CN107857993A - A kind of thrust washer material compositions and preparation method - Google Patents
A kind of thrust washer material compositions and preparation method Download PDFInfo
- Publication number
- CN107857993A CN107857993A CN201711168879.0A CN201711168879A CN107857993A CN 107857993 A CN107857993 A CN 107857993A CN 201711168879 A CN201711168879 A CN 201711168879A CN 107857993 A CN107857993 A CN 107857993A
- Authority
- CN
- China
- Prior art keywords
- thrust washer
- material compositions
- washer material
- carbon fiber
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3009—Sulfides
Abstract
The invention provides a kind of thrust washer material compositions and preparation method thereof, and it includes the following component matched by constant weight number:Polyamide compound, long carbon fiber, kollag and auxiliary agent.The preparation method of described thrust washer material compositions comprises the following steps:Polyamide compound is extruded into plastic melt;Carbon fiber is passed through in the plastics in body, coextrusion, through cooling, pelletizing, obtains the thrust washer material compositions.The present invention has following beneficial effect:1st, the plastic formula of the mechanical strength higher than common plasticses is obtained, there is very high impact strength and rigidity;2nd, the length due to carbon fiber and distribution, the material of acquisition have more preferable thermal conductivity;3rd, the good high-abrasive material that the present invention obtains.
Description
Technical field
The present invention relates to a kind of thrust washer material compositions and preparation method, belong to technical field of polymer materials.
Background technology
At present, most of thrust washer for using metal, have it is using cast iron, also to use copper, cast iron pad and copper
The features such as not wear-resisting all be present in pad;And copper backing can chemically react with lubricating oil, cause the replacement cycle of lubricating oil
Shorten.So people have focused on the thrust washer of plastics;General high temperature resistant wear-resisting plastics again, such as polyether-ether-ketone and
The special plastic energy work such as polyimides meets the needs of this thrust washer, still, due to the factor of cost;Can not be by high-volume
Use, popularization limited.
As thrust washer, wear-resistant is essential, therefore the material of selection high abrasion is in the selection of material
It is very necessary;This province of common plasticses is athermanous;, can not be by heat derives in high speed rotary grinding, and cause common
Plastics cause the decline and thermal expansion of mechanical strength with the rise of temperature, further cause the mistake of plastics thrust washer
Effect;In addition, the impact being subject in the case of thrust washer in general is all very big.Therefore, material needs very high mechanical strength.
The content of the invention
It is an object of the invention to provide a kind of brand-new high intensity, high abrasion and the thrust washer material of heat conduction and preparation
Method, by material made from the method for adjustment and the preparation of formula, meet the wear-resistant of thrust washer, high intensity and can and
When by heat derives.
The present invention is achieved by the following technical solutions:
The invention provides a kind of thrust washer material compositions, and it includes the following component counted in parts by weight:
Preferably, the polyamide compound includes at least one of PA6, PA66, PA6T, PT9T, PT46.
Preferably, the monofilament number of share of stock of the carbon fiber is 3000~6000 strands.
Preferably, the kollag is in molybdenum disulfide, polytetrafluoroethylene (PTFE), heat curing-type polyimides
It is at least one.
Preferably, the auxiliary agent is one or two kinds of in antioxidant, stabilizer.
A kind of preparation method of thrust washer material compositions as the aforementioned, it comprises the following steps:
Polyamide compound, kollag and auxiliary agent are extruded into plastic melt;
Long carbon fiber is passed through in the plastics in body, coextrusion, through cooling, pelletizing, obtains the thrust washer material
Composition.
Compared with prior art, the present invention has following beneficial effect:
1st, the plastic formula of the mechanical strength higher than common plasticses is obtained, there is very high impact strength and rigidity;
2nd, the length due to carbon fiber and distribution, the material of acquisition have more preferable thermal conductivity;
3rd, the good high-abrasive material that the present invention obtains.
Embodiment
With reference to specific embodiment, the present invention is described in detail.Following examples will be helpful to the technology of this area
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill to this area
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection domain.
Embodiment 1
The present invention a kind of plastic formula, be made up below of the number raw material of weight, by 70 parts of PA6,1 part of antioxidant, 1 part
Stabilizer passes through twin-screw extrusion shear melting;Meanwhile the plastic melt by branched 3K long carbon fiber beam through melting;Regulation
The size of extrusion neck ring mold, the content for ensureing long carbon fiber are 30 parts;Cooled down by tank, then, be granulated by cutting knife and be
The particle of 9mm length.
Embodiment 2
A kind of plastic formula of the present invention, is made up of the number raw material of weight, by 60 parts of PA66,5 parts of molybdenum disulfide below
With 1 part of antioxidant, pass through twin-screw extrusion shear melting;Meanwhile branched 3K long carbon fiber beam is melted through the plastics of melting
Body;The size of extrusion neck ring mold is adjusted, the content for ensureing long carbon fiber is 40 parts;Cooled down by tank, then, by cutting knife by its
It is granulated as the particle of 9mm length.
Embodiment 3
A kind of plastic formula of the present invention, is made up of the number raw material of weight, by 70 parts of PA6T, 5 parts of polytetrafluoroethyl-nes below
Alkene and 2 parts of stabilizers, pass through twin-screw extrusion shear melting;Meanwhile the plastics by branched 3K long carbon fiber beam through melting
Melt;The size of extrusion neck ring mold is adjusted, the content for ensureing carbon fiber is 30 parts;Cooled down by tank, then, by cutting knife by its
It is granulated as the particle of 9mm length.
Embodiment 4
A kind of plastic formula of the present invention, is made up of the number raw material of weight, 60 parts of PA9T, 5 parts of thermosettings is gathered below
Acid imide, 1 part of antioxidant and 2 parts of stabilizers, pass through twin-screw extrusion shear melting;Meanwhile by branched 3K long carbon fiber beam
Through the plastic melt of melting;The size of extrusion neck ring mold is adjusted, the content for ensureing carbon fiber is 40 parts;Cooled down by tank, so
Afterwards, the particle for 9mm length is granulated by cutting knife.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (6)
1. a kind of thrust washer material compositions, it is characterised in that including the following component counted in parts by weight:
2. thrust washer material compositions as claimed in claim 1, it is characterised in that the polyamide compound include PA6,
At least one of PA66, PA6T, PT9T, PT46.
3. thrust washer material compositions as claimed in claim 1, it is characterised in that the monofilament number of share of stock of the carbon fiber is
3000~6000 strands.
4. thrust washer material compositions as claimed in claim 1, it is characterised in that the kollag is selected from curing
At least one of molybdenum, polytetrafluoroethylene (PTFE), heat curing-type polyimides.
5. thrust washer material compositions as claimed in claim 1, it is characterised in that the auxiliary agent is selected from antioxidant, stably
One or both of agent.
6. a kind of preparation method of thrust washer material compositions as described in any one in Claims 1 to 5, its feature exist
In comprising the following steps:
Polyamide compound, kollag and auxiliary agent are extruded into plastic melt;
Carbon fiber is passed through in the plastics in body, coextrusion, through cooling, pelletizing, obtains the thrust washer material compositions.
Priority Applications (1)
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CN201711168879.0A CN107857993A (en) | 2017-11-21 | 2017-11-21 | A kind of thrust washer material compositions and preparation method |
Applications Claiming Priority (1)
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CN201711168879.0A CN107857993A (en) | 2017-11-21 | 2017-11-21 | A kind of thrust washer material compositions and preparation method |
Publications (1)
Publication Number | Publication Date |
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CN107857993A true CN107857993A (en) | 2018-03-30 |
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CN201711168879.0A Pending CN107857993A (en) | 2017-11-21 | 2017-11-21 | A kind of thrust washer material compositions and preparation method |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108547934A (en) * | 2018-07-10 | 2018-09-18 | 南通汇平高分子新材料有限公司 | A kind of automotive axle thrust washer and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103534317A (en) * | 2011-09-28 | 2014-01-22 | 株式会社理研 | Resin composition and sliding member using same |
CN103540127A (en) * | 2012-07-12 | 2014-01-29 | 中国石油化工股份有限公司 | Wear-resistant carbon fiber reinforced nylon 66 resin composition and synthesis method thereof |
CN104725845A (en) * | 2013-12-24 | 2015-06-24 | 上海杰事杰新材料(集团)股份有限公司 | Continuous-long-fiber-reinforced high-temperature-resistant nylon composite material and preparation method thereof |
-
2017
- 2017-11-21 CN CN201711168879.0A patent/CN107857993A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103534317A (en) * | 2011-09-28 | 2014-01-22 | 株式会社理研 | Resin composition and sliding member using same |
CN103540127A (en) * | 2012-07-12 | 2014-01-29 | 中国石油化工股份有限公司 | Wear-resistant carbon fiber reinforced nylon 66 resin composition and synthesis method thereof |
CN104725845A (en) * | 2013-12-24 | 2015-06-24 | 上海杰事杰新材料(集团)股份有限公司 | Continuous-long-fiber-reinforced high-temperature-resistant nylon composite material and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108547934A (en) * | 2018-07-10 | 2018-09-18 | 南通汇平高分子新材料有限公司 | A kind of automotive axle thrust washer and preparation method thereof |
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