CN107815252A - A kind of environmental protection coating material of a construction molding and preparation method thereof - Google Patents
A kind of environmental protection coating material of a construction molding and preparation method thereof Download PDFInfo
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- CN107815252A CN107815252A CN201711248558.1A CN201711248558A CN107815252A CN 107815252 A CN107815252 A CN 107815252A CN 201711248558 A CN201711248558 A CN 201711248558A CN 107815252 A CN107815252 A CN 107815252A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
- C08L2205/20—Hollow spheres
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
A kind of environmental protection coating material of a construction molding and preparation method thereof, the coating includes:Water, polyvinyl alcohol, modified associative fiber type element, dispersant, wetting agent, citric acid, defoamer, antimildew disinfectant, rutile type titanium white, filler, bentonite, coalescents, ethylene glycol, water-based emulsion, Opacifying polymers, pH value regulator and solvay-type organo-metallic compound class thickener.Methods described is:(1)Yu Shuizhong adds modified associative fiber type element and polyvinyl alcohol;(2)Dispersant, wetting agent, citric acid, defoamer, antimildew disinfectant are added, adds rutile type titanium white, filler, bentonite;(3)Grinding distribution, add coalescents, ethylene glycol, water-based emulsion, Opacifying polymers;(4)PH value is adjusted, adds solvay-type organo-metallic compound class thickener, is filtered,.Coating of the present invention without dilution, can a construction molding, cost is low;The inventive method is simple and convenient, and cost is low.
Description
Technical field
The present invention relates to a kind of environmental protection coating material and preparation method thereof, and in particular to a kind of environmental protection coating material of a construction molding
And preparation method thereof.
Background technology
At present, there are two technological deficiencies in building coating product on the market:
(1)Most of building coating product is constructed after being required for dilution, in this link being diluted to building coating product,
Also tend to easily go wrong:1)Cost of labor is gradually increasing, and the workload of workmen can be increased by being watered dilution, time-consuming
Arduously, operating expenses expenditure is caused to rise;2)Workmen often advises according to oneself experience and preference, rather than according to product
Fixed dilution ratio carries out being watered dilution, and which results in film quality risk;3)Workmen is anxious for success, not mixed during dilution
Conjunction uniformly begins to construct, and causes coating thickness uneven.
(2)Traditional building coating product construction technology is the construction technology of twice of finish paint of a priming paint, to 2010 with
Come, the ratio shared by the cost of labor and material cost of domestic coating industry changes year by year, and cost of labor is increasingly
It is high.Simplify construction technology, greatly develop time saving, saving of labor, labour-saving product turns into the task of top priority.
Hollow beads disclosed in heat reflection paint with hollow glass microballoon disclosed in CN101712835A and CN101831229A
The formula of insulating mold coating, it is a kind of to add coating of the hollow beads as main heat-barrier material, is saved as building wall
Insulation, cooling function use.But want to reach preferable effect of heat insulation, product must support the use from bottom to face, Er Qieshi
Work is complicated, and cost of labor is higher.
It would therefore be highly desirable to research and develop it is a kind of without dilution, without twice of the finish paint construction of a priming paint, can a construction molding, save
When, it is saving of labor, laborsaving, moreover it is possible to reach the environmental protection coating material of existing coating decorative effect.
The content of the invention
The technical problems to be solved by the invention are to overcome drawbacks described above existing for prior art, there is provided a kind of without dilute
Release, can a construction molding, cost is low, and efficiency of construction is high, the environmental protection coating material of a construction molding of good decorating effect.
Further technical problems to be solved of the invention are to overcome drawbacks described above existing for prior art, there is provided Yi Zhongsuo
The coating of preparation is uniform, stability is good, and simple and convenient, cost is low, is suitable for the environmental protection of a construction molding of industrialized production
The preparation method of coating.
The technical solution adopted for the present invention to solve the technical problems is as follows:A kind of environmental protection coating material of a construction molding,
Comprising:Water, polyvinyl alcohol, modified associative fiber type element, dispersant, wetting agent, citric acid, defoamer, antimildew disinfectant, golden red
Stone-type titanium dioxide, filler, bentonite, coalescents, ethylene glycol, water-based emulsion, Opacifying polymers, pH value regulator and complexing
Type organo-metallic compound class thickener.In coating of the present invention, the polyvinyl alcohol of addition so that this coating has longer surface drying
Time, it is not in the phenomenon of lapping defect of growing dim on the big metope of water absorption rate to ensure product;The modified associative fiber type element of addition,
So that this coating has excellent flow leveling, ensure this coating when not being diluted with water with good workability;Add
Opacifying polymers so that this coating has superpower covering power, ensures that this coating need to only construct one time and can reach screening
The effect of base material;The solvay-type organo-metallic compound class thickener and wetting agent of addition, viscosity stabilization can be kept, and caused
This coating can store for a long time, without being layered;Citric acid, the antimildew disinfectant of addition, are not easy the metope for being coated with this coating
Mouldy blackening.
Preferably, the parts by weight of each raw material of environmental protection coating material of a construction molding are:15~35 parts of water, polyvinyl alcohol 1
~5 parts, 0.2~1.0 part of modified associative fiber type element, 0.5~1.0 part of dispersant, 0.1~0.5 part of wetting agent, citric acid 0.1
~0.3 part, 0.2~0.6 part of defoamer, 0.1~1.0 part of antimildew disinfectant, 10~25 parts of rutile type titanium white, filler 15~
40 parts, 0.1~0.8 part of bentonite, 0.5~1.5 part of coalescents, 0.5~1.5 part of ethylene glycol, 10~30 parts of water-based emulsion, no
10~20 parts of transparent polymer, 0.1~0.4 part of pH value regulator, solvay-type organo-metallic compound class thickener 0.1~0.4
Part.
Preferably, when the dosage of water-based emulsion is the 10~20% of gross mass, and the dosage of rutile type titanium white is total matter
Amount 10~15% when, the environmental protection coating material is only applicable to as indoor construction coating.
Preferably, as the > 20~34% that the dosage of water-based emulsion is gross mass, and the dosage of rutile type titanium white is total
During > 15~30% of quality, the environmental protection coating material is not only suitable for as indoor construction coating, is suitable as outdoor construction painting again
Material.
Preferably, modified associative fiber type element be hydroxyethyl cellulose, carboxymethyl cellulose, hydroxymethyl cellulose or
One or more in hydroxypropyl cellulose etc..It is highly preferred that hydroxyl of the modified associative fiber type element for South Korea's Samsung production
Ethyl cellulose B30K, hydroxypropyl cellulose HPMC-100000 or carboxymethyl cellulose model MHPC-100000.
Preferably, the filler is the one or more in calcium carbonate, talcum powder or kaolin etc..
Preferably, the coalescents are alcohol ester 12.
Preferably, the water-based emulsion is Styrene-acrylic copolymer, vinyl acetate-acrylic copolymer or pure
One or more in acrylate copolymer etc..
Preferably, the Opacifying polymers are hollow polymer spheroid.It is further preferred that the hollow polymer spheroid is by moral
Sa Masuo Chemical Co., Ltd.s of state produce, model UD8280.
Preferably, the pH value regulator is 2-amino-2-methyl-1-propanol.It is highly preferred that the 2- amino -2- first
Base -1- propyl alcohol is produced by DOW Chemical, model AMP-95.
Preferably, the solvay-type organo-metallic compound class thickener is that amino alcohol is complexed titanate ester thickener.More
Preferably, the amino alcohol complexing titanate ester thickener foretells the production of inside door company by Britain.The solvay-type Organometallic compounds
Species thickener has the function that the structural thickening of emulsion paint by the effect of hydrogen bond and water.
Technical scheme is as follows used by the present invention further solves its technical problem:A kind of environmental protection of a construction molding
The preparation method of coating, comprises the following steps:
(1)Under agitation, modified associative fiber type element and polyvinyl alcohol are added in water, is evenly stirred until transparent solution;
(2)In step(1)In gained clear solution, dispersant, wetting agent, citric acid, defoamer, antimildew disinfectant are added, is stirred
After mixing uniformly, rutile type titanium white, filler, bentonite are added, is stirred, obtains compound 1;
(3)By step(2)Gained compound 1 is ground scattered, is placed in paint pot, adds coalescents, second while stirring
Glycol, water-based emulsion, Opacifying polymers, stir, and obtain compound 2;
(4)With pH value regulator regulating step(3)The pH value of gained compound 2 adds solvay-type organometallic to 8~9
Compound class thickener to viscosity is 65~70KU, is stirred, screen filtration,.
Preferably, step(1)In, the speed of the stirring is 400~600 turns/min.
Preferably, step(2)In, the speed of the stirring is 600~800 turns/min.
Preferably, step(3)In, grinding distribution to fineness reaches≤70 μm.
Preferably, step(3)In, the speed of the stirring is 600~800 turns/min.
Preferably, step(4)In, the speed of the stirring is 400~500 turns/min.
Preferably, step(4)In, the mesh number of the screen cloth is 80~120 mesh.
The construction method of coating of the present invention is:Roller coating or airless spraying.
Beneficial effects of the present invention are as follows:
(1)Environmental protection coating material of the present invention complies fully with building inner, external wall coating,《GB/T9756-2009 synthetic resin emulsions interior wall applies
Material》、《GB/T9755-2014 exterior wall coating material of synthetic resin emulsion》Technical indicator;
(2)Coating of the present invention construction when need not be watered dilution, can a construction molding, at least dropped relative to existing coating application
Low 1/2 cost of labor, efficiency of construction is improved, and avoid the occurrence of existing priming paint because dilution ratio is incorrect or uneven
It is even, cause caused quality problems after construction;
(3)Coating prepared by the preparation method of coating of the present invention is uniform, stability is good, and simple and convenient, cost is low, is suitable for work
Industry metaplasia is produced.
Embodiment
With reference to embodiment, the invention will be further described.
The model B30K of hydroxyethyl cellulose used in the embodiment of the present invention, the model of hydroxypropyl cellulose
HPMC-100000, the model MHPC-100000 of carboxymethyl cellulose, is purchased from South Korea's Samsung;The embodiment of the present invention is used
Hollow polymer spheroid be purchased from German Sa Masuo Chemical Co., Ltd.s, model UD8280;Used in the embodiment of the present invention
2-amino-2-methyl-1-propanol is purchased from DOW Chemical, model AMP-95;Amino alcohol used in the embodiment of the present invention is complexed
Titanate ester thickener is purchased from Britain and foretells inside door company;Chemical reagent used in the embodiment of the present invention, unless otherwise specified,
Obtained by routine business approach.
The environmental protection coating material embodiment 1~3 of a time construction molding
The dosage of 1~3 each raw material of environmental protection coating material embodiment of a time construction molding is as shown in table 1:
1~3 each raw material of environmental protection coating material embodiment of 1 times construction moldings of table uses scale
Wherein, the environmental protection coating material embodiment 1,2 of a construction molding is suitable as interior wall coating;The environmental protection of a time construction molding
Paint Examples 3 are suitable as inner, external wall coating.
Note:"-" represents to be not added with table.
The preparation method embodiment 1 of the environmental protection coating material of a time construction molding
(1)According to parts by weight described in 1 embodiment of table, 1 each raw material, under the stirring of 400 turns/min speed, modified form is added in water
Mould assembly cellulose and polyvinyl alcohol, under 400 turns/min speed, it is evenly stirred until transparent solution;
(2)According to parts by weight described in 1 embodiment of table, 1 each raw material, in step(1)In gained clear solution, dispersant, wetting are added
Agent, citric acid, defoamer, antimildew disinfectant, under 600 turns/min speed, after stirring, add rutile titanium dioxide
Powder, filler, bentonite, under 600 turns/min speed, stir, obtain compound 1;
(3)According to parts by weight described in 1 embodiment of table, 1 each raw material, by step(2)Gained compound 1, which is ground, is dispersed to fineness
For≤65 μm, be placed in paint pot, under 800 turns/min speed, while stirring add coalescents, ethylene glycol, water-based emulsion,
Opacifying polymers, under 800 turns/min speed, stir, obtain compound 2;
(4)According to parts by weight described in 1 embodiment of table, 1 each raw material, with pH value regulator regulating step(3)The pH of gained compound 2
Value is to 8, and it is 70KU to add solvay-type organo-metallic compound class thickener to viscosity, and under 400 turns/min speed, stirring is equal
It is even, with 80 mesh sieve net filtrations,.
The preparation method embodiment 2 of the environmental protection coating material of a time construction molding
(1)According to parts by weight described in 1 embodiment of table, 2 each raw material, under the stirring of 500 turns/min speed, modified form is added in water
Mould assembly cellulose and polyvinyl alcohol, under 500 turns/min speed, it is evenly stirred until transparent solution;
(2)According to parts by weight described in 1 embodiment of table, 2 each raw material, in step(1)In gained clear solution, dispersant, wetting are added
Agent, citric acid, defoamer, antimildew disinfectant, under 700 turns/min speed, after stirring, add rutile titanium dioxide
Powder, filler, bentonite, under 700 turns/min speed, stir, obtain compound 1;
(3)According to parts by weight described in 1 embodiment of table, 2 each raw material, by step(2)Gained compound 1, which is ground, is dispersed to fineness
For≤70 μm, be placed in paint pot, under 700 turns/min speed, while stirring add coalescents, ethylene glycol, water-based emulsion,
Opacifying polymers, under 700 turns/min speed, stir, obtain compound 2;
(4)According to parts by weight described in 1 embodiment of table, 2 each raw material, with pH value regulator regulating step(3)The pH of gained compound 2
Value is to 9, and it is 69KU to add solvay-type organo-metallic compound class thickener to viscosity, and under 500 turns/min speed, stirring is equal
It is even, with 100 mesh sieve net filtrations,.
The preparation method embodiment 3 of the environmental protection coating material of a time construction molding
(1)According to parts by weight described in 1 embodiment of table, 3 each raw material, under the stirring of 600 turns/min speed, modified form is added in water
Mould assembly cellulose and polyvinyl alcohol, under 600 turns/min speed, it is evenly stirred until transparent solution;
(2)According to parts by weight described in 1 embodiment of table, 3 each raw material, in step(1)In gained clear solution, dispersant, wetting are added
Agent, citric acid, defoamer, antimildew disinfectant, under 800 turns/min speed, after stirring, add rutile titanium dioxide
Powder, filler, bentonite, under 800 turns/min speed, stir, obtain compound 1;
(3)According to parts by weight described in 1 embodiment of table, 3 each raw material, by step(2)Gained compound 1, which is ground, is dispersed to fineness
For≤60 μm, be placed in paint pot, under 600 turns/min speed, while stirring add coalescents, ethylene glycol, water-based emulsion,
Opacifying polymers, under 600 turns/min speed, stir, obtain compound 2;
(4)According to parts by weight described in 1 embodiment of table, 3 each raw material, with pH value regulator regulating step(3)The pH of gained compound 2
Value is to 8, and it is 70KU to add solvay-type organo-metallic compound class thickener to viscosity, and under 400 turns/min speed, stirring is equal
It is even, with 120 mesh sieve net filtrations,.
Performance test one:
By the main performance of the environmental protection coating material embodiment 1,2 of a construction molding with《In GB/T9756-2009 synthetic resin emulsions
Wall coating》Technical indicator be compared, the main performance of the environmental protection coating material embodiment 3 of a construction molding with《GB/T9755-
2014 exterior wall coating material of synthetic resin emulsion》Technical indicator be compared, its performance characterization result is shown in Table 2, table 3 respectively.
The environmental protection coating material embodiment 1 of 2 times construction moldings of table, 2 performance characterization tables
It is well known that on the market traditional coating due to initial viscosity it is too high, must be carried out during use with water necessarily
Just can be with construction usage after the dilution of ratio.However, the solids content reduction of product necessarily causes to hide after being diluted due to coating
Lid power declines, and it is difficult to be completely covered by base material to construct one time, and has the function that decoration protection metope.As shown in Table 2, the present invention is real
The initial viscosity of applying the environmental protection coating material of time construction molding of gained of example 1,2 is low, strong covering power, can reach directly construct will
Ask, while the technical indicator of dope for inner wall of architecture can be reached, the decoration particularly suitable for inner wall of building uses.
The performance characterization table of environmental protection coating material embodiment 3 of 3 times construction moldings of table
It is well known that on the market traditional coating due to initial viscosity it is too high, must be carried out during use with water necessarily
Just can be with construction usage after the dilution of ratio.However, the solids content reduction of product necessarily causes to hide after being diluted due to coating
Lid power declines, and it is difficult to be completely covered by base material to construct one time, and has the function that decoration protection metope.As shown in Table 3, the present invention is real
It is low to apply the initial viscosity of the environmental protection coating material of time construction molding of gained of example 3, strong covering power, good weatherability, alkaline-resisting, water-tolerant,
The requirement directly constructed can be reached, while the technical indicator of building external paint can be reached, particularly suitable for external wall
Decoration uses.
Performance test two:
By the environmental protection coating material of time construction molding of gained of the embodiment of the present invention 1 and certain commercially available brand coating, using roller construct into
Row effect compares;Construction temperature:32 DEG C, humidity of constructing:65%, weather condition:It is fine, base material situation:Indoor smooth metope, construction
Method:Roller coating;As a result it is as shown in table 4.
The environmental protection coating material of the 1 times construction moldings of embodiment of table 4 and certain commercially available brand coating application effect performance contrast table
As shown in Table 4, the environmental protection coating material of a time construction molding of the gained of the embodiment of the present invention 1 is relative to commercial coating, in identical
Under the conditions of construct, without adding water, covering effect is significantly better than commercial coating, the particularly cost in terms of artificial and material,
6 one-tenth of only existing coating application.
By the environmental protection coating material of time construction molding of gained of the embodiment of the present invention 2 and certain commercially available brand coating, applied using roller
Work carries out effect comparison;Construction temperature:32 DEG C, humidity of constructing:65%, weather condition:It is fine, base material situation:The indoor poor wall of processing
Face, construction method:Roller coating;As a result it is as shown in table 5.
The environmental protection coating material of the 2 times construction moldings of embodiment of table 5 and certain commercially available brand coating application effect performance contrast table
As shown in Table 5, the environmental protection coating material of a time construction molding of the gained of the embodiment of the present invention 2 is relative to commercial coating, in identical
Under the conditions of construct, without adding water, when handling poor metope, its covering effect is better than commercial coating from far away, particularly exists
Cost in terms of artificial and material, 6 one-tenth of only existing coating application.
By the environmental protection coating material of time construction molding of gained of the embodiment of the present invention 3 and certain commercially available brand coating, applied using roller
Work carries out effect comparison;Construction temperature:32 DEG C, humidity of constructing:65%, weather condition:It is fine, base material situation:Outdoor smooth metope,
Construction method:Roller coating;As a result it is as shown in table 6.
The environmental protection coating material of the 3 times construction moldings of embodiment of table 6 and certain commercially available brand coating application effect performance contrast table
As shown in Table 6, the environmental protection coating material of a time construction molding of the gained of the embodiment of the present invention 3 is relative to commercial coating, in identical
Under the conditions of construct, without adding water, when handling outdoor wall surface, its covering effect is better than commercial coating from far away, particularly in people
Cost in terms of work and material, 6 one-tenth of only existing coating application.
To sum up, the environmental protection coating material of a construction molding obtained by the embodiment of the present invention is either used for indoor or room exterior wall
Face, in the case where that need not dilute, it is only necessary to roller coating 1 time, you can reach good decorative effect, cost is low, and efficiency of construction is high.
Claims (9)
1. a kind of environmental protection coating material of a construction molding, it is characterised in that include:Water, polyvinyl alcohol, modified associative fiber type
Element, dispersant, wetting agent, citric acid, defoamer, antimildew disinfectant, rutile type titanium white, filler, bentonite, film forming help
Agent, ethylene glycol, water-based emulsion, Opacifying polymers, pH value regulator and solvay-type organo-metallic compound class thickener.
2. the environmental protection coating material of a construction molding according to claim 1, it is characterised in that the parts by weight of each raw material are:
15~35 parts of water, 1~5 part of polyvinyl alcohol, 0.2~1.0 part of modified associative fiber type element, 0.5~1.0 part of dispersant, wetting agent
0.1~0.5 part, 0.1~0.3 part of citric acid, 0.2~0.6 part of defoamer, 0.1~1.0 part of antimildew disinfectant, rutile type titanium
10~25 parts of white powder, 15~40 parts of filler, 0.1~0.8 part of bentonite, 0.5~1.5 part of coalescents, ethylene glycol 0.5~1.5
Part, 10~30 parts of water-based emulsion, 10~20 parts of Opacifying polymers, 0.1~0.4 part of pH value regulator, solvay-type organic metal
0.1~0.4 part of compounds thickener.
3. the environmental protection coating material of a construction molding according to claim 1 or claim 2, it is characterised in that:When the dosage of water-based emulsion
For the 10~20% of gross mass, and when the dosage of rutile type titanium white is the 10~15% of gross mass, the environmental protection coating material is only suitable
For as indoor construction coating;When the > 20~34% that the dosage of water-based emulsion is gross mass, and the use of rutile type titanium white
When measuring > 15~30% for gross mass, the environmental protection coating material is not only suitable for, as indoor construction coating, being suitable as outdoor again
Construction paint.
4. according to the environmental protection coating material of one of claims 1 to 3 construction molding, it is characterised in that:The modified associative
Fiber type element is the one or more in hydroxyethyl cellulose, carboxymethyl cellulose, hydroxymethyl cellulose or hydroxypropyl cellulose;
The filler is the one or more in calcium carbonate, talcum powder or kaolin;The coalescents are alcohol ester 12;It is described water-based
Emulsion be Styrene-acrylic copolymer, vinyl acetate-acrylic copolymer or one kind in pure acrylic acid ester copolymer or
It is several;The Opacifying polymers are hollow polymer spheroid;The pH value regulator is 2-amino-2-methyl-1-propanol;Institute
State solvay-type organo-metallic compound class thickener and be complexed titanate ester thickener for amino alcohol.
5. according to the preparation method of the environmental protection coating material of one of Claims 1 to 4 construction molding, it is characterised in that bag
Include following steps:
(1)Under agitation, modified associative fiber type element and polyvinyl alcohol are added in water, is evenly stirred until transparent solution;
(2)In step(1)In gained clear solution, dispersant, wetting agent, citric acid, defoamer, antimildew disinfectant are added, is stirred
After mixing uniformly, rutile type titanium white, filler, bentonite are added, is stirred, obtains compound 1;
(3)By step(2)Gained compound 1 is ground scattered, is placed in paint pot, adds coalescents, second while stirring
Glycol, water-based emulsion, Opacifying polymers, stir, and obtain compound 2;
(4)With pH value regulator regulating step(3)The pH value of gained compound 2 adds solvay-type organometallic to 8~9
Compound class thickener to viscosity is 65~70KU, is stirred, screen filtration,.
6. the preparation method of the environmental protection coating material of a construction molding according to claim 5, it is characterised in that:Step(1)In,
The speed of the stirring is 400~600 turns/min.
7. according to the preparation method of the environmental protection coating material of the construction molding of claim 5 or 6, it is characterised in that:Step(2)
In, the speed of the stirring is 600~800 turns/min.
8. according to the preparation method of the environmental protection coating material of one of claim 5~7 construction molding, it is characterised in that:Step
Suddenly(3)In, grinding distribution to fineness reaches≤70 μm;The speed of the stirring is 600~800 turns/min.
9. according to the preparation method of the environmental protection coating material of one of claim 5~8 construction molding, it is characterised in that:Step
Suddenly(4)In, the speed of the stirring is 400~500 turns/min;The mesh number of the screen cloth is 80~120 mesh.
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CN201711248558.1A Pending CN107815252A (en) | 2017-12-01 | 2017-12-01 | A kind of environmental protection coating material of a construction molding and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114736574A (en) * | 2022-05-06 | 2022-07-12 | 龙牌涂料(北京)有限公司 | Environment-friendly interior wall coating without flowering after being applied and preparation method thereof |
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CN103540202A (en) * | 2013-09-28 | 2014-01-29 | 三棵树涂料股份有限公司 | Thinning-free one-time brush-molded latex paint finishing coat and preparation method thereof |
CN104610828A (en) * | 2014-12-25 | 2015-05-13 | 三棵树涂料股份有限公司 | Double-function aqueous emulsion paint and preparation method thereof |
CN105038353A (en) * | 2015-07-13 | 2015-11-11 | 中山市泰莱涂料化工有限公司 | Low-VOC zero-DEC G film-forming anti-formaldehyde interiro wall latex paint |
CN105440830A (en) * | 2015-12-17 | 2016-03-30 | 三棵树涂料股份有限公司 | Inner wall paint with low viscosity, strong covering performance, and strong scrubbing resistant performance and preparation method thereof |
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CN103540202A (en) * | 2013-09-28 | 2014-01-29 | 三棵树涂料股份有限公司 | Thinning-free one-time brush-molded latex paint finishing coat and preparation method thereof |
CN104610828A (en) * | 2014-12-25 | 2015-05-13 | 三棵树涂料股份有限公司 | Double-function aqueous emulsion paint and preparation method thereof |
CN105038353A (en) * | 2015-07-13 | 2015-11-11 | 中山市泰莱涂料化工有限公司 | Low-VOC zero-DEC G film-forming anti-formaldehyde interiro wall latex paint |
CN105440830A (en) * | 2015-12-17 | 2016-03-30 | 三棵树涂料股份有限公司 | Inner wall paint with low viscosity, strong covering performance, and strong scrubbing resistant performance and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114736574A (en) * | 2022-05-06 | 2022-07-12 | 龙牌涂料(北京)有限公司 | Environment-friendly interior wall coating without flowering after being applied and preparation method thereof |
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