CN107829311A - A kind of preparation method of multifilament blended high intensity dress materials - Google Patents

A kind of preparation method of multifilament blended high intensity dress materials Download PDF

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Publication number
CN107829311A
CN107829311A CN201711259077.0A CN201711259077A CN107829311A CN 107829311 A CN107829311 A CN 107829311A CN 201711259077 A CN201711259077 A CN 201711259077A CN 107829311 A CN107829311 A CN 107829311A
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China
Prior art keywords
cloth
bed
dope layer
mass fraction
raw material
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CN201711259077.0A
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何金蓉
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Chengdu Jereh Sun Engineering Co Ltd
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Chengdu Jereh Sun Engineering Co Ltd
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Priority to CN201711259077.0A priority Critical patent/CN107829311A/en
Publication of CN107829311A publication Critical patent/CN107829311A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0034—Polyamide fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0036—Polyester fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
    • D06N3/106—Elastomers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/186—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials one of the layers is on one surface of the fibrous web and the other layer is on the other surface of the fibrous web
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/02—Synthetic macromolecular fibres
    • D06N2201/0218—Vinyl resin fibres
    • D06N2201/0236—Vinyl halide, e.g. PVC, PVDC, PVF, PVDF
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/10—Particulate form, e.g. powder, granule
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    • D06N2209/00—Properties of the materials
    • D06N2209/10—Properties of the materials having mechanical properties
    • D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
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    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/126—Permeability to liquids, absorption
    • D06N2209/128—Non-permeable
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    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
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  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
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  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of preparation method of multifilament blended high intensity dress materials, the bed of cloth as basic unit is prepared first, is taken raw material and is carried out that blending obtains yarn and that bed of cloth is made by machine is standby；Then fluoro-silicone emulsion, natrium nitrosum, talcum powder and superfine alumina silicate are taken as dope layer raw material, superfine alumina silicate is first poured into fluoro-silicone emulsion the progress 20min of heating stirring 10 according to mass fraction ratio, natrium nitrosum and talcum powder is then added into its mixed liquor again and continues to stir 20 25min and obtain coating；PE40 60%, DOP plasticizer 30 40% and superchlorinated polyvinyl chloride resin 20 35% taken as film layer raw material carry out granulation that to form modified PE particle standby；Then coating is uniformly coated in bed of cloth side, after its stabilization forms dope layer, ready PE particles is heated and is uniformly coated on dope layer and dope layer is completely covered；The present invention is by that can provide preferable waterproof effect.

Description

A kind of preparation method of multifilament blended high intensity dress materials
Technical field
The present invention relates to cloth field, in particular to a kind of preparation method of multifilament blended high intensity dress materials.
Background technology
Clothes are made with fabric, and fabric is exactly the material for making clothes.As one of clothes three elements, fabric Can not only annotate the style and characteristic of clothes, and directly left and right the color of clothes, the expression effect of moulding.Presentation is come from The noble quality of body is perfect, soft.Wherein chemical fiber plus material is so that its fastness is big, good, well-pressed, wear-resisting washable, the easy keeping of elasticity is collected And liked by people.Pure chemical fiber fabric is the fabric formed by pure chemistry fibrous woven.Its characteristic is by its chemical fibre sheet The characteristic of body determines.Chemical fibre can be processed into certain length according to different needs, and be made into by different technique imitative Silk, imitative cotton, imitative fiber crops, elastic force imitate hair, middle length imitates the fabrics such as hair.And present chemical fiber plus material is required to increase certain feature, Such as water resistance, therefore produce so-called waterproof fabrics.The major function of Water-proof breathable fabric has：Waterproof, moisture-inhibiting, breathe freely, absolutely Edge, it is windproof, it is warming.From manufacture craft, much higher than in general waterproof fabrics of the technical requirements of Water-proof breathable fabric；Together When from quality, Water-proof breathable fabric also have other waterproof fabrics not available for functional characteristics.Waterproof and breathable face Material its unique permeability performance, can be such that inside configuration steam discharges rapidly, keep away while cloth air-tightness, watertightness is strengthened Exempt from structure and multiply mould, and keep human body dry and comfortable all the time, perfection solves the problems such as breathing freely and windproof, waterproof, warming, is a kind of The novel fabric of health environment-friendly.Real waterproof fabrics, which is chronically in the climatic environment of humidity, can also stand seepage pressure, It is impermeable.For example damp ground is kneeled or is sitting in, all without infiltration in the outdoor walking that it's raining and blowing hard for a long time.In steam In the state of, particle water is very tiny, according to the principle of capillary moving, can smoothly penetrate into capillary to opposite side, so that The saturating vapour phenomenon of generation.After moisture condensation becomes the globule, particle becomes big, due to the effect of globule surface tension（Between hydrone " pull and contend with " mutually）, hydrone cannot smoothly depart from the globule and penetrate into opposite side, that is, prevent the infiltration of water to send out It is raw, steam film is had the function of waterproof.
Existing outdoor clothing fabric is generally configured with certain waterproof effect, but its material is more frivolous, causes its knot Structure intensity is relatively low, and clothing surface can be caused the problem of damaged occur in long-term outdoor activities, and using Multilayer plus material Outdoor clothing coloring is single, in order to meet functional requirements so as to cause its surface can not adhere to more three-dimensional dope layer knot Structure.
The content of the invention
It is poor for above-mentioned structural strength in the prior art and can not be of the invention the surface spraying complexity coating the problem of Purpose is that provide one kind makes it by rationally setting to reach higher-strength and also protect dope layer by multilayer material The preparation method of the stable clothing fabric cloth for being attached to cloth layer surface.
The present invention is achieved through the following technical solutions：A kind of preparation method of multifilament blended high intensity dress materials, tool Body step is as follows：
A1. the bed of cloth as basic unit is prepared first, and the polyphenyl dicarboxylic acid dimethyl ester that 50-75% is taken according to mass fraction meter is fine The nylon fiber of dimension, 20-40% polyacrylonitrile fibre and 20-35% obtains yarn as raw material progress blending and passes through machine It is standby that bed of cloth is made；
A2. fluoro-silicone emulsion 40-60%, natrium nitrosum 15-25%, talcum powder 10-15% and ultra-fine and then according to mass fraction meter are taken Superfine alumina silicate is first poured into fluoro-silicone emulsion and added as dope layer raw material by alumina silicate 10-20% according to mass fraction ratio Thermal agitation 10-20min, then adds into its mixed liquor natrium nitrosum and talcum powder and continues to stir 20-25min and obtain again Coating；
A3. PE40-60%, DOP plasticizer 30-40% and superchlorinated polyvinyl chloride resin 20-35% are taken as film according to mass fraction meter Layer raw material carry out granulation, and to form modified PE particle standby；
A4. bed of cloth side uniformly and then by coating is coated in, after its stabilization forms dope layer, by ready PE particles Heat and be uniformly coated on dope layer and dope layer is completely covered；
A5. butadiene-styrene rubber 45-85%, zinc oxide 8-16% and hexanedioic acid dioctyl ester 20-30% are chosen as pressure using in terms of mass fraction again The raw material of glue-line, which carry out melting copolymerization, to be obtained modified styrene butadiene rubber and is fitted in bed of cloth by gilding technology being provided with dope layer Opposite side forms moulding layer on face, so as to obtain clothing fabric.
Further, blending resultant yarn is 60-80 branch in the step A1, and the yarn by obtained mixed yarn according to 110*90 Density is knitted to carry out being woven into bed of cloth.
Further, the heating stirring mistake of fluoro-silicone emulsion is specifically carried out in the step A2 under conditions of 140-175 DEG C Journey.
Further, middle granulation extrusion temperature scope is 120-145 DEG C in the step A3；Granulating extruder head temperature For 120-125 DEG C, 140-145 DEG C of middle-end temperature, rear end is 135-138 DEG C.
Further, the gilding technology in the step A5 is plastics cold stamping process.Cold wave technology for gold is Europe in recent years High-Tech result in U.S. printing industry.It has broken traditional gold stamping traditional handicraft by hot pressing transfer anodized aluminum paper tinsel, and makes With a kind of brand-new concept --- cold press technique shifts electrochemical paper tinsel.Cold wave technology for gold not only solves many printing industry mistakes Remove insoluble technological problemses, and more importantly saved the energy, and avoid make metallic plate during to ring Polluted caused by border.Cold wave technology for gold is used to, when printing adhesive material on narrow rotary press, need to only set original Some standby additional devices.Situations such as The following present the technological process principle and its optional equipment of cold wave gold.
The present invention compared with prior art, has advantages below and beneficial effect：
The method of the present invention is rationally controlled reaction condition and prepared a kind of suitable by the proportioning between rationally controlling each reactant High intensity and the clothing fabric with preferable waterproof effect, waterproof matrix of the invention are film layer and the inside of surface covering The mechanical properties such as the solidfied material that moulding layer obtains, excellent moisture resistance, and impact resistance also excellent performance, adhesive property is good, Excellent in durability, and preparation method is simple and easy, is adapted to industrialized production power.
Embodiment
Embodiments of the invention are described below in detail.
Embodiment 1：
A kind of multifilament blended high intensity dress materials of the present embodiment, using bed of cloth as basic unit, and are provided with bed of cloth side For increasing the dope layer of perception, and covered with for keeping dope layer is long-term use of stable to be attached to bed of cloth on dope layer On film layer；The moulding layer that cloth layer surface is fitted in using gilding technology is provided with bed of cloth opposite side, wherein every layer of material The specific formula of material is as follows：Bed of cloth：Including polyphenyl dicarboxylic acid dimethyl ester fiber 50-75%, the polyacrylonitrile in terms of mass fraction Fiber 20-40% and nylon fiber 20-35%；Dope layer：Including fluoro-silicone emulsion 40-60%, the natrium nitrosum in terms of mass fraction 15-25%, talcum powder 10-15% and superfine alumina silicate 10-20%；Film layer：Increase including PE40-60%, DOP in terms of mass fraction Mould agent 30-40% and superchlorinated polyvinyl chloride resin 20-35%；Moulding layer：Including butadiene-styrene rubber 45-85%, the zinc oxide in terms of mass fraction 8-16% and hexanedioic acid dioctyl ester 20-30%.
The preparation method of the present invention, is concretely comprised the following steps：
（1）The preparation of bed of cloth：The bed of cloth as basic unit is prepared first, the polyphenyl dioctyl phthalate two taken according to mass fraction meter Methyl esters fiber, polyacrylonitrile fibre and nylon fiber obtain yarn as raw material progress blending and bed of cloth are made by machine It is standby；Wherein blending resultant yarn is 60-80 branch, and obtained mixed yarn is knitted into density according to 110*90 yarn and carries out being woven into cloth Layer.
（2）Then fluoro-silicone emulsion, natrium nitrosum, talcum powder 10-15% and superfine alumina silicate is taken according to mass fraction meter to make For dope layer raw material, first superfine alumina silicate is poured into according to mass fraction ratio heating stirring 10- is carried out in fluoro-silicone emulsion 20min, then adds into its mixed liquor natrium nitrosum and talcum powder and continues to stir 20-25min and obtain coating again；Wherein The heating stirring process of fluoro-silicone emulsion is specifically carried out under conditions of 140-175 DEG C.
（3）PE, DOP plasticizer and superchlorinated polyvinyl chloride resin are taken according to mass fraction meter to be made as film layer raw material Particle shape is standby into modified PE particle；It is 120-145 DEG C to be wherein granulated extrusion temperature scope；Granulating extruder head temperature is 120- 125 DEG C, 140-145 DEG C of middle-end temperature, rear end is 135-138 DEG C.
（4）Then coating is uniformly coated in bed of cloth side, after its stabilization forms dope layer, by ready PE Particle heats and is uniformly coated on dope layer and dope layer is completely covered；
（5）Butadiene-styrene rubber, zinc oxide and hexanedioic acid dioctyl ester are chosen using in terms of mass fraction again to carry out as the raw material of moulding layer Melting copolymerization obtains modified styrene butadiene rubber and is fitted in bed of cloth provided with being formed on dope layer opposite side face by gilding technology Moulding layer, so as to obtain clothing fabric.
Embodiment 2：
The present embodiment is on the basis of above-described embodiment 1, is further limited, including the polyphenyl dioctyl phthalate in terms of mass fraction Diformazan ester fiber 60%, polyacrylonitrile fibre 20% and nylon fiber 20%；Dope layer：Including the fluoro-silicone emulsion in terms of mass fraction 55%th, natrium nitrosum 15%, talcum powder 15% and superfine alumina silicate 15%；Film layer：Increase including PE50%, DOP in terms of mass fraction Mould agent 30% and superchlorinated polyvinyl chloride resin 20%；Moulding layer：Including the butadiene-styrene rubber 70% in terms of mass fraction, zinc oxide 9% and two Dioctyl phthalate 21%.The other parts of the present embodiment are same as the previously described embodiments, repeat no more.
Embodiment 3：
The present embodiment is on the basis of above-described embodiment 1, is further limited, the polyphenyl two including in terms of mass fraction Formic acid diformazan ester fiber 50%, polyacrylonitrile fibre 25% and nylon fiber 25%；Dope layer：Including the fluorine silicon in terms of mass fraction Emulsion 40%, natrium nitrosum 25%, talcum powder 15% and superfine alumina silicate 20%；Film layer：Including the PE45% in terms of mass fraction, DOP plasticizer 35% and superchlorinated polyvinyl chloride resin 20%；Moulding layer：Including the butadiene-styrene rubber 58% in terms of mass fraction, zinc oxide 12% With hexanedioic acid dioctyl ester 30%.The other parts of the present embodiment are same as the previously described embodiments, repeat no more.
Embodiment 4：
The present embodiment is on the basis of above-described embodiment 1, is further limited, the polyphenyl two including in terms of mass fraction Formic acid diformazan ester fiber 59%, polyacrylonitrile fibre 17% and nylon fiber 23%；Dope layer：Including the fluorine silicon in terms of mass fraction Emulsion 56%, natrium nitrosum 16%, talcum powder 14% and superfine alumina silicate 14%；Film layer：Including the PE42% in terms of mass fraction, DOP plasticizer 34% and superchlorinated polyvinyl chloride resin 23%；Moulding layer：Including the butadiene-styrene rubber 66% in terms of mass fraction, the and of zinc oxide 9% Hexanedioic acid dioctyl ester 25%.The other parts of the present embodiment are same as the previously described embodiments, repeat no more.
Embodiment 4：
The present embodiment is on the basis of above-described embodiment 1, further limits its preparation method, concretely comprises the following steps：（1）Cloth The preparation of layer：The bed of cloth as basic unit is prepared first, it is the polyphenyl dicarboxylic acid dimethyl ester fiber taken according to mass fraction meter, poly- Dralon and nylon fiber carry out that blending obtains yarn and that bed of cloth is made by machine is standby as raw material；It is wherein mixed Spun yarn is 70, and obtained mixed yarn is knitted into density according to 110*90 yarn and carries out being woven into bed of cloth.（2）Then according to Mass fraction meter takes fluoro-silicone emulsion, natrium nitrosum, talcum powder 10-15% and superfine alumina silicate as dope layer raw material, first will be super Thin alumina silicate pours into progress heating stirring 15min in fluoro-silicone emulsion according to mass fraction ratio, then adds again into its mixed liquor Enter natrium nitrosum and talcum powder and continue stirring 24min and obtain coating；Fluorine silicon breast is wherein specifically carried out under conditions of 156 DEG C The heating stirring process of liquid.（3）It is former as film layer that PE, DOP plasticizer and superchlorinated polyvinyl chloride resin are taken according to mass fraction meter Material carries out granulation, and to form modified PE particle standby；It is 120-145 DEG C to be wherein granulated extrusion temperature scope；Granulating extruder front end Temperature is 120 DEG C, 140 DEG C of middle-end temperature, and rear end is 138 DEG C；（4）Then coating is uniformly coated in bed of cloth side, treated After its stabilization forms dope layer, ready PE particles are heated and is uniformly coated on dope layer and covers dope layer completely Lid；（5）Again butadiene-styrene rubber, zinc oxide and hexanedioic acid dioctyl ester is chosen using in terms of mass fraction to be melted as the raw material of moulding layer Melt copolymerization to obtain modified styrene butadiene rubber and be fitted in bed of cloth provided with formation pressure on dope layer opposite side face by gilding technology Glue-line, so as to obtain clothing fabric.
Embodiment 5：
The present embodiment is on the basis of above-described embodiment 1, further limits its preparation method, concretely comprises the following steps：（1）Cloth The preparation of layer：The bed of cloth as basic unit is prepared first, it is the polyphenyl dicarboxylic acid dimethyl ester fiber taken according to mass fraction meter, poly- Dralon and nylon fiber carry out that blending obtains yarn and that bed of cloth is made by machine is standby as raw material；It is wherein mixed Spun yarn is 70, and obtained mixed yarn is knitted into density according to 110*90 yarn and carries out being woven into bed of cloth.（2）Then according to Mass fraction meter takes fluoro-silicone emulsion, natrium nitrosum, talcum powder 10-15% and superfine alumina silicate as dope layer raw material, first will be super Thin alumina silicate pours into progress heating stirring 17min in fluoro-silicone emulsion according to mass fraction ratio, then adds again into its mixed liquor Enter natrium nitrosum and talcum powder and continue stirring 22min and obtain coating；Fluorine silicon breast is wherein specifically carried out under conditions of 155 DEG C The heating stirring process of liquid；（3）It is former as film layer that PE, DOP plasticizer and superchlorinated polyvinyl chloride resin are taken according to mass fraction meter Material carries out granulation, and to form modified PE particle standby；It is 120-145 DEG C to be wherein granulated extrusion temperature scope；Granulating extruder front end Temperature is 124 DEG C, 145 DEG C of middle-end temperature, and rear end is 136 DEG C；（4）Then coating is uniformly coated in bed of cloth side, treated After its stabilization forms dope layer, ready PE particles are heated and is uniformly coated on dope layer and covers dope layer completely Lid；（5）Again butadiene-styrene rubber, zinc oxide and hexanedioic acid dioctyl ester is chosen using in terms of mass fraction to be melted as the raw material of moulding layer Melt copolymerization to obtain modified styrene butadiene rubber and be fitted in bed of cloth provided with formation pressure on dope layer opposite side face by gilding technology Glue-line, so as to obtain clothing fabric.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that：Not A variety of change, modification, replacement and modification can be carried out to these embodiments by departing under the principle and objective of the present invention, of the invention Scope is limited by claim and its equivalent.

Claims (5)

  1. A kind of 1. preparation method of multifilament blended high intensity dress materials, it is characterised in that：Comprise the following steps that：
    A1. the bed of cloth as basic unit is prepared first, and the polyphenyl dicarboxylic acid dimethyl ester that 50-75% is taken according to mass fraction meter is fine The nylon fiber of dimension, 20-40% polyacrylonitrile fibre and 20-35% obtains yarn as raw material progress blending and passes through machine It is standby that bed of cloth is made；
    A2. fluoro-silicone emulsion 40-60%, natrium nitrosum 15-25%, talcum powder 10-15% and ultra-fine and then according to mass fraction meter are taken Superfine alumina silicate is first poured into fluoro-silicone emulsion and added as dope layer raw material by alumina silicate 10-20% according to mass fraction ratio Thermal agitation 10-20min, then adds into its mixed liquor natrium nitrosum and talcum powder and continues to stir 20-25min and obtain again Coating；
    A3. PE40-60%, DOP plasticizer 30-40% and superchlorinated polyvinyl chloride resin 20-35% are taken as film according to mass fraction meter Layer raw material carry out granulation, and to form modified PE particle standby；
    A4. bed of cloth side uniformly and then by coating is coated in, after its stabilization forms dope layer, by ready PE particles Heat and be uniformly coated on dope layer and dope layer is completely covered；
    A5. butadiene-styrene rubber 45-85%, zinc oxide 8-16% and hexanedioic acid dioctyl ester 20-30% are chosen as pressure using in terms of mass fraction again The raw material of glue-line, which carry out melting copolymerization, to be obtained modified styrene butadiene rubber and is fitted in bed of cloth by gilding technology being provided with dope layer Opposite side forms moulding layer on face, so as to obtain clothing fabric.
  2. A kind of 2. preparation method of multifilament blended high intensity dress materials according to claim 1, it is characterised in that：Institute It is 60-80 branch to state blending resultant yarn in step A1, and obtained mixed yarn is knitted into density according to 110*90 yarn and carries out being woven into cloth The bed of material.
  3. A kind of 3. preparation method of multifilament blended high intensity dress materials according to claim 1, it is characterised in that：Institute State the heating stirring process for specifically carrying out fluoro-silicone emulsion in step A2 under conditions of 140-175 DEG C.
  4. A kind of 4. preparation method of multifilament blended high intensity dress materials according to claim 1, it is characterised in that：Institute It is 120-145 DEG C to state middle granulation extrusion temperature scope in step A3；Granulating extruder head temperature is 120-125 DEG C, middle-end temperature 140-145 DEG C of degree, rear end are 135-138 DEG C.
  5. A kind of 5. preparation method of multifilament blended high intensity dress materials according to claim 1, it is characterised in that：Institute It is plastics cold stamping process to state the gilding technology in step A5.
CN201711259077.0A 2017-12-04 2017-12-04 A kind of preparation method of multifilament blended high intensity dress materials Withdrawn CN107829311A (en)

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Application publication date: 20180323