CN107815585A - A kind of special low copper high-ductility abrasive resistant casting ball of alumina powder and its production method - Google Patents

A kind of special low copper high-ductility abrasive resistant casting ball of alumina powder and its production method Download PDF

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Publication number
CN107815585A
CN107815585A CN201710969335.8A CN201710969335A CN107815585A CN 107815585 A CN107815585 A CN 107815585A CN 201710969335 A CN201710969335 A CN 201710969335A CN 107815585 A CN107815585 A CN 107815585A
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ductility
alumina powder
agent
secondary metamorphic
special low
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汪德发
徐超
汤新明
张国芳
李英虎
徐光清
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Ningguo Kaiyuan Electric Power Co Ltd & Anti-Friction Material Plant
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Ningguo Kaiyuan Electric Power Co Ltd & Anti-Friction Material Plant
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Publication of CN107815585A publication Critical patent/CN107815585A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/36Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for balls; for rollers
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • C22C33/06Making ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/08Making cast-iron alloys
    • C22C33/10Making cast-iron alloys including procedures for adding magnesium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/06Cast-iron alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/20Ferrous alloys, e.g. steel alloys containing chromium with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/36Ferrous alloys, e.g. steel alloys containing chromium with more than 1.7% by weight of carbon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/60Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur

Abstract

The invention discloses a kind of special low copper high-ductility abrasive resistant casting ball of alumina powder and its production method, by weight percentage containing following chemical composition:C 2.0 3.1%, Si 0.8 1.5%, Mn 0.4 1.0%, Cr 18.0 20.0%, S 0 0.06%, P 0 0.06%, Mo 0.05 1.0%, Cu 0 0.1%, Fe surpluses.The special low copper high-ductility abrasive resistant casting ball of alumina powder and its production method of the present invention, by optimizing composition design, secondary metamorphic processing and multi-temperature zone quenching technical, improve product hardness, reduce product abrasion and percentage of damage, the cast ball of production has the advantages of hardness is high, abrasion are low, good corrosion resistance, good toughness.

Description

A kind of special low copper high-ductility abrasive resistant casting ball of alumina powder and its production method
Technical field
The present invention relates to cast ball technical field, more particularly to a kind of special low copper high-ductility abrasive resistant casting ball of alumina powder and its life Production method.
Background technology
Abrasion is one of principal mode of workpiece failure, and abrasion causes a large amount of consumption of the energy and steel raw material.Mill Ball is the conventional medium of milling of alumina industry, and in grinding operation prepared by raw material, abrading-ball consumption is most important index.With The raising of aluminum oxide technology technique and energy-conserving and environment-protective requirement, the abrading-ball processed using traditional handicraft, its performance can not meet The requirement of aluminum oxide grinding machine so that grinding efficiency is poor, it is clear, mend, match somebody with somebody, the plan of ball is difficult to ensure that, also cause grinding machine equipment maintenance, Maintenance workload increase, dielectric dissipation increase, cost increase of milling.This not only consumes the resources such as substantial amounts of steel, ferrochrome, increase Electric power energy consumes, and reduces the production efficiency of ball mill.Therefore, constantly research to improve the performance of abrading-ball, reduces it Specific loss has great economic implications.According to incomplete statistics, China's alumina industry year 100000 tons of consumption abrading-ball amount with On, external annual about 200,000 tons of the abrading-ball demand of aluminium industry, its market is quite varied.The special low wear-resistant casting of copper high-ductility of alumina powder Ball research project, by with very strong application or industrialization prospect.The aluminum oxide produced using the inventive method is there are no at present The report of the special low copper high-ductility abrasive resistant casting ball of powder.
The content of the invention
The purpose of the present invention is overcome the deficiencies in the prior art, and section performance is ground with all kinds of cast balls for existing alumina industry Not good enough, the problem of abrasion are higher, there is provided a kind of special low copper high-ductility abrasive resistant casting ball of alumina powder and its production method, pass through optimization Composition design, secondary metamorphic processing and multi-temperature zone quenching technical, improve product hardness, reduce product abrasion and percentage of damage, it is raw The cast ball of production has the advantages of hardness is high, abrasion are low, good corrosion resistance, good toughness.
To achieve these goals, the present invention adopts the following technical scheme that:
A kind of special low copper high-ductility abrasive resistant casting ball of alumina powder, by weight percentage containing following chemical composition:C2.0- 3.1%, Si 0.8-1.5%, Mn 0.4-1.0%, Cr 18.0-20.0%, S 0-0.06%, P 0-0.06%, Mo 0.05- 1.0%, Cu 0-0.1%, Fe surplus.
The production method of the special low copper high-ductility abrasive resistant casting ball of described alumina powder, comprises the following steps:
(1) dispensing:Composition detection is carried out to steel, it is major ingredient to choose the qualified steel of C, P, S content, then ratio on request Ferrosilicon, ferromanganese, ferrochrome and molybdenum-iron are added, carries out dispensing;
(2) melting:The raw material prepared is inserted into medium frequency induction melting furnace and carries out heating melting, when molten iron temperature reaches At 1450-1480 DEG C, sampling carries out chemical composition analysis, and is finely tuned by line feeding to control the percentage by weight of each composition, when When temperature reaches 1520-1540 DEG C, precipitation desoxydation and final deoxidizing are carried out successively;
(3) molten steel by step (2) deoxidation is cooled to 1480-1500 DEG C, and collection slag agent is sprinkled into smelting furnace and scratches clean stove After interior slag, weight continues melting 3-5 minutes, completed than adding the ferro-boron, the ferrotianium that were toasted through 200 DEG C as described in claim 1 A Metamorphism treatment, comes out of the stove after final deoxidizing in stove;
(4) secondary metamorphic is handled;By weight percentage by industrial potassium nitrate 10%, the rare-earth silicon alloy through 150 DEG C of bakings 85%th, magnesium-rare earth 5% is well mixed is configured to secondary metamorphic agent;Then with the secondary metamorphic agent prepared to through once becoming Molten iron after matter processing carries out secondary metamorphic processing with pouring method in wrapping, and the weight ratio of the secondary metamorphic agent and molten iron is 0.3- 0.5:100;
(5) pour into a mould:Collection slag agent is added into the molten iron handled through secondary metamorphic and scratches clean the bits in bag, is then sprinkled into again One layer of collection slag agent, is poured into a mould after being cooled to 1460-1480 DEG C, obtains casting;
(6) it is heat-treated:Casting is warming up to 980-1000 DEG C, carries out high temperature quenching, the quenching oil temperature of oil quenching processing is 80-120 DEG C, then it is tempered at 230-280 DEG C, wherein, the soaking time of the high temperature quenching is small per the insulation 1 of 25mm wall thickness When, the soaking time of the tempering is to be incubated 1.5-2 hours per 25mm wall thickness, obtains finished product.
Product the key technical indexes of the present invention reaches:Hardness HRC >=59, impact value ak >=6.0J/cm2, ball falling impact is tired Labor life-span (number) >=16000, percentage of damage < 0.5%.By in alumina balls grinding machine comparative test, product abrasion < 330g/t raw ores, similar high-Cr grinding balls abrasion >=390/t raw ores, the product abrasion reduce by more than 17%.
Compared with the prior art, beneficial effects of the present invention are as follows:
(1) the special low copper high-ductility abrasive resistant casting ball of alumina powder of the invention and its production method, by optimizing composition design And control, control Cr, C content simultaneously suitably match (Cr/C >=6), can obtain the M7C3 type eutectic carbides of enough amounts, M7C3's Hardness isolates distribution, in nodular and chrysanthemum shape and vermiform, work is isolated to matrix up to 1200~1800HV hexagonal crystal systems With smaller, be advantageous to improve toughness and wearability;It is appropriate to increase Si contents by controlling Cu contents, improve molten steel flow, profit In deoxidation, improve eutectic carbide shape, increase eutectic carbide quantity, strengthen matrix, improve corrosion resistance;
(2) the special low copper high-ductility abrasive resistant casting ball of alumina powder of the invention and its production method, go bad by using titanium boron + Metamorphism treatment is once bred in agent (Ti/B 3/1), crystal grain thinning, improves quenching degree;Using rare earth alloy alterant (85% rare earth silicon, 5% rare earth magnesium and 10% industrial potassium nitrate) carries out secondary metamorphic processing, improves eutectic carbide form And distribution, improve toughness.
(3) the special low copper high-ductility abrasive resistant casting ball of alumina powder of the invention and its production method, quench by using multi-temperature zone Ignition technique, (austenitizing processing is warming up to 990 ± 10 DEG C in four stages, and the quenching oil temperature of oil quenching processing is 80-120 DEG C, low Warm 230-280 DEG C of temperature), each warm area temperature and time, quenching oil temperature are accurately controlled, homogeneous heating, stress is reduced, has Imitate Crack prevention to extend along eutectic carbide carbide, reduce eutectic carbide and fracture, peel off probability.
Embodiment
The present invention is further illustrated with reference to embodiments, but the present invention is not limited only to these embodiments, not On the premise of departing from present inventive concept, any improvement made is within the scope of the present invention.
Embodiment 1:
A kind of special low copper high-ductility abrasive resistant casting ball of alumina powder, by weight percentage containing following chemical composition:C2.0%, Si 0.8%, Mn 1.0%, Cr 18.0%, S 0-0.06%, P 0-0.06%, Mo 0.05%, Cu 0.1%, Fe surpluses.
The production method of the special low copper high-ductility abrasive resistant casting ball of described alumina powder, comprises the following steps:
(1) dispensing:Composition detection is carried out to steel, it is major ingredient to choose the qualified steel of C, P, S content, then ratio on request Ferrosilicon, ferromanganese, ferrochrome and molybdenum-iron are added, carries out dispensing;
(2) melting:The raw material prepared is inserted into medium frequency induction melting furnace and carries out heating melting, when molten iron temperature reaches 1450 DEG C when, sampling carries out chemical composition analysis, and is finely tuned by line feeding to control the percentage by weight of each composition, when temperature reaches At 1520 DEG C, precipitation desoxydation and final deoxidizing are carried out successively;
(3) molten steel by step (2) deoxidation is cooled to 1480 DEG C, and collection slag agent is sprinkled into smelting furnace and scratches clean slag in stove Afterwards, weight than adding the ferro-boron, the ferrotianium that were toasted through 200 DEG C, continues melting 3 minutes, completed one in stove as described in claim 1 Secondary Metamorphism treatment, comes out of the stove after final deoxidizing;
(4) secondary metamorphic is handled;By weight percentage by industrial potassium nitrate 10%, the rare-earth silicon alloy through 150 DEG C of bakings 85%th, magnesium-rare earth 5% is well mixed is configured to secondary metamorphic agent;Then with the secondary metamorphic agent prepared to through once becoming Molten iron after matter processing carries out secondary metamorphic processing with pouring method in bag, and the weight ratio of the secondary metamorphic agent and molten iron is 0.3: 100;
(5) pour into a mould:Collection slag agent is added into the molten iron handled through secondary metamorphic and scratches clean the bits in bag, is then sprinkled into again One layer of collection slag agent, is poured into a mould after being cooled to 1460 DEG C, obtains casting;
(6) it is heat-treated:Casting is warming up to 980 DEG C, carries out high temperature quenching, the quenching oil temperature of oil quenching processing is 80 DEG C, Then it is tempered at 230 DEG C, wherein, the soaking time of the high temperature quenching is to be incubated 1 hour per 25mm wall thickness, the tempering Soaking time is to be incubated 1.5 hours per 25mm wall thickness, obtains finished product.
Embodiment 2:
A kind of special low copper high-ductility abrasive resistant casting ball of alumina powder, by weight percentage containing following chemical composition:C2.5%, Si 1.0%, Mn 0.6%, Cr 20.0%, S 0-0.06%, P 0-0.06%, Mo 0.08%, Cu 0.05%, Fe surpluses.
The production method of the special low copper high-ductility abrasive resistant casting ball of described alumina powder, comprises the following steps:
(1) dispensing:Composition detection is carried out to steel, it is major ingredient to choose the qualified steel of C, P, S content, then ratio on request Ferrosilicon, ferromanganese, ferrochrome and molybdenum-iron are added, carries out dispensing;
(2) melting:The raw material prepared is inserted into medium frequency induction melting furnace and carries out heating melting, when molten iron temperature reaches 1465 DEG C when, sampling carries out chemical composition analysis, and is finely tuned by line feeding to control the percentage by weight of each composition, when temperature reaches At 1530 DEG C, precipitation desoxydation and final deoxidizing are carried out successively;
(3) molten steel by step (2) deoxidation is cooled to 1490 DEG C, and collection slag agent is sprinkled into smelting furnace and scratches clean slag in stove Afterwards, weight than adding the ferro-boron, the ferrotianium that were toasted through 200 DEG C, continues melting 4 minutes, completed one in stove as described in claim 1 Secondary Metamorphism treatment, comes out of the stove after final deoxidizing;
(4) secondary metamorphic is handled;By weight percentage by industrial potassium nitrate 10%, the rare-earth silicon alloy through 150 DEG C of bakings 85%th, magnesium-rare earth 5% is well mixed is configured to secondary metamorphic agent;Then with the secondary metamorphic agent prepared to through once becoming Molten iron after matter processing carries out secondary metamorphic processing with pouring method in bag, and the weight ratio of the secondary metamorphic agent and molten iron is 0.4: 100;
(5) pour into a mould:Collection slag agent is added into the molten iron handled through secondary metamorphic and scratches clean the bits in bag, is then sprinkled into again One layer of collection slag agent, is poured into a mould after being cooled to 1470 DEG C, obtains casting;
(6) it is heat-treated:Casting is warming up to 990 DEG C, carries out high temperature quenching, the quenching oil temperature of oil quenching processing is 100 DEG C, Then it is tempered at 250 DEG C, wherein, the soaking time of the high temperature quenching is to be incubated 1 hour per 25mm wall thickness, the tempering Soaking time is to be incubated 1.8 hours per 25mm wall thickness, obtains finished product.
Embodiment 3:
A kind of special low copper high-ductility abrasive resistant casting ball of alumina powder, by weight percentage containing following chemical composition:C3.1%, Si 1.5%, Mn 1.0%, Cr 20.0%, S 0-0.06%, P 0-0.06%, Mo 1.0%, Cu 0.1%, Fe surpluses.
The production method of the special low copper high-ductility abrasive resistant casting ball of described alumina powder, comprises the following steps:
(1) dispensing:Composition detection is carried out to steel, it is major ingredient to choose the qualified steel of C, P, S content, then ratio on request Ferrosilicon, ferromanganese, ferrochrome and molybdenum-iron are added, carries out dispensing;
(2) melting:The raw material prepared is inserted into medium frequency induction melting furnace and carries out heating melting, when molten iron temperature reaches 1480 DEG C when, sampling carries out chemical composition analysis, and is finely tuned by line feeding to control the percentage by weight of each composition, when temperature reaches At 1540 DEG C, precipitation desoxydation and final deoxidizing are carried out successively;
(3) molten steel by step (2) deoxidation is cooled to 1500 DEG C, and collection slag agent is sprinkled into smelting furnace and scratches clean slag in stove Afterwards, weight than adding the ferro-boron, the ferrotianium that were toasted through 200 DEG C, continues melting 5 minutes, completed one in stove as described in claim 1 Secondary Metamorphism treatment, comes out of the stove after final deoxidizing;
(4) secondary metamorphic is handled;By weight percentage by industrial potassium nitrate 10%, the rare-earth silicon alloy through 150 DEG C of bakings 85%th, magnesium-rare earth 5% is well mixed is configured to secondary metamorphic agent;Then with the secondary metamorphic agent prepared to through once becoming Molten iron after matter processing carries out secondary metamorphic processing with pouring method in bag, and the weight ratio of the secondary metamorphic agent and molten iron is 0.5: 100;
(5) pour into a mould:Collection slag agent is added into the molten iron handled through secondary metamorphic and scratches clean the bits in bag, is then sprinkled into again One layer of collection slag agent, is poured into a mould after being cooled to 1480 DEG C, obtains casting;
(6) it is heat-treated:Casting is warming up to 1000 DEG C, carries out high temperature quenching, the quenching oil temperature of oil quenching processing is 120 DEG C, then it is tempered at 280 DEG C, wherein, the soaking time of the high temperature quenching is to be incubated 1 hour, described time per 25mm wall thickness The soaking time of fire is to be incubated 2 hours per 25mm wall thickness, obtains finished product.

Claims (2)

  1. A kind of 1. special low copper high-ductility abrasive resistant casting ball of alumina powder, it is characterised in that:By weight percentage containing it is following chemistry into Point:C 2.0-3.1%, Si 0.8-1.5%, Mn 0.4-1.0%, Cr 18.0-20.0%, S 0-0.06%, P 0- 0.06%, Mo 0.05-1.0%, Cu 0-0.1%, Fe surplus.
  2. A kind of 2. production method of the special low copper high-ductility abrasive resistant casting ball of alumina powder as claimed in claim 1, it is characterised in that: Comprise the following steps:
    (1) dispensing:Composition detection is carried out to steel, it is major ingredient to choose the qualified steel of C, P, S content, then ratio adds on request Ferrosilicon, ferromanganese, ferrochrome and molybdenum-iron, carry out dispensing;
    (2) melting:The raw material prepared is inserted into medium frequency induction melting furnace and carries out heating melting, when molten iron temperature reaches 1450- At 1480 DEG C, sampling carries out chemical composition analysis, and is finely tuned by line feeding to control the percentage by weight of each composition, when temperature reaches During to 1520-1540 DEG C, precipitation desoxydation and final deoxidizing are carried out successively;
    (3) molten steel by step (2) deoxidation is cooled to 1480-1500 DEG C, and collection slag agent is sprinkled into smelting furnace and scratches clean slag in stove Afterwards, weight than adding the ferro-boron, the ferrotianium that were toasted through 200 DEG C, continues melting 3-5 minutes, completed in stove as described in claim 1 Metamorphism treatment, comes out of the stove after final deoxidizing;
    (4) secondary metamorphic is handled;By weight percentage by industrial potassium nitrate 10%, through 150 DEG C baking rare-earth silicon alloy 85%, Magnesium-rare earth 5% is well mixed to be configured to secondary metamorphic agent;Then with the secondary metamorphic agent prepared to through the place that once goes bad Molten iron after reason carries out secondary metamorphic processing with pouring method in bag, and the weight ratio of the secondary metamorphic agent and molten iron is 0.3-0.5: 100;
    (5) pour into a mould:Collection slag agent is added into the molten iron handled through secondary metamorphic and scratches clean the bits in bag, is then sprinkled into one layer again Collect slag agent, poured into a mould after being cooled to 1460-1480 DEG C, obtain casting;
    (6) it is heat-treated:Casting is warming up to 980-1000 DEG C, carries out high temperature quenching, the quenching oil temperature of oil quenching processing is 80- 120 DEG C, then it is tempered at 230-280 DEG C, wherein, the soaking time of the high temperature quenching is to be incubated 1 hour per 25mm wall thickness, The soaking time of the tempering is to be incubated 1.5-2 hours per 25mm wall thickness, obtains finished product.
CN201710969335.8A 2017-10-18 2017-10-18 A kind of special low copper high-ductility abrasive resistant casting ball of alumina powder and its production method Pending CN107815585A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108796390A (en) * 2018-06-29 2018-11-13 中山市恒翔不锈钢丸有限公司 A kind of new grinding-material of the alloy of high rigidity and its manufacturing process
CN109576597A (en) * 2018-11-20 2019-04-05 湘潭大学 Ferrous alloy and preparation method thereof, outer tube and internal heater
CN113755742A (en) * 2021-08-05 2021-12-07 宁国东方碾磨材料股份有限公司 High-hardness chromium alloy cast ball

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Publication number Priority date Publication date Assignee Title
CN1038844A (en) * 1989-04-17 1990-01-17 丰润县合金铸件厂 HI-chrome cast iron for grinding balls
CN1054100A (en) * 1991-03-10 1991-08-28 朴铁军 The new high chromium cast iron manufacture method that is used for highly abrasive parts using
CN103667866A (en) * 2013-11-16 2014-03-26 宁国市开源电力耐磨材料有限公司 Special high-chromium grinding ball for mining and secondary modification processing technique thereof
CN103667865A (en) * 2013-11-16 2014-03-26 宁国市开源电力耐磨材料有限公司 Ultrahigh-wear-resistance high-chromium multi-alloy grinding ball and composite modification processing technique thereof
CN105177404A (en) * 2015-09-10 2015-12-23 宁国市开源电力耐磨材料有限公司 High anti-wear micro-copper alloy cast ball and processing technique thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1038844A (en) * 1989-04-17 1990-01-17 丰润县合金铸件厂 HI-chrome cast iron for grinding balls
CN1054100A (en) * 1991-03-10 1991-08-28 朴铁军 The new high chromium cast iron manufacture method that is used for highly abrasive parts using
CN103667866A (en) * 2013-11-16 2014-03-26 宁国市开源电力耐磨材料有限公司 Special high-chromium grinding ball for mining and secondary modification processing technique thereof
CN103667865A (en) * 2013-11-16 2014-03-26 宁国市开源电力耐磨材料有限公司 Ultrahigh-wear-resistance high-chromium multi-alloy grinding ball and composite modification processing technique thereof
CN105177404A (en) * 2015-09-10 2015-12-23 宁国市开源电力耐磨材料有限公司 High anti-wear micro-copper alloy cast ball and processing technique thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108796390A (en) * 2018-06-29 2018-11-13 中山市恒翔不锈钢丸有限公司 A kind of new grinding-material of the alloy of high rigidity and its manufacturing process
CN109576597A (en) * 2018-11-20 2019-04-05 湘潭大学 Ferrous alloy and preparation method thereof, outer tube and internal heater
CN113755742A (en) * 2021-08-05 2021-12-07 宁国东方碾磨材料股份有限公司 High-hardness chromium alloy cast ball

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