CN107805464A - A kind of novel advertisement film with porous structural adhesive layer - Google Patents
A kind of novel advertisement film with porous structural adhesive layer Download PDFInfo
- Publication number
- CN107805464A CN107805464A CN201711211928.4A CN201711211928A CN107805464A CN 107805464 A CN107805464 A CN 107805464A CN 201711211928 A CN201711211928 A CN 201711211928A CN 107805464 A CN107805464 A CN 107805464A
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- China
- Prior art keywords
- porous
- adhesive layer
- advertisement film
- structural adhesive
- film
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J107/00—Adhesives based on natural rubber
- C09J107/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2407/00—Presence of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2409/00—Presence of diene rubber
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/10—Presence of homo or copolymers of propene
- C09J2423/106—Presence of homo or copolymers of propene in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesive Tapes (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention provides a kind of novel advertisement film with porous structural adhesive layer, including advertisement film basement membrane, porous glue-line and release layer, the volume in the duct in porous glue-line accounts for 35% the 80% of glue-line volume, and the aperture in duct is 1 micron 200 microns, and porous bondline thickness is 50 200 microns.Compared with traditional gum adhesive technology, the present invention is prepared substantial amounts of air vent channel in glue-line, is helped advertisement film to absorb and discharge and putting up caused bubble, ensure advertisement film surfacing by structure design.
Description
Technical field
The invention belongs to advertisement consumptive material field, more particularly to a kind of novel advertisement film with porous structural adhesive layer.
Background technology
As digital printing technology is increasingly extensive in the application of advertisement field, the demand of advertisement film is increasing, at present
Advertisement film is mainly puted up by the way of gum stickup, and in order to ensure to put up firmly, used gum is mainly high viscous
Property adhesive, venting quality is poor when putting up, can advertisement film and by between patch base material produce bubble, it is necessary to be struck off with professional mode
Bubble, it is not high to put up convenience, in addition, high viscosity glue easily leave cull on adherend surface after long-time is pasted, it is necessary to
Wipe and remove, influence outward appearance and advertisement replacing efficiency.Therefore, easily put up it is removable and can Reusability performance be increasingly becoming advertisement
The new demand of film consumptive material.Patent CN201410243009.5 and CN201420138899.9 are prepared using thermic inflatable elastomeric particulate
Low viscous pressure sensitive adhesive, but exhausting problem when being pasted without reference to large area；Patent CN201410121701.0 is sent out using azo
Infusion prepares porous discharge type pressure sensitive adhesive, and azo foaming agent blowing temperature high energy consumption is big, is only suitable for being coated on heat-resist
On base material；Patent CN201610276200.9 and 201610804305.7 mentions the system of easily peelable discharge type acrylic type pressure sensitive adhesive
Preparation Method, although by reduce peeling force realize it is low viscous easily peelable compared with fruit because glue-line is still simple planar structure, big
Venting quality is still insufficient to when breadth pastes, and the fitting of small area diaphragm surface is only suitable for, in addition in synthetic adhesive and system
A large amount of organic solvents are used in standby adhesive tape technique, the feature of environmental protection is poor.
In order to meet now the needs of to high-performance advertisement film, it is contemplated that preparation one kind is environmentally friendly, it is removable easily to put up,
Repeatedly used novel advertisement film, to meet the needs of advertisement consumptive material field market development.
The content of the invention
For insufficient existing for the existing advertisement film in market, the invention provides a kind of new wide with porous structural adhesive layer
Accuse film
To realize object above, the technical scheme is that：
A kind of novel advertisement film with porous structural adhesive layer, including advertisement film basement membrane, porous glue-line and release layer, porous glue-line
In the volume in duct account for the 35%-80% of glue-line volume, the aperture in duct is 1-200 micron, and porous bondline thickness is 50-200
Micron.
Preferably, the duct in porous glue-line is prepared by the oil phase drying and volatilizing in oil-in-water emulsion, porous
180 ° of peel strengths of glue-line are 0.1-5.0N/25mm.
Preferably, described oil-in-water emulsion is prepared by inversion process.
Preferably, water, organic solvent, emulsifying agent, film forming matter, PH conditioning agents and increasing are contained in described oil-in-water emulsion
Thick dose.
Preferably, described organic solvent includes：One or more of groups in petroleum ether, toluene, hexamethylene, dimethylbenzene
Close.
Preferably, described emulsifying agent includes：One or both of ionic emulsifying agent or nonionic emulsifier group
Close.
Preferably, described film forming matter includes：Polyacrylate, polyvingl ether, one or more of groups of rubber latex
Close.
Preferably, described PH conditioning agents include：One in sodium acid carbonate, sodium carbonate, ammoniacal liquor, sodium hydroxide or sodium phosphate
Kind or several combinations.
Preferably, described thickener includes：One kind in cellulose family, polyacrylate and polyurethanes thickener
Or several combinations.
Preferably, advertisement film basement membrane is polyester film, polypropylene screen, Dampler Ace, polychloroethylene film, makrolon
One kind in film, polystyrene film, polyethylene film, polyimide film, or any of two of which and above composite membrane；Extensively
The front for accusing film layer is coated with printing adaptation layer, and printing adaptation layer is used for UV inks, Weak solvent ink, water-base ink and HP
The printing of latex ink jets, and HP Indigo digital printings, the printing of laser carbon dust and traditional ink printing, printing adapt to
The thickness of layer is 0.2-50 microns.
The described release layer is that polypropylene screen, polyester film, polyethylene with organosilicon or fluorine element mould release are release
Any of film or release liners.
Compared with prior art, the beneficial effects of the invention are as follows：
1st, compared with traditional gum adhesive technology, the present invention prepares substantial amounts of stomata by structure design in glue-line
Passage, help advertisement film to absorb and discharge and putting up caused bubble, ensure advertisement film surfacing；
2nd, the glue-line with loose structure assigns two kinds of advertisement film and pastes characteristic, and a kind of is the adhesivity that glue-line has in itself, and one
Kind is that stomata glue-line itself can produce certain negative pressure after receiving and discharging gas, helps product to paste tighter.Two kinds of fittings are special
Property interaction, advertisement film can be ensured to put up under the conditions of the viscosity of middle low stripping force firmly, while have and easily put up
The advantages of easily peelable；
2nd, the present invention makes solvent volatilize using oil-in-water emulsion by heating, and stomata duct is formed in glue-line, and preparation technology fits
It is strong with property, it can be applied on most films and paper substrate, be more suitable for industrialization.
Brief description of the drawings
Fig. 1 is agent structure diagrammatic cross-section of the present invention.
In figure：1st, advertisement film basement membrane；2nd, porous glue-line；3rd, release film layer.
Embodiment
One embodiment of the present invention is further illustrated with reference to the accompanying drawings.
Embodiment 1
15 parts of toluene, 1.2 parts of anhydrous sorbitol laurates and 0.3 part of NaLS are added in dispersion slot, stirring is mixed
After closing 10min, add 36 parts of deionized waters and 0.02 part of organic silicon modified by polyether class defoamer, and control water addition speed and
Mixing speed, phase reversal occurs to system and forms homogeneous emulsion.Then sequentially added in emulsion 25 parts of pure-acrylic emulsions, 20 parts from
Crosslinking butadiene Atrolactamide, 0.3 part of ammoniacal liquor, 1 part of cmc soln and 0.7 part of polyacrylate-type thickeners.Finally handle
Emulsion coating on polypropylene screen, porous bondline thickness be 100 microns, through 80-130 DEG C heat 10min after, be covered with polypropylene from
Type film, obtain the novel advertisement film with porous structural adhesive layer.
Embodiment 2
15 parts of hexamethylenes, 0.9 part of anhydrous sorbitol laurate and 1.1 parts of enuatrols are added in dispersion slot, are stirred
After 10min, 36 parts of deionized waters and 0.02 part of organic silicon modified by polyether class defoamer are added, and controls the addition speed of water and stirs
Speed is mixed, phase reversal, which occurs, to system forms homogeneous emulsion.Then 25 parts of pure-acrylic emulsions, 20 parts of selfings are sequentially added in emulsion
Connection type butadiene-styrene latex, 0.3 part of ammoniacal liquor, 1 part of cmc soln and 0.7 part of polyacrylate-type thickeners.Finally breast
Liquid is coated on polypropylene screen, and porous bondline thickness is 100 microns, and after 80-130 DEG C is heated 10min, it is release to be covered with polypropylene
Film, obtain the novel advertisement film with porous structural adhesive layer.
Embodiment 3
15 parts of toluene, 1.2 parts of anhydrous sorbitol laurates and 0.3 part of NaLS are added in dispersion slot, stirring is mixed
After closing 10min, add 36 parts of deionized waters and 0.01 part of organic silicon modified by polyether class defoamer, and control water addition speed and
Mixing speed, phase reversal occurs to system and forms homogeneous emulsion.Then 15 parts of water-soluble polypropylene acid are sequentially added in emulsion
Ester, 10 parts of polyvingl ethers, 20 parts of natural emulsions, 0.3 part of ammoniacal liquor, 1 part of hydroxyethyl cellulose solution and 1 part of polyacrylate
Thickener.Finally emulsion coating on polyester film, porous bondline thickness is 100 microns, after 80-130 DEG C is heated 10min,
Polyester release film is covered with, obtains the novel advertisement film with porous structural adhesive layer.
Embodiment 4
20 parts of toluene, 1.8 parts of anhydrous sorbitol laurates and 0.6 part of NaLS are added in dispersion slot, stirring is mixed
After closing 10min, add 32 parts of deionized waters and 0.02 part of organic silicon modified by polyether class defoamer, and control water addition speed and
Mixing speed, phase reversal occurs to system and forms homogeneous emulsion.Then 28 parts of modified polyacrylates are sequentially added in emulsion
Emulsion, 15 parts of natural emulsions, 0.3 part of ammoniacal liquor, 1 part of cmc soln and 0.5 part of polyacrylate-type thickeners.Finally
Emulsion coating on polyester film, porous bondline thickness is 100 microns, and after 80-130 DEG C is heated 10min, it is release to be covered with polyester
Film, obtain the novel advertisement film with porous structural adhesive layer.
Embodiment 5
10 parts of petroleum ethers, 10 parts of dimethylbenzene, 1 part of octyl phenyl polyoxyethylene ether and 1 part of anhydrous sorbitol are added in dispersion slot
Laurate and 0.4 part of NaLS, after being stirred 20min, add 35 parts of deionized waters and 0.02 part polyether-modified
Organic silicon defoamer, and the addition speed and mixing speed of water are controlled, phase reversal, which occurs, to system forms homogeneous emulsion.Then
25 parts of modified polyacrylate emulsions, 15 parts of butyl latexes, 0.3 part of ammoniacal liquor, 1 part of carboxymethyl cellulose are sequentially added in emulsion
Solution and 0.5 part of polyacrylate-type thickeners.Finally emulsion coating on polyester film, porous bondline thickness is 100 microns,
After 80-130 DEG C is heated 10min, polyester release film is covered with, obtains the novel advertisement film with porous structural adhesive layer.
Comparative example 1
Commercially available acrylic acid high viscosity pressure sensitive adhesive is coated on polyester film, bondline thickness is 20 microns, through 80-130 DEG C of heating
After 10min, polyester release film is covered with, obtains gum advertisement film.
Performance test is carried out to embodiment 1-5 and comparative example 1-2 advertisement film, test result is as shown in table 1.
The performance test results of the advertisement film of table 1
By above table as can be seen that the advertisement film with porous structural adhesive layer for preparing of the present invention compared to the prior art,
With peeling force it is low, put up bubble-free and will not the obvious advantage such as cull.
Embodiments of the invention are the foregoing is only, not limit the technical scope of the present invention, it is all according to explanation of the invention
Any modification, equivalent variations and the modification that book content is made, belong in the scope of patent protection of the present invention.
Claims (10)
- A kind of 1. novel advertisement film with porous structural adhesive layer, it is characterised in that：Including advertisement film basement membrane, porous glue-line and from Type layer, the volume in the duct in porous glue-line account for the 35%-80% of glue-line volume, and the aperture in duct is 1-200 micron, porous glue Thickness degree is 50-200 microns.
- 2. the novel advertisement film according to claim 1 with porous structural adhesive layer, it is characterised in that：In porous glue-line Duct is prepared by the oil phase drying and volatilizing in oil-in-water emulsion, and 180 ° of peel strengths of porous glue-line are 0.1- 5.0N/25mm。
- 3. the novel advertisement film according to claim 2 with porous structural adhesive layer, it is characterised in that：Described oil-in-water Emulsion is prepared by inversion process.
- 4. the novel advertisement film according to claim 3 with porous structural adhesive layer, it is characterised in that：Described oil-in-water Contain water, organic solvent, emulsifying agent, film forming matter, PH conditioning agents and thickener in emulsion.
- 5. the novel advertisement film according to claim 4 with porous structural adhesive layer, it is characterised in that：Described is organic molten Agent includes：One or more combination in petroleum ether, toluene, hexamethylene, dimethylbenzene.
- 6. the novel advertisement film according to claim 4 with porous structural adhesive layer, it is characterised in that：Described emulsifying agent Including：One or both of ionic emulsifying agent or nonionic emulsifier combine.
- 7. the novel advertisement film according to claim 4 with porous structural adhesive layer, it is characterised in that：Described film forming matter Including：Polyacrylate, polyvingl ether, the one or more combination of rubber latex.
- 8. the novel advertisement film according to claim 4 with porous structural adhesive layer, it is characterised in that：Described PH regulations Agent includes：One or more combination in sodium acid carbonate, sodium carbonate, ammoniacal liquor, sodium hydroxide or sodium phosphate.
- 9. the novel advertisement film according to claim 4 with porous structural adhesive layer, it is characterised in that：Described thickener Including：One or more combination in cellulose family, polyacrylate and polyurethanes thickener.
- 10. the novel advertisement film according to claim 1 with porous structural adhesive layer, it is characterised in that：Advertisement film basement membrane For polyester film, polypropylene screen, Dampler Ace, polychloroethylene film, polycarbonate membrane, polystyrene film, polyethylene film, polyamides One kind in imines film, or any of two of which and above composite membrane；The front of advertisement film layer is coated with printing and adapted to Layer, printing adaptation layer are used for the printing of UV inks, Weak solvent ink, water-base ink and HP latex ink jets, and HP Indigo digital printings, the printing of laser carbon dust and traditional ink printing, the thickness for printing adaptation layer is 0.2-50 microns.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711211928.4A CN107805464A (en) | 2017-11-28 | 2017-11-28 | A kind of novel advertisement film with porous structural adhesive layer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711211928.4A CN107805464A (en) | 2017-11-28 | 2017-11-28 | A kind of novel advertisement film with porous structural adhesive layer |
Publications (1)
| Publication Number | Publication Date |
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| CN107805464A true CN107805464A (en) | 2018-03-16 |
Family
ID=61590065
Family Applications (1)
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| CN201711211928.4A Pending CN107805464A (en) | 2017-11-28 | 2017-11-28 | A kind of novel advertisement film with porous structural adhesive layer |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108531094A (en) * | 2018-05-30 | 2018-09-14 | 奇鋐科技股份有限公司 | Bonding structure |
| CN109263080A (en) * | 2018-08-30 | 2019-01-25 | 杨仲辉 | With the artificial composite synthetic paper and preparation method for improving printing performance |
| CN112940640A (en) * | 2020-12-30 | 2021-06-11 | 南京盛凯新材料有限公司 | Matte release film produced by EB (Electron Beam) curing |
| US11125267B2 (en) | 2018-05-29 | 2021-09-21 | Asia Vital Components Co., Ltd. | Attachment structure |
| WO2022032761A1 (en) * | 2020-08-10 | 2022-02-17 | 深圳市华星光电半导体显示技术有限公司 | Flexible base plate and manufacturing method thereof, and electronic device |
| CN114558451A (en) * | 2022-02-23 | 2022-05-31 | 泰州清润环保科技有限公司 | Three-dimensional trapezoidal concave-convex structured PEG desulfurization film and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11125267B2 (en) | 2018-05-29 | 2021-09-21 | Asia Vital Components Co., Ltd. | Attachment structure |
| CN108531094A (en) * | 2018-05-30 | 2018-09-14 | 奇鋐科技股份有限公司 | Bonding structure |
| CN108531094B (en) * | 2018-05-30 | 2021-02-05 | 奇鋐科技股份有限公司 | Attaching structure |
| CN109263080A (en) * | 2018-08-30 | 2019-01-25 | 杨仲辉 | With the artificial composite synthetic paper and preparation method for improving printing performance |
| CN109263080B (en) * | 2018-08-30 | 2022-01-07 | 湖北金三峡印务有限公司 | Artificial composite synthetic paper with improved printing performance and preparation method thereof |
| WO2022032761A1 (en) * | 2020-08-10 | 2022-02-17 | 深圳市华星光电半导体显示技术有限公司 | Flexible base plate and manufacturing method thereof, and electronic device |
| CN112940640A (en) * | 2020-12-30 | 2021-06-11 | 南京盛凯新材料有限公司 | Matte release film produced by EB (Electron Beam) curing |
| CN114558451A (en) * | 2022-02-23 | 2022-05-31 | 泰州清润环保科技有限公司 | Three-dimensional trapezoidal concave-convex structured PEG desulfurization film and preparation method thereof |
| CN114558451B (en) * | 2022-02-23 | 2023-06-23 | 泰州禾益新材料科技有限公司 | PEG desulfurization film with three-dimensional trapezoid concave-convex structure and preparation method thereof |
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Application publication date: 20180316 |