CN107857937A - A kind of polypropylene polyamide heat-conductive composite material - Google Patents
A kind of polypropylene polyamide heat-conductive composite material Download PDFInfo
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- CN107857937A CN107857937A CN201711161167.6A CN201711161167A CN107857937A CN 107857937 A CN107857937 A CN 107857937A CN 201711161167 A CN201711161167 A CN 201711161167A CN 107857937 A CN107857937 A CN 107857937A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
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- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/14—Solid materials, e.g. powdery or granular
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
- C08K2003/282—Binary compounds of nitrogen with aluminium
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention belongs to Material Field, and in particular to a kind of polypropylene polyamide heat-conductive composite material, in parts by weight, have following raw material to be prepared：30~70 parts of polypropylene, 0~70 part of kymene, 50~100 parts of heat filling, 20~40 parts of modified glass-fiber, 20~30 parts of compatilizer, 10~15 parts of fire retardant, 0.5~1.0 part of light stabilizer, 0.2~0.3 part of coupling agent, 0.2~0.3 part of antioxidant；Described modified glass-fiber is that glass fibre passes through the modified composite nitride aluminium in dopamine surface.The present invention enters modification using dopamine to fiberglass surfacing, so as to adhere to aluminium nitride particulate, the thermal conductivity of glass fibre is improved with this, and modified glass fibre is added in the composite of polypropylene polyamide, while strengthened composite product mechanical performance, and ensure the requirement of thermal conductivity.
Description
Technical field
The invention belongs to Material Field, and in particular to a kind of polypropylene-polyamide heat-conducting composite.
Background technology
Polypropylene (PP) is a kind of wide variety of thermoplastic, and its raw material sources enriches, cheap, is had preferable
Combination property, occupy critical role in the plastic.Relative to polyamide, polypropylene hardly absorbs water, not by use environment tide
The influence of humidity, but the shortcomings of molding shrinkage is big, notch impact toughness is poor be present in polypropylene.Polyamide (PA) is commonly called as Buddhist nun
Dragon, it is a kind of thermoplastic engineering plastic for being widely used in the fields such as automobile, electronics, machinery, instrument and meter.PA has excellent
Wearability, oil resistivity and wider use temperature range, its shortcoming are big water absorption rate, poor dimensional stability, low temperature and dry state punching
Hit intensity is low, and these shortcomings greatly limit its application.Blending and modifying is carried out to polyamide with polypropylene, can be changed
The shortcomings that kind polyamide, widen the application field of polyamide.By PA/PP composites made from blending, nylon is both combined
Heat resistance and oil resistivity, combine PP characteristic again, the material has excellent impact strength, excellent mobility and surface
Glossiness, it can be widely applied to the fields such as automobile interior exterior part, electronic apparatus, oil field equipment and sports goods.
Due to polymeric material compared to metal material in resistant to chemical etching, processing and forming, good insulating and light etc.
The advantage of aspect, can be with alternative metals material in the reality of engineering, heating engineering, Electronics and Information Engineering, LED etc. that exchanges heat
Using, thus the novel high polymer material with Thermal conductivity is developed, turn into the important development direction of current Heat Conduction Material.
Realizing the approach of polymer bond has two kinds：First, intrinsic thermal conductivity type polymer of the synthesis with high heat conductance.Such as
The conducting polymers such as polyacetylene, polyaniline, polypyrrole just have Thermal conductivity, by being doped to material, Ke Yitong
Cross electronics heat transfer mechanism and realize heat conduction；And for example there is the highly crystalline polymer of complete crystal, can be realized and led by phonon
Heat.Second, inorganic matter/polymer bond's composite is prepared with the inorganics filled polymer of high heat conduction, as graphite, aluminium nitride are filled out
Fill high density polyethylene (HDPE) and prepare heat conduction composite plastic.In general, Intrinsical heat-conducting polymer preparation technology is cumbersome, difficulty is big,
Cost is high, at present using less；And filled-type processing and forming is relatively easy, cost is low, and thermal conductivity is high, can carry out industrial metaplasia
Production, is the main method for preparing heat-conducting polymer at present.But most of preferable plastics of heat-conducting effect all with the addition of at present
The inorganic filler of high specific weight, easily cause the mechanical properties decrease of material serious, it is therefore desirable to some toughening auxiliary agents are added,
The glass fibre then Typical Representative as toughening auxiliary agent.
Glass fibre (GF) is a kind of inorganic filler of one-dimentional structure, and main component is aluminum oxide, calcium oxide, silica etc.
Oxide, using the inorganic matters such as silica or discarded glass ball as raw material, through melting, drawing under the condition of high temperature more than 1000 DEG C
Silk, oil, boundling, the technique such as drying are prepared.Glass fibre in addition to excellent mechanical property, also with high temperature resistant,
Electric insulation, corrosion-resistant, moisture absorption is low, a series of anti-oxidant, elongation performances better than other artificial macromolecular fibres such as small, when itself plus
When entering to polymeric matrix, it can effectively undertake stress and load as skeleton, so as to significantly improve polymer matrix
The mechanical property and heat resistance of body.But the thermal conductivity factor of glass fibre is too low, only 0.035 (W/m-K), if glass
Incorporation it is too high, the thermal conductivity of material can be had a strong impact on, glass incorporation is too low, then can not meet again suitable physical
Energy.Therefore, glass fibre is modified in itself, makes it have certain thermal conductivity, while met that glass fibre is compound and lead
The requirement of physical property and thermal conductivity required for hot material.
In nature, marine mussel binding proteins contain a kind of substantial amounts of special amino acid and are referred to as 3,4- dihydroxy
Phenylalanine, i.e. dopamine (DOPA), great pass is caused due to mussel can be made to adhere to the magical ability on various surfaces
Note.Dopamine can polymerize to form poly-dopamine coating under aerobic alkaline aqueous environment in material surface spontaneous oxidation.DOPA
The mode of oxidation auto polymerization occurs for amine, is that catechol contained in dopamine is oxidized to benzoquinones first, then proceed to amine and its
He generates poly-dopamine coating at the reaction of catechol quinones.The catechol and quinone of poly-dopamine coating are functional group, to a variety of materials
Material all has the ability being covalently attached, and reaction condition is simple, it is not necessary to carries out any surface preparation to carrier in advance.For
Dopamine is to the study on the modification of material surface, and nowadays great mass of data is recorded, such as by deposit dopamine in polyethylene, gather
The microporous barrier surface of the materials such as vinylidene, polytetrafluoroethylene (PTFE), the surface hydrophilicity of hydrophobic polymer film can obtain significantly
Improve, and by selecting suitable reaction condition, be improved membrane flux.The material such as modified PE, PTEF leads to for another example
Cross and reacted using the oxidation auto polymerization of poly-dopamine, the compatibility between modified material surface and Gegenbaur's cell substantially improves.
Aluminium nitride has high thermal conductivity still reachable for monocrystalline, its theoretical value 320W/ (mK), its actual value because of it
100~280W/ (mK), 5~10 times equivalent to aluminum oxide, also there is high intensity, high specific insulation, high insulation is pressure-resistant,
Low-dielectric loss, thermal coefficient of expansion such as match at the good characteristic with silicon, it has also become current most promising high heat-conducting ceramic of new generation
Electric substrate and encapsulating material.
The content of the invention
For above the deficiencies in the prior art, the present invention provides a kind of polypropylene-polyamide heat-conducting composite, using more
Bar amine enters modification to fiberglass surfacing, and so as to adhere to aluminium nitride particulate, the thermal conductivity of glass fibre is improved with this, and will be modified
Glass fibre be added in the composite of polypropylene-polyamide, while strengthened composite product mechanical performance, and
Ensure the requirement of thermal conductivity.
A kind of polypropylene-polyamide heat-conducting composite of the present invention, it is characterised in that in parts by weight, have
Following raw material is prepared：30~70 parts of polypropylene, 0~70 part of kymene, 50~100 parts of heat filling, modified glass-fiber
20~40 parts, it is 20~30 parts of compatilizer, 10~15 parts of fire retardant, 0.5~1.0 part of light stabilizer, 0.2~0.3 part of coupling agent, anti-
0.2~0.3 part of oxygen agent；Described modified glass-fiber is that glass fibre passes through the modified composite nitride aluminium in dopamine surface.
Wherein, preferred scheme is as follows：
Described polypropylene is selected from HOPP, one kind of COPP or their mixture, melt index and existed
10~25g/10min.
Described polyamide is nylon-6 or nylon -66.
Described modified glass-fiber is prepared according to following steps：
(1) glass fibre is burnt into 1~2h under the conditions of 500~600 DEG C, be then washed with deionized 2~3 times, done
It is dry standby；
(2) dopamine is added to the aqueous dopamine solution that 2g/L is configured in deionized water, with Tris-HCl to its PH
Adjust to 8.5；
(3) glass fibre is added to progress 24~36h of magnetic agitation in aqueous dopamine solution, then by glass fiber filter
And cleaned with deionized water, dried after cleaning under the conditions of 60~80 DEG C；
(4) aluminium nitride powder is added in alcohol solvent and adds the stearic acid of aluminium nitride powder quality 8~10%, stirred
2~3h is stood after mixing uniformly, adds the Tween 80 of aluminium nitride powder quality 2~3%, stir 3 under the conditions of 60~70 DEG C~
5h, the aluminium nitride powder finally filtered out are washed 2~3 times with alcohol solvent, and modified aluminium nitride powder is produced after drying, according to changing
Property aluminium nitride powder weight account for 8~10% ratio of glass fiber weight, modified aluminium nitride powder is distributed to distilled water
In, 5~10min of supersonic oscillations, form stable modification aluminium nitride suspension；
(5) aluminium nitride suspension and then with spray gun spraying is modified to fiberglass surfacing, that is, obtains modified glass-fiber.
Described glass fibre is alkali-free glass fibre, 6 μm~9 μm of diameter.
Described compatilizer is maleic anhydride inoculated polypropylene.Polyamide is a kind of crystallinity, highly polar polymer, and
Polypropylene is a kind of polymer of low pole, and both solubility parameter differences are larger, without thermodynamic compatibility, therefore add
Enter the shortcomings that compatilizer overcomes both comixing compatibility differences.
Described heat filling is magnesium hydroxide, magnesia, zinc oxide, boron nitride, one kind in titanium dioxide or any several
The combination of kind.
Described fire retardant is nano melamine cyanurate, aluminum diethylphosphinate, brominated Polystyrene, three oxidations
One kind or any several combination in two antimony.
Described light stabilizer is that light stabilizer UV-3853, light stabilizer UV-3346, light stabilizer UV-3529 and light are steady
Determine one kind in agent UV-770 or any several combination.
Described coupling agent is silane coupler, one kind in KH-550, KH-560 or KH-570.
Described antioxidant is antioxidant 1010, antioxidant 1790, antioxidant 1098, irgasfos 168, antioxidant DLTDP
In one or more of mixtures.
The preparation method of PP composite material of the present invention with high thermal conductivity coefficient, modified glass-fiber will be removed
Other raw materials in addition are put into 10~20min of mixing in batch mixer, are sufficiently mixed it, then add mixture to twin-screw
Extruding pelletization unit is melted, and processing temperature is 220~240 DEG C, 300~350r/min of screw speed, is fed in side entrance
Modified glass-fiber, single-size is made through double-screw extruding pelletizing machine extrusion, pelletizing.
The advantage of the invention is that：(1) fiberglass surfacing is modified by dopamine, improves glass fibre and its
Adhesion between its interface, so as to by the adhesion of dopamine in fiberglass surfacing composite nitride aluminium, to improve glass fibers
The thermal conductivity of dimension；(2) because aluminium nitride powder easily hydrolyzes, aluminium hydroxide can be formed with the hydroxyl in water, in aluminium nitride powder
Surface forms alumina layer, and aluminium nitride lattice dissolves in substantial amounts of oxygen, reduces its thermal conductivity, therefore carry out waterproof to aluminium nitride powder
Solution is modified, and is avoided aluminium nitride powder from hydrolyzing to form alumina layer in adition process, is influenceed its heat conductivility；(3) modified glass
Fiber surface is in coarse structure due to being compounded with aluminium nitride, surface, while by dopamine, can significantly increase with polypropylene-
Interface binding power between polyamide；(4) modified glass-fiber thermal conductivity factor can exceed 1.0W/ (mK), to a certain extent
The polyacrylic thermal conductivity factor of heat conduction is improved, while modified glass-fiber effectively improves poly- third as main toughening auxiliary agent
The toughness of alkene-polyamide heat-conducting composite, dimensional stability is improved, reduce shrinkage factor, reduced buckling deformation, meet mechanicalness
The needs of energy；(5) integrated artistic route is simple, low to reaction condition and equipment requirement degree, suitable for industrialized production；(6) this hair
Bright polypropylene-polyamide heat-conducting the composite products being prepared can alternative metals raw material production spare and accessory parts or shell,
Relevant cost declines to a great extent, and improves competitiveness comprehensively, and application prospect is extensive.
Embodiment
The invention will be further described with reference to embodiments.
Embodiment 1：
Prepare modified glass-fiber
(1) alkali-free glass fibre selected between 6 μm~9 μm of diameter, 1h is burnt by glass fibre under the conditions of 600 DEG C,
Then 3 times are washed with deionized, drying for standby.
(2) dopamine is added to the aqueous dopamine solution that 2g/L is configured in deionized water, with Tris-HCl to its PH
Adjust to 8.5.
(3) pretreated glass fibre is added to progress magnetic agitation 24h in aqueous dopamine solution, then by glass
Fiber filter is simultaneously cleaned with deionized water, is dried after cleaning under the conditions of 60 DEG C and be can obtain dopamine modified glass-fiber.
(4) aluminium nitride powder that average particle size particle size is 1.50 μm is added in alcohol solvent and adds aluminium nitride powder
The stearic acid of quality 10%, 2h is stood after stirring, add the Tween 80 of aluminium nitride powder quality 3%, in 60 DEG C of conditions
Lower stirring 4h, the aluminium nitride powder finally filtered out are washed 3 times with alcohol solvent, and modified aluminium nitride powder is produced after drying.Will
The modification aluminium nitride powder for accounting for glass fiber weight 10% is distributed in distilled water, supersonic oscillations 10min, forms stable change
Property aluminium nitride suspension.
(5) fiberglass surfacing and then with spray gun spraying modification aluminium nitride suspension being modified to dopamine, spraying process
In it is noted that spraying is uniform, glass fibre can be stirred by other aids or equipment.Using DRE-2C heat conduction
Coefficient tester carries out Determination of conductive coefficients to it, is as a result 1.221W/ (mK).
Embodiment 2：
Modified glass-fiber prepared by embodiment 1 is applied in polypropylene-polyamide heat-conducting composite preparation, formula
In：50 parts of polypropylene, 50 parts of nylon-6,100 parts of boron nitride, 20 parts of modified glass-fiber, maleic anhydride inoculated polypropylene 20
Part, 15 parts of antimony oxide, 0.5 part of light stabilizer UV-770, KH-5700.2 parts, 0.2 part of antioxidant 1010.
During preparation, other raw materials in addition to modified glass-fiber are put into batch mixer and mix 20min, make it fully mixed
Close, then add mixture to double-screw extruding pelletizing unit and melted, processing temperature is 220 DEG C, screw speed 300r/
Min, modified glass-fiber is fed in side entrance, single-size is made through double-screw extruding pelletizing machine extrusion, pelletizing.
Determination of conductive coefficients is carried out to it using DRE-2C heat conduction coefficient testers, is as a result 6.557W/ (mK).
Embodiment 3：
Modified glass-fiber prepared by embodiment 1 is applied in polypropylene-polyamide heat-conducting composite preparation, formula
In：50 parts of polypropylene, 70 parts of nylon-6,80 parts of boron nitride, 30 parts of modified glass-fiber, 20 parts of maleic anhydride inoculated polypropylene,
10 parts of antimony oxide, 0.5 part of light stabilizer UV-770,0.2 part of KH-570,0.2 part of antioxidant 1010.
During preparation, other raw materials in addition to modified glass-fiber are put into batch mixer and mix 20min, make it fully mixed
Close, then add mixture to double-screw extruding pelletizing unit and melted, processing temperature is 240 DEG C, screw speed 350r/
Min, modified glass-fiber is fed in side entrance, single-size is made through double-screw extruding pelletizing machine extrusion, pelletizing.
Determination of conductive coefficients is carried out to it using DRE-2C heat conduction coefficient testers, is as a result 4.893W/ (mK).
Embodiment 4：
Modified glass-fiber prepared by embodiment 1 is applied in polypropylene-polyamide heat-conducting composite preparation, formula
In：30 parts of polypropylene, 60 parts of nylon-6,80 parts of boron nitride, 20 parts of modified glass-fiber, 20 parts of maleic anhydride inoculated polypropylene,
10 parts of antimony oxide, 1.0 parts of light stabilizer UV-770,0.3 part of KH-570,0.3 part of antioxidant 1010.
During preparation, other raw materials in addition to modified glass-fiber are put into batch mixer and mix 20min, make it fully mixed
Close, then add mixture to double-screw extruding pelletizing unit and melted, processing temperature is 200 DEG C, screw speed 320r/
Min, modified glass-fiber is fed in side entrance, single-size is made through double-screw extruding pelletizing machine extrusion, pelletizing.
Determination of conductive coefficients is carried out to it using DRE-2C heat conduction coefficient testers, is as a result 6.310W/ (mK).
Claims (10)
- A kind of 1. polypropylene-polyamide heat-conducting composite, it is characterised in that in parts by weight, have following raw material prepare and Into：It is 30~70 parts of polypropylene, 0~70 part of kymene, 50~100 parts of heat filling, 20~40 parts of modified glass-fiber, compatible 20~30 parts of agent, 10~15 parts of fire retardant, 0.5~1.0 part of light stabilizer, 0.2~0.3 part of coupling agent, antioxidant 0.2~0.3 Part；Described modified glass-fiber is that glass fibre passes through the modified composite nitride aluminium in dopamine surface.
- A kind of 2. polypropylene-polyamide heat-conducting composite according to claim 1, it is characterised in that：Described poly- third Alkene is selected from HOPP, one kind of COPP or their mixture, and melt index is in 10~25g/10min.
- A kind of 3. polypropylene-polyamide heat-conducting composite according to claim 1, it is characterised in that：Described polyamides Amine is nylon-6 or nylon -66.
- A kind of 4. polypropylene-polyamide heat-conducting composite according to claim 1, it is characterised in that：Described modification Glass fibre is prepared according to following steps：(1) glass fibre is burnt into 1~2h under the conditions of 500~600 DEG C, be then washed with deionized 2~3 times, drying is standby With；(2) dopamine is added to the aqueous dopamine solution that 2g/L is configured in deionized water, its PH adjusted with Tris-HCl To 8.5；(3) glass fibre is added to progress 24~36h of magnetic agitation in aqueous dopamine solution, is then used in combination glass fiber filter Deionized water is cleaned, and is dried after cleaning under the conditions of 60~80 DEG C；(4) aluminium nitride powder is added in alcohol solvent and adds the stearic acid of aluminium nitride powder quality 8~10%, stirring is equal 2~3h is stood after even, adds the Tween 80 of aluminium nitride powder quality 2~3%, 3~5h is stirred under the conditions of 60~70 DEG C, most The aluminium nitride powder filtered out afterwards is washed 2~3 times with alcohol solvent, and modified aluminium nitride powder is produced after drying, according to modified nitrogen The weight for changing aluminium powder accounts for 8~10% ratio of glass fiber weight, and modified aluminium nitride powder is distributed in distilled water, surpassed 5~10min of sonication, form stable modification aluminium nitride suspension；(5) aluminium nitride suspension and then with spray gun spraying is modified to fiberglass surfacing, that is, obtains modified glass-fiber.
- A kind of 5. polypropylene-polyamide heat-conducting composite according to claim 1 or 4, it is characterised in that：Described glass Glass fiber is alkali-free glass fibre, 6 μm~9 μm of diameter.
- A kind of 6. polypropylene-polyamide heat-conducting composite according to claim 1, it is characterised in that：Described is compatible Agent is maleic anhydride inoculated polypropylene.
- A kind of 7. polypropylene-polyamide heat-conducting composite according to claim 1, it is characterised in that：Described heat conduction Filler is magnesium hydroxide, magnesia, zinc oxide, boron nitride, one kind in titanium dioxide or any several combination.
- A kind of 8. polypropylene-polyamide heat-conducting composite according to claim 1, it is characterised in that：Described is fire-retardant Agent is nano melamine cyanurate, aluminum diethylphosphinate, brominated Polystyrene, one kind in antimony oxide or any Several combinations.
- A kind of 9. polypropylene-polyamide heat-conducting composite according to claim 1, it is characterised in that：Described light is steady Agent is determined for one kind in light stabilizer UV-3853, light stabilizer UV-3346, light stabilizer UV-3529 and light stabilizer UV-770 Or any several combination.
- A kind of 10. polypropylene-polyamide heat-conducting composite according to claim 1, it is characterised in that：Described coupling Agent is silane coupler, one kind in KH-550, KH-560 or KH-570；Described antioxidant is antioxidant 1010, resisted One or more of mixtures in oxygen agent 1790, antioxidant 1098, irgasfos 168, antioxidant DLTDP.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111410792A (en) * | 2020-06-01 | 2020-07-14 | 天津美亚化工有限公司 | High-specific-strength modified polypropylene-based composite material and preparation method thereof |
| CN112940495A (en) * | 2020-12-31 | 2021-06-11 | 华南理工大学 | Nylon dielectric composite material with high resistance stability and preparation method and application thereof |
| CN114591566A (en) * | 2022-01-27 | 2022-06-07 | 武汉金发科技有限公司 | Polyolefin composition and preparation method and application thereof |
| CN115353683A (en) * | 2022-08-05 | 2022-11-18 | 安徽杰蓝特新材料有限公司 | Glass fiber reinforced polypropylene corrugated pipe and preparation method thereof |
| CN115558288A (en) * | 2022-10-12 | 2023-01-03 | 安徽省华晟塑胶股份有限公司 | Lightweight polyamide material for automobiles and preparation method thereof |
| CN116254084A (en) * | 2023-04-27 | 2023-06-13 | 广东省华锐高新材料股份有限公司 | Aluminum substrate heat-conducting adhesive for mini LED and preparation method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101899209A (en) * | 2010-03-30 | 2010-12-01 | 金发科技股份有限公司 | Heat conductive insulation material and preparation method thereof |
| CN104387762A (en) * | 2014-11-18 | 2015-03-04 | 上海大学 | Polyamide/polypropylene alloy heat-conducting composite material and preparation method thereof |
| CN106336221A (en) * | 2016-07-28 | 2017-01-18 | 烟台同立高科新材料股份有限公司 | Preparation method of anti-hydrolysis AlN powder |
-
2017
- 2017-11-21 CN CN201711161167.6A patent/CN107857937A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101899209A (en) * | 2010-03-30 | 2010-12-01 | 金发科技股份有限公司 | Heat conductive insulation material and preparation method thereof |
| CN104387762A (en) * | 2014-11-18 | 2015-03-04 | 上海大学 | Polyamide/polypropylene alloy heat-conducting composite material and preparation method thereof |
| CN106336221A (en) * | 2016-07-28 | 2017-01-18 | 烟台同立高科新材料股份有限公司 | Preparation method of anti-hydrolysis AlN powder |
Non-Patent Citations (1)
| Title |
|---|
| 张婕等: "纳米氮化硼协同玻璃纤维复合增强尼龙6", 《塑料》 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111410792A (en) * | 2020-06-01 | 2020-07-14 | 天津美亚化工有限公司 | High-specific-strength modified polypropylene-based composite material and preparation method thereof |
| CN112940495A (en) * | 2020-12-31 | 2021-06-11 | 华南理工大学 | Nylon dielectric composite material with high resistance stability and preparation method and application thereof |
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