CN107854999B - A kind of catalysis fibre material and preparation method for air cleaning - Google Patents
A kind of catalysis fibre material and preparation method for air cleaning Download PDFInfo
- Publication number
- CN107854999B CN107854999B CN201711178200.6A CN201711178200A CN107854999B CN 107854999 B CN107854999 B CN 107854999B CN 201711178200 A CN201711178200 A CN 201711178200A CN 107854999 B CN107854999 B CN 107854999B
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- Prior art keywords
- titanium dioxide
- cobalt oxide
- colloidal sol
- fibre
- catalysis
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- 239000000835 fiber Substances 0.000 title claims abstract description 90
- 238000006555 catalytic reaction Methods 0.000 title claims abstract description 44
- 239000000463 material Substances 0.000 title claims abstract description 44
- 238000004140 cleaning Methods 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 78
- IUJHOHSBALVOLS-UHFFFAOYSA-N [Co]=O.[O-2].[Ti+4].[O-2] Chemical compound [Co]=O.[O-2].[Ti+4].[O-2] IUJHOHSBALVOLS-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000002131 composite material Substances 0.000 claims abstract description 44
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 38
- 229920003043 Cellulose fiber Polymers 0.000 claims abstract description 27
- 239000011248 coating agent Substances 0.000 claims abstract description 25
- 238000000576 coating method Methods 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 20
- 150000001875 compounds Chemical class 0.000 claims abstract description 18
- 238000010521 absorption reaction Methods 0.000 claims abstract description 17
- 238000009987 spinning Methods 0.000 claims abstract description 17
- 238000007605 air drying Methods 0.000 claims abstract description 15
- PTHCMJGKKRQCBF-UHFFFAOYSA-N Cellulose, microcrystalline Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC)C(CO)O1 PTHCMJGKKRQCBF-UHFFFAOYSA-N 0.000 claims abstract description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 126
- 239000004408 titanium dioxide Substances 0.000 claims description 61
- 239000000243 solution Substances 0.000 claims description 49
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 33
- 239000003960 organic solvent Substances 0.000 claims description 29
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- 239000007864 aqueous solution Substances 0.000 claims description 25
- 239000000843 powder Substances 0.000 claims description 25
- SVMCDCBHSKARBQ-UHFFFAOYSA-N acetic acid;cobalt Chemical compound [Co].CC(O)=O SVMCDCBHSKARBQ-UHFFFAOYSA-N 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 19
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 16
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 12
- 239000003093 cationic surfactant Substances 0.000 claims description 12
- 238000000605 extraction Methods 0.000 claims description 12
- 239000012535 impurity Substances 0.000 claims description 12
- 239000012074 organic phase Substances 0.000 claims description 12
- 230000010355 oscillation Effects 0.000 claims description 12
- 239000002244 precipitate Substances 0.000 claims description 12
- 238000010992 reflux Methods 0.000 claims description 12
- 238000000926 separation method Methods 0.000 claims description 12
- 229910001415 sodium ion Inorganic materials 0.000 claims description 12
- 238000005406 washing Methods 0.000 claims description 12
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 11
- 238000009835 boiling Methods 0.000 claims description 11
- 229910017052 cobalt Inorganic materials 0.000 claims description 10
- 239000010941 cobalt Substances 0.000 claims description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 10
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 229910010416 TiO(OH)2 Inorganic materials 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 abstract description 14
- 238000006731 degradation reaction Methods 0.000 abstract description 14
- 238000004887 air purification Methods 0.000 abstract description 9
- 239000000126 substance Substances 0.000 abstract description 9
- 230000003197 catalytic effect Effects 0.000 abstract description 8
- 230000009931 harmful effect Effects 0.000 abstract description 5
- 239000011941 photocatalyst Substances 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 239000005416 organic matter Substances 0.000 abstract description 3
- 238000007654 immersion Methods 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 45
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 27
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 24
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 20
- 230000000694 effects Effects 0.000 description 18
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 16
- 238000004378 air conditioning Methods 0.000 description 10
- 238000005259 measurement Methods 0.000 description 10
- 210000002374 sebum Anatomy 0.000 description 10
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 8
- 230000008859 change Effects 0.000 description 8
- 239000000084 colloidal system Substances 0.000 description 8
- 150000002148 esters Chemical class 0.000 description 7
- 239000003292 glue Substances 0.000 description 7
- 238000007747 plating Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 229940053662 nickel sulfate Drugs 0.000 description 5
- 229910052761 rare earth metal Inorganic materials 0.000 description 5
- 150000002910 rare earth metals Chemical class 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(II,III) oxide Inorganic materials [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 4
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 4
- 239000002957 persistent organic pollutant Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000002000 scavenging effect Effects 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910052691 Erbium Inorganic materials 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- 241000080590 Niso Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- 229910052769 Ytterbium Inorganic materials 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- -1 anhydride nickel sulfate Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 2
- 229940074391 gallic acid Drugs 0.000 description 2
- 235000004515 gallic acid Nutrition 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- CHPZKNULDCNCBW-UHFFFAOYSA-N gallium nitrate Chemical compound [Ga+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CHPZKNULDCNCBW-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910001453 nickel ion Inorganic materials 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 229960002415 trichloroethylene Drugs 0.000 description 2
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 2
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- NLZQVLUEFDOPMA-UHFFFAOYSA-N [Cl].[Ni] Chemical compound [Cl].[Ni] NLZQVLUEFDOPMA-UHFFFAOYSA-N 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 229940044658 gallium nitrate Drugs 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000004298 light response Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- RRIWRJBSCGCBID-UHFFFAOYSA-L nickel sulfate hexahydrate Chemical compound O.O.O.O.O.O.[Ni+2].[O-]S([O-])(=O)=O RRIWRJBSCGCBID-UHFFFAOYSA-L 0.000 description 1
- 229940116202 nickel sulfate hexahydrate Drugs 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B01J35/33—
-
- B01J35/58—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
- B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/02—Chemical after-treatment of artificial filaments or the like during manufacture of cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
Abstract
The present invention relates to material for air purification fields, and in particular to catalysis fibre material and preparation method for air cleaning.A kind of catalysis fibre material for air cleaning of the invention is prepared by the following method: (1) preparing titanium dioxide-cobalt oxide colloidal sol；(2) by titanium dioxide-cobalt oxide colloidal sol and the compound first break draft of cellulose gel, spinning obtains composite fibre；(3) composite fibre carries out air drying；(4) composite fibre immersion nickel source is electroplated, is formed using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode.Using the catalysis fibre material for air cleaning of the invention, anode and cathode form micro cell system, generate micro-current, by the absorption of cellulose fibre by organic matter fast degradation.The catalytic degradation material carries out catalytic degradation to harmful organic substance under no light condition, and reaction rate is faster with respect to photocatalyst.
Description
Technical field
The present invention relates to material for air purification fields, and in particular to for the catalysis fibre material of air cleaning and preparation side
Method.
Background technique
Air pollution source mainly has formaldehyde, benzene, ether-ether class, the volatile organic matters such as trichloro ethylene, acrylonitrile；Existing air
Purification medium material mainly has: efficient material of photochemical catalyst, active carbon, synthetic fibers, HEAP etc..Conventional purification style at present
For activated carbon adsorption, but since adsorbance is limited, it is difficult to eradicating pests.Degradation is to solve the preferable skill of air organic pollution
Art means.And it is existing main using catalytic degradation, due to by catalysis material and environmental restrictions, current catalytic degradation material efficiency
It is not high.Often take TiO2 as photocatalyst in the market, the generation of this kind of material catalytic degradation effect needs 12 hours or more, and
It need to just can guarantee that degradation is normally carried out under the conditions of ultraviolet light.Therefore, developing efficient catalytic degradation material is to realize that air is net
The critical bottleneck of change.
A kind of microporous medium catalysis oxidation, which is disclosed, application No. is the patent application of CN201610699772.8 prepares air
The method and material for air purification of scavenging material.Using microporous medium matrix, oxidant, catalyst and pH color developing agent as raw material, warp
S1. centrifugal dipping load, the load of S2. steam pressure, S3. be dry and the processing of S4. surface staining and etc. prepare material for air purification.
Preparation method supported catalyst oxidant on microporous medium wall surface and micro channel in a manner of centrifugal dipping, loading speed is fast,
Loading level is deep；It is loaded by steam pressure, under saturation vapour pressure and interior energy, loading level can be aggravated, while steam pressure load can
Optimize microporous medium structure, through hole improves, and is conducive to the promotion of its purifying property；After surface staining processing, what when purification generated
Acidic materials can make scavenging material surface discolouration, to obtain the experience sense of detergent power and effect；Air provided by the invention is net
Changing material has many advantages, such as that purification is thorough, quick, lasting.Its preparation process is complicated and cannot reuse, higher operating costs.
Application No. is 201710038229.8 patent applications to disclose the preparation method and sky of a kind of material for air purification
Gas scavenging material, embodiment mixing zinc acetate and gallium nitrate obtain compounding substances, and addition solvent is formed molten in compounding substances
Be gelled gluey presoma, and collosol and gel shape presoma is sintered, porous prilled gallic acid zinc precursor is formed, by porous
Granular gallic acid zinc precursor carries out nitrogen treatment, forms nitride porous gallium zinc oxide solid solution.Thus it solves traditional light to urge
The utilization efficiency of agent solar energy is not high, and smaller with the contact surface area of organic pollutant, the light degradation effect of organic pollutant
The problem of fruit difference, the nitride porous gallium zinc oxide solid solution synthesized by the method for collosol and gel, may be implemented to visible light
Response, improves the utilization efficiency of solar energy, while porous structure increases the contact surface area with organic pollutant, improves light
The utilization efficiency of catalyst increases the light degradation effect of organic pollutant.However its preparation process is complicated, it is organic by increasing
The contact surface area of pollutant and catalyst, although efficiency is promoted, but still not high.
Disclosing a kind of material for air purification application No. is 201210458120.7 patent application includes following composition portion
Point, 100-200 parts of active carbon, 20-50 parts of nano zircite, 30-50 parts of titanium dioxide, 10-15 parts of epoxy resin, high rare earth
20-50 parts.The content of the nano zircite is 25-30 parts.The partial size of the nano zircite is 20-50 nanometers.The present invention
Material for air purification be it is a kind of there are the multiple functions such as the moisture absorption, deodorization, sterilizing, especially by addition nano material,
There is the nano composite material for air cleaning of permanent photocatalytic sterilization effect under the action of natural light, is various places sky
The new material of gas purification and sterilization disinfection.It has the function of that absorption, photocatalysis poisonous and harmful substance are decomposed and sterilized, however its
Light-catalysed efficiency is still very low, can not meet demand.
Application No. is 201610263737.1 patent applications to disclose one kind except formaldehyde air cleaning new material, including
Basis material, surfactant, macromolecule organic amine class compound and rare-earth metal catalyst；Described matrix material is cation
Exchange fiber, the surfactant are fatty alcohol polyoxyethylene ether, and the macromolecule organic amine class compound is triethylene four
Amine, the rare-earth metal catalyst are the mixture of metal erbium and metallic ytterbium；The weight of each ingredient in the air cleaning new material
The ratio between part are as follows: 80~120 parts of basis material, 4~6 parts of surfactant, 20~30 parts of macromolecule organic amine class compound, rare earth
2~4 parts of metallic catalyst, wherein the weight ratio of metal erbium and metallic ytterbium is 1~3:1 in rare-earth metal catalyst.This hair
The air cleaning new material with function of removing formaldehyde of bright offer has excellent formaldehyde removing effect, and clearance rate is high, and right
The adsorption capacity of formaldehyde is big.Its absorption and removal only for formaldehyde.
Summary of the invention
For disadvantages described above, the first purpose of the invention is to provide a kind of catalysis fibre material for air cleaning,
The cellulosic material can adsorb formaldehyde, benzene, ether-ether class in air, the volatile harmfuls organic matter such as trichloro ethylene, acrylonitrile, and
Quickly catalytic organism is degraded, the reaction rate of catalysis harmful organic substance degradation is faster with respect to photocatalyst.
In order to solve the above technical problems, a kind of catalysis fibre material for air cleaning of the invention is made by the following method
It is standby to obtain: (1) to prepare titanium dioxide-cobalt oxide colloidal sol；(2) by titanium dioxide-cobalt oxide colloidal sol and cellulose gel it is compound after
Drawing-off, spinning obtain composite fibre；(3) composite fibre carries out air drying；(4) composite fibre immersion nickel source is electroplated,
It is formed using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode.
The preparation of the titanium dioxide-cobalt oxide colloidal sol can be molten using nano-titanium dioxide and nanometer cobalt oxide is mixed
Solution, then be prepared using conventional colloidal sol preparation method, the nano-titanium dioxide and nanometer cobalt oxide can use commercially available
Nano-titanium dioxide and nanometer cobalt oxide, can also synthesize, wherein sulfuric acid process, hydrochloric acid method, chlorine can be used in nano-titanium dioxide
The methods of change method and liquid phase method etc. are prepared.
Cobalt oxide (Co203) it is a kind of important transition metal oxide, it is the high oxide of cobalt, theoretical amount containing cobalt is
71.06%, oxygen content 28.94%, density 6.079g/cm3.It is a kind of black amorphous powder, and when heating can generate four
Co 3 O (Co304).Cobalt oxide is a kind of unstable, it is also not possible in the compound of free state.Usually signified cobalt oxide
Actually still contain a certain number of cobaltosic oxides.Co203Just stablize when being only in hydrated state, and this hyrate is 265
It can be dehydrated at DEG C and be transformed into intermidate oxide cobaltosic oxide (Co304)。
Titanium dioxide (TiO2) it is white solid or powdered amphoteric oxide, it is decomposed and is extracted with acid by rutile, or
It decomposes to obtain by titanium tetrachloride, generally divides Detitanium-ore-type (abbreviation A type) and rutile-type (abbreviation R type), can be employed as the present invention
Raw material.Titanium dioxide property is stablized, surface super hydrophilic.
The drawing-off is conventional drafting method, in spinning that fiber assembly (such as strip, rove) is regular
Ground leads length and attenuates, and is the process that combing is further loosened and gathered later.Bulk fiber Raw material processing at fibrous layer or strip, then
As rove, spun yarn, it is necessary to by the process that gradually attenuates, so the almost main machine or work of every kind of spinning in the prior art
Sequence has drawing-off effect.
It is uniformly mixed in order to be prepared, granular superfine, stable titanium dioxide-cobalt oxide colloidal sol, by a large amount of real
The following preferred technical solution of existing use, obtained titanium dioxide-cobalt oxide Stability of Sols are issued after examination and approval, and is uniformly mixed, particle
Ultra-fine: titanium dioxide-cobalt oxide colloidal sol method is prepared described in step (1) includes:
A. by TiO(OH)2After white precipitate washing removes the impurity such as sulfate radical, the sodium ion of solvable fluidity, addition 2~
4mol/L hydrochloric acid solution obtains transparent colourless titanium dioxide aqueous solution in the above-mentioned 40~60min of solution of 60 DEG C or more water-baths；
The titanium dioxide aqueous solution is taken, cationic surfactant, which is added, makes colloidal sol be converted to hydrophobicity condensate；It adds
Organic solvent, acutely oscillation is rinsed, and is transferred to colloidal particle in organic phase, up to transparent organosol after being separated from water；It will extraction
Organosol after taking separation, lower than organic solvent boiling point at a temperature of, after reflux removes absorption water, then be evaporated under reduced pressure removing
Organic solvent is heat-treated to get colourless titanium dioxide ultra-micro powder at 200~220 DEG C；
B. surfactant is added in acetic acid cobalt liquor and is uniformly mixed, add sodium hydroxide solution, it is small to stand 1~2
When, obtain cobalt oxide colloidal sol；
C. the titanium dioxide ultra-micro powder that a step is prepared is dissolved in the cobalt oxide colloidal sol that b step is prepared,
Up to titanium dioxide-cobalt oxide colloidal sol.
Titanium dioxide in titanium dioxide as described in step (1)-cobalt oxide colloidal sol as a preferred technical solution: oxidation
The mass ratio of cobalt is 8~15:4~10.
The mass ratio of step (2) cellulose and titanium dioxide is 50~100:2~5 as a preferred technical solution,.
Step (4) nickel source is NiSO as a preferred technical solution,4Or NiCl2.Nickel sulfate have anhydride nickel sulfate,
Nickel sulfate hexahydrate NiSO4·6H2O) He Qishui nickel sulfate NiSO4·7H2O) three kinds.Commercially available nickel sulfate is mostly six water objects, there is α-
Two kinds of variants of type and β-type, the former is the crystallization of blue four directions, and the latter is green monoclinic crystal, is used equally for nickel source of the invention.
The hydrate heating of nickel sulfate loses the crystallization water.It is soluble easily in water, it is slightly soluble in ethyl alcohol, methanol, aqueous solution is slightly soluble in acidity
Acid, ammonium hydroxide are toxic.It is mainly used for electroplating industry, is the main nickel salt of electronickelling and chemical nickel and coming for metallic nickel ions
Source can dissociate nickel ion and sulfate ion in the plating process.Anhydrous Nickel Chloride is yellow, but it is in nature very
It is rare, only it can be found that and more familiar to people is six green hydration dichlorides in the ore as water chlorine nickel stone
Nickel (NiCl2·6H2O).Nickel Chloride is green there are also a series of known hydrates, may be used as nickel of the invention
Source, generally, Nickel Chloride are that most important important nickel source, raw material are easy to get in chemical industry synthesis.
A second object of the present invention is to provide a kind of above-mentioned preparation method of the catalysis fibre material for air cleaning,
To solve second technical problem of the invention, a kind of preparation method of catalysis fibre material for air cleaning of the invention
Include the following steps: that (1) prepares titanium dioxide-cobalt oxide colloidal sol；(2) by titanium dioxide-cobalt oxide colloidal sol and cellulose gel
Compound first break draft, spinning obtain composite fibre；(3) composite fibre carries out air drying；(4) by composite fibre immerse nickel source into
Row plating, forms using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode.
Preparing titanium dioxide-cobalt oxide colloidal sol method described in step (1) as a preferred technical solution, includes:
A. by TiO(OH)2After white precipitate washing removes the impurity such as sulfate radical, the sodium ion of solvable fluidity, addition 2~
4mol/L hydrochloric acid solution obtains transparent colourless titanium dioxide aqueous solution in the above-mentioned 40~60min of solution of 60 DEG C or more water-baths；
The titanium dioxide aqueous solution is taken, cationic surfactant, which is added, makes colloidal sol be converted to hydrophobicity condensate；It adds
Organic solvent, acutely oscillation is rinsed, and is transferred to colloidal particle in organic phase, up to transparent organosol after being separated from water；It will extraction
Organosol after taking separation, lower than organic solvent boiling point at a temperature of, after reflux removes absorption water, then be evaporated under reduced pressure removing
Organic solvent is heat-treated to get colourless titanium dioxide ultra-micro powder at 200~220 DEG C；
B. surfactant is added in acetic acid cobalt liquor and is uniformly mixed, add sodium hydroxide solution, it is small to stand 1~2
When, obtain cobalt oxide colloidal sol；
C. the titanium dioxide ultra-micro powder that a step is prepared is dissolved in the cobalt oxide colloidal sol that b step is prepared,
Up to titanium dioxide-cobalt oxide colloidal sol.
Titanium dioxide in titanium dioxide as described in step (1)-cobalt oxide colloidal sol as a preferred technical solution: oxidation
The mass ratio of cobalt is 8~15:4~10.
The mass ratio of step (2) cellulose and titanium dioxide is 50~100:2~5 as a preferred technical solution,.
Step (4) nickel source is NiSO as a preferred technical solution,4Or NiCl2。
Using technical solution of the present invention, first prepare titanium dioxide-cobalt oxide colloidal sol, with cellulose gel it is compound after lead
It stretches, spinning obtains composite fibre；Composite fibre carries out air drying；Then composite fibre is immersed into nickel source (such as NiSO4Or
NiCl2) be electroplated, it is formed using cellulose fibre as skeleton, titanium dioxide-cobalt oxide is anode, nickel coating is urging for cathode
Chemical fibre dimension.Compared with prior art, significant advantage is that anode and cathode form micro cell system, generates micro-current, passes through fiber
The absorption of cellulose fiber is by organic matter fast degradation.The catalytic degradation material carries out catalysis drop to harmful organic substance under no light condition
Solution, and reaction rate is faster with respect to photocatalyst.
The titanium dioxide that the present invention is prepared-cobalt oxide colloidal sol transparency is good, and stability is high, good product dispersibility, thoroughly
The high organic solvent of lightness is recyclable to be recycled, no coupling product, and product purity is high.
Specific embodiment
In the following, the present invention will be further described in detail by way of specific embodiments, but this should not be interpreted as to the present invention
Range be only limitted to example below.Without departing from the idea of the above method of the present invention, according to ordinary skill
The various replacements or change that knowledge and customary means are made, should be included in the scope of the present invention.
Embodiment 1
(1) prepare titanium dioxide-cobalt oxide colloidal sol: a. is by 650gTiO(OH)2White precipitate washing removes solvable fluidity
After the impurity such as sulfate radical, sodium ion, the hydrochloric acid of 2mol/L is added, in the above-mentioned solution 40min of 60 DEG C or more water-baths, obtains transparent
Colourless titanium dioxide aqueous solution；The titanium dioxide aqueous solution being prepared is taken, two fourth of cationic surfactant sebacic acid is added
Ester 20g makes colloidal sol be converted to hydrophobicity condensate；Toluene organic solvent 1L is added, acutely oscillation is rinsed, and makes colloid grains
Son is transferred in organic phase, up to transparent organosol after being separated from water；By the organosol after extraction and separation, lower than organic molten
80 DEG C at a temperature of agent boiling point, after reflux removes absorption water, then it is evaporated under reduced pressure removing organic solvent, is heat-treated at 200 DEG C,
Up to colourless titanium dioxide ultra-micro powder；B. acetic acid cobalt content is added in surfactant sebum dibutyl phthalate 15g is 620g's
It is uniformly mixed in acetic acid cobalt liquor, adds the sodium hydroxide solution for the 1mol/L that 300ml concentration is, stood 1 hour, obtain oxygen
Change cobalt colloidal sol；C. it is molten that the titanium dioxide ultra-micro powder 450g for taking a step to be prepared is dissolved in the cobalt oxide that b step is prepared
To get titanium dioxide-cobalt oxide colloidal sol in glue.(2) by titanium dioxide-cobalt oxide colloidal sol and 5Kg cellulose gel it is compound after lead
It stretches, spinning obtains composite fibre.(3) composite fibre carries out air drying.(4) composite fibre is immersed into NiCl2Solution carries out electricity
Plating is formed using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode.
PM10 particle, content of formaldehyde in the air inside and outside newly-decorated office are measured, see Table 1 for details for measurement result.It will system
It is standby obtain using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode is packed into new
The air-conditioning air inlet in the house of finishing, its clean-up effect is measured after 2 hours, and see Table 1 for details.
Embodiment 2
(1) prepare titanium dioxide-cobalt oxide colloidal sol: a. is by 650gTiO(OH)2White precipitate washing removes solvable fluidity
After the impurity such as sulfate radical, sodium ion, the hydrochloric acid of 2.5mol/L is added, in the above-mentioned solution 45min of 60 DEG C or more water-baths, obtains transparent
Colourless titanium dioxide aqueous solution；The titanium dioxide aqueous solution being prepared is taken, cationic surfactant sebacic acid two is added
Butyl ester 20g makes colloidal sol be converted to hydrophobicity condensate；Toluene organic solvent 1L is added, acutely oscillation is rinsed, and makes colloid
Particle is transferred in organic phase, up to transparent organosol after being separated from water；By the organosol after extraction and separation, lower than organic
80 DEG C at a temperature of solvent boiling point, after reflux removes absorption water, then it is evaporated under reduced pressure removing organic solvent, carries out hot place at 210 DEG C
Reason is to get colourless titanium dioxide ultra-micro powder；B. it is by surfactant sebum dibutyl phthalate 15g addition acetic acid cobalt content
It is uniformly mixed in the acetic acid cobalt liquor of 620g, adds the sodium hydroxide solution for the 1mol/L that 300ml concentration is, it is small to stand 1.5
When, obtain cobalt oxide colloidal sol；C. the titanium dioxide ultra-micro powder 450g for taking a step to be prepared is dissolved in b step and is prepared
Cobalt oxide colloidal sol in get titanium dioxide-cobalt oxide colloidal sol.(2) by titanium dioxide-cobalt oxide colloidal sol and 5Kg cellulose gel
The compound first break draft of glue, spinning obtain composite fibre.(3) composite fibre carries out air drying.(4) composite fibre is immersed into NiSO4
Solution is electroplated, and is formed using cellulose fibre as skeleton, the catalysis that titanium dioxide-cobalt oxide is anode, nickel coating is cathode
Fiber.
PM10 particle, content of formaldehyde in the air inside and outside newly-decorated office are measured, see Table 1 for details for measurement result.It will system
It is standby obtain using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode is packed into new
The air-conditioning air inlet in the house of finishing, its clean-up effect is measured after 2 hours, and see Table 1 for details.
Embodiment 3
(1) prepare titanium dioxide-cobalt oxide colloidal sol: a. is by 650gTiO(OH)2White precipitate washing removes solvable fluidity
After the impurity such as sulfate radical, sodium ion, the hydrochloric acid of 2mol/L is added, in the above-mentioned solution 50min of 60 DEG C or more water-baths, obtains transparent
Colourless titanium dioxide aqueous solution；The titanium dioxide aqueous solution being prepared is taken, two fourth of cationic surfactant sebacic acid is added
Ester 20g makes colloidal sol be converted to hydrophobicity condensate；Toluene organic solvent 1L is added, acutely oscillation is rinsed, and makes colloid grains
Son is transferred in organic phase, up to transparent organosol after being separated from water；By the organosol after extraction and separation, lower than organic molten
80 DEG C at a temperature of agent boiling point, after reflux removes absorption water, then it is evaporated under reduced pressure removing organic solvent, is heat-treated at 220 DEG C,
Up to colourless titanium dioxide ultra-micro powder；B. acetic acid cobalt content is added in surfactant sebum dibutyl phthalate 15g is 620g's
It is uniformly mixed in acetic acid cobalt liquor, adds the sodium hydroxide solution for the 1mol/L that 300ml concentration is, stood 2 hours, obtain oxygen
Change cobalt colloidal sol；C. it is molten that the titanium dioxide ultra-micro powder 450g for taking a step to be prepared is dissolved in the cobalt oxide that b step is prepared
To get titanium dioxide-cobalt oxide colloidal sol in glue.(2) by titanium dioxide-cobalt oxide colloidal sol and 5Kg cellulose gel it is compound after lead
It stretches, spinning obtains composite fibre.(3) composite fibre carries out air drying.(4) composite fibre is immersed into NiCl2Solution carries out electricity
Plating is formed using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode.
PM10 particle, content of formaldehyde in the air inside and outside newly-decorated office are measured, see Table 1 for details for measurement result.It will system
It is standby obtain using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode is packed into new
The air-conditioning air inlet in the house of finishing, its clean-up effect is measured after 2 hours, and see Table 1 for details.
Embodiment 4
(1) prepare titanium dioxide-cobalt oxide colloidal sol: a. is by 750gTiO(OH)2White precipitate washing removes solvable fluidity
After the impurity such as sulfate radical, sodium ion, the hydrochloric acid of 3mol/L is added, in the above-mentioned solution 45min of 60 DEG C or more water-baths, obtains transparent
Colourless titanium dioxide aqueous solution；The titanium dioxide aqueous solution being prepared is taken, two fourth of cationic surfactant sebacic acid is added
Ester 20g makes colloidal sol be converted to hydrophobicity condensate；Toluene organic solvent 1.5L is added, acutely oscillation is rinsed, and makes colloid
Particle is transferred in organic phase, up to transparent organosol after being separated from water；By the organosol after extraction and separation, lower than organic
80 DEG C at a temperature of solvent boiling point, after reflux removes absorption water, then it is evaporated under reduced pressure removing organic solvent, carries out hot place at 220 DEG C
Reason is to get colourless titanium dioxide ultra-micro powder；B. it is by surfactant sebum dibutyl phthalate 15g addition acetic acid cobalt content
It is uniformly mixed in the acetic acid cobalt liquor of 620g, adds the sodium hydroxide solution for the 1mol/L that 300ml concentration is, it is small to stand 1.5
When, obtain cobalt oxide colloidal sol；C. the titanium dioxide ultra-micro powder 600g for taking a step to be prepared is dissolved in b step and is prepared
Cobalt oxide colloidal sol in get titanium dioxide-cobalt oxide colloidal sol.(2) by titanium dioxide-cobalt oxide colloidal sol and 5Kg cellulose gel
The compound first break draft of glue, spinning obtain composite fibre.(3) composite fibre carries out air drying.(4) composite fibre is immersed into NiSO4
Solution is electroplated, and is formed using cellulose fibre as skeleton, the catalysis that titanium dioxide-cobalt oxide is anode, nickel coating is cathode
Fiber.
PM10 particle, content of formaldehyde in the air inside and outside newly-decorated office are measured, see Table 1 for details for measurement result.It will system
It is standby obtain using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode is packed into new
The air-conditioning air inlet in the house of finishing, its clean-up effect is measured after 2 hours, and see Table 1 for details.
Embodiment 5
(1) prepare titanium dioxide-cobalt oxide colloidal sol: a. is by 650gTiO(OH)2White precipitate washing removes solvable fluidity
After the impurity such as sulfate radical, sodium ion, the hydrochloric acid of 2mol/L is added, in the above-mentioned solution 60min of 60 DEG C or more water-baths, obtains transparent
Colourless titanium dioxide aqueous solution；The titanium dioxide aqueous solution being prepared is taken, two fourth of cationic surfactant sebacic acid is added
Ester 20g makes colloidal sol be converted to hydrophobicity condensate；Toluene organic solvent 1L is added, acutely oscillation is rinsed, and makes colloid grains
Son is transferred in organic phase, up to transparent organosol after being separated from water；By the organosol after extraction and separation, lower than organic molten
80 DEG C at a temperature of agent boiling point, after reflux removes absorption water, then it is evaporated under reduced pressure removing organic solvent, is heat-treated at 200 DEG C,
Up to colourless titanium dioxide ultra-micro powder；B. acetic acid cobalt content is added in surfactant sebum dibutyl phthalate 15g is 620g's
It is uniformly mixed in acetic acid cobalt liquor, adds the sodium hydroxide solution for the 1mol/L that 300ml concentration is, stood 1 hour, obtain oxygen
Change cobalt colloidal sol；C. it is molten that the titanium dioxide ultra-micro powder 450g for taking a step to be prepared is dissolved in the cobalt oxide that b step is prepared
To get titanium dioxide-cobalt oxide colloidal sol in glue.(2) by titanium dioxide-cobalt oxide colloidal sol and 5Kg cellulose gel it is compound after lead
It stretches, spinning obtains composite fibre.(3) composite fibre carries out air drying.(4) composite fibre is immersed into NiCl2Solution carries out electricity
Plating is formed using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode.
PM10 particle, content of formaldehyde in the air inside and outside newly-decorated office are measured, see Table 1 for details for measurement result.It will system
It is standby obtain using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode is packed into new
The air-conditioning air inlet in the house of finishing, its clean-up effect is measured after 2 hours, and see Table 1 for details.
Embodiment 6
(1) prepare titanium dioxide-cobalt oxide colloidal sol: a. is by 940gTiO(OH)2White precipitate washing removes solvable fluidity
After the impurity such as sulfate radical, sodium ion, the hydrochloric acid of 2mol/L is added, in the above-mentioned solution 40min of 60 DEG C or more water-baths, obtains transparent
Colourless titanium dioxide aqueous solution；The titanium dioxide aqueous solution being prepared is taken, two fourth of cationic surfactant sebacic acid is added
Ester 20g makes colloidal sol be converted to hydrophobicity condensate；Toluene organic solvent 1.5L is added, acutely oscillation is rinsed, and makes colloid
Particle is transferred in organic phase, up to transparent organosol after being separated from water；By the organosol after extraction and separation, lower than organic
80 DEG C at a temperature of solvent boiling point, after reflux removes absorption water, then it is evaporated under reduced pressure removing organic solvent, carries out hot place at 210 DEG C
Reason is to get colourless titanium dioxide ultra-micro powder；B. it is by surfactant sebum dibutyl phthalate 15g addition acetic acid cobalt content
It is uniformly mixed in the acetic acid cobalt liquor of 620g, adds the sodium hydroxide solution for the 1mol/L that 300ml concentration is, stand 2 hours,
Obtain cobalt oxide colloidal sol；C. the titanium dioxide ultra-micro powder 750g for taking a step to be prepared is dissolved in the oxygen that b step is prepared
Change in cobalt colloidal sol to get titanium dioxide-cobalt oxide colloidal sol.(2) titanium dioxide-cobalt oxide colloidal sol is answered with 5Kg cellulose gel
First break draft is closed, spinning obtains composite fibre.(3) composite fibre carries out air drying.(4) composite fibre is immersed into NiSO4Solution
It is electroplated, is formed using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode.
PM10 particle, content of formaldehyde in the air inside and outside newly-decorated office are measured, see Table 1 for details for measurement result.It will system
It is standby obtain using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode is packed into new
The air-conditioning air inlet in the house of finishing, its clean-up effect is measured after 2 hours, and see Table 1 for details.
Comparative example 1
(1) prepare titanium dioxide-cobalt oxide colloidal sol: a. is by 100gTiO(OH)2White precipitate washing removes solvable fluidity
After the impurity such as sulfate radical, sodium ion, the hydrochloric acid of 2mol/L is added, in the above-mentioned solution 40min of 60 DEG C or more water-baths, obtains transparent
Colourless titanium dioxide aqueous solution；The titanium dioxide aqueous solution being prepared is taken, two fourth of cationic surfactant sebacic acid is added
Ester 20g makes colloidal sol be converted to hydrophobicity condensate；Toluene organic solvent 1L is added, acutely oscillation is rinsed, and makes colloid grains
Son is transferred in organic phase, up to transparent organosol after being separated from water；By the organosol after extraction and separation, lower than organic molten
80 DEG C at a temperature of agent boiling point, after reflux removes absorption water, then it is evaporated under reduced pressure removing organic solvent, is heat-treated at 210 DEG C,
Up to colourless titanium dioxide ultra-micro powder；B. acetic acid cobalt content is added in surfactant sebum dibutyl phthalate 15g is 620g's
It is uniformly mixed in acetic acid cobalt liquor, adds the sodium hydroxide solution for the 1mol/L that 300ml concentration is, stood 2 hours, obtain oxygen
Change cobalt colloidal sol；C. it is molten that the titanium dioxide ultra-micro powder 50g for taking a step to be prepared is dissolved in the cobalt oxide that b step is prepared
To get titanium dioxide-cobalt oxide colloidal sol in glue.(2) by titanium dioxide-cobalt oxide colloidal sol and 5Kg cellulose gel it is compound after lead
It stretches, spinning obtains composite fibre.(3) composite fibre carries out air drying.(4) composite fibre is immersed into NiSO4Solution carries out electricity
Plating is formed using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode.
PM10 particle, content of formaldehyde in the air inside and outside newly-decorated office are measured, see Table 1 for details for measurement result.It will system
It is standby obtain using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode is packed into new
The air-conditioning air inlet in the house of finishing, its clean-up effect is measured after 2 hours, and see Table 1 for details.
Comparative example 2
(1) prepare titanium dioxide-cobalt oxide colloidal sol: a. is by 940gTiO(OH)2White precipitate washing removes solvable fluidity
After the impurity such as sulfate radical, sodium ion, the hydrochloric acid of 2mol/L is added, in the above-mentioned solution 40min of 60 DEG C or more water-baths, obtains transparent
Colourless titanium dioxide aqueous solution；The titanium dioxide aqueous solution being prepared is taken, two fourth of cationic surfactant sebacic acid is added
Ester 20g makes colloidal sol be converted to hydrophobicity condensate；Toluene organic solvent 1.5L is added, acutely oscillation is rinsed, and makes colloid
Particle is transferred in organic phase, up to transparent organosol after being separated from water；By the organosol after extraction and separation, lower than organic
80 DEG C at a temperature of solvent boiling point, after reflux removes absorption water, then it is evaporated under reduced pressure removing organic solvent, carries out hot place at 210 DEG C
Reason is to get colourless titanium dioxide ultra-micro powder；B. acetic acid cobalt content is added in surfactant sebum dibutyl phthalate 15g is 40g
Acetic acid cobalt liquor in be uniformly mixed, add the sodium hydroxide solution for the 1mol/L that 300ml concentration is, stand 2 hours, obtain
Cobalt oxide colloidal sol；C. the titanium dioxide ultra-micro powder 750g for taking a step to be prepared is dissolved in the cobalt oxide that b step is prepared
To get titanium dioxide-cobalt oxide colloidal sol in colloidal sol.(2) by titanium dioxide-cobalt oxide colloidal sol and 5Kg cellulose gel it is compound after
Drawing-off, spinning obtain composite fibre.(3) composite fibre carries out air drying.(4) composite fibre is immersed into NiSO4Solution carries out
Plating is formed using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode.
PM10 particle, content of formaldehyde in the air inside and outside newly-decorated office are measured, see Table 1 for details for measurement result.It will system
It is standby obtain using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide-cobalt oxide is anode, nickel coating is cathode is packed into new
The air-conditioning air inlet in the house of finishing, its clean-up effect is measured after 2 hours, and see Table 1 for details.
Comparative example 3
(1) it prepares cobalt oxide colloidal sol: surfactant being added in the acetic acid cobalt liquor that acetic acid cobalt content is 620g and is mixed
Uniformly, sodium hydroxide solution is added, 2 hours is stood, obtains cobalt oxide colloidal sol.(2) by cobalt oxide colloidal sol and 5Kg cellulose gel
The compound first break draft of glue, spinning obtain composite fibre.(3) composite fibre carries out air drying.(4) composite fibre is immersed into NiSO4
Solution is electroplated, and is formed using cellulose fibre as skeleton, the catalysis fibre that cobalt oxide is anode, nickel coating is cathode.
PM10 particle, content of formaldehyde in the air inside and outside newly-decorated office are measured, see Table 1 for details for measurement result.It will system
It is standby obtain using cellulose fibre as skeleton, the catalysis fibre that cobalt oxide is anode, nickel coating is cathode is packed into newly-decorated room
The air-conditioning air inlet of son, its clean-up effect is measured after 2 hours, and see Table 1 for details.
Comparative example 4
(1) prepare TiO 2 sol: a. is by 940gTiO(OH)2The sulfate radical of the solvable fluidity of white precipitate washing removing,
After the impurity such as sodium ion, the hydrochloric acid of 2mol/L is added, in the above-mentioned solution 40min of 60 DEG C or more water-baths, obtains transparent colourless two
Titanium oxide aqueous solution；The titanium dioxide aqueous solution being prepared is taken, cationic surfactant sebum dibutyl phthalate 20g is added
Colloidal sol is set to be converted to hydrophobicity condensate；Toluene organic solvent 1.5L is added, acutely oscillation is rinsed, and turns colloidal particle
Enter in organic phase, up to transparent organosol after being separated from water；By the organosol after extraction and separation, boiled lower than organic solvent
80 DEG C at a temperature of point, after reflux removes absorption water, then be evaporated under reduced pressure removing organic solvent, be heat-treated at 210 DEG C to get
Colourless titanium dioxide ultra-micro powder；B., surfactant sebum dibutyl phthalate 15g is added to the hydroxide of the 1mol/L of 300ml
Sodium solution stands 2 hours；C. the titanium dioxide ultra-micro powder 750g for taking a step to be prepared is dissolved in the solution of b step,
Up to TiO 2 sol.(2) by TiO 2 sol and the compound first break draft of 5Kg cellulose gel, spinning obtains compound fibre
Dimension.(3) composite fibre carries out air drying.(4) composite fibre is immersed into NiSO4Solution is electroplated, and is formed with cellulose fiber
Dimension is skeleton, the catalysis fibre that titanium dioxide is anode, nickel coating is cathode.
PM10 particle, content of formaldehyde in the air inside and outside newly-decorated office are measured, see Table 1 for details for measurement result.It will system
It is standby obtain using cellulose fibre as skeleton, the catalysis fibre that titanium dioxide is anode, nickel coating is cathode is packed into newly-decorated
The air-conditioning air inlet in house, its clean-up effect is measured after 2 hours, and see Table 1 for details.
1 embodiment of table and comparative example indoor air purification effect
Claims (4)
1. a kind of preparation method of the catalysis fibre material for air cleaning, which is characterized in that described for air cleaning
Catalysis fibre material is prepared by the following method: (1) preparing titanium dioxide-cobalt oxide colloidal sol；(2) by titanium dioxide-oxidation
Cobalt colloidal sol and the compound first break draft of cellulose gel, spinning obtain composite fibre；(3) composite fibre carries out air drying；(4) will
Composite fibre immerses nickel source and is electroplated, and is formed using cellulose fibre as skeleton, and titanium dioxide-cobalt oxide is anode, nickel coating
For the catalysis fibre of cathode, the nickel source is NiSO4Or NiCl2；
Titanium dioxide-cobalt oxide colloidal sol method is prepared described in step (1) includes:
A. by TiO(OH)2After white precipitate washing removes the sulfate radical of solvable fluidity, sodium ion impurity, 2~4mol/L salt is added
Acid solution obtains transparent colourless titanium dioxide aqueous solution in the above-mentioned 40~60min of solution of 60 DEG C or more water-baths；Take described two
Titanium oxide aqueous solution, cationic surfactant, which is added, makes colloidal sol be converted to hydrophobicity condensate；Organic solvent is added,
Acutely oscillation is rinsed, and is transferred to colloidal particle in organic phase, up to transparent organosol after being separated from water；After extraction and separation
Organosol, lower than organic solvent boiling point at a temperature of, after reflux removes absorption water, then be evaporated under reduced pressure removing organic solvent,
It is heat-treated at 200~220 DEG C to get colourless titanium dioxide ultra-micro powder；
B. surfactant is added in acetic acid cobalt liquor and is uniformly mixed, add sodium hydroxide solution, stood 1~2 hour, obtain
To cobalt oxide colloidal sol；
C. by the titanium dioxide ultra-micro powder that a step is prepared be dissolved in the cobalt oxide colloidal sol that b step is prepared to get
Titanium dioxide-cobalt oxide colloidal sol.
2. a kind of preparation method of catalysis fibre material for air cleaning according to claim 1, which is characterized in that
Titanium dioxide in titanium dioxide as described in step (1)-cobalt oxide colloidal sol: the mass ratio of cobalt oxide is 8~15:4~10.
3. a kind of preparation method of catalysis fibre material for air cleaning according to claim 1, which is characterized in that
The mass ratio of step (2) cellulose and titanium dioxide is 50~100:2~5.
4. a kind of catalysis fibre material for air cleaning, which is characterized in that the catalysis fibre material is by claim 1-3
Any one preparation method is prepared.
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| CN1389932A (en) * | 2002-04-27 | 2003-01-08 | 江汉石油钻头股份有限公司 | Composite titanium-base film photoelectrode and its making process |
| CN1600424A (en) * | 2003-09-22 | 2005-03-30 | 中国科学院化学研究所 | Photocatalyst responding to visible light, and preparation method and application |
| CN101187646A (en) * | 2007-11-23 | 2008-05-28 | 东华大学 | Granule electrode possessing photoelectric catalytic function and its uses |
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| JP4048266B2 (en) * | 2003-01-29 | 2008-02-20 | 株式会社ゼンワールド | Article surface coating method and article surface coating agent of photocatalyst composition |
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| CN1389932A (en) * | 2002-04-27 | 2003-01-08 | 江汉石油钻头股份有限公司 | Composite titanium-base film photoelectrode and its making process |
| CN1600424A (en) * | 2003-09-22 | 2005-03-30 | 中国科学院化学研究所 | Photocatalyst responding to visible light, and preparation method and application |
| CN101187646A (en) * | 2007-11-23 | 2008-05-28 | 东华大学 | Granule electrode possessing photoelectric catalytic function and its uses |
| CN106732808A (en) * | 2016-11-25 | 2017-05-31 | 江苏爱西施科技服务咨询股份有限公司 | A kind of fibroin albumen/TiO2The preparation method of composite catalyst |
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