CN107858041A - A kind of ink for PVDC surface printings - Google Patents
A kind of ink for PVDC surface printings Download PDFInfo
- Publication number
- CN107858041A CN107858041A CN201711475697.8A CN201711475697A CN107858041A CN 107858041 A CN107858041 A CN 107858041A CN 201711475697 A CN201711475697 A CN 201711475697A CN 107858041 A CN107858041 A CN 107858041A
- Authority
- CN
- China
- Prior art keywords
- parts
- ester
- ink
- molten
- pvdc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
A kind of ink for PVDC surface printings, its raw material includes the molten vinyl chloride-vinyl acetate resin of ester, the molten fluororesin of ester, the molten silicones of ester, pigment, dispersant, ethyl acetate, n-propyl acetate, propylene glycol methyl ether acetate, by disperseing, grinding, the processing step such as being stirred and prepare product ink.The present invention is directed to PVDC surface printing, solve the problems, such as that ink easily comes off during PVDC surface printings, each resin and pigment are dissolved with various environmentally friendly solvents, it instead of the larger solvent of existing ink Poisoning, when it is applied to food packaging applications, not only meet food safety requirements, it is more safe and harmless.
Description
Technical field
The invention belongs to technical field of ink, is specially that one kind is used for PVDC（Poly (vinylidene chloride),
Polyvinylidene chloride）The ink of surface printing.
Background technology
In packaging field, particularly food packaging applications, there are several film materials to be widely used：Polyvinylidene chloride
（PVDC）, polyethylene terephthalate（PET）And bidirectional stretching polypropylene film（BOPP）, wherein, PVDC have it is resistance to combustion,
Corrosion-resistant, the advantages of air-tightness is good, barrier is high, but it is poor in light, heat endurance, therefore in food packaging applications,
PVDC deviations are applied to quick-freezing fresh-keeping packaging and food flexible packing, are applied to ham sausage, square ham etc. especially as casing film
Food；PET has excellent physical and mechanical properties within the scope of wider temperature, and electrical insulating property is excellent, creep resistance, endurance
Property, rub resistance, dimensional stability are all fine, but it easily reacts with some oxidants, and eyes can be stimulated under certain condition, are exhaled
Desorption system and skin, therefore in food packaging applications, PET deviations are applied to make the bottle as hard, box body etc.；BOPP
For macromolecule polypropylene by biaxial tension after, by appropriate cooling or heat treatment or the special film being processed into, tool
There are the high grade of transparency and glossiness, excellent ink and coating adhesion, excellent water vapour and grease barrier property, low static behaviour
Can, but its elasticity is poor, is heated and easily shrinks, therefore possess more in the outermost layer packaging of food in food packaging applications, BOPP
Good effect.
Because PVDC is poor to the adhesive force of ink, and they need to participate in and gone in the production technologies of the food such as ham,
Will be by various tests so that its to ink there is it is nontoxic, stability is good, high temperature high voltage resistant steam etc. is new will
Ask.The current existing surface printing to PVDC, or by being printed onto on paster, then paster is pasted into PVDC surfaces and come in fact
Its existing printing effect, otherwise selection be directly printed onto in the ink on PVDC surfaces ingredient such as butanone, dimethylformamide or
Composition that person contains benzene and do not meet the requirement of national food safety standard, exist to user's body and injure.Therefore, one is researched and developed
Kind meets the PVDC surface printing ink of all standard, is the requirement of food packaging applications.
The content of the invention
It is an object of the invention to provide a kind of ink for PVDC surface printings, to solve the above problems.
To achieve the above object, technical scheme proposed by the present invention is：
A kind of ink for PVDC surface printings, its raw material components include according to its parts by weight：The molten vinyl chloride-vinyl acetate resin 8 ~ 12 of ester
Part, 5 ~ 8 parts of the molten fluororesin of ester, 2 ~ 5 parts of the molten silicones of ester, 15 ~ 25 parts of pigment, 1 part of dispersant, 20 ~ 30 parts of ethyl acetate, acetic acid
20 ~ 30 parts of n-propyl, 5 ~ 10 parts of propylene glycol methyl ether acetate.
Further, the ink for PVDC surface printings, its raw material components and its parts by weight match preferred
Scheme is：10 parts of the molten vinyl chloride-vinyl acetate resin of ester, 6 parts of the molten fluororesin of ester, 3 parts of the molten silicones of ester, 20 parts of pigment, 1 part of dispersant, acetic acid second
25 parts of ester, 25 parts of n-propyl acetate, 10 parts of propylene glycol methyl ether acetate.
Preferably, the molten fluororesin of the ester is Isosorbide-5-Nitrae-phthalic acid and adipic acid and the polymer of 1,6- hexamethylene diamine.
Preferably, the solvent of the molten silicones of the ester is propylene glycol methyl ether acetate.
Based on the ink of above-mentioned raw materials component, when its application method is to mix with curing agent, the ratio of ink and curing agent
Example is 10:1.
In the present invention, the dispersant is made a living the general name of oil-producing ink coating additive, the generally height with various groups
Molecular compound, it is added in ink and pigment particles is separated from each other and avoids aggregation from turning into larger particle and precipitate, to carry
Mobility, rheological characteristic, color developing, spreadability, glossiness and the stability of high ink, convenient use and storage.
In the present invention, the curing agent is with isocyanates（-NCO）The high-molecular compound of group, its by with
It is other to carry hydroxyl（-OH）The compound of group is reacted and forms various types of patience polymer substances.
Compared with prior art, the present invention is directed to PVDC surface printing, and ink is easy when solving PVDC surface printings
The problem of coming off, each resin and pigment are dissolved with various environmentally friendly solvents, the larger solvent of existing ink Poisoning is instead of, makes it
During applied to food packaging applications, not only meet food safety requirements, it is more safe and harmless.
Embodiment
Below in conjunction with specific preferred embodiment, the invention will be further described, but not thereby limiting the invention
Protection domain.
Embodiment 1
A kind of ink for PVDC surface printings, preparing raw material includes：The molten vinyl chloride-vinyl acetate resin 100g of ester, the molten fluororesin 60g of ester, ester
Molten silicones 30g, pigment 200g, dispersant 10g, ethyl acetate 250g, n-propyl acetate 250g, propylene glycol methyl ether acetate
100g。
Embodiment 2
A kind of ink for PVDC surface printings, preparing raw material includes：The molten vinyl chloride-vinyl acetate resin 80g of ester, the molten fluororesin 80g of ester, ester
Molten silicones 20g, pigment 200g, dispersant 10g, ethyl acetate 200g, n-propyl acetate 300g, propylene glycol methyl ether acetate
100g。
Embodiment 3
A kind of ink for PVDC surface printings, preparing raw material includes：The molten vinyl chloride-vinyl acetate resin 120g of ester, the molten fluororesin 50g of ester, ester
Molten silicones 50g, pigment 200g, dispersant 10g, ethyl acetate 250g, n-propyl acetate 250g, propylene glycol methyl ether acetate
80g。
Embodiment 4
A kind of ink for PVDC surface printings, preparing raw material includes：The molten vinyl chloride-vinyl acetate resin 90g of ester, the molten fluororesin 70g of ester, ester
Molten silicones 40g, pigment 200g, dispersant 10g, ethyl acetate 300g, n-propyl acetate 300g, propylene glycol methyl ether acetate
50g。
Embodiment 5
A kind of ink for PVDC surface printings, preparing raw material includes：The molten vinyl chloride-vinyl acetate resin 100g of ester, the molten fluororesin 70g of ester, ester
Molten silicones 30g, pigment 200g, dispersant 10g, ethyl acetate 200g, n-propyl acetate 200g, propylene glycol methyl ether acetate
100g。
The ink for PVDC surface printings prepared according to the raw material proportioning in above-described embodiment 1 ~ 5, during use with
Curing agent mixes, and the ratio of ink and curing agent is 10:1.
In the present invention, the ink prepared is applied in PVDC surface printings, have it is nontoxic, stability is good, high temperature resistant
The advantages that high steam, the character pattern printed out is difficult for drop-off, svelteness, full color, by whole food processing
Still as new after flow, in addition, material composition safety and environmental protection, product ink meet the requirement of food security, therefore be can not be more
The good ink obtained.
The present invention is not limited to above-mentioned preferred forms, and anyone can show that other are various under the enlightenment of the present invention
The product of form, however, make any change in its shape or structure, it is every that there is skill identical or similar to the present application
Art scheme, is within the scope of the present invention.
Claims (5)
1. a kind of ink for PVDC surface printings, it is characterised in that its raw material components includes according to its parts by weight：Ester is molten
5 ~ 8 parts of the molten fluororesin of 8 ~ 12 parts of vinyl chloride-vinyl acetate resin, ester, 2 ~ 5 parts of the molten silicones of ester, 15 ~ 25 parts of pigment, 1 part of dispersant, ethyl acetate
20 ~ 30 parts, 20 ~ 30 parts of n-propyl acetate, 5 ~ 10 parts of propylene glycol methyl ether acetate.
2. the ink according to claim 1 for PVDC surface printings, it is characterised in that its raw material components and its weight
Number proportioning preferred scheme be：10 parts of the molten vinyl chloride-vinyl acetate resin of ester, 6 parts of the molten fluororesin of ester, 3 parts of the molten silicones of ester, pigment 20 part, point
1 part of powder, 25 parts of ethyl acetate, 25 parts of n-propyl acetate, 10 parts of propylene glycol methyl ether acetate.
3. the ink according to claim 1 or 2 for PVDC surface printings, it is characterised in that the molten fluororesin of the ester
For 1,4- phthalic acids and the polymer of adipic acid and 1,6- hexamethylene diamines.
4. the ink according to claim 1 or 2 for PVDC surface printings, it is characterised in that the molten silicones of the ester
Solvent be propylene glycol methyl ether acetate.
5. the ink according to claim 1 or 2 for PVDC surface printings, it is characterised in that its application method is
When being mixed with curing agent, the ratio of ink and curing agent is 10:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711475697.8A CN107858041A (en) | 2017-12-29 | 2017-12-29 | A kind of ink for PVDC surface printings |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711475697.8A CN107858041A (en) | 2017-12-29 | 2017-12-29 | A kind of ink for PVDC surface printings |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107858041A true CN107858041A (en) | 2018-03-30 |
Family
ID=61707638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711475697.8A Pending CN107858041A (en) | 2017-12-29 | 2017-12-29 | A kind of ink for PVDC surface printings |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107858041A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110183904A (en) * | 2019-06-13 | 2019-08-30 | 广东顺德洋紫薇化工有限公司 | Fire-retardant ink and preparation method thereof and inflaming retarding membrane |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1884007A (en) * | 2005-06-22 | 2006-12-27 | 河南双汇投资发展股份有限公司 | PVDC casing sandwiched printing package film and method for producing same |
| CN102618120A (en) * | 2012-04-16 | 2012-08-01 | 珠海市希友达油墨涂料有限公司 | Printing ink for polyvinylidene chloride (PVDC) surface printing |
| CN104231731A (en) * | 2014-09-16 | 2014-12-24 | 洋紫荆油墨(中山)有限公司 | Alcohol-soluble high-speed printing ink for PVDC (polyvinyl dichloride) film and preparation method of alcohol-soluble high-speed printing ink |
-
2017
- 2017-12-29 CN CN201711475697.8A patent/CN107858041A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1884007A (en) * | 2005-06-22 | 2006-12-27 | 河南双汇投资发展股份有限公司 | PVDC casing sandwiched printing package film and method for producing same |
| CN102618120A (en) * | 2012-04-16 | 2012-08-01 | 珠海市希友达油墨涂料有限公司 | Printing ink for polyvinylidene chloride (PVDC) surface printing |
| CN104231731A (en) * | 2014-09-16 | 2014-12-24 | 洋紫荆油墨(中山)有限公司 | Alcohol-soluble high-speed printing ink for PVDC (polyvinyl dichloride) film and preparation method of alcohol-soluble high-speed printing ink |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110183904A (en) * | 2019-06-13 | 2019-08-30 | 广东顺德洋紫薇化工有限公司 | Fire-retardant ink and preparation method thereof and inflaming retarding membrane |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2583834B1 (en) | Modified polyvinyl alcohol coated film used for printing and preparation method thereof | |
| JP2016514181A5 (en) | ||
| CN102146248B (en) | Acid resistance and high temperature resistance antiseptic waterborne coating for inner wall of pop can | |
| CN103966897B (en) | A kind of antibacterial release paper of uvioresistant and preparation method thereof | |
| CN105504618B (en) | A kind of polyvinyl alcohol-chitosan-graphene oxide sponge and preparation method thereof | |
| EP3149081A1 (en) | Heat seal coating for use on substrates | |
| JP2013127038A (en) | Gravure top side printing ink composition for antifog packaging material | |
| EP3149080B1 (en) | Thermal lamination adhesive coatings for use on substrates | |
| CN107858041A (en) | A kind of ink for PVDC surface printings | |
| CN104946125A (en) | Impact-resistance antistatic coating | |
| JP2006096981A (en) | Dampproof coating liquid, dampproof composite material and its preparation process | |
| CN103739785B (en) | The preparation method of PVC heat shrink films alcohol water-based ink resin | |
| JP5735278B2 (en) | Release film | |
| CN104212232A (en) | Printing ink for various compound processes | |
| US4160752A (en) | Process for making closure sealing compounds and other latex based preparations | |
| CN106566400A (en) | Water varnish for protection of printable aluminum foil for drug packing and preparation method of water varnish | |
| CN103467890A (en) | Strippable protective film and composition formula thereof | |
| CN106675187A (en) | Printing ink with low viscosity | |
| CN107512096A (en) | Heat transfer film for temperature-sensitive color-changing type transfusion soft bag and preparation method | |
| CN106675198A (en) | Printing ink composition | |
| JPS605628B2 (en) | Releaseable laminated film | |
| JP3957499B2 (en) | Coating agent | |
| CN106675197A (en) | High-performance printing ink coating for ink-jet printing machine | |
| JP2005527645A5 (en) | ||
| CN105238249B (en) | A kind of Fabric transfer coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180330 |
|
| RJ01 | Rejection of invention patent application after publication |