CN107857839A - A kind of flame resistant glass film for the polymerization that is separated based on PN MAM and inorganic matrix and its preparation method and application - Google Patents
A kind of flame resistant glass film for the polymerization that is separated based on PN MAM and inorganic matrix and its preparation method and application Download PDFInfo
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- CN107857839A CN107857839A CN201711172566.2A CN201711172566A CN107857839A CN 107857839 A CN107857839 A CN 107857839A CN 201711172566 A CN201711172566 A CN 201711172566A CN 107857839 A CN107857839 A CN 107857839A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
- C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/24—Homopolymers or copolymers of amides or imides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/164—Aluminum halide, e.g. aluminium chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
- C08K2003/3081—Aluminum sulfate
Abstract
The present invention discloses a kind of flame resistant glass film for the polymerization that is separated based on PN MAM and inorganic matrix and its preparation method and application, the preparation method is specially by the N NMA N MAM of 30~60 parts by weight and saturated aqueous solution, 40~70 parts by weight and the pH of N, N ' methylene diacrylamide MBAA mixtures>9 inorganic matrix saturated aqueous solution is sufficiently mixed, the mass fraction for adding 0.2~1.5 parts by weight into mixed liquor again is 10% initiator, after stirring, by salivating shaping or mould molding, polymerization obtains PN MAM and the flame resistant glass film of inorganic matrix phase separation polymerization, and described inorganic matrix is made up of any one in waterglass and aluminium salt or two kinds by any proportioning.The flame resistant glass film of the present invention is under the high temperature sintering of fire, refractory material coating can be formed, and the coating is turned into inorganic fire skeleton, mechanical strength, fire resistance and the effect of heat insulation of fireprotection layer are improved, and mechanical integrity and insulating refractory can be kept in a fire.
Description
Technical field
The present invention relates to fire proofing material manufacturing field, and in particular to one kind is separated based on PN-MAM and inorganic matrix to be polymerize
Flame resistant glass film and its preparation method and application.
Background technology
One kind of flame resistant glass category safety glass, it is that one kind can stop flame, smog, heat radiation, prevent propagation of flame,
Within a certain period of time, the special glass with the transparency of integrality, stability is kept, and there should be certain shock resistance strong
Degree, remains to play a protective role within a certain period of time under 1000 DEG C of flame baking.Flame resistant glass is now just progressively extensive
Applied to construction sites such as large public building cut-off, fire compartment, outdoor curtain walls, flame resistant glass with transparent for characteristic, it is maximum
Meet to limit Building Fire Protection and the harmony of the aesthetics of architecture.
By structure point, flame resistant glass includes two categories below：Single-sheet fire-resistant glass and composite fireproof glass.Single-sheet fire-resistant glass
The shortcomings that be that can only obstruct flame, it is but not heat-insulated, and antidetonation, shock resistance are poor.Composite fireproof glass includes using sandwich method
The A class doubling method compound heat-insulation types and A classes prepared with grouting method does not send out pouring type flame resistant glass black.Sandwich method is prepared compound anti-
Flint glass is although heat-insulated, antidetonation, shock resistance, but fire resistance is generally poor；And pouring type flame resistant glass prepared by grouting method, although
It has preferable fire integrity and preferable effect of heat insulation, but due to containing substantial amounts of moisture in its grouting so that fire prevention
The thickness of glass is big, and weight is big, and which has limited its installation cost and use range.Meanwhile due to being to customize during processing
Double glazing box in perfusion as formed gel layer after fire-resistant fluid, this causes the processed complex of filling type flame resistant glass, and
And the compound glass after sizing the shortcomings of can not arbitrarily cutting.
The content of the invention
In view of the shortcomings of the prior art, the present invention proposes a kind of fire prevention for the polymerization that is separated based on PN-MAM and inorganic matrix
Glass-film and its preparation method and application, the flame resistant glass film can be by after any cut, and doubling becomes between two blocks of glass
Compound flame resistant glass.Such a flame resistant glass is manufactured simple, and weight is small, area is big, variable properties, processing installation and transports
It is convenient.Concrete technical scheme is as follows：
A kind of preparation method for the flame resistant glass film polymerizeing that is separated based on PN-MAM and inorganic matrix, it is characterised in that
This method is specific as follows：By the N hydroxymethyl acrylamide N-MAM and N, N ' of 30~60 parts by weight-methylene diacrylamide MBAA
The saturated aqueous solution of mixture, 40~70 parts by weight and pH>9 inorganic matrix saturated aqueous solution is sufficiently mixed, then to mixed liquor
It is middle add 0.2~1.5 parts by weight mass fraction be 10% initiator, after stirring, by salivate shaping or mould into
Type, polymerization obtain PN-MAM and the flame resistant glass film of inorganic matrix phase separation polymerization；
Described inorganic matrix is made up of any one in waterglass and aluminium salt or two kinds by any proportioning.
Further, described inorganic matrix also includes sodium chloride, and the content of described sodium chloride is no more than inorganic matrix
The 15% of gross weight.
Further, described aluminium salt is aluminium chloride or aluminum sulfate or alum or water miscible meta-aluminate.
Further, described waterglass is sodium silicate or KP1.
Further, described initiator is hydrogen peroxide, potassium peroxydisulfate or ammonium persulfate.
The flame resistant glass film that a kind of preparation method by above-mentioned any one obtains.
A kind of flame resistant glass made of above-mentioned flame resistant glass film, it is by upper and lower layer glass and doubling upper and lower two
Flame resistant glass film composition between layer glass.
Compared with prior art, beneficial effects of the present invention are as follows：
After the flame resistant glass film polymerizeing that is separated based on PN-MAM and inorganic matrix of the present invention can arbitrarily be cut, doubling arrives
Between two blocks of glass, compound flame resistant glass is become, preparation technology is simple, and obtained flame resistant glass weight is small, area is big, property
Matter is variable, processing installation and transport are all very convenient.Under the high temperature sintering of fire, inorganic constituents is alkaline, is wrapped in compound
The moisture content vaporization buried so that macromolecule resin foaming turns into foamed resin.Meanwhile the inorganic substrate of doping is covered in foamed resin
Foam wall on, formed inorganic substrate covering flame-retardant layer.Meanwhile in the presence of high temperature of fire, inorganic substrate further by
Sintering and crosslinking condensation are the refractory material coating of inorganic porous property structure, and the coating is turned into inorganic fire skeleton,
Mechanical strength, fire resistance and the effect of heat insulation of fireprotection layer are improved, and mechanical integrity and heat-insulated resistance to can be played in a fire
The effect of fire.
Embodiment
The invention is not restricted to embodiment above, in the invention scope recorded in detail in the claims, can be planted
The change of kind, these changes are also contained in the scope of the present invention certainly, and this is self-evident.
Embodiment 1
The first step, by sodium metaaluminate deionized water dissolving, and with sodium hydrate regulator solution pH to 9.0, make meta-aluminic acid
It is completely dissolved sodium, by solution heating evaporation to nearly saturation, is cooled to room temperature, stands, and filtering, takes filtrate to satisfy as inorganic matrix
It is standby with solution A；
Second step, by the N hydroxymethyl acrylamide of 92 parts by weight and the N of 8 parts by weight, N '-methylene diacrylamide mixing
Thing saturated aqueous solution mixing, under agitation plus pure water to being just completely dissolved, filtered after standing saturated solution B is standby.
3rd step, hydrogen peroxide is made into pure water to 10% aqueous solution, it is standby to obtain initiator solution C.
4th step, the B solution of the solution A of 40 parts by weight and 60 parts by weight is sufficiently mixed, the C for adding 0.2 parts by weight is molten
Liquid, after stirring, by mould molding, aggregate into PN-MAM and the flame resistant glass film of inorganic matrix phase separation polymerization.
Embodiment 2
The first step, by the alum deionized water dissolving of 70 parts by weight, and with sodium hydrate regulator solution pH extremely
11.0, it is completely dissolved alum, then add the waterglass of 25 parts by weight, the sodium chloride of 5 parts by weight, heating stirring in solution
It is completely dissolved, by solution heating evaporation to saturation, is cooled to room temperature, is stood, filtering, takes filtrate as inorganic matrix saturation
Solution A is standby；
Second step, by the N hydroxymethyl acrylamide of 98 parts by weight and the N of 2 parts by weight, N '-methylene diacrylamide mixing
Thing saturated aqueous solution mixing, under agitation plus pure water to being just completely dissolved, filtered after standing saturated solution B is standby.
3rd step, potassium peroxydisulfate is made into the aqueous solution of mass fraction 10% with pure water, filter initiator solution C is standby
With.
4th step, the B solution of the solution A of 70 parts by weight and 30 parts by weight is sufficiently mixed, the C for adding 0.8 parts by weight is molten
Liquid, after stirring, it is molded by salivating, aggregates into PN-MAM and the flame resistant glass film of inorganic matrix phase separation polymerization.
Embodiment 3
The first step, by the aluminium chloride deionized water dissolving of 40 parts by weight, and with sodium hydrate regulator solution pH to 10.0,
Making aluminium chloride, it is completely dissolved, and adds waterglass, the sodium chloride of 15 parts by weight of 45 parts by weight in the solution, and heating stirring makes it
It is completely dissolved, by solution heating evaporation to saturation, is cooled to room temperature, stand, filtering, takes filtrate as inorganic matrix saturated solution
A is standby；
Second step, by the N hydroxymethyl acrylamide of 97 parts by weight and the N of 3 parts by weight, N '-methylene diacrylamide mixing
Thing saturated aqueous solution mixing, under agitation plus pure water to being just completely dissolved, filtered after standing saturated solution B is standby.
3rd step, ammonium persulfate is made into the aqueous solution of quality maple 10% with pure water, filter initiator solution C is standby
With.
4th step, the B solution of the solution A of 45 parts by weight and 55 parts by weight is sufficiently mixed, the C for adding 1.5 parts by weight is molten
Liquid, after stirring, by mould molding, aggregate into PN-MAM and the flame resistant glass film of inorganic matrix phase separation polymerization.
Embodiment 4
The first step, by the sodium metaaluminate deionized water dissolving of 20 parts by weight, and with sodium hydrate regulator solution pH extremely
10.5, making sodium metaaluminate, it is completely dissolved, and adds waterglass, the sodium chloride of 10 parts by weight of 70 parts by weight in the solution, heating
Stirring is completely dissolved it, by solution heating evaporation to saturation, is cooled to room temperature, stands, and filtering, takes filtrate as inorganic matrix
Saturated solution A is standby；
Second step, by the N hydroxymethyl acrylamide of 96 parts by weight and the N of 4 parts by weight, N '-methylene diacrylamide mixing
Thing saturated aqueous solution mixing, under agitation plus pure water to being just completely dissolved, filtered after standing saturated solution B is standby.
3rd step, potassium peroxydisulfate is made into the aqueous solution of mass fraction 10% with pure water, filter initiator solution C is standby
With.
4th step, the B solution of the solution A of 50 parts by weight and 50 parts by weight is sufficiently mixed, the C for adding 0.5 parts by weight is molten
Liquid, continue after stirring, be molded by salivating, aggregate into PN-MAM and the flame resistant glass film of inorganic matrix phase separation polymerization.
Embodiment 5
The first step, by waterglass deionized water dissolving, and with sodium hydrate regulator solution pH to 10.0, make waterglass its
It is completely dissolved, by solution heating evaporation to nearly saturation, is cooled to room temperature, stand, filtering, takes filtrate molten as inorganic substrate saturation
Liquid A is standby；
Second step, by the N hydroxymethyl acrylamide of 95 parts by weight and the N of 5 parts by weight, N '-methylene diacrylamide mixing
Thing saturated aqueous solution mixing, under agitation plus pure water to being just completely dissolved, filtered after standing saturated solution B is standby.
3rd step, hydrogen peroxide is made into the aqueous solution of mass fraction 10% with pure water, filter initiator solution C is standby
With.
4th step, the B solution of the solution A of 55 parts by weight and 45 parts by weight is sufficiently mixed, the C for adding 1.2 parts by weight is molten
Liquid, after stirring, by mould molding, aggregate into PN-MAM and the flame resistant glass film of inorganic matrix phase separation polymerization.
Embodiment 6
The first step, by the aluminum sulfate deionized water dissolving of 50 parts by weight, and with sodium hydrate regulator solution pH to 10.0,
Aluminum sulfate is completely dissolved, adds the waterglass of 50 parts by weight in the solution, heating stirring is completely dissolved it, and solution is heated
Saturation is evaporated to, is cooled to room temperature, is stood, filtering, takes filtrate standby as inorganic matrix saturated solution A；
Second step, by the N hydroxymethyl acrylamide of 94 parts by weight and the N of 6 parts by weight, N '-methylene diacrylamide mixing
Thing saturated aqueous solution mixing, under agitation plus pure water to being just completely dissolved, filtered after standing saturated solution B is standby.
3rd step, ammonium persulfate is made into the aqueous solution of mass fraction 10% with pure water, filter initiator solution C is standby
With.
4th step, the B solution of the solution A of 60 parts by weight and 40 parts by weight is sufficiently mixed, the C for adding 1.0 parts by weight is molten
Liquid, after stirring, it is molded by salivating, aggregates into PN-MAM and the flame resistant glass film of inorganic matrix phase separation polymerization.
The fire prevention film that thickness is 5mm is made in above-described embodiment 1-6, is respectively commonly floated with 5mm is thick inside and outside fire prevention film
Method glass, doubling is vacuumized under conditions of 80 DEG C experiment flame resistant glass is made.Prevent according to A classes in GB15763.1-2001
Flint glass standard is tested.1100 DEG C of the light transmittance and side towards the fire of obtained embodiment 1-6 flame resistant glass, unexposed surface temperature
≤ 140 DEG C of fire resistance period (min) is as shown in table 1.
1100 DEG C of the light transmittance and side towards the fire of the embodiment 1-6 of table 1 flame resistant glass, the fire resisting of unexposed surface temperature≤140 DEG C
Time (min) list
As can be seen from the table, added light transmittance and the fire resistance period of the flame resistant glass of flame resistant glass film preferable, simultaneously
Have small weight, simple production process concurrently, can cut, be readily transported the advantages that installation etc..
Embodiment described above, the simply present invention more preferably one kind in embodiment, the technology of this area
The usual variations and alternatives that personnel are carried out in the range of technical solution of the present invention should all include within the scope of the present invention.
Claims (7)
1. a kind of preparation method for the flame resistant glass film polymerizeing that is separated based on PN-MAM and inorganic matrix, it is characterised in that should
Method is specific as follows：By the N hydroxymethyl acrylamide (N-MAM) and N, N '-methylene diacrylamide of 30~60 parts by weight
(MBAA) saturated aqueous solution of mixture, 40~70 parts by weight and pH>9 inorganic matrix saturated aqueous solution is sufficiently mixed, then to
In mixed liquor add 0.2~1.5 parts by weight mass fraction be 10% initiator, after stirring, by salivate shaping or
Mould molding, polymerization obtain PN-MAM and the flame resistant glass film of inorganic matrix phase separation polymerization；
Described inorganic matrix is made up of any one in waterglass and aluminium salt or two kinds by any proportioning.
2. the flame resistant glass film of the polymerization according to claim 1 that is separated based on PN-MAM and inorganic matrix, described nothing
Machine matrix also includes sodium chloride, and the content of described sodium chloride is no more than the 15% of inorganic matrix gross weight.
3. the preparation side of the flame resistant glass film according to claim 1 that polymerize that is separated based on PN-MAM and inorganic matrix
Method, described aluminium salt are aluminium chloride or aluminum sulfate or alum or water miscible meta-aluminate.
4. the preparation side of the flame resistant glass film according to claim 1 that polymerize that is separated based on PN-MAM and inorganic matrix
Method, described waterglass are sodium silicate or KP1.
5. the preparation side of the flame resistant glass film according to claim 1 that polymerize that is separated based on PN-MAM and inorganic matrix
Method, described initiator are hydrogen peroxide, potassium peroxydisulfate or ammonium persulfate.
A kind of 6. flame resistant glass film that preparation method by above-mentioned any one claim obtains.
A kind of 7. flame resistant glass made of the flame resistant glass film of claim 6, it is characterised in that its by upper and lower layer glass with
And flame resistant glass film composition of the doubling between upper and lower layer glass.
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| CN201711172566.2A CN107857839A (en) | 2017-11-22 | 2017-11-22 | A kind of flame resistant glass film for the polymerization that is separated based on PN MAM and inorganic matrix and its preparation method and application |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711172566.2A CN107857839A (en) | 2017-11-22 | 2017-11-22 | A kind of flame resistant glass film for the polymerization that is separated based on PN MAM and inorganic matrix and its preparation method and application |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1110666A (en) * | 1995-03-09 | 1995-10-25 | 公安部天津消防科学研究所 | Fireproof glass |
| US20040003892A1 (en) * | 2002-07-08 | 2004-01-08 | Lehman Nicholas C. | One part woodworking adhesive composition |
| CN106147666A (en) * | 2016-06-27 | 2016-11-23 | 蚌埠市鑫民玻璃有限公司 | A kind of composite fireproof glass fire retardant glue and preparation method thereof |
| CN106147619A (en) * | 2016-06-27 | 2016-11-23 | 蚌埠市鑫民玻璃有限公司 | A kind of high printing opacity composite fireproof glass |
| CN106145699A (en) * | 2016-06-27 | 2016-11-23 | 蚌埠市鑫民玻璃有限公司 | The composite fireproof glass that a kind of heat-proof quality is good |
| CN107880290A (en) * | 2017-11-22 | 2018-04-06 | 浙江树人学院 | A kind of flame resistant glass film for the polymerization that is separated based on PAM inorganic matrixes and its preparation method and application |
-
2017
- 2017-11-22 CN CN201711172566.2A patent/CN107857839A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1110666A (en) * | 1995-03-09 | 1995-10-25 | 公安部天津消防科学研究所 | Fireproof glass |
| US20040003892A1 (en) * | 2002-07-08 | 2004-01-08 | Lehman Nicholas C. | One part woodworking adhesive composition |
| CN106147666A (en) * | 2016-06-27 | 2016-11-23 | 蚌埠市鑫民玻璃有限公司 | A kind of composite fireproof glass fire retardant glue and preparation method thereof |
| CN106147619A (en) * | 2016-06-27 | 2016-11-23 | 蚌埠市鑫民玻璃有限公司 | A kind of high printing opacity composite fireproof glass |
| CN106145699A (en) * | 2016-06-27 | 2016-11-23 | 蚌埠市鑫民玻璃有限公司 | The composite fireproof glass that a kind of heat-proof quality is good |
| CN107880290A (en) * | 2017-11-22 | 2018-04-06 | 浙江树人学院 | A kind of flame resistant glass film for the polymerization that is separated based on PAM inorganic matrixes and its preparation method and application |
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Application publication date: 20180330 |