CN107828310A - A kind of high brightness wide angle refecting material and preparation method thereof - Google Patents

A kind of high brightness wide angle refecting material and preparation method thereof Download PDF

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Publication number
CN107828310A
CN107828310A CN201711128237.8A CN201711128237A CN107828310A CN 107828310 A CN107828310 A CN 107828310A CN 201711128237 A CN201711128237 A CN 201711128237A CN 107828310 A CN107828310 A CN 107828310A
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CN
China
Prior art keywords
parts
wide angle
preparation
high brightness
brightness wide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711128237.8A
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Chinese (zh)
Inventor
武全福
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Hefei Huafu Geotextile Material Co Ltd
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Hefei Huafu Geotextile Material Co Ltd
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Application filed by Hefei Huafu Geotextile Material Co Ltd filed Critical Hefei Huafu Geotextile Material Co Ltd
Priority to CN201711128237.8A priority Critical patent/CN107828310A/en
Publication of CN107828310A publication Critical patent/CN107828310A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0806Silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to reflectorized material technical field, specifically, it is related to a kind of high brightness wide angle refecting material and preparation method thereof, it is made up of the raw material of following parts by weight, 10 30 parts of aqueous epoxy resins, 8 12 parts of aluminium powder, 26 parts of silver powder, 10 25 parts of deionized water, 46 parts of methanol, 0.1 1 parts of anti-settling agent, 0.2 5 parts of plasticizer, 20 50 parts of reflective glass beads, 10 15 parts of nanoscale reflective powder, 6 12 parts of wax liquor, 12 parts of wetting dispersing agent, 13 parts of association thickener, 13 parts of PH conditioning agents, 58 parts of additive, 0.5 2 parts of curing agent.Matching design of the present invention is reasonable, by adding plasticizer and curing agent on the basis of original, makes the metallic luster effect after spray treatment more preferable, will not fall off, fades, appearance is preferable, and product durability is stronger, substantially increases reflecting effect.

Description

A kind of high brightness wide angle refecting material and preparation method thereof
Technical field
The present invention relates to reflectorized material technical field, specifically, is related to a kind of high brightness wide angle refecting material and its system Preparation Method.
Background technology
With the development of society, the progress of science and technology, increasing vehicle benz is panoramic in face of this on road Vehicle, but sanitation cart has its special use, operation operation is carried out on road, vehicle is more on road, is particularly insulting The highlighting of vehicle color when morning or night work, will also influence its security, and existing environmental sanitation vehicles shell body is main to use Common paint processing, performance it is not bright enough, in the case of night or dark, its security also reduces, existing for it Paint typically only takes into account its anticorrosive property, persistence;Without the special use in view of its reflective, in feelings in need Condition, in the external painting last layer reflectorized paint of anti-corrosive properties paint, increase its spraying coating process complexity.
Chinese invention patent application number 201510251063.9 discloses a kind of high brightness metal reflective paint, each raw material weight Measure part aqueous epoxy resins 10-40 parts, aluminium powder 2-10 parts, silver powder 2-10 parts, 10-30 parts of deionized water, methanol 3-8 parts, anti-settling Agent 0.1-2 parts, plasticizer 0.1-1 parts, reflective glass beads 20-40 parts, 10-20 parts of nanoscale reflective powder, wax liquor 5-10 parts, 1-3 parts of wetting dispersing agent, association thickener 1-5 parts, 1-2 parts of PH conditioning agents.Instant invention overcomes the deficiencies in the prior art, Matching design is reasonable, has metallic luster effect after spray treatment, will not fall off, fades, and appearance is preferable, product durability By force, reflecting effect is good;Manufacture craft is simple and convenient.But foregoing invention lacks plasticizer and curing agent in preparation, so that system The reflectorized paint performance produced still has been short of, and durability is not high, reflecting effect is undesirable, in consideration of it, it is proposed that one Kind high brightness wide angle refecting material and preparation method thereof.
The content of the invention
Present disclosure is to provide a kind of high brightness wide angle refecting material and preparation method thereof, and it can overcome existing skill Certain or some defects of art.
A kind of high brightness wide angle refecting material according to the present invention and preparation method thereof, by the raw material system of following parts by weight Into aqueous epoxy resins 10-30 parts, aluminium powder 8-12 parts, silver powder 2-6 parts, deionized water 10-25 parts, methanol 4-6 parts, anti-settling agent 0.1-1 parts, plasticizer 0.2-5 parts, reflective glass beads 20-50 parts, nanoscale reflective powder 10-15 parts, wax liquor 6-12 parts, wetting Dispersant 1-2 parts, association thickener 1-3 parts, PH conditioning agent 1-3 parts, additive 5-8 parts, curing agent 0.5-2 parts.
Preferably, be made up of the raw material of following parts by weight, 20 parts of aqueous epoxy resins, 10 parts of aluminium powder, 4 parts of silver powder, go 15 parts of ionized water, 5 parts of methanol, 0.5 part of anti-settling agent, 0.3 part of plasticizer, 30 parts of reflective glass beads, 12 parts of nanoscale reflective powder, 10 parts of wax liquor, 1.5 parts of wetting dispersing agent, 1.5 parts of association thickener, 1.5 parts of PH conditioning agents, 6 parts of additive, 1 part of curing agent.
Preferably, described high brightness wide angle refecting viscosity of material is 25-35S.
Preferably, the reflective glass beads fineness is 100-200 mesh.
Preferably, the additive is mixed by the raw material of following parts by weight:Dysprosia 2-3 parts, nanometer palygorskite 4-6 parts, ceric hydroxide 3-4 parts, antimonous acid anhydride 5-8 parts, barium molybdate 6-12 parts, sodium tungstate 4-7 parts, basic bismuth carbonate 8-14 Part, titanium sponge 3-5 parts, antimony trisulfide 2-4 parts, zinc selenide 2-3 parts.
Preferably, the additive is mixed by the raw material of following parts by weight:2 parts of dysprosia, nanometer palygorskite 4 Part, 3 parts of ceric hydroxide, 5 parts of antimonous acid anhydride, 6 parts of barium molybdate, 4 parts of sodium tungstate, 8 parts of basic bismuth carbonate, 3 parts of titanium sponge, vulcanization 2 parts of antimony, 2 parts of zinc selenide.
Preferably, the composition of any one of the plasticizer in glucoside or ACR or both.
Preferably, any one or several composition of the curing agent in SE, GW and UP.
Compared with prior art, beneficial effects of the present invention:Matching design of the present invention is reasonable, by the basis of original Plasticizer and curing agent to be added, makes the metallic luster effect after spray treatment more preferable, will not fall off, fades, appearance is preferable, Product durability is stronger, substantially increases reflecting effect.
Embodiment
To further appreciate that present disclosure, the present invention is described in detail in conjunction with the embodiments.It is it should be appreciated that real Apply example be only the present invention is explained and and it is non-limiting.
A kind of high brightness wide angle refecting material and preparation method thereof is present embodiments provided, by the raw material system of following parts by weight Into aqueous epoxy resins 10-30 parts, aluminium powder 8-12 parts, silver powder 2-6 parts, deionized water 10-25 parts, methanol 4-6 parts, anti-settling agent 0.1-1 parts, plasticizer 0.2-5 parts, reflective glass beads 20-50 parts, nanoscale reflective powder 10-15 parts, wax liquor 6-12 parts, wetting Dispersant 1-2 parts, association thickener 1-3 parts, PH conditioning agent 1-3 parts, additive 5-8 parts, curing agent 0.5-2 parts.
In the present embodiment, be made up of the raw material of following parts by weight, 20 parts of aqueous epoxy resins, 10 parts of aluminium powder, 4 parts of silver powder, 15 parts of deionized water, 5 parts of methanol, 0.5 part of anti-settling agent, 0.3 part of plasticizer, 30 parts of reflective glass beads, nanoscale reflective powder 12 Part, 10 parts of wax liquor, 1.5 parts of wetting dispersing agent, 1.5 parts of association thickener, 1.5 parts of PH conditioning agents, 6 parts of additive, curing agent 1 Part.
In the present embodiment, described high brightness wide angle refecting viscosity of material is 25-35S.
In the present embodiment, the reflective glass beads fineness is 100-200 mesh.
In the present embodiment, the additive is mixed by the raw material of following parts by weight:Dysprosia 2-3 parts, nanometer slope thread Stone 4-6 parts, ceric hydroxide 3-4 parts, antimonous acid anhydride 5-8 parts, barium molybdate 6-12 parts, sodium tungstate 4-7 parts, basic bismuth carbonate 8-14 Part, titanium sponge 3-5 parts, antimony trisulfide 2-4 parts, zinc selenide 2-3 parts.
In the present embodiment, the additive is mixed by the raw material of following parts by weight:2 parts of dysprosia, nanometer palygorskite 4 Part, 3 parts of ceric hydroxide, 5 parts of antimonous acid anhydride, 6 parts of barium molybdate, 4 parts of sodium tungstate, 8 parts of basic bismuth carbonate, 3 parts of titanium sponge, vulcanization 2 parts of antimony, 2 parts of zinc selenide.
In the present embodiment, the composition of any one of the plasticizer in glucoside or ACR or both.
In the present embodiment, any one or several composition of the curing agent in SE, GW and UP.
The high brightness wide angle refecting material of gained in embodiment is subjected to performance test, experimental result is as follows:
Schematically the present invention and embodiments thereof are described above, the description is not restricted.So if One of ordinary skill in the art is enlightened by it, without departing from the spirit of the invention, without creatively designing Go out the scheme and embodiment similar to the technical scheme, protection scope of the present invention all should be belonged to.

Claims (8)

  1. A kind of 1. high brightness wide angle refecting material and preparation method thereof, it is characterised in that:It is made up of the raw material of following parts by weight, water Property epoxy resin 10-30 parts, aluminium powder 8-12 parts, silver powder 2-6 parts, deionized water 10-25 parts, methanol 4-6 parts, anti-settling agent 0.1-1 Part, plasticizer 0.2-5 parts, reflective glass beads 20-50 parts, nanoscale reflective powder 10-15 parts, wax liquor 6-12 parts, wetting and dispersing Agent 1-2 parts, association thickener 1-3 parts, PH conditioning agent 1-3 parts, additive 5-8 parts, curing agent 0.5-2 parts.
  2. A kind of 2. high brightness wide angle refecting material and preparation method thereof according to claim 1, it is characterised in that:By following heavy The raw material of amount part is made, 20 parts of aqueous epoxy resins, 10 parts of aluminium powder, 4 parts of silver powder, 15 parts of deionized water, 5 parts of methanol, anti-settling agent 0.5 part, 0.3 part of plasticizer, 30 parts of reflective glass beads, 12 parts of nanoscale reflective powder, 10 parts of wax liquor, 1.5 parts of wetting dispersing agent, 1.5 parts of association thickener, 1.5 parts of PH conditioning agents, 6 parts of additive, 1 part of curing agent.
  3. A kind of 3. high brightness wide angle refecting material and preparation method thereof according to claim 1, it is characterised in that:Described height Brightness wide angle refecting viscosity of material is 25-35S.
  4. A kind of 4. high brightness wide angle refecting material according to claim 1 or claim 2 and preparation method thereof, it is characterised in that:It is described Reflective glass beads fineness is 100-200 mesh.
  5. A kind of 5. high brightness wide angle refecting material according to claim 1 or claim 2 and preparation method thereof, it is characterised in that:It is described Additive is mixed by the raw material of following parts by weight:Dysprosia 2-3 parts, nanometer palygorskite 4-6 parts, ceric hydroxide 3-4 parts, Antimonous acid anhydride 5-8 parts, barium molybdate 6-12 parts, sodium tungstate 4-7 parts, basic bismuth carbonate 8-14 parts, titanium sponge 3-5 parts, antimony trisulfide 2-4 Part, zinc selenide 2-3 parts.
  6. A kind of 6. high brightness wide angle refecting material according to claim 1 or claim 2 and preparation method thereof, it is characterised in that:It is described Additive is mixed by the raw material of following parts by weight:2 parts of dysprosia, 4 parts of nanometer palygorskite, 3 parts of ceric hydroxide, antimonious acid 5 parts of acid anhydride, 6 parts of barium molybdate, 4 parts of sodium tungstate, 8 parts of basic bismuth carbonate, 3 parts of titanium sponge, 2 parts of antimony trisulfide, 2 parts of zinc selenide.
  7. A kind of 7. high brightness wide angle refecting material according to claim 1 or claim 2 and preparation method thereof, it is characterised in that:It is described The composition of any one of plasticizer in glucoside or ACR or both.
  8. A kind of 8. high brightness wide angle refecting material according to claim 1 or claim 2 and preparation method thereof, it is characterised in that:It is described Any one or several composition of the curing agent in SE, GW and UP.
CN201711128237.8A 2017-11-15 2017-11-15 A kind of high brightness wide angle refecting material and preparation method thereof Pending CN107828310A (en)

Priority Applications (1)

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CN201711128237.8A CN107828310A (en) 2017-11-15 2017-11-15 A kind of high brightness wide angle refecting material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711128237.8A CN107828310A (en) 2017-11-15 2017-11-15 A kind of high brightness wide angle refecting material and preparation method thereof

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Publication Number Publication Date
CN107828310A true CN107828310A (en) 2018-03-23

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109400992A (en) * 2018-09-03 2019-03-01 安徽新恒辉反光材料有限公司 A kind of high-brightness reflective material and its preparation process
CN111580202A (en) * 2020-05-25 2020-08-25 合肥路明反光材料有限公司 High-brightness folding-resistant reflective cloth
CN112442274A (en) * 2019-08-30 2021-03-05 中国石油化工股份有限公司 Composition for preparing seismic physical model, seismic physical model and preparation and construction methods

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109400992A (en) * 2018-09-03 2019-03-01 安徽新恒辉反光材料有限公司 A kind of high-brightness reflective material and its preparation process
CN112442274A (en) * 2019-08-30 2021-03-05 中国石油化工股份有限公司 Composition for preparing seismic physical model, seismic physical model and preparation and construction methods
CN111580202A (en) * 2020-05-25 2020-08-25 合肥路明反光材料有限公司 High-brightness folding-resistant reflective cloth

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Application publication date: 20180323