CN107857993A - A kind of thrust washer material compositions and preparation method - Google Patents

A kind of thrust washer material compositions and preparation method Download PDF

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Publication number
CN107857993A
CN107857993A CN201711168879.0A CN201711168879A CN107857993A CN 107857993 A CN107857993 A CN 107857993A CN 201711168879 A CN201711168879 A CN 201711168879A CN 107857993 A CN107857993 A CN 107857993A
Authority
CN
China
Prior art keywords
thrust washer
material compositions
washer material
carbon fiber
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711168879.0A
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Chinese (zh)
Inventor
顾伟
杨帆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Leveling Macromolecule New Material Co Ltd
Original Assignee
Nantong Leveling Macromolecule New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Leveling Macromolecule New Material Co Ltd filed Critical Nantong Leveling Macromolecule New Material Co Ltd
Priority to CN201711168879.0A priority Critical patent/CN107857993A/en
Publication of CN107857993A publication Critical patent/CN107857993A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/06Elements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06Polyamides derived from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009Sulfides

Abstract

The invention provides a kind of thrust washer material compositions and preparation method thereof, and it includes the following component matched by constant weight number:Polyamide compound, long carbon fiber, kollag and auxiliary agent.The preparation method of described thrust washer material compositions comprises the following steps:Polyamide compound is extruded into plastic melt;Carbon fiber is passed through in the plastics in body, coextrusion, through cooling, pelletizing, obtains the thrust washer material compositions.The present invention has following beneficial effect:1st, the plastic formula of the mechanical strength higher than common plasticses is obtained, there is very high impact strength and rigidity;2nd, the length due to carbon fiber and distribution, the material of acquisition have more preferable thermal conductivity;3rd, the good high-abrasive material that the present invention obtains.

Description

A kind of thrust washer material compositions and preparation method
Technical field
The present invention relates to a kind of thrust washer material compositions and preparation method, belong to technical field of polymer materials.
Background technology
At present, most of thrust washer for using metal, have it is using cast iron, also to use copper, cast iron pad and copper The features such as not wear-resisting all be present in pad;And copper backing can chemically react with lubricating oil, cause the replacement cycle of lubricating oil Shorten.So people have focused on the thrust washer of plastics;General high temperature resistant wear-resisting plastics again, such as polyether-ether-ketone and The special plastic energy work such as polyimides meets the needs of this thrust washer, still, due to the factor of cost;Can not be by high-volume Use, popularization limited.
As thrust washer, wear-resistant is essential, therefore the material of selection high abrasion is in the selection of material It is very necessary;This province of common plasticses is athermanous;, can not be by heat derives in high speed rotary grinding, and cause common Plastics cause the decline and thermal expansion of mechanical strength with the rise of temperature, further cause the mistake of plastics thrust washer Effect;In addition, the impact being subject in the case of thrust washer in general is all very big.Therefore, material needs very high mechanical strength.
The content of the invention
It is an object of the invention to provide a kind of brand-new high intensity, high abrasion and the thrust washer material of heat conduction and preparation Method, by material made from the method for adjustment and the preparation of formula, meet the wear-resistant of thrust washer, high intensity and can and When by heat derives.
The present invention is achieved by the following technical solutions:
The invention provides a kind of thrust washer material compositions, and it includes the following component counted in parts by weight:
Preferably, the polyamide compound includes at least one of PA6, PA66, PA6T, PT9T, PT46.
Preferably, the monofilament number of share of stock of the carbon fiber is 3000~6000 strands.
Preferably, the kollag is in molybdenum disulfide, polytetrafluoroethylene (PTFE), heat curing-type polyimides It is at least one.
Preferably, the auxiliary agent is one or two kinds of in antioxidant, stabilizer.
A kind of preparation method of thrust washer material compositions as the aforementioned, it comprises the following steps:
Polyamide compound, kollag and auxiliary agent are extruded into plastic melt;
Long carbon fiber is passed through in the plastics in body, coextrusion, through cooling, pelletizing, obtains the thrust washer material Composition.
Compared with prior art, the present invention has following beneficial effect:
1st, the plastic formula of the mechanical strength higher than common plasticses is obtained, there is very high impact strength and rigidity;
2nd, the length due to carbon fiber and distribution, the material of acquisition have more preferable thermal conductivity;
3rd, the good high-abrasive material that the present invention obtains.
Embodiment
With reference to specific embodiment, the present invention is described in detail.Following examples will be helpful to the technology of this area Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill to this area For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention Protection domain.
Embodiment 1
The present invention a kind of plastic formula, be made up below of the number raw material of weight, by 70 parts of PA6,1 part of antioxidant, 1 part Stabilizer passes through twin-screw extrusion shear melting;Meanwhile the plastic melt by branched 3K long carbon fiber beam through melting;Regulation The size of extrusion neck ring mold, the content for ensureing long carbon fiber are 30 parts;Cooled down by tank, then, be granulated by cutting knife and be The particle of 9mm length.
Embodiment 2
A kind of plastic formula of the present invention, is made up of the number raw material of weight, by 60 parts of PA66,5 parts of molybdenum disulfide below With 1 part of antioxidant, pass through twin-screw extrusion shear melting;Meanwhile branched 3K long carbon fiber beam is melted through the plastics of melting Body;The size of extrusion neck ring mold is adjusted, the content for ensureing long carbon fiber is 40 parts;Cooled down by tank, then, by cutting knife by its It is granulated as the particle of 9mm length.
Embodiment 3
A kind of plastic formula of the present invention, is made up of the number raw material of weight, by 70 parts of PA6T, 5 parts of polytetrafluoroethyl-nes below Alkene and 2 parts of stabilizers, pass through twin-screw extrusion shear melting;Meanwhile the plastics by branched 3K long carbon fiber beam through melting Melt;The size of extrusion neck ring mold is adjusted, the content for ensureing carbon fiber is 30 parts;Cooled down by tank, then, by cutting knife by its It is granulated as the particle of 9mm length.
Embodiment 4
A kind of plastic formula of the present invention, is made up of the number raw material of weight, 60 parts of PA9T, 5 parts of thermosettings is gathered below Acid imide, 1 part of antioxidant and 2 parts of stabilizers, pass through twin-screw extrusion shear melting;Meanwhile by branched 3K long carbon fiber beam Through the plastic melt of melting;The size of extrusion neck ring mold is adjusted, the content for ensureing carbon fiber is 40 parts;Cooled down by tank, so Afterwards, the particle for 9mm length is granulated by cutting knife.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow Ring the substantive content of the present invention.

Claims (6)

1. a kind of thrust washer material compositions, it is characterised in that including the following component counted in parts by weight:
2. thrust washer material compositions as claimed in claim 1, it is characterised in that the polyamide compound include PA6, At least one of PA66, PA6T, PT9T, PT46.
3. thrust washer material compositions as claimed in claim 1, it is characterised in that the monofilament number of share of stock of the carbon fiber is 3000~6000 strands.
4. thrust washer material compositions as claimed in claim 1, it is characterised in that the kollag is selected from curing At least one of molybdenum, polytetrafluoroethylene (PTFE), heat curing-type polyimides.
5. thrust washer material compositions as claimed in claim 1, it is characterised in that the auxiliary agent is selected from antioxidant, stably One or both of agent.
6. a kind of preparation method of thrust washer material compositions as described in any one in Claims 1 to 5, its feature exist In comprising the following steps:
Polyamide compound, kollag and auxiliary agent are extruded into plastic melt;
Carbon fiber is passed through in the plastics in body, coextrusion, through cooling, pelletizing, obtains the thrust washer material compositions.
CN201711168879.0A 2017-11-21 2017-11-21 A kind of thrust washer material compositions and preparation method Pending CN107857993A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711168879.0A CN107857993A (en) 2017-11-21 2017-11-21 A kind of thrust washer material compositions and preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711168879.0A CN107857993A (en) 2017-11-21 2017-11-21 A kind of thrust washer material compositions and preparation method

Publications (1)

Publication Number Publication Date
CN107857993A true CN107857993A (en) 2018-03-30

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711168879.0A Pending CN107857993A (en) 2017-11-21 2017-11-21 A kind of thrust washer material compositions and preparation method

Country Status (1)

Country Link
CN (1) CN107857993A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108547934A (en) * 2018-07-10 2018-09-18 南通汇平高分子新材料有限公司 A kind of automotive axle thrust washer and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103534317A (en) * 2011-09-28 2014-01-22 株式会社理研 Resin composition and sliding member using same
CN103540127A (en) * 2012-07-12 2014-01-29 中国石油化工股份有限公司 Wear-resistant carbon fiber reinforced nylon 66 resin composition and synthesis method thereof
CN104725845A (en) * 2013-12-24 2015-06-24 上海杰事杰新材料(集团)股份有限公司 Continuous-long-fiber-reinforced high-temperature-resistant nylon composite material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103534317A (en) * 2011-09-28 2014-01-22 株式会社理研 Resin composition and sliding member using same
CN103540127A (en) * 2012-07-12 2014-01-29 中国石油化工股份有限公司 Wear-resistant carbon fiber reinforced nylon 66 resin composition and synthesis method thereof
CN104725845A (en) * 2013-12-24 2015-06-24 上海杰事杰新材料(集团)股份有限公司 Continuous-long-fiber-reinforced high-temperature-resistant nylon composite material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108547934A (en) * 2018-07-10 2018-09-18 南通汇平高分子新材料有限公司 A kind of automotive axle thrust washer and preparation method thereof

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