CN107833755A - A kind of high-performance SiC@Fe2O3Hybrid supercapacitor negative material - Google Patents
A kind of high-performance SiC@Fe2O3Hybrid supercapacitor negative material Download PDFInfo
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- 239000000463 material Substances 0.000 title claims abstract description 32
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002070 nanowire Substances 0.000 claims abstract description 17
- 239000000126 substance Substances 0.000 claims abstract description 7
- 230000004087 circulation Effects 0.000 claims abstract description 6
- 238000003491 array Methods 0.000 claims abstract description 5
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 4
- 239000007772 electrode material Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 4
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims description 2
- 235000012149 noodles Nutrition 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 239000003990 capacitor Substances 0.000 abstract description 5
- 239000002131 composite material Substances 0.000 abstract description 5
- 239000002086 nanomaterial Substances 0.000 abstract 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 27
- 229910010271 silicon carbide Inorganic materials 0.000 description 27
- 239000002114 nanocomposite Substances 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 239000011149 active material Substances 0.000 description 4
- 238000001291 vacuum drying Methods 0.000 description 4
- 239000003575 carbonaceous material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000011812 mixed powder Substances 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LLYXJBROWQDVMI-UHFFFAOYSA-N 2-chloro-4-nitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1Cl LLYXJBROWQDVMI-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 238000000627 alternating current impedance spectroscopy Methods 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(III) oxide Inorganic materials O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000002484 cyclic voltammetry Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- UZVNCLCLJHPHIF-NOJKMYKQSA-J zinc;(1e)-2-(ethylcarbamoylamino)-n-methoxy-2-oxoethanimidoyl cyanide;manganese(2+);n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[Zn+2].[S-]C(=S)NCCNC([S-])=S.[S-]C(=S)NCCNC([S-])=S.CCNC(=O)NC(=O)C(\C#N)=N\OC UZVNCLCLJHPHIF-NOJKMYKQSA-J 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/46—Metal oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Crystallography & Structural Chemistry (AREA)
- Nanotechnology (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
The present invention is prepared for SiC@Fe using hydro-thermal method2O3Composite nano materials, kernel are SiC nanowire, and they are entangled to each other, constitute a kind of special network structure, and shell is by Fe2O3The array that nanoneedle is formed, Fe2O3A diameter of 50 80nm of nanoneedle, length are 200 300nm, and nano needle arrays proper alignment, are uniformly dispersed, and the free space of abundance is formd between adjacent nano pin；SiC@Fe produced by the present invention2O3Composite has excellent chemical property, and its biggest quality specific capacitance value is 721F g‑1, and after 3000 circle circulations, its specific capacitance remains to keep the 90.7% of former specific capacitance, and this provides high-quality candidate's negative material to construct high-performance super capacitor of new generation.
Description
Technical field
The present invention relates to new energy field of storage, and in particular to a kind of high-performance SiC@Fe2O3Hybrid supercapacitor negative pole
Material.
Technical background
Ultracapacitor is a kind of new type of energy storage device developed in recent years, has power density height, charging rate
Hurry up, service life cycle is long, operating temperature range is wide, the advantages that having a safety feature and be environmentally friendly, in new-energy automobile, miniature communication
The fields such as equipment, heavy-duty machinery, Aero-Space have broad application prospects (Chinese invention patent, application number
201310326357.4；Chinese invention patent, application number 201610024861.2).However, ultracapacitor positive and negative electrode is not
Matching often lead to ultracapacitor specific energy density reduce, especially in recent years, carbon material (such as activated carbon, CNT and
Graphene) it is often used as super capacitor anode material (Journal of Power Sources, 2015,283,270-278；
NPG Asia Materials, 2015,7, e165), because its theoretical specific capacitance is relatively low, this problem more highlights, seriously
Its industrialized production process is constrained, therefore, designs and constructs a kind of new and and just have the negative pole of matched well
Material is of great significance to the specific energy density tool for improving ultracapacitor.At present, researcher attempts to use V2O5,
MoO3, Fe2O3And Bi2O3Traditional carbon material is replaced to improve its specific capacitance, wherein Fe Deng transition metal oxide2O3Most by people
Pay close attention to, this is mainly due to Fe2O3With higher theoretical specific capacitance, excellent redox characteristic and electro-chemical activity, and
And abundant raw material, environment-friendly and advantage (J.Mater.Chem.A, the 2016,4,12289-12295 such as cheap；
Chemical Engineering Journal,2016,306,193-203).However, as other transition metal oxides,
Fe2O3The shortcomings that electric conductivity and cyclical stability difference be present, and reunite (Chinese invention patent, Shen easily occur on substrate
Please numbers 201110150179.5；Chinese invention patent, application number 201610024861.2), this will make the ratio surface of active material
Reduce, so as to cause the specific capacitance actually obtained to be far below its theoretical value.In order to overcome above mentioned problem, researcher often utilizes
The carbon material that electric conductivity is preferable and specific surface area is larger, inorganic semiconductor or conducting polymer are as skeleton and Fe2O3Answered
Close, effectively improve active material reunite and the defects of capacitance characteristic difference (J.Mater.Chem.A, 2016,4,9977-
9985；ACS Appl.Mater.Interfaces 2015,7,27518-27525).Although the above-mentioned combination electrode material prepared
Material has preferable chemical property, but still can not meet Novel super capacitor in charge and discharge process to high specific capacitance and again
The demand of rate characteristic, therefore, it is imperative to develop a kind of preferably framework material.It is well known that SiC nanowire is not only with good
Good mechanical performance and physical and chemical stability, big major diameter when specific surface area, excellent electric conductivity with it is anticorrosive anti-oxidant
Characteristic, and they are entangled to each other, may be constructed a kind of special network structure.Therefore, the network structure that SiC nanowire is formed
Not only make active material dispersed, and a variety of transmission channels are provided for electronics conduction in charge and discharge process, can also solve
Certainly active material because volumetric expansion/diminution and caused by electrode structure cave in, this makes them turn into the super of great competitiveness
The framework material of capacitor composite electrode；In addition, SiC nanowire electrode material can also show high area specific capacitance, long-term
Cyclical stability and excellent electrochemically resistant etching characteristic and excellent pliability (Gu, et al.Performance
characteristics of supercapacitor electrodes made of silicon carbide
nanowires grown on carbon fabric.Journal of Power Sources 2013,243,648-
653.Alper,et al.Silicon carbide nanowires as highly robust electrodes for
microsupercapacitors.Journal of Power Sources 2013,230,298-302).Therefore, when SiC receives
Rice noodles are as skeleton and nanometer Fe2O3Compound tense is carried out, the capacitance characteristic of this composite negative pole material can be substantially improved.Do not have still at present
It is related to Fe2O3The report of nano needle arrays coated Si/C nano wire hybrid supercapacitor negative material.
The content of the invention
The invention aims to overcome single-activity material to reunite, capacitance characteristic is poor and framework material is easy to corrosion etc.
Shortcoming, using a kind of hydro-thermal method simple to operate, prepare with better quality specific capacitance and high rate performance and long-term circulation
Stability Fe2O3Nano needle arrays coated Si/C nano wire hybrid supercapacitor negative material, its specific preparation process include：It is first
It is secondary, using SiC nanowire as framework material, Fe is deposited on its surface using hydro-thermal method2O3Presoma, then obtained by calcination processing
To SiC@Fe2O3Hybrid supercapacitor negative material.
The composite negative pole material that this method is prepared shows excellent chemical property, when current density is 2Ag-1When,
Quality is 721F g than capacitance-1, when current density increases to 12Ag-1When, quality is 366F g than capacitance-1；And pass through
After 3000 circle circulations, its specific capacitance remains to keep the 90.7% of former specific capacitance, and this is SiC nanowire base functional nanocomposite
Theoretical and experiment basis have been established in application in high-performance super capacitor of new generation.
Brief description of the drawings
Below in conjunction with the accompanying drawings and embodiment the invention will be further described.
Fig. 1 is SiC nanowire and SiC@Fe2O3The SEM photograph of nano composite material.
Fig. 2 is SiC@Fe2O3The XRD spectrum of nano composite material.
Fig. 3 is SiC@Fe2O3The CV curves of nano composite material.
Fig. 4 is SiC@Fe2O3The constant current charge-discharge curve of nano composite material and quality specific capacitance with current density change
Change curve.
Fig. 5 is SiC@Fe2O3The EIS curves of nano composite material.
Fig. 6 is SiC@Fe2O3The cyclical stability of nano composite material.
Embodiment
Embodiment 1
The preparation of SiC nanowire
Respectively using mol ratio as 1:1.5 Si powder and graphite powder mixed powder be raw material, carbon cloth and nickel nitrate be substrate with
Catalyst, SiC nanowire is prepared on carbon cloth using chemical gas-phase reaction method.Concretely comprise the following steps：First, carbon cloth is immersed into nitric acid
10min in nickel alcohol mixed solution, is then dried in atmosphere；Again by Si- graphite powders mixed powder and carbon with catalyst
Cloth is sequentially placed into graphite reative cell, and is placed on the good vacuum lid of vacuum drying oven interior sealing, is switched on power and circulation,
Subsequent start-up vacuum system, after vacuumizing 30min, close valve and stop vacuumizing, high-purity Ar is then passed through into vacuum drying oven extremely
Close to normal pressure, close Ar valves and vacuumize again, stop to vacuumize after 30min and fill Ar to close to normal pressure, repeat operation 2-3
It is secondary to exclude furnace air as far as possible；Then make vacuum drying oven with 350-400 DEG C of h-1Heating rate rise to 1250 DEG C simultaneously from room temperature
13-16min is incubated, finally closing power supply makes vacuum drying oven naturally cool to room temperature.SiC nanowire SEM characterization results are shown in Fig. 1 a.
SiC@Fe2O3The preparation of nano composite material
First, 75ml distilled water is measured, and 0.08M and 0.06M Fe (NO are distinguished as solvent compound concentration3)3·
6H2O and Na2SO4Mixed solution, itself and deposition are then had into carbon cloth (1 × 1cm of SiC nanowire2) to be together put into high pressure anti-
To answer in kettle, after sealing, 8h is incubated at 120 DEG C, question response kettle takes out after being cooled to room temperature, after distilled water flushing 2~3 times,
Spontaneously dry in atmosphere, then dried sample is inserted in Muffle furnace, 450 DEG C are heated to 2 DEG C/min heating rate
Afterwards, 2h is incubated, room temperature is naturally cooled to, obtains SiC@Fe2O3Nano composite material.SiC@Fe2O3The SEM of nano composite material,
XRD characterization results are shown in Fig. 1 b and Fig. 2 respectively.
SiC@Fe2O3The electrochemical property test of nano composite material
With SiC@Fe2O3Nanometer combined electrode material is working electrode, and saturated calomel electrode is reference electrode, platinum electrode
To form three-electrode system to electrode, in 2molL-1KOH solution in, it is 10~50mV s to control sweep speed-1, measure
Cyclic voltammetry curve, see Fig. 3, from figure 3, it can be seen that redox reaction during discharge and recharge be present in the electrode, and
And without now obvious electrode polarization phenomenon；Control electric current density is 2Ag-1~12Ag-1, constant current charge-discharge curve is determined, sees figure
4, figure 4, it is seen that when current density is 2Ag-1When, quality is 721F g than capacitance-1, when current density increases to
12Ag-1When, quality is 366F g than capacitance-1；0.01~100000Hz of frequency range is controlled, ac impedance spectroscopy is determined, sees figure
5, from figure 5 it can be seen that the electrode material has less internal resistance and charge transfer resistance；Control electric current density is
12Ag-1, cyclical stability is determined, sees Fig. 6, from fig. 6 it can be seen that after the circle of circulation 3000, remains to keep original specific capacitance
90.7%, this illustrates that this electrode material has excellent cyclical stability.
Claims (3)
- A kind of 1. high-performance SiC@Fe2O3Hybrid supercapacitor negative material, it is characterised in that：The combination electrode material Kernel is SiC nanowire, and shell is the Fe of proper alignment2O3Nano needle arrays, specific preparation process include：First, received with SiC Rice noodles are framework material, and Fe is deposited on its surface using hydro-thermal method2O3Presoma, then obtain SiC@Fe by calcination processing2O3 Hybrid supercapacitor negative material.
- A kind of 2. high-performance SiC@Fe according to claim 12O3Hybrid supercapacitor negative material, it is characterised in that： Kernel is SiC nanowire, and they are entangled to each other, constitutes a kind of special network structure；Shell is by Fe2O3Nanoneedle is formed Array, Fe2O3A diameter of 50-80nm of nanoneedle, length 200-300nm, and it is nano needle arrays proper alignment, scattered Uniformly, the free space of abundance is formd between adjacent nano pin.
- A kind of 3. high-performance SiC@Fe according to claim 12O3Hybrid supercapacitor negative material, it is characterised in that： The combination electrode material shows excellent chemical property, when current density is 2Ag-1When, quality is than capacitance 721Fg-1；And after 3000 circle circulations, its specific capacitance remains to keep the 90.7% of former specific capacitance.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710751296.4A CN107833755A (en) | 2017-08-28 | 2017-08-28 | A kind of high-performance SiC@Fe2O3Hybrid supercapacitor negative material |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110772890A (en) * | 2018-07-30 | 2020-02-11 | 天津大学 | Ferroferric oxide-loaded SiC foamed ceramic and preparation method and application thereof |
| CN112614705A (en) * | 2020-11-03 | 2021-04-06 | 宁波工程学院 | Preparation method of zigzag nitrogen-doped SiC nanowires growing on carbon fiber cloth |
| CN115341384A (en) * | 2022-09-19 | 2022-11-15 | 青岛科技大学 | SiC NWs @MnO 2 Preparation method of @ PPy heterostructure nano composite wave-absorbing material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103187180A (en) * | 2013-03-06 | 2013-07-03 | 浙江理工大学 | Preparation method for nanometre silicon carbide-ruthenium oxide composite material |
| CN105826086A (en) * | 2015-08-20 | 2016-08-03 | 青岛大学 | Flexible all-solid-state super capacitor based on SiC nano array and preparation method thereof |
-
2017
- 2017-08-28 CN CN201710751296.4A patent/CN107833755A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103187180A (en) * | 2013-03-06 | 2013-07-03 | 浙江理工大学 | Preparation method for nanometre silicon carbide-ruthenium oxide composite material |
| CN105826086A (en) * | 2015-08-20 | 2016-08-03 | 青岛大学 | Flexible all-solid-state super capacitor based on SiC nano array and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| LIN GU, ET AL.: ""Performance characteristics of supercapacitor electrodes made of silicon carbide nanowires grown on carbon fabric"", 《JOURNAL OF POWER SOURCES》 * |
| YING-CHU CHEN, ET AL.: ""Synthesis of Fe2O3 nanorods/silver nanowires on coffee filter as low-cost and efficient electrodes for supercapacitors"", 《JOURNAL OF ELECTROANALYTICAL CHEMISTRY》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110772890A (en) * | 2018-07-30 | 2020-02-11 | 天津大学 | Ferroferric oxide-loaded SiC foamed ceramic and preparation method and application thereof |
| CN110772890B (en) * | 2018-07-30 | 2021-11-19 | 天津大学 | Ferroferric oxide-loaded SiC foamed ceramic and preparation method and application thereof |
| CN112614705A (en) * | 2020-11-03 | 2021-04-06 | 宁波工程学院 | Preparation method of zigzag nitrogen-doped SiC nanowires growing on carbon fiber cloth |
| CN115341384A (en) * | 2022-09-19 | 2022-11-15 | 青岛科技大学 | SiC NWs @MnO 2 Preparation method of @ PPy heterostructure nano composite wave-absorbing material |
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Application publication date: 20180323 |