In pole room S1 the electrolysis water of generation when magnetic valve V21 be ON to hold-up tank 12A conveyings, stop when magnetic valve V21 is OFF to
Hold-up tank 12A is conveyed.Also, magnetic valve V31 is the electromagnetism controlled by electrolytic ionized water producing apparatus 10A user or external device (ED)
Valve.Hold-up tank 12A electrolysis water provides when magnetic valve V31 opens to point of use.Stop when magnetic valve V31 is closed to point of use
There is provided.
Equally, magnetic valve V22, V32 are respectively arranged with pipeline 111B, 112B.In the electrolysis water of cathode chamber S2 generations
Conveyed when magnetic valve V22 is ON to hold-up tank 12B.Stop conveying to hold-up tank 12B when magnetic valve V22 is OFF.Also,
Electrolysis water in hold-up tank 12B provides when magnetic valve V32 opens to point of use.Stop when magnetic valve V32 is closed to use
Point provides.
Control device 50 is according to the above-mentioned dc source 31 of the driven by program being stored in auxiliary storage portion and each magnetic valve
V11、V12、V21、V22。
Then the electrolytic ionized water producing apparatus 10A of said structure action is illustrated.Fig. 4 is to represent control device 50 performs one
The flow chart of consecutive processing.Electrolytic ionized water producing apparatus 10A carries out the processing of the flow chart according to Fig. 4 by control device 50 to enter
Action is made.Illustrate the processing of the execution of control device 50 referring to Fig. 4.
Premise as explanation, it is assumed that each magnetic valve V11, V12, V21, V22 closure, dc source 31 stop.It is also, false
If anode chamber S1, cathode chamber S2 and hold-up tank 12A, 12B are empty state, salt solution is filled with medial compartment S3.
First, control device 50 judges whether that level sensor W2, W4 both sides are ON (step S201).When hold-up tank 12A,
When 12B is full water, level sensor W2, W4 become ON, and when hold-up tank 12A, 12B are not full waters, level sensor W2, W4 become
Into OFF.Control device 50 be determined as level sensor W2, W4 both sides be ON in the case of (being Yes in step S201), wait
Hold-up tank 12A, 12B electrolysis water are by user or external device (ED) draining.
On the other hand, control device 50 be determined as in level sensor W2, W4 it is at least one be OFF in the case of
(being No in step S201), makes magnetic valve V11, V12 become ON (step S202).Thus, anode of the running water to electrolytic cell 11
Room S1 and cathode chamber S2 is provided.
Then, control device 50 judges whether level sensor W1 is ON (step S203).When anode chamber S1 is full water,
Level sensor W1 becomes ON, and when anode chamber S1 is not full water, level sensor W1 becomes OFF.Control device 50 is judging
In the case of being OFF for level sensor W1 (being No in step S203), continue to make magnetic valve V11 be ON.On the other hand, control
Device 50 be determined as level sensor W1 be ON in the case of (being Yes in step S203), make magnetic valve V11 become OFF (step
Rapid S204).Thus, stop providing running water to anode chamber S1.
Then, control device 50 judges whether level sensor W3 is ON (step S205).When cathode chamber S2 is full water,
Level sensor W3 becomes ON, and when cathode chamber S2 is not full water, level sensor W3 becomes OFF.Control device 50 is judging
In the case of being OFF for level sensor W3 (being No in step S205), continue to make magnetic valve V12 be ON.On the other hand, control
Device 50 be determined as level sensor W3 be ON in the case of (being Yes in step S205), make magnetic valve V12 become OFF (step
Rapid S206).Thus, stop providing running water to cathode chamber S2.
Then, control device 50 judges whether that level sensor W1, W3 both sides are ON (step S207).Control device 50 exists
Be determined as at least one party in level sensor W1, W3 be OFF in the case of (being No in step S207), perform step repeatedly
S203~S206 processing.
On the other hand, control device 50 is being determined as level sensor W1, W3 both sides in the case of being ON (in step S207
For Yes), dc source 31 is run (step S208).Thus, the chlorion Cl in salt solution-From positioned at electrode 23 and electrode 24
Between medial compartment S3 by amberplex 21 to anode chamber S1 move.The chlorion Cl moved to anode chamber S1-By oxygen
Change, and with the water (H in anode chamber S12O) reacted.Thus, included as shown in following formula (3) in anode chamber S1 generations
Hypochlorous acid and hydrochloric acid, acid water in acidity.
2Cl-+H2O→HClO+HCl+2e-………(3)
Also, sodium ion Na+Moved from medial compartment S3 by amberplex 22 to cathode chamber S2.Moved to cathode chamber S2
Sodium ion Na+With cathode chamber S2 hydroxyl ion OH-Reacted.Thus, sodium hydroxide is generated.Also, in cathode chamber
S2, as hydroxyl ion OH-Counter ion counterionsl gegenions hydrogen ion H+It is reduced, generates hydrogen.In negative electrode as shown in following formula (4)
Generation includes sodium hydroxide, alkaline water and hydrogen in alkalescence in the S2 of room.
2Na++2e-+2H2O→2NaOH+H2………(4)
Then, control device 50 judges whether to have passed through defined time (step after the operation for starting dc source 31
S209).Control device 50 be determined as from the operation for starting dc source 31 do not pass through as defined in (step in the case of the time
It is No in S209), continue the operation of dc source 31.
On the other hand, control device 50 is being judged to have passed through the defined time after the operation for starting dc source 31
In the case of (being Yes in step S209), stop dc source 31 operation (step S210).Thus, turn into anode chamber S1
The acid water using hypochloric acid water as main component is generated, is generated in cathode chamber S2 using sodium hydroxide as the alkaline water of main component
State.
Then, control device 50 makes magnetic valve V21, V22 become ON (step S211).Thus, in anode chamber S1 generations
Electrolysis water is conveyed to hold-up tank 12A, conveyed in the cathode chamber S2 electrolysis waters generated to hold-up tank 12B.
Then, since control device 50 judge whether have passed through the defined time magnetic valve V21, V22 is become ON
(step S212).Control device 50 continues in the case where being judged to not by the defined time (being No in step S212)
Make magnetic valve V21, V22 ON.
On the other hand, control device 50 is being judged to have passed through the situation of defined time after the conveying for starting electrolysis water
Under (being Yes in step S212), magnetic valve V21, V22 is become OFF.Thus, electrolysis water is stopped to the defeated of hold-up tank 12A, 12B
Send.After, control device 50 performs step S201~S213 processing repeatedly.
As described above, in the electrolytic ionized water producing apparatus 10A involved by this embodiment, it is electrolysed to generation
The anode chamber S1 and cathode chamber S2 of water provide the water of fixed amount, become the quiet of no water discrepancy making anode chamber S1 and cathode chamber S2
Water state is electrolysed later.Also, temporarily stop electrolysis after electrolysis water is generated, by anode chamber S1 and cathode chamber S2 electrolysis
Water conveys to hold-up tank 12A, 12B respectively.So, by the way that the electricity of electrolysis and generation to the water of ormal weight is alternately repeated
Xie Shui conveying, the electrolysis water of constant concentration are stored in hold-up tank 12A, 12B.Therefore, it is possible to carry out continuous electrolysis water
Offer both sides with the electrolysis water of high quality are provided.Also, the electrolytic ionized water producing apparatus 10A involved by this embodiment can be real
The continuous offer of electrolysis water and the simplification of device of existing high quality.
Also, the electrolytic ionized water producing apparatus 10A involved by this embodiment possess store respectively using hypochlorous acid as mainly into
The anode water divided and hold-up tank 12A, 12B using sodium hydroxide as the negative electrode water of main component.Therefore, it is possible to independently use
Anode water and negative electrode water.
For example, conventional channelling water electrolytic ionized water producing apparatus is in the situation without using same amount of anode water and negative electrode water
Under, it has to the electrolysis water of a remaining side is discarded.But the electrolytic ionized water producing apparatus 10A involved by this embodiment leads to
Cross and store anode water and negative electrode water respectively, can independently use.
Also, the electricity by hold-up tank 12A electrolysis water and hold-up tank 12B can be set in electrolytic ionized water producing apparatus 10A
The mixed organization of Xie Shui mixing.Thereby, it is possible to obtain the electrolysis water of desired pH value, electrolytic ionized water producing apparatus can be sought
Expand and use.
The embodiment ＞ of ＜ the 3rd
Below according to the 3rd embodiment of brief description of the drawings.For the structure same or equivalent with above-mentioned embodiment, phase is used
When mark, while its explanation is omitted or simplified.
Fig. 5 is the figure for the schematic configuration for representing the electrolytic ionized water producing apparatus 10B involved by the 3rd embodiment.Electrolysis water system
Make device 10B possess this point of brine tank 13 and hold-up tank 12 configure with the identical of electrolytic cell 11 height or top this
Point is different from the electrolytic ionized water producing apparatus 10 involved by the 1st embodiment.
Brine tank 13 is the tank of storage salt solution.Brine tank 13 is connected by pipeline 113,114 with electrolytic cell 11.In pipeline
Circulating pump 51 is provided with 114.The salt solution of brine tank 13 is supplied to electrolytic cell by circulating pump 51 according to the instruction of control device 50
11 cathode chamber S2.Thus, salt solution circulates between the cathode chamber S2 of electrolytic cell 11 and brine tank 13.Salt is returned to from cathode chamber S2
The amount of the salt solution of water pot 13 is for example adjusted with pressure-regulating valve (not shown).
Hold-up tank 12 is not arranged in the lower section of electrolytic cell 11, and be provided in set electrolytic cell 11 floor it is identical or
On the floor of the upper level of person.Delivery pump 52 is set to substitute magnetic valve in the pipeline 111 of connection hold-up tank 12 and electrolytic cell 11.It is defeated
Pump 52 is sent to be conveyed the electrolysis water generated in anode chamber S1 to hold-up tank 12 according to the instruction of control device 50.
In the electrolytic ionized water producing apparatus 10B involved by this embodiment, salt solution is between brine tank 13 and cathode chamber S2
Circulation.Therefore, suppress the change in concentration of cathode chamber S2 salt solution, as a result can stably generate electrolysis water.
Also, the electrolytic ionized water producing apparatus 10B involved by this embodiment possesses delivery pump 52.Therefore, it is not necessary to will
Hold-up tank 12 is configured in the lower section of electrolytic cell 11, can be arranged on such as side of electrolytic cell 11 or be left the ground of electrolytic cell 11
Side.Therefore, free degree during electrolytic ionized water producing apparatus is set to improve.For example, even in the place for setting electrolytic ionized water producing apparatus
Ceiling it is low in the case of, or be necessary by hold-up tank configuration in the case of the place higher than electrolytic cell, can also set
Electrolytic ionized water producing apparatus.
The embodiment ＞ of ＜ the 4th
Below according to the 4th embodiment of brief description of the drawings.For the structure same or equivalent with above-mentioned embodiment, phase is used
When mark, its explanation is omitted or simplified.
Fig. 6 is the figure for the schematic configuration for representing the electrolytic ionized water producing apparatus 10C involved by the 4th embodiment.Electrolysis water system
Device 10C is made to possess on this point of multiple electrolytic cell 11 different from the electrolytic ionized water producing apparatus 10 involved by the 1st embodiment.
As shown in fig. 6, electrolytic ionized water producing apparatus 10C possesses including electrolytic cell 11, electrode 23,24 and amberplex 21
Unit U1, U2.The anode chamber S1 of each unit U1, U2 is connected with unit U1, U2 hold-up tank 12 shared.Also, each unit U1, U2
Flowchart control as shown in control device 50 according to Fig. 2.
Electrolytic ionized water producing apparatus 10C involved by this embodiment possesses multiple unit U1, U2 with electrolytic cell 11.Cause
This, by increasing capacitance it is possible to increase the growing amount of electrolysis water, and the reliability to failure can be improved.
For example, in channelling water electrolytic ionized water producing apparatus, in order to increase the growing amount of electrolysis water, generally by increase electricity
The electric current when area of pole is to increase electrolysis, make the amount increase of the electrolysis water of generation in time per unit.But if excessively increase
Electric current during big electrolysis, then the CURRENT DISTRIBUTION in electrolytic cell easily become uneven, the electrolysis water for causing generation sometimes does not reach
Situation or electrolytic cell to desired property and state are generated heat.Also, electrolytic ionized water producing apparatus also maximizes.
The electrolytic cell of storage type electrolytic ionized water producing apparatus, the structure of auxiliary equipment class manufacture than in general channelling water electrolysis water
The electrolytic cell of device, the structure of auxiliary equipment class are simple.Wherein, it is multiple comprising electricity to employ carrying by electrolytic ionized water producing apparatus 10C
Solve the unit of groove, the structure electrolysis water generated in unit being stored in shared hold-up tank.It is outer thereby, it is possible to increase
The growing amount of electrolysis water in sight.
By using such structure, the electrolytic cell of standard specification is preset as the electrolytic cell for forming each unit, root
The quantity of each unit is increased to more than 2 times according to the specification of electrolytic ionized water producing apparatus, by can so realize desired rule
The electrolytic ionized water producing apparatus of lattice.By making the specification standardization of electrolytic cell, can simplify electrolytic ionized water producing apparatus process management,
Quality management, and then the manufacturing cost of product, operating cost can be cut down.
If also, possess multiple units the electrolytic ionized water producing apparatus 10C as involved by this embodiment, even if ten thousand
The electrolytic cell of one some unit produces problem, can also use remaining unit, can although electrolysis water production efficiency declines
Continue to generate electrolysis water.Therefore, it is possible to which the reliability of electrolytic ionized water producing apparatus is significantly increased, turn into suitable for electrolysis water
There is provided left and right the device of situation as the operation of whole factory.
The embodiment ＞ of ＜ the 5th
Below according to the 5th embodiment of brief description of the drawings.For the structure same or equivalent with above-mentioned embodiment, phase is used
When mark, while its explanation is omitted or simplified.
Fig. 7 is the figure for the schematic configuration for representing the electrolytic ionized water producing apparatus 10D involved by the 5th embodiment.Electrolysis water system
Make device 10D with storage be supplied to anode chamber S1 water hold-up tank 14 on this point with the 1st embodiment involved by
Electrolytic ionized water producing apparatus 10 is different.
As shown in fig. 7, hold-up tank 14 is configured in the top of electrolytic cell 11.Before being electrolysed, in hold-up tank 14 in advance
Filled with the raw water such as running water or well water.Hold-up tank 14 is connected with anode chamber's S1 pipelines 110.If it is arranged in pipeline 110
Magnetic valve V1 becomes ON, then the raw water being stored in hold-up tank 14 is supplied to anode chamber S1 by gravity.Manufacture and fill in electrolysis water
Put in 10D, also perform control according to the flow chart shown in Fig. 2 with control device 50.
Electrolytic ionized water producing apparatus 10D involved by this embodiment has and can be pre-charged with the raw waters such as running water or well water
Hold-up tank 14.Therefore, it is possible to improve the mobility of electrolytic ionized water producing apparatus or the free degree of setting place can be improved.
For example, electrolytic ionized water producing apparatus 10,10A~10C involved by above-mentioned embodiment are to be supplied to anode chamber S1's
Premised on the water that well water that water conveys for running water or with pump etc. was pressurized.Therefore, if by make magnetic valve V1, V11,
V12 just can provide raw water to open to anode chamber S1.But this electrolytic ionized water producing apparatus must be set with pipeline and running water
It is standby to wait connection.Therefore, the mobility of electrolytic ionized water producing apparatus, the free degree of setting place are deteriorated.
The electrolytic ionized water producing apparatus good as mobility, there is the small-sized storage type electrolysis water manufacture dress of tank shape electrolytic cell
Put and listed.But such electrolytic ionized water producing apparatus is small-sized, the growing amount of each electrolysis water is also small.And, it is difficult to it is continuous
Ground provides electrolysis water, if the electrolysis water of generation is consumed, needs to generate the time of electrolysis water again.
Electrolytic ionized water producing apparatus 10D involved by this embodiment possesses the hold-up tank 12 for storing electrolysis water and is used for
Store the both sides of hold-up tank 14 of raw water.Therefore, it is possible to make lasting offer electricity the advantages of as channelling water electrolytic ionized water producing apparatus
The electrolysis water of the offer high quality for the advantages of Xie Shuihe is as storage type electrolytic ionized water producing apparatus is simultaneously deposited, and can be improved removable
The free degree of dynamic property and setting place.
As described in detail above, according to the electrolytic ionized water producing apparatus of the present invention, conventional channelling water electrolysis can solve the problem that
The various problems that water making device, storage type electrolytic ionized water producing apparatus have respectively, using the teaching of the invention it is possible to provide the electrolysis water system of favorable expandability
Make device.
Also, the electrolytic ionized water producing apparatus involved by least one embodiment as stated above, by alternately
The conveying of the electrolysis water of the electrolysis and generation to the water of ormal weight is repeated, can realize that the continuous of electrolysis water of high quality carries
For the simplification with device.
Although being explained above the embodiment of the present invention, the invention is not limited in above-mentioned embodiment.On for example,
State the pipe that embodiment illustrates the top of the anode chamber S1 or cathode chamber S2 by introduction into electrolytic cell 11 as shown in FIG. 3
Road 110 provides the situation of raw water to electrolytic cell 11.But it is not limited thereto, as one, can also passes through as shown in FIG. 8
Pipeline 110A, the 110B for being incorporated into the bottom of electrolytic cell 11 provide raw water to electrolytic cell 11.
By setting the delivery pump that can be rotated forward and reverse in pipeline 110A, the 110B for extend to the bottom of electrolytic cell 11
53rd, 54, or the pump to supply water with draining is set, raw water can not only be provided using pipeline 110A, 110B, additionally it is possible to discharge
Raw water.Thereby, it is possible to the simplification of realization device and miniaturization.
In addition, in example shown in Fig. 8, pipeline 110A, 110B introduce from the top of electrolytic cell 11 to bottom.But not office
It is limited to this, pipeline 110A, 110B can also be connected to the bottom of electrolytic cell 11.
Although being explained above the embodiment of the present invention, these embodiments are intended only as example proposition, do not beat
Calculate the scope for limiting invention.Their new embodiment can be implemented in the form of other are various, without departing from invention
A variety of omission, substitution, and alteration can be entered in the range of objective.These embodiments or its deformation included in invention scope and
In the invention being also contained in objective described in the scope of claim and its scope of equalization.
Claims (16)
1. a kind of electrolytic ionized water producing apparatus, possesses：
Electrolytic cell,
Barrier film, above-mentioned electrolytic cell zoning into the 1st electrode chamber at least configuring the 1st electrode and is configured into polarity and above-mentioned 1st electrode
2nd electrode chamber of the 2nd different electrodes；
Power supply, apply voltage to above-mentioned 1st electrode and above-mentioned 2nd electrode；
Feed system, water is provided to above-mentioned 1st electrode chamber；
Drainage system, water is discharged from above-mentioned 1st electrode chamber to storage unit；And
Control unit, above-mentioned feed system, above-mentioned power supply and above-mentioned drainage system are alternately driven, alternately continue electrolysis water
Generation and the draining of electrolysis water.
2. electrolytic ionized water producing apparatus as claimed in claim 1,
Water is provided to above-mentioned 1st electrode chamber,
Salt solution is stored in above-mentioned 2nd electrode chamber,
With not replacing the salt solution in above-mentioned 2nd electrode chamber, at least carried out in above-mentioned 1st electrode chamber more than 2 times, enter water-filling
The circulation of offer, the generation of electrolysis water and the draining of electrolysis water.
3. electrolytic ionized water producing apparatus as claimed in claim 1,
Possess by above-mentioned barrier film to open, store the medial compartment of salt solution with above-mentioned 1st electrode chamber and above-mentioned 2nd electrode chamber zoning,
With not replacing the salt solution of above-mentioned medial compartment, at least carried out more than 2 times in above-mentioned 1st electrode chamber or above-mentioned 2nd electrode chamber
, the offer for entering water-filling, the circulation of the generation of electrolysis water and the draining of electrolysis water.
4. electrolytic ionized water producing apparatus as claimed in claim 2, store the Capacity Ratio the above-mentioned 1st of above-mentioned 2nd electrode chamber of salt solution
The capacity of electrode chamber is small.
5. electrolytic ionized water producing apparatus as claimed in claim 3, store above-mentioned 1st electrode of Capacity Ratio of the above-mentioned medial compartment of salt solution
The capacity of room is small.
6. the electrolytic ionized water producing apparatus as described in any one of claim 2 to 5, the capacity of above-mentioned 1st electrode chamber is in 0.5L
Above, below 5L.
7. the electrolytic ionized water producing apparatus as described in any one of claim 2 to 6, enter the offer of water-filling, electrolysis water generation and
The circulation of electrolysis water draining is carried out 2~20 times, the displacement with regard to carrying out 1 above-mentioned salt solution.
8. the electrolytic ionized water producing apparatus as described in any one of claim 1 to 7,
The top of above-mentioned 1st electrode chamber formed with for from above-mentioned feed system provide water feed water inlet,
In the bottom of above-mentioned 1st electrode chamber formed with for the discharge outlet to above-mentioned drainage system discharge water.
9. the electrolytic ionized water producing apparatus as described in any one of claim 1 to 8, store the water from the discharge of above-mentioned drainage system
Hold-up tank configure in the lower section of above-mentioned electrolytic cell.
10. electrolytic ionized water producing apparatus as claimed in claim 9, the capacity of the capacity of above-mentioned hold-up tank in above-mentioned 1st electrode chamber
More than 5 times.
11. the electrolytic ionized water producing apparatus as described in claim 9 or 10,
The full water sensor of the water of detection storage rated capacity is set in above-mentioned hold-up tank,
Above-mentioned full water sensor leaves the rich earthquake of the capacity equal with the capacity of above-mentioned 1st electrode chamber in above-mentioned hold-up tank
Make.
12. electrolytic ionized water producing apparatus as claimed in claim 11, the top ends of above-mentioned full water sensor and above-mentioned drainage system
It is integrally provided.
13. the electrolytic ionized water producing apparatus as described in any one of claim 9 to 12, possess multiple above-mentioned electrolytic cells, it is above-mentioned
Drainage system is by the water of the 1st electrode chamber of each electrolytic cell in above-mentioned electrolytic cell to above-mentioned hold-up tank draining.
14. electrolytic ionized water producing apparatus as claimed in claim 13, some generation of above-mentioned control unit in above-mentioned electrolytic cell
The electrolysis for the above-mentioned electrolytic cell for making to break down in the case of failure stops, and electrolysis water is generated using normal above-mentioned electrolytic cell.
15. the electrolytic ionized water producing apparatus as described in any one of claim 1 to 14, in each subregion of above-mentioned electrolytic cell, lead to
The pipeline that is connected with the bottom of above-mentioned electrolytic cell is crossed to enter the water supply of water-filling and draining.
16. the electrolytic ionized water producing apparatus as described in any one of claim 1 to 15,
Above-mentioned feed system possesses：
Raw water tank, configure and be supplied to the water of above-mentioned electrolytic cell in the top of above-mentioned electrolytic cell, savings；And
Pipeline, connect above-mentioned raw water tank and above-mentioned electrolytic cell.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016-186827 | 2016-09-26 | ||
| JP2016186827A JP6776077B2 (en) | 2016-09-26 | 2016-09-26 | Electrolyzed water production equipment |
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| Publication Number | Publication Date |
|---|---|
| CN107867738A true CN107867738A (en) | 2018-04-03 |
Family
ID=61762117
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| CN201710103831.5A Withdrawn CN107867738A (en) | 2016-09-26 | 2017-02-24 | Electrolytic ionized water producing apparatus |
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| CN (1) | CN107867738A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111334816A (en) * | 2020-04-20 | 2020-06-26 | 浙江高成绿能科技有限公司 | Method for preparing hypochlorous acid water by electrolysis |
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| WO2022059464A1 (en) * | 2020-09-17 | 2022-03-24 | パナソニックＩｐマネジメント株式会社 | Device for yielding hypochlorous acid water |
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| EP2521697A2 (en) * | 2010-01-07 | 2012-11-14 | Sealed Air Corporation (US) | Modular cartridge system for apparatus producing cleaning and/or sanitizing solutions |
| WO2015141329A1 (en) * | 2014-03-19 | 2015-09-24 | 株式会社 東芝 | Device for yielding electrolyzed water, method for yielding electrolyzed water, and electrolyzed water |
| WO2016047161A1 (en) * | 2014-09-22 | 2016-03-31 | 株式会社 東芝 | Electrolytic device and electrolyzed water generation method |
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|---|---|---|---|---|
| CN1332120A (en) * | 2000-07-07 | 2002-01-23 | 松下电器产业株式会社 | Electrolytic water and its generating device |
| JP2002035751A (en) * | 2000-07-21 | 2002-02-05 | Matsushita Electric Ind Co Ltd | Batchwise electrolytic water making apparatus |
| JP2003080250A (en) * | 2001-09-07 | 2003-03-18 | Shimadzu Corp | Equipment for producing electrolytic water |
| WO2016143165A1 (en) * | 2015-03-11 | 2016-09-15 | 株式会社 東芝 | Device for producing electrolyzed water and method for producing electrolyzed water |
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| CN111334816A (en) * | 2020-04-20 | 2020-06-26 | 浙江高成绿能科技有限公司 | Method for preparing hypochlorous acid water by electrolysis |
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| JP6776077B2 (en) | 2020-10-28 |
| JP2018051428A (en) | 2018-04-05 |
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Application publication date: 20180403 |