CN107858056A - A kind of basement, kitchen and toilet anti-fire and water-proof paint and preparation method thereof - Google Patents

A kind of basement, kitchen and toilet anti-fire and water-proof paint and preparation method thereof Download PDF

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Publication number
CN107858056A
CN107858056A CN201711142206.8A CN201711142206A CN107858056A CN 107858056 A CN107858056 A CN 107858056A CN 201711142206 A CN201711142206 A CN 201711142206A CN 107858056 A CN107858056 A CN 107858056A
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Prior art keywords
parts
water
fire
kitchen
proof paint
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CN201711142206.8A
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Chinese (zh)
Inventor
汤谏好
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New Mstar Technology Ltd In Qingyuan
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New Mstar Technology Ltd In Qingyuan
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Priority to CN201711142206.8A priority Critical patent/CN107858056A/en
Publication of CN107858056A publication Critical patent/CN107858056A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides a kind of basement, kitchen and toilet anti-fire and water-proof paint, and its raw material includes following components by weight:80 120 parts of acrylic acid ester emulsion, 25 35 parts of aluminium hydroxide, 8 12 parts of Firebrake ZB, 36 parts of dispersant, 58 parts of plasticizer, face, 25 parts of filler, 12 parts of titanium dioxide, 0.1 0.3 parts of initiator, 58 parts of coalescents, 0.1 0.5 parts of antimildew disinfectant, 0.1 0.3 parts of defoamer, 1 1.5 parts of thickener, 30 50 parts of deionized water.The present invention also provides its preparation method, it is to be solved by this invention to be to provide a kind of basement, kitchen and toilet anti-fire and water-proof paint, the coating of the present invention not only have good antibacterial and mouldproof effect, resistance to artificial weathering aging, resistance to erosion, it is firmly indeformable, high-decoration is strong the characteristics of, decorative effect that environmental protection attractive in appearance nontoxic to human body, also there is UV resistant irradiation, caking ability is big, waterproof anti seismic efficiency is good, fire protecting performance is good.

Description

A kind of basement, kitchen and toilet anti-fire and water-proof paint and preparation method thereof
Technical field
The present invention relates to a kind of coating, relates in particular to a kind of basement, kitchen and toilet anti-fire and water-proof paint and its preparation Method.
Background technology
China's major part basement, kitchen and toilet anti-fire and water-proof paint exist loss of properties on aging, tensile strength it is low, to temperature The shortcomings of sensitive, easily cause aging, dry and cracked, deformation, trisection, layering, seepage easy for basement, kitchen and toilet fire-proof and water-proof Phenomena such as catching fire is relatively common.With the continuous development of economic construction of China, all kinds of skyscrapers, underground engineering, office building, joy Basement, the kitchen and toilet in happy place are developed and built, and superior and luxuriousization of its inside fitting makes making for building and ornament materials Expanded with further, the thing followed is increased the worry of disaster hidden-trouble and leak.For fire-proof and water-proof protection and dicoration More preferable cooperation, for people to the requirement also more and more higher of basement, kitchen and toilet anti-fire and water-proof paint, application is also more and more extensive, Therefore basement, kitchen and toilet anti-fire and water-proof paint will have more wide application development prospect.
The content of the invention
Therefore, to be solved by this invention be to provide a kind of basement, kitchen and toilet anti-fire and water-proof paint, coating of the invention Not only have good antibacterial and mouldproof effect, resistance to artificial weathering aging, resistance to erosion, it is firmly indeformable, high-decoration is strong the characteristics of to people The decorative effect that body is nontoxic, environmental protection is attractive in appearance, also with UV resistant irradiation, caking ability is big, waterproof anti seismic efficiency is good, anti- The advantages that fiery excellent performance.
In order to solve the above technical problems, the technical scheme is that:A kind of basement, kitchen and toilet anti-fire and water-proof paint, Its raw material includes following components by weight:Acrylic acid ester emulsion 80-120 parts, aluminium hydroxide 25-35 parts, Firebrake ZB 8-12 Part, dispersant 3-6 parts, plasticizer 5-8 parts, face, filler 2-5 parts, titanium dioxide 1-2 parts, initiator 0.1-0.3 parts, coalescents 5-8 parts, antimildew disinfectant 0.1-0.5 parts, defoamer 0.1-0.3 parts, thickener 1-1.5 parts, deionized water 30-50 parts.
Further, a kind of described basement, kitchen and toilet anti-fire and water-proof paint, its raw material include with the following group by weight Point:80 parts of acrylic acid ester emulsion, 25 parts of aluminium hydroxide, 8 parts of Firebrake ZB, 3 parts of dispersant, 5 parts of plasticizer, face, 2 parts of filler, titanium 1 part of white powder, 0.1 part of initiator, 5 parts of coalescents, 0.1 part of antimildew disinfectant, 0.1 part of defoamer, 1 part of thickener, deionization 30 parts of water.
Further, a kind of described basement, kitchen and toilet anti-fire and water-proof paint, its raw material include with the following group by weight Point:120 parts of acrylic acid ester emulsion, 35 parts of aluminium hydroxide, 12 parts of Firebrake ZB, 6 parts of dispersant, 8 parts of plasticizer, face, filler 5 Part, 2 parts of titanium dioxide, 0.3 part of initiator, 8 parts of coalescents, 0.5 part of antimildew disinfectant, 0.3 part of defoamer, 1.5 parts of thickener, 50 parts of deionized water.
Further, a kind of described basement, kitchen and toilet anti-fire and water-proof paint, its raw material include with the following group by weight Point:100 parts of acrylic acid ester emulsion, 30 parts of aluminium hydroxide, 10 parts of Firebrake ZB, 5 parts of dispersant, 6 parts of plasticizer, face, 4 parts of filler, 1.5 parts of titanium dioxide, 0.2 part of initiator, 6 parts of coalescents, 0.4 part of antimildew disinfectant, 0.2 part of defoamer, 1.2 parts of thickener, 40 parts of deionized water.
Further, its preparation method comprises the following steps:
S10, by formula design(Recipe ratio)Weigh each component, by portions of de-ionized water, plasticizer, coalescents, dispersant, Antimildew disinfectant, part defoamer are added in stirring filling, and stirring at low speed disperses 15-20min;
S11, under conditions of high-speed stirred, add face, filler, aluminium hydroxide, Firebrake ZB by formula design quantity, titanium dioxide stirs Scattered 60-70min is mixed, regulation fineness is then ground to by sand mill, discharging is standby;
S12, under conditions of stirring at low speed, by acrylic acid ester emulsion, remaining defoamer, thickener, initiator and remainder go from Sub- water is added in slurry, is stirred and is adjusted to suitable viscosity, produces this kind of basement, kitchen and toilet anti-fire and water-proof paint.
Further, the pigment is that any one of nano zine oxide or nanometer lithopone or two kinds arbitrarily match Mixture;Described filler is that two or more in calcium carbonate, talcum powder, mica powder, diatom ooze, wollastonite in powder mixes Thing, and wanted 1250 mesh sieves.
Further, the titanium dioxide is rutile type titanium white.
Further, the dispersant is one kind in acrylic copolymer ammonium salt, ammonium polyacrylate salt, polycarboxylic acids ammonium salt Or more than one mixtures.
Further, described defoamer is organic silicon defoamer, mineral oil defoaming agent or its combination.
Beneficial effects of the present invention:The present invention is using acrylic acid ester emulsion as base-material, combustion adjuvant aluminium hydroxide and boric acid Zinc compounding prepares the existing good mechanical property of combustion-supporting type polymer emulsion water-repellent paint of gained, has good combustion-supporting property again Can, the materials'use is convenient, and green, safety and stability, can be widely applied between building roof, basement, kitchen, In the waterproof fireproofing engineering such as toilet, while can both having met waterproof durable design requirement, the anti-of building can also be improved Fiery performance.The coating of the present invention not only has good antibacterial and mouldproof effect, resistance to artificial weathering aging, resistance to erosion, firmly indeformable, high The decorative effect that the characteristics of ornamental strong is nontoxic to human body, environmental protection is attractive in appearance, also with UV resistant irradiation, caking ability it is big, The advantages that waterproof anti seismic efficiency is good, fire protecting performance is good.
Embodiment
In order that present disclosure is more likely to be clearly understood, below according to the specific embodiment of the present invention, to this Invention is described in further detail.
Embodiment 1
A kind of basement, kitchen and toilet anti-fire and water-proof paint, its raw material include following components by weight:Acrylic acid ester emulsion 80 Part, 25 parts of aluminium hydroxide, 8 parts of Firebrake ZB, 3 parts of dispersant, 5 parts of plasticizer, face, 2 parts of filler, 1 part of titanium dioxide, initiator 0.1 Part, 5 parts of coalescents, 0.1 part of antimildew disinfectant, 0.1 part of defoamer, 1 part of thickener, 30 parts of deionized water.
Its preparation method comprises the following steps:
S10, by formula design(Recipe ratio)Weigh each component, by portions of de-ionized water, plasticizer, coalescents, dispersant, Antimildew disinfectant, part defoamer are added in stirring filling, and stirring at low speed disperses 15min;
S11, under conditions of high-speed stirred, add face, filler, aluminium hydroxide, Firebrake ZB by formula design quantity, titanium dioxide stirs Scattered 60min is mixed, regulation fineness is then ground to by sand mill, discharging is standby;
S12, under conditions of stirring at low speed, by acrylic acid ester emulsion, remaining defoamer, thickener, initiator and remainder go from Sub- water is added in slurry, is stirred and is adjusted to suitable viscosity, produces this kind of basement, kitchen and toilet anti-fire and water-proof paint.
The pigment is nano zine oxide;The mixture that described filler is calcium carbonate, talcum powder arbitrarily matches, and will Cross 1250 mesh sieves.
The titanium dioxide is rutile type titanium white.
The dispersant is acrylic copolymer ammonium salt.
Described defoamer is organic silicon defoamer.
Embodiment 2
A kind of basement, kitchen and toilet anti-fire and water-proof paint, its raw material include following components by weight:Acrylic acid ester emulsion 120 Part, 35 parts of aluminium hydroxide, 12 parts of Firebrake ZB, 6 parts of dispersant, 8 parts of plasticizer, face, 5 parts of filler, 2 parts of titanium dioxide, initiator 0.3 part, 8 parts of coalescents, 0.5 part of antimildew disinfectant, 0.3 part of defoamer, 1.5 parts of thickener, 50 parts of deionized water.
Its preparation method comprises the following steps:
S10, by formula design(Recipe ratio)Weigh each component, by portions of de-ionized water, plasticizer, coalescents, dispersant, Antimildew disinfectant, part defoamer are added in stirring filling, and stirring at low speed disperses 20min;
S11, under conditions of high-speed stirred, add face, filler, aluminium hydroxide, Firebrake ZB by formula design quantity, titanium dioxide stirs Scattered 70min is mixed, regulation fineness is then ground to by sand mill, discharging is standby;
S12, under conditions of stirring at low speed, by acrylic acid ester emulsion, remaining defoamer, thickener, initiator and remainder go from Sub- water is added in slurry, is stirred and is adjusted to suitable viscosity, produces this kind of basement, kitchen and toilet anti-fire and water-proof paint.
The pigment is nanometer lithopone;The mixing that described filler is calcium carbonate, talcum powder, mica powder arbitrarily match Thing, and wanted 1250 mesh sieves.
The titanium dioxide is rutile type titanium white.
The dispersant is acrylic copolymer ammonium salt, ammonium polyacrylate salt mixture.
The combination that described defoamer is organic silicon defoamer, mineral oil defoaming agent arbitrarily matches.
Embodiment 3
A kind of basement, kitchen and toilet anti-fire and water-proof paint, its raw material include following components by weight:Acrylic acid ester emulsion 100 Part, 30 parts of aluminium hydroxide, 10 parts of Firebrake ZB, 5 parts of dispersant, 6 parts of plasticizer, face, 4 parts of filler, 1.5 parts of titanium dioxide, initiator 0.2 part, 6 parts of coalescents, 0.4 part of antimildew disinfectant, 0.2 part of defoamer, 1.2 parts of thickener, 40 parts of deionized water.
Its preparation method comprises the following steps:
S10, by formula design(Recipe ratio)Weigh each component, by portions of de-ionized water, plasticizer, coalescents, dispersant, Antimildew disinfectant, part defoamer are added in stirring filling, and stirring at low speed disperses 18min;
S11, under conditions of high-speed stirred, add face, filler, aluminium hydroxide, Firebrake ZB by formula design quantity, titanium dioxide stirs Scattered 65min is mixed, regulation fineness is then ground to by sand mill, discharging is standby;
S12, under conditions of stirring at low speed, by acrylic acid ester emulsion, remaining defoamer, thickener, initiator and remainder go from Sub- water is added in slurry, is stirred and is adjusted to suitable viscosity, produces this kind of basement, kitchen and toilet anti-fire and water-proof paint.
The pigment is the mixture that nano zine oxide or nanometer lithopone arbitrarily match;Described filler be calcium carbonate, The mixture that talcum powder, mica powder, diatom ooze, wollastonite in powder arbitrarily match, and wanted 1250 mesh sieves.
The titanium dioxide is rutile type titanium white.
The mixture that the dispersant is acrylic copolymer ammonium salt, ammonium polyacrylate salt, polycarboxylic acids ammonium salt arbitrarily match.
The combination that described defoamer is organic silicon defoamer, mineral oil defoaming agent arbitrarily matches.

Claims (9)

1. a kind of basement, kitchen and toilet anti-fire and water-proof paint, it is characterised in that its raw material includes following components by weight:Third Olefin(e) acid ester emulsion 80-120 parts, aluminium hydroxide 25-35 parts, Firebrake ZB 8-12 parts, dispersant 3-6 parts, plasticizer 5-8 parts, face, Filler 2-5 parts, titanium dioxide 1-2 parts, initiator 0.1-0.3 parts, coalescents 5-8 parts, antimildew disinfectant 0.1-0.5 parts, defoaming Agent 0.1-0.3 parts, thickener 1-1.5 parts, deionized water 30-50 parts.
2. a kind of basement according to claim 1, kitchen and toilet anti-fire and water-proof paint, it is characterised in that its raw material is by weight Amount part includes following components:80 parts of acrylic acid ester emulsion, 25 parts of aluminium hydroxide, 8 parts of Firebrake ZB, 3 parts of dispersant, 5 parts of plasticizer, Face, 2 parts of filler, 1 part of titanium dioxide, 0.1 part of initiator, 5 parts of coalescents, 0.1 part of antimildew disinfectant, 0.1 part of defoamer, thickening 1 part of agent, 30 parts of deionized water.
3. a kind of basement according to claim 1, kitchen and toilet anti-fire and water-proof paint, it is characterised in that its raw material is by weight Amount part includes following components:120 parts of acrylic acid ester emulsion, 35 parts of aluminium hydroxide, 12 parts of Firebrake ZB, 6 parts of dispersant, plasticizer 8 parts, face, 5 parts of filler, 2 parts of titanium dioxide, 0.3 part of initiator, 8 parts of coalescents, 0.5 part of antimildew disinfectant, 0.3 part of defoamer, 1.5 parts of thickener, 50 parts of deionized water.
4. a kind of basement according to claim 1, kitchen and toilet anti-fire and water-proof paint, it is characterised in that its raw material is by weight Amount part includes following components:100 parts of acrylic acid ester emulsion, 30 parts of aluminium hydroxide, 10 parts of Firebrake ZB, 5 parts of dispersant, plasticizer 6 Part, face, 4 parts of filler, 1.5 parts of titanium dioxide, 0.2 part of initiator, 6 parts of coalescents, 0.4 part of antimildew disinfectant, defoamer 0.2 Part, 1.2 parts of thickener, 40 parts of deionized water.
5. according to a kind of any described basements of claim 1-4, kitchen and toilet anti-fire and water-proof paint, it is characterised in that it is made Preparation Method comprises the following steps:
S10, by formula design(Recipe ratio)Each component is weighed, by portions of de-ionized water, plasticizer, coalescents, scattered Agent, antimildew disinfectant, part defoamer are added in stirring filling, and stirring at low speed disperses 15-20min;
S11, under conditions of high-speed stirred, add face, filler, aluminium hydroxide, Firebrake ZB by formula design quantity, titanium dioxide stirs Scattered 60-70min is mixed, regulation fineness is then ground to by sand mill, discharging is standby;
S12, under conditions of stirring at low speed, by acrylic acid ester emulsion, remaining defoamer, thickener, initiator and remainder go from Sub- water is added in slurry, is stirred and is adjusted to suitable viscosity, produces this kind of basement, kitchen and toilet anti-fire and water-proof paint.
6. according to a kind of any described basements of claim 1-4, kitchen and toilet anti-fire and water-proof paint, it is characterised in that described Pigment is any one of nano zine oxide or nanometer lithopone or two kinds of mixtures arbitrarily matched;Described filler is carbon Two or more mixture in sour calcium, talcum powder, mica powder, diatom ooze, wollastonite in powder, and wanted 1250 mesh sieves.
7. according to a kind of any described basements of claim 1-4, kitchen and toilet anti-fire and water-proof paint, it is characterised in that described Titanium dioxide is rutile type titanium white.
8. according to a kind of any described basements of claim 1-4, kitchen and toilet anti-fire and water-proof paint, it is characterised in that described Dispersant is one or more kinds of mixtures in acrylic copolymer ammonium salt, ammonium polyacrylate salt, polycarboxylic acids ammonium salt.
9. according to a kind of any described basements of claim 1-4, kitchen and toilet anti-fire and water-proof paint, it is characterised in that described Defoamer for organic silicon defoamer, mineral oil defoaming agent or its combination.
CN201711142206.8A 2017-11-17 2017-11-17 A kind of basement, kitchen and toilet anti-fire and water-proof paint and preparation method thereof Pending CN107858056A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109626903A (en) * 2018-12-27 2019-04-16 宁波中石化科技股份有限公司 Polymer cement waterproof paint and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109626903A (en) * 2018-12-27 2019-04-16 宁波中石化科技股份有限公司 Polymer cement waterproof paint and preparation method thereof

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