CN107841164A - A kind of antireflective coated solution and preparation method and the production method of photovoltaic glass - Google Patents
A kind of antireflective coated solution and preparation method and the production method of photovoltaic glass Download PDFInfo
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- CN107841164A CN107841164A CN201711052282.XA CN201711052282A CN107841164A CN 107841164 A CN107841164 A CN 107841164A CN 201711052282 A CN201711052282 A CN 201711052282A CN 107841164 A CN107841164 A CN 107841164A
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- coated solution
- antireflective coated
- antireflective
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
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- Engineering & Computer Science (AREA)
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- Inorganic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Composite Materials (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Surface Treatment Of Glass (AREA)
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Abstract
The invention discloses a kind of antireflective coated solution, main component is included by volumn concentration：High transmission sol 3.0%~5.0%, solvent alcohols 85.0%~93.0%, catalyst 0.1~5.0, adhesive 0.1~1.5%, pH value acid regulator 2.0~3.5%, surfactant 0.1~0.8%, case hardness reinforcing agent 0.5~1.2%, auxiliary agent 0.1~0.3%, increase face agent 0.1 0.3%, and a kind of method of photovoltaic glass using the molten preparation of antireflective plated film；The present invention can be up to more than 2.5% with the transmitance gain between visible region, with high transmittance, the spectral transmittance in solar cell power generation response wave length scope can further be increased, lift value-added content of product, and preparation method, this method is carried out at normal temperatures, easy to operate, technique is simple, cost is relatively low, the cycle is short.
Description
Technical field
The invention belongs to solar energy photovoltaic glass technical field, and in particular to a kind of antireflective coated solution and preparation method
And its photovoltaic glass manufacture method.
Background technology
As crystalline silicon price declines to a great extent, solar energy power generating plate has obtained the popularization and use of increasingly photovoltaic.
The preposition cover plate of photovoltaic module is based on photovoltaic glass surface coated with antireflection film at present, antireflective coated solution based on water-based,
The cost of its reclaimed water accounts for more than 90%.Water-based coated solution is primarily present both sides problem.The transmission of one side light is to glass
The gain of glass is not high, and usual gain is between 1.7%-1.95%.It is to widely use film layer that 1 non-coated glass, which is illustrated, with coating
Glass light transmission rate contrast curve, make it that the generated output of final photovoltaic module is not high because transmitance is low.Another aspect film layer
Surface mechanical strength is low, it is illustrated that 2 be widest water-based coating liquid pencil hardness micrograph；By GB/T 30984.1-2015 only
Pencil 3H standard can be met, it is impossible to fully meet the rigors that photovoltaic module product uses more than 20 years out of doors.
The content of the invention
For problem present in background technology, the invention provides a kind of antireflective coated solution and preparation method and
The production method of photovoltaic glass, it is desirable to provide it is a kind of can improve glass transmitance, high mechanical properties antireflective coated solution with
And using the photovoltaic glass made by the plated film, so as to improve mechanical strength, meet requirement.
To achieve the above object, the present invention provides following technical scheme：A kind of antireflective coated solution, main component press body
Product percentage composition includes high transmission sol 3.0%~5.0%, solvent alcohols 85.0%~93.0%, and catalyst 0.1~
5.0%, adhesive 0.1~1.5%, pH value acid regulator 2.0~3.5%, surfactant 0.1~0.8%, case hardness
Reinforcing agent 0.5~1.2%, auxiliary agent 0.1~0.3%, increase face agent 0.1-0.3%.
Preferably, the high transmission sol is in silicon dioxide gel, TiO 2 sol, zirconia sol
It is at least one.
Preferably, the high transmission sol molecular particle size is between 20nm~90nm.
Preferably, the solvent alcohols is at least one of ethanol, isopropanol, propyl alcohol.
Preferably, the adhesive is at least one of silane coupler, acetone, stupid ethene, butanone.
Preferably, the pH value acid regulator is at least one of glacial acetic acid, hydrochloric acid, sulfuric acid.
Preferably, the surfactant is at least one of neopelex, butyl.
Preferably, the case hardness reinforcing agent is that aluminium isopropoxide, alundum (Al2O3) are a kind of at least within.
Preferably, the solution acid alkalinity PH is between 1.5~5.0.
To achieve the above object, a kind of preparation method of antireflective coated solution of the present invention, comprises the following steps：S01：Press
Each component is measured respectively according to the formula of above-mentioned antireflective coated solution；S02：By colloidal sol, solution component mixing, heating, stirring, obtain
To mixed system；S03：Catalyst, adhesive and case hardness reinforcing agent are sequentially added into the mixed system, stirs, obtains
Mixed solution；S04：Remaining ingredient is added in mixed solution, stirs, obtains the antireflective coated solution.
In step S01, each component can also can be obtained, each component by commercially available by existing preparation method
Accurately measure, it is standby.
Step S03 specifically, sequentially add catalyst, adhesive, case hardness reinforcing agent into the mixed system, and
1-2 hours are stirred with 400~900rpm mixing speed, obtain mixed solution；
In step S04, it is added in mixed solution, stirs containing auxiliary agent, pH value conditioning agent, surfactant, increasing face agent
At least 60 minutes, obtain antireflective coated solution.
To achieve the above object, the present invention also provides prepares photovoltaic glass using antireflective coated solution, the glass structure
Include the film plating layer on glass substrate and glass substrate including photovoltaic glass, the film plating layer is one kind described in claim 1
The film layer that antireflective coated solution is formed.The preparation process of the photovoltaic glass includes：S05：In glass surface by pre-processing；
S06：Plate the film layer that a kind of antireflective coated solution described in claim 1 is formed；S07：Heat treatment drying, heat treatment temperature
For 120~200 DEG C, 3~10 minutes time；S08：Tempering processing, tempering temperature are 680~735 DEG C, and the time is 3~7 minutes.
After glass surface is pre-processed, dried using foregoing antireflective coated solution through plated film, then through Overheating Treatment,
Tempering processing, obtains the high transmittance photovoltaic glass.Wherein, plated film is preferably roller coat plated film or spraying, dip-coating etc.
Method, auxiliary agent is added in coating process, primarily to regulation viscosity, volatilization controlling agent etc., to adapt to wanting for roller coat
Ask.
Glass in the present invention preferably uses energy ultrawhite figured glass, to energy ultrawhite figured glass pretreatment include, cutting, edging,
Cleaning, drying, are dried using foregoing antireflective coated solution through roller coat plated film, then through Overheating Treatment afterwards, tempering processing, are obtained
The photovoltaic glass finished product of high transmittance.
Compared with prior art, the beneficial effects of the invention are as follows：One increases transmitance of the coated glass between visible region
Benefit can be up to more than 2.5%, and the photovoltaic glass with high transmittance can further increase solar cell power generation response wave length model
Interior spectral transmittance is enclosed, lifts value-added content of product, the competitiveness for lifting solar cell power generation, shortening is generated electricity by way of merging two or more grid systems
Period of cost recovery have the function that positive, there is extraordinary market value and application prospect.Two provide a kind of photovoltaic glass
With the preparation method of coating liquid, this method is carried out at normal temperatures, easy to operate, technique is simple, cost is relatively low, the cycle is short, high hard
The film layer of degree, and fine and close Surface Microstructure can avoid current coating liquid film in use once lack of homogeneity, film layer easily opened
Split, poor adhesive force the shortcomings that.
Brief description of the drawings
Fig. 1 is non-coated glass and coating is the glass light transmission rate contrast curve for widely using film layer；
Fig. 2 is widest water-based coating liquid pencil hardness micrograph；
Fig. 3 is the glass light transmission rate contrast curve of non-coated glass and coating film layer of the present invention；
Fig. 4 is the pencil hardness figure after solid line of the present invention is applied；
Fig. 5 is the SEM micrograph of 600,000 times of amplification after solid line of the present invention is applied.
Embodiment
With reference to the embodiment in the present invention and accompanying drawing 3-5, the technical scheme in the embodiment of the present invention is carried out clear
Chu, it is fully described by, it is clear that described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.
Based on the embodiment in the present invention, those of ordinary skill in the art are obtained all under the premise of creative work is not made
Other embodiment, belong to the scope of protection of the invention.
Embodiment 1:
Comprise the following steps：
Step 1,72 DEG C are warming up to by solvent alcohols and catalyst together, are continuously stirred with 400rpm speed at 72 DEG C
Mix to obtain mixed liquor A；
Step 2, a certain amount of adhesive is stirred under 500rpm speed with silicon dioxide gel, and is warming up to 50
30 minutes are incubated at DEG C, mixed liquid B is made；
Step 3, case hardness reinforcing agent is sequentially added in the system of step 1, and stirred with 900rpm mixing speed
Mix 50 minutes, obtain solution C；
Step 4, mixed solution B is poured into mixed liquor C, stirred 60 minutes under the conditions of 50 DEG C, obtain mixed liquor D.
Step 5, face agent, surfactant will be increased and be added in mixed liquor D, after adding the dilution of certain proportion solvent, normal temperature
Continuously it is stirred for producing coated solution in 60 minutes.
Glass is after cutting, edging, cleaning, drying, using previous solu after roller coat plated film, using roller coat plated film
Mode, transporting velocity 8.0m/min, rubber roll rotating speed is 9.0m/min, and after roller coat plated film, glass passes through 180 DEG C of drying
Line, 8min is dried, tempering processing, 680~735 DEG C, the time is 4~7 minutes, is obtained in high transmittance photovoltaic glass finished product.
Embodiment 2：
Comprise the following steps：
Step 1, solvent, catalyst and silicon dioxide gel are continuously stirred with 400rpm speed at normal temperatures together
Mix to obtain mixed liquor A；
Step 2, a certain amount of adhesive is poured into mixed liquor A, and be warming up to 50 DEG C, 30 minutes are incubated at 50 DEG C, made
Obtain mixed liquid B；
Step 3, case hardness reinforcing agent is sequentially added in the system of step 2, and stirred with 900rpm mixing speed
Mix 50 minutes, obtain solution C；
Step 4, face agent will be increased and poured into mixed liquor C, stirred 60 minutes under normal temperature, obtain mixed liquor D.
Step 5, finally surfactant is added in mixed liquor D, after adding the dilution of certain proportion solvent, normal temperature connects
It is continuous to be stirred for producing coated solution in 2 hours.
Glass is after cutting, edging, cleaning, drying, using previous solu after roller coat plated film, using roller coat plated film
Mode, transporting velocity is 8.0m/ minutes, and rubber roll rotating speed is 9.5m/ minutes, and after roller coat plated film, glass passes through 160 DEG C of drying
Line, dry 4 minutes, tempering processing, 680~720 DEG C, the time is 3~6 minutes, is obtained in high transmittance photovoltaic glass finished product.
Transmitance is carried out to photovoltaic glass prepared by the present invention and pencil hardness is tested, obtains experimental data Fig. 3
It is the glass light transmission rate contrast curve of non-coated glass and coating film layer of the present invention, Fig. 4 is the lead after solid line of the present invention is applied
Hardness figure, Fig. 5 are that to amplify 600,000 times of SEM micrograph after solid line of the present invention is applied be to amplify 600,000 times after solid line of the present invention is applied
SEM micrograph.As can be seen from Figure 3 the plated film of photovoltaic glass that coated solution of the present invention obtains relative to no smearing is smeared
Glass and smear other plated films in the past, it is found that the obtained photovoltaic glass of the present invention can increase spectral transmittance, from hardness
It can be seen that photovoltaic glass coating liquid film uniformity in use prepared by the present invention is good, film layer is not easy to crack in Fig. 4.
Based on above-mentioned, present invention has the advantage that：One makes transmitance gain of the coated glass between visible region can
So that up to more than 2.5%, the photovoltaic glass with high transmittance can further increase in solar cell power generation response wave length scope
Spectral transmittance, lifted value-added content of product, for lifted solar cell power generation competitiveness, shorten generate electricity by way of merging two or more grid systems into
This payoff period has the function that positive, has extraordinary market value and application prospect.Two provide a kind of photovoltaic glass plating
The preparation method of film liquid, this method are carried out at normal temperatures, easy to operate, technique is simple, cost is relatively low, the cycle is short, high rigidity
Film layer, and fine and close Surface Microstructure can avoid current coating liquid film in use once lack of homogeneity, film layer are easy to crack, attached
The shortcomings that putting forth effort difference.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
All any modification, equivalent and improvement made within refreshing and principle etc., should be included in the scope of the protection.
Claims (12)
- A kind of 1. antireflective coated solution, it is characterised in that：Main component is included by volumn concentration：High transmission sol 3.0%~5.0%Solvent alcohols 85.0%~93.0%Catalyst 0.1~5.0%Adhesive 0.1~1.5%PH value acid regulator 2.0~3.5%Surfactant 0.1~0.8%Case hardness reinforcing agent 0.5~1.2%Auxiliary agent 0.1~0.3%Increase face agent 0.1-0.3%.
- A kind of 2. antireflective coated solution according to claim 1, it is characterised in that：The high transmission sol is two At least one of silica sol, TiO 2 sol, zirconia sol.
- 3. any one antireflective coated solution according to claim 1-2, it is characterised in that：The high transmission colloidal sol base Body molecular particle size is between 20nm~90nm.
- A kind of 4. antireflective coated solution according to claim 1, it is characterised in that：The solvent alcohols is ethanol, different At least one of propyl alcohol, propyl alcohol.
- A kind of 5. antireflective coated solution according to claim 1, it is characterised in that：The adhesive is silane coupled At least one of agent, acetone, stupid ethene, butanone.
- A kind of 6. antireflective coated solution according to claim 1, it is characterised in that：The pH value acid regulator is ice At least one of acetic acid, hydrochloric acid, sulfuric acid.
- A kind of 7. antireflective coated solution according to claim 1, it is characterised in that：The surfactant is dodecane At least one of base benzene sulfonic acid sodium salt, butyl.
- A kind of 8. antireflective coated solution according to claim 1, it is characterised in that：The case hardness reinforcing agent is different Aluminium propoxide, alundum (Al2O3) are a kind of at least within.
- A kind of 9. antireflective coated solution according to claim 1, it is characterised in that：The solution acid alkalinity PH is 1.5 Between~5.0.
- A kind of 10. preparation method of antireflective coated solution according to claim 1, it is characterised in that：Including following step Suddenly：S01：Formula according to above-mentioned antireflective coated solution measures each component respectively；S02：By colloidal sol, solution component mixing, heating, stirring, mixed system is obtained；S03：Catalyst, adhesive and case hardness reinforcing agent are sequentially added into the mixed system, with 400~900rpm's Mixing speed stirs 1-2 hours, obtains mixed solution；S04：Remaining ingredient is added in mixed solution, stirs at least 60 minutes, obtains the antireflective coated solution.
- 11. a kind of photovoltaic glass, including photovoltaic glass include the film plating layer on glass substrate and glass substrate, it is characterised in that： The film plating layer is the film layer that a kind of antireflective coated solution described in claim 1 is formed.
- A kind of 12. photovoltaic glass according to claim 11, it is characterised in that：The preparation process of the photovoltaic glass includes：S05：In glass surface by pre-processing；S06：Plate the film layer that a kind of antireflective coated solution described in claim 1 is formed；S07：Heat treatment drying, heat treatment temperature are 120~200 DEG C, 3~10 minutes time；S08：Tempering processing, tempering temperature are 680~735 DEG C, and the time is 3~7 minutes.
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| CN201711052282.XA CN107841164A (en) | 2017-10-30 | 2017-10-30 | A kind of antireflective coated solution and preparation method and the production method of photovoltaic glass |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108676388A (en) * | 2018-04-28 | 2018-10-19 | 浙江福莱新材料股份有限公司 | A kind of cold lamination film anti-reflection anti-reflective coating and preparation method thereof |
| CN111909550A (en) * | 2020-08-07 | 2020-11-10 | 齐鲁工业大学 | Coating for improving cracking resistance of medicinal glass surface and preparation method and application thereof |
| CN112174541A (en) * | 2020-10-22 | 2021-01-05 | 安徽凯盛基础材料科技有限公司 | Surface treatment method of glass ball cabin |
| CN113943110A (en) * | 2021-10-20 | 2022-01-18 | 安徽工程大学 | Coating liquid and preparation method thereof, photovoltaic glass anti-reflection film and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6168350A (en) * | 1984-09-11 | 1986-04-08 | Shibata Hario Glass Kk | Inorganic plate reduced in surface reflection and its production |
| JP2000160056A (en) * | 1998-09-22 | 2000-06-13 | Toto Ltd | Photocatalytic coating composition, photocatalytic composite material and preparation of photocatalytic composite material |
| CN101891394A (en) * | 2009-05-19 | 2010-11-24 | 信义超薄玻璃(东莞)有限公司 | Anti-reflection solution, ultra-white photovoltaic glass and manufacturing method thereof |
| CN102531406A (en) * | 2012-01-17 | 2012-07-04 | 信义玻璃工程（东莞）有限公司 | Antireflective coating solution and preparation method thereof, as well as photovoltaic glass and preparation method of photovoltaic glass |
| CN102838288A (en) * | 2012-08-16 | 2012-12-26 | 浙江格拉威宝玻璃技术有限公司 | Antireflection coated glass with self-cleaning effect and preparation method thereof |
-
2017
- 2017-10-30 CN CN201711052282.XA patent/CN107841164A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6168350A (en) * | 1984-09-11 | 1986-04-08 | Shibata Hario Glass Kk | Inorganic plate reduced in surface reflection and its production |
| JP2000160056A (en) * | 1998-09-22 | 2000-06-13 | Toto Ltd | Photocatalytic coating composition, photocatalytic composite material and preparation of photocatalytic composite material |
| CN101891394A (en) * | 2009-05-19 | 2010-11-24 | 信义超薄玻璃(东莞)有限公司 | Anti-reflection solution, ultra-white photovoltaic glass and manufacturing method thereof |
| CN102531406A (en) * | 2012-01-17 | 2012-07-04 | 信义玻璃工程（东莞）有限公司 | Antireflective coating solution and preparation method thereof, as well as photovoltaic glass and preparation method of photovoltaic glass |
| CN102838288A (en) * | 2012-08-16 | 2012-12-26 | 浙江格拉威宝玻璃技术有限公司 | Antireflection coated glass with self-cleaning effect and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108676388A (en) * | 2018-04-28 | 2018-10-19 | 浙江福莱新材料股份有限公司 | A kind of cold lamination film anti-reflection anti-reflective coating and preparation method thereof |
| CN108676388B (en) * | 2018-04-28 | 2020-11-03 | 浙江福莱新材料股份有限公司 | Anti-reflection coating for cold-mounted film and preparation method thereof |
| CN111909550A (en) * | 2020-08-07 | 2020-11-10 | 齐鲁工业大学 | Coating for improving cracking resistance of medicinal glass surface and preparation method and application thereof |
| CN112174541A (en) * | 2020-10-22 | 2021-01-05 | 安徽凯盛基础材料科技有限公司 | Surface treatment method of glass ball cabin |
| CN113943110A (en) * | 2021-10-20 | 2022-01-18 | 安徽工程大学 | Coating liquid and preparation method thereof, photovoltaic glass anti-reflection film and preparation method thereof |
| CN113943110B (en) * | 2021-10-20 | 2023-08-15 | 安徽工程大学 | Coating liquid and preparation method thereof, photovoltaic glass anti-reflection film and preparation method thereof |
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Correction item: Application Date Correct: 2017.12.11 False: 2017.10.30 Number: 13-01 Page: The title page Volume: 34 Correction item: Application Date Correct: 2017.12.11 False: 2017.10.30 Number: 13-01 Volume: 34 |
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Application publication date: 20180327 |