CN107805047A - High feldspathic ceramic body material and preparation method thereof, the method for preparing with it ceramic - Google Patents

High feldspathic ceramic body material and preparation method thereof, the method for preparing with it ceramic Download PDF

Info

Publication number
CN107805047A
CN107805047A CN201711052699.6A CN201711052699A CN107805047A CN 107805047 A CN107805047 A CN 107805047A CN 201711052699 A CN201711052699 A CN 201711052699A CN 107805047 A CN107805047 A CN 107805047A
Authority
CN
China
Prior art keywords
ceramic body
ball milling
ceramic
body material
high feldspathic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711052699.6A
Other languages
Chinese (zh)
Inventor
包启富
郭建洲
郑春凤
林章铨
郭缨琨
方锦峰
徐彩丽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujian Dehua Wuzhou Ceramic Co Ltd
Original Assignee
Fujian Dehua Wuzhou Ceramic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujian Dehua Wuzhou Ceramic Co Ltd filed Critical Fujian Dehua Wuzhou Ceramic Co Ltd
Priority to CN201711052699.6A priority Critical patent/CN107805047A/en
Publication of CN107805047A publication Critical patent/CN107805047A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/131Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3436Alkaline earth metal silicates, e.g. barium silicate
    • C04B2235/3445Magnesium silicates, e.g. forsterite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6562Heating rate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567Treatment time

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The method that ceramic is prepared the invention discloses a kind of high feldspathic ceramic body material and preparation method thereof, with it, belongs to ceramic technology field.High feldspathic ceramic body material includes base-material and additive, and the preparation method of described high feldspathic ceramic body material comprises the following steps:Stock, ball milling, dehydration, vacuum pugging and old, the method for preparing ceramic with high feldspathic ceramic body material, comprise the following steps:Shaping, glazing and firing.The raw material of the present invention is easy to get, and moderate, product strength is big, and anti-deformation is strong, and thermal stability is strong, and in sintering process, firing temperature is low, and has widened firing range, environmental protection and energy saving, promotes the sustainable development of industry production.

Description

High feldspathic ceramic body material and preparation method thereof, with it prepare ceramic Method
Technical field
The invention belongs to ceramic technology field, and in particular to a kind of high feldspathic ceramic body material and preparation method thereof, use It prepares the method for ceramic.
Background technology
Feldspathic china is with long masonry fluxing agent " feldspar-quartz-kaolin " three-component system porcelain.Its feature:Porcelain It is pure white, translucent, section is fine and close, water absorption rate is low, intensity is high and thermostabilization is good, chemical stability is good.Feldspathic china is main at present Kind is tea set, tableware kind.As the improvement of consumer's living standards, quality of life requires also more and more higher, to tea tableware Requirement it is also high, it is desirable to high-transmittance, good transmittance has to generate more glass phases, and other performance can't drop It is low.
How to solve the above problems, be also a great problem, in the prior art, technology people for ceramic technology worker Member have developed a kind of high feldspathic china, its K2O、Na2O content summation accounts for the 4.5% of raw material total content, employs and burns till twice, High temperature biscuiting and low temperature sinter technique, base substrate firing temperature are 1290 DEG C, and temperature of glaze firing is 1150 DEG C, but its light transmittance still reaches Less than requiring, and burn till twice, energy consumption increase, improve production cost, have impact on the market competitiveness.Due to single in blank Low temperature flux K2O、Na2O is more, when the base substrate temperature is reached lowest total of the melting point temperature, just occurs a large amount of liquid phases, and liquid phase suddenly Amount is raised and increased sharply with temperature, so as to cause porcelain billet drastically to deform, can not once be realized and be burnt till.
Current country controls standard more and more tighter in terms of environmental protection, most tight in NOx emission standard history, is up to 100mg/ m3, the NOx emission of Production of Ceramics is higher, and main cause is that firing temperature height causes nitrogen in air and oxygen reacts life Into NOx, NOx emission is reduced, it is necessary to reduce firing temperature.According to above formula system, after reducing firing temperature, production can be reduced Moral character energy.
Therefore it provides a kind of high feldspathic ceramic body material and preparation method thereof, the method for preparing with it ceramic, its Raw material is easy to get, and moderate, product strength is big, and anti-deformation is strong, and thermal stability is strong, in sintering process, firing temperature It is low, and firing range has been widened, environmental protection and energy saving, promote the sustainable development of industry production.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of raw material to be easy to get, moderate, product strength Greatly, anti-deformation is strong, and thermal stability is strong, and in sintering process, firing temperature is low, and has widened firing range, ring Energy-conservation is protected, promotes high feldspathic ceramic body material of sustainable development of industry production and preparation method thereof, made pottery with its preparation The method of ceramic products.
The present invention adopts the following technical scheme that:
High feldspathic ceramic body material includes base-material and additive, and the mass ratio of the base-material and additive is 100:3~ 8, wherein, the base-material includes following component in percentage by weight:Potassium feldspar 30~40%, albite 15~28%, Longyan kaolin 15~25%, lithium feldspar 5~15%, Guangxi white clay 18~25%, calcination of talc 1~5%, add up to 100%.
Further, the additive is thickening transparent agent.
Further, the thickening transparent agent is boron frit.
Further, the additive includes following component in percentage by weight:Transparent agent 40~50% is viscosified, Glass phase tackifier 50~60%, total amount 100%.
Further, the thickening transparent agent is boron frit, and the glass phase tackifier are white carbon.
The preparation method of described high feldspathic ceramic body material, comprises the following steps:
S11, stock:
The potassium feldspar, albite, lithium feldspar, calcination of talc and Guangxi white clay are mixed according to the quality proportioning It is even, the first proportioning material is obtained, Longyan kaolin and additive are well mixed according to the quality proportioning, obtain the second proportioning Material;
S12, ball milling:
First proportioning material obtained by step 1 is subjected to a ball milling, the first ball milling material is obtained, then second obtained by step 1 Proportioning material is added in the first ball milling material, obtains mixed once material after being well mixed, mixed once material finally is carried out into secondary ball milling, obtained Second ball milling material;
S13, dehydration:
Second ball milling material obtained by step 2 is dehydrated, material must be dehydrated;
S14, vacuum pugging:
Dehydration material obtained by step 3 is placed in pugging in vacuum deairing machine, obtains pugging material;
It is S15, old:
Pugging material progress obtained by step 4 is old, obtain high feldspathic ceramic body material.
Further, described in step S12 during a ball milling, ball milling is carried out according to following mass ratio:First proportioning material:Mill Ball:Water=1~1.2:3:0.7, Ball-milling Time is 20~22h, is then sieved with 300~350 mesh mesh screens, and its screen over-size is 0.1 ~0.3%, during the secondary ball milling, ball milling, mixed once material are carried out according to following mass ratio:Abrading-ball:Water=1~1.2:2.5: 0.9, Ball-milling Time is 2~3h.
Further, the water content of dehydration material is 23~26% obtained by step S13.
The method for preparing ceramic with described high feldspathic ceramic body material, comprises the following steps:
S21, shaping:
Ceramic molding blank is made in high feldspathic ceramic body material obtained by step S15;
S22, glazing:
Glazing is carried out to ceramic molding blank obtained by step S21, obtains glazing ceramic body;
S23, firing:
Glazing ceramic body obtained by step S22 is fired, high feldspathic ceramics are obtained after cooling.
Further, in step S23 sintering procedures, 1180~1220 first are warming up to 1~2 DEG C/min heating rate DEG C, then soaking time 40~60 minutes, finally cool down and produce high feldspathic ceramics and prepare ceramic.
The present invention compared with prior art, has the advantages that:
Firstth, in high feldspathic ceramic body material of the invention, glass phase tackifier are employed, its glass phase tackifier is White carbon, it is easily melted by albite at high temperature, high viscous high saturating glass melt is formed, to improve the resistance to deformation energy of mold Power;
Secondth, in high feldspathic ceramic body material of the invention, glass phase tackifier are employed, thickening transparent agent melts for boron Block, contain boron element in boron frit, form glass phase at high temperature, light transmittance can be increased;Moreover, in order to ensure the saturating of product Lightness, more glass phase is needed in preparation process, now, we are used as flux using potassium feldspar and albite, and still, potassium is grown Stone and albite can reduce glass phase viscosity, and obtained product is easily deformed, and therefore, with the addition of boron element, boron element is glass Body is formed, while glass metal is formed, can enter in silicate glass, increase glass phase, play reinforcement silicate network Effect, reinforcing glass network phase structure, improve glass phase viscosity, so as to improve ceramics intensity, reduce the deformation of product Rate;
3rd, in high feldspathic ceramic body material of the invention, lithium feldspar is introduced, using more alkali effects, is formd polynary Composite fluxing agent, i.e., lithium potassium sodium magnalium system on silicon is become by original potassium sodium magnalium system on silicon, while firing temperature is reduced, Glass viscosity is added, reduces the deformation ratio of product;The addition of composite fluxing agent, enable base substrate in different temperature-rise periods by The higher liquid phase of existing viscosity is walked out of, so as to expand the sintering range of base substrate, improves the performance of product;
4th, raw material is easy to get, cheap, reduces cost of material, is easy to production to implement, and is easy to Industry Promotion and answers With.
Embodiment
The raw material that the present invention uses is commercially available product.
Embodiment 1
High feldspathic ceramic body material, it is characterised in that including base-material and additive, the quality of the base-material and additive Than for:100:5, wherein, the base-material includes following component in percentage by weight:Potassium feldspar 30%, albite 15%, Longyan kaolin 20%, lithium feldspar 10%, Guangxi white clay 22%, calcination of talc 3%, add up to 100%.
Wherein, the additive is thickening transparent agent, and it is boron frit to viscosify transparent agent.
With the preparation method of described high feldspathic ceramic body material, comprise the following steps:
S11, stock:
The potassium feldspar, albite, lithium feldspar, calcination of talc and Guangxi white clay are mixed according to the quality proportioning It is even, the first proportioning material is obtained, Longyan kaolin and additive are well mixed according to the quality proportioning, obtain the second proportioning Material;
S12, ball milling:
First proportioning material obtained by step 1 is subjected to a ball milling, the first ball milling material is obtained, then second obtained by step 1 Proportioning material is added in the first ball milling material, obtains mixed once material after being well mixed, mixed once material then is carried out into secondary ball milling, obtained Second ball milling material;
Wherein, described in S12 during a ball milling, ball milling is carried out according to following mass ratio:First proportioning material:Abrading-ball:Water=1: 3:0.7, Ball-milling Time 22h, then sieved with 325 mesh mesh screens, its screen over-size is 0.2%, during the secondary ball milling, according to such as Lower mass ratio carries out ball milling, mixed once material:Abrading-ball:Water=1:2.5:0.9, Ball-milling Time 2h;
S13, dehydration:
Second ball milling material obtained by step 2 is dehydrated, material must be dehydrated;
Wherein, the water content of gained dehydration material is 23%;
S14, vacuum pugging:
Dehydration material obtained by step 3 is placed in pugging in vacuum deairing machine, obtains pugging material;
It is S15, old:
Pugging material progress obtained by step 4 is old, obtain high feldspathic ceramic body material.
The method for preparing ceramic with described high feldspathic ceramic body material, comprises the following steps:
S21, shaping:
Ceramic molding blank is made in high feldspathic ceramic body material obtained by step S15;
S22, glazing:
Glazing is carried out to ceramic molding blank obtained by step S21, obtains glazing ceramic body;
S23, firing:
Glazing ceramic body obtained by step S22 is fired, high feldspathic ceramics are obtained after cooling.
Wherein, in step S23 sintering procedures, 1220 DEG C, when being then incubated first are warming up to 1.6 DEG C/min heating rate Between 90 minutes, produce high feldspathic ceramics after finally cooling down and prepare ceramic.
Embodiment 2
High feldspathic ceramic body material, it is characterised in that including base-material and additive, the quality of the base-material and additive Than for:100:8, wherein, the base-material includes following component in percentage by weight:Potassium feldspar 35%, albite 15%, Longyan kaolin 18%, lithium feldspar 13%, Guangxi white clay 18%, calcination of talc 1%, add up to 100%.
Wherein, the additive includes following component in percentage by weight:Transparent agent 50% is viscosified, glass mutually increases Stick 50%, the thickening transparent agent is boron frit, and the glass phase tackifier are white carbon.
With the preparation method of described high feldspathic ceramic body material, comprise the following steps:
S11, stock:
The potassium feldspar, albite, lithium feldspar, calcination of talc and Guangxi white clay are mixed according to the quality proportioning It is even, the first proportioning material is obtained, Longyan kaolin and additive are well mixed according to the quality proportioning, obtains the second proportioning material;
S12, ball milling:
First proportioning material obtained by step 1 is subjected to a ball milling, the first ball milling material is obtained, then second obtained by step 1 Proportioning material is added in the first ball milling material, obtains mixed once material after being well mixed, mixed once material then is carried out into secondary ball milling, obtained Second ball milling material;
Wherein, described in S12 during a ball milling, ball milling is carried out according to following mass ratio:First proportioning material:Abrading-ball:Water= 1.1:3:0.7, Ball-milling Time 20h, then sieved with 300 mesh mesh screens, its screen over-size is 0.1%, during the secondary ball milling, is pressed Ball milling, mixed once material are carried out according to following mass ratio:Abrading-ball:Water=1.1:2.5:0.9, Ball-milling Time 2.5h;
S13, dehydration:
Second ball milling material obtained by step 2 is dehydrated, material must be dehydrated;
Wherein, the water content of gained dehydration material is 24%;
S14, vacuum pugging:
Dehydration material obtained by step 3 is placed in pugging in vacuum deairing machine, obtains pugging material;
It is S15, old:
Pugging material progress obtained by step 4 is old, obtain high feldspathic ceramic body material.
The method for preparing ceramic with described high feldspathic ceramic body material, comprises the following steps:
S21, shaping:
Ceramic molding blank is made in high feldspathic ceramic body material obtained by step S15;
S22, glazing:
Glazing is carried out to ceramic molding blank obtained by step S21, obtains glazing ceramic body;
S23, firing:
Glazing ceramic body obtained by step S22 is fired, high feldspathic ceramics are obtained after cooling.
Wherein, in step S23 sintering procedures, 1180 DEG C first are warming up to 1 DEG C/min heating rate, then soaking time 80 minutes, produce high feldspathic ceramics after finally cooling down and prepare ceramic.
Embodiment 3
High feldspathic ceramic body material, it is characterised in that including base-material and additive, the quality of the base-material and additive Than for:100:5, wherein, the base-material includes following component in percentage by weight:Potassium feldspar 30%, albite 18%, Longyan kaolin 20%, lithium feldspar 11%, Guangxi white clay 20%, calcination of talc 1%, add up to 100%.
Wherein, the additive includes following component in percentage by weight:Transparent agent 40% is viscosified, glass mutually increases Stick 60%, the thickening transparent agent is boron frit, and the glass phase tackifier are white carbon.
With the preparation method of described high feldspathic ceramic body material, comprise the following steps:
S11, stock:
The potassium feldspar, albite, lithium feldspar, calcination of talc and Guangxi white clay are mixed according to the quality proportioning It is even, the first proportioning material is obtained, Longyan kaolin and additive are well mixed according to the quality proportioning, obtains the second proportioning material;
S12, ball milling:
First proportioning material obtained by step 1 is subjected to a ball milling, the first ball milling material is obtained, then second obtained by step 1 Proportioning material is added in the first ball milling material, obtains mixed once material after being well mixed, mixed once material then is carried out into secondary ball milling, obtained Second ball milling material;
Wherein, described in S12 during a ball milling, ball milling is carried out according to following mass ratio:First proportioning material:Abrading-ball:Water= 1.2:3:0.7, Ball-milling Time 20h, then sieved with 350 mesh mesh screens, its screen over-size is 0.3%, during the secondary ball milling, is pressed Ball milling, mixed once material are carried out according to following mass ratio:Abrading-ball:Water=1.2:2.5:0.9, Ball-milling Time 3h;
S13, dehydration:
Second ball milling material obtained by step 2 is dehydrated, material must be dehydrated;
Wherein, the water content of gained dehydration material is 25%;
S14, vacuum pugging:
Dehydration material obtained by step 3 is placed in pugging in vacuum deairing machine, obtains pugging material;
It is S15, old:
Pugging material progress obtained by step 4 is old, obtain high feldspathic ceramic body material.
The method for preparing ceramic with described high feldspathic ceramic body material, comprises the following steps:
S21, shaping:
Ceramic molding blank is made in high feldspathic ceramic body material obtained by step S15;
S22, glazing:
Glazing is carried out to ceramic molding blank obtained by step S21, obtains glazing ceramic body;
S23, firing:
Glazing ceramic body obtained by step S22 is fired, high feldspathic ceramics are obtained after cooling.
Wherein, in step S23 sintering procedures, 1200 DEG C first are warming up to 2 DEG C/min heating rate, then soaking time 70 minutes, produce high feldspathic ceramics after finally cooling down and prepare ceramic.
Embodiment 4
High feldspathic ceramic body material, it is characterised in that including base-material and additive, the quality of the base-material and additive Than for:100:3, wherein, the base-material includes following component in percentage by weight:Potassium feldspar 40%, albite 15%, Longyan kaolin 18%, lithium feldspar 8%, Guangxi white clay 18%, calcination of talc 1%, amount to 100%.
Wherein, the additive includes following component in percentage by weight:Transparent agent 50% is viscosified, glass mutually increases Stick 50%, the thickening transparent agent is boron frit, and the glass phase tackifier are white carbon.
With the preparation method of described high feldspathic ceramic body material, comprise the following steps:
S11, stock:
The potassium feldspar, albite, lithium feldspar, calcination of talc and Guangxi white clay are mixed according to the quality proportioning It is even, the first proportioning material is obtained, Longyan kaolin and additive are well mixed according to the quality proportioning, obtains the second proportioning material;
S12, ball milling:
First proportioning material obtained by step 1 is subjected to a ball milling, the first ball milling material is obtained, then second obtained by step 1 Proportioning material is added in the first ball milling material, obtains mixed once material after being well mixed, mixed once material then is carried out into secondary ball milling, obtained Second ball milling material;
Wherein, described in S12 during a ball milling, ball milling is carried out according to following mass ratio:First proportioning material:Abrading-ball:Water= 1.2:3:0.7, Ball-milling Time 21h, then sieved with 325 mesh mesh screens, its screen over-size is 0.2%, during the secondary ball milling, is pressed Ball milling, mixed once material are carried out according to following mass ratio:Abrading-ball:Water=1.2:2.5:0.9, Ball-milling Time 2.5h;
S13, dehydration:
Second ball milling material obtained by step 2 is dehydrated, material must be dehydrated;
Wherein, the water content of gained dehydration material is 26%;
S14, vacuum pugging:
Dehydration material obtained by step 3 is placed in pugging in vacuum deairing machine, obtains pugging material;
It is S15, old:
Pugging material progress obtained by step 4 is old, obtain high feldspathic ceramic body material.
The method for preparing ceramic with described high feldspathic ceramic body material, comprises the following steps:
S21, shaping:
Ceramic molding blank is made in high feldspathic ceramic body material obtained by step S15;
S22, glazing:
Glazing is carried out to ceramic molding blank obtained by step S21, obtains glazing ceramic body;
S23, firing:
Glazing ceramic body obtained by step S22 is fired, high feldspathic ceramics are obtained after cooling.
Wherein, in step S23 sintering procedures, 1180 DEG C, when being then incubated first are warming up to 1.5 DEG C/min heating rate Between 60 minutes, produce high feldspathic ceramics after finally cooling down and prepare ceramic.
Embodiment 5
High feldspathic ceramic body material, it is characterised in that including base-material and additive, the quality of the base-material and additive Than for:100:6, wherein, the base-material includes following component in percentage by weight:Potassium feldspar 35%, albite 15%, Longyan kaolin 18%, lithium feldspar 10%, Guangxi white clay 20%, calcination of talc 2%, add up to 100%.
Wherein, the additive includes following component in percentage by weight:Transparent agent 50% is viscosified, glass mutually increases Stick 50%, the thickening transparent agent is boron frit, and the glass phase tackifier are white carbon.
With the preparation method of described high feldspathic ceramic body material, comprise the following steps:
S11, stock:
The potassium feldspar, albite, lithium feldspar, calcination of talc and Guangxi white clay are mixed according to the quality proportioning It is even, the first proportioning material is obtained, Longyan kaolin and additive are well mixed according to the quality proportioning, obtains the second proportioning material;
S12, ball milling:
First proportioning material obtained by step 1 is subjected to a ball milling, the first ball milling material is obtained, then second obtained by step 1 Proportioning material is added in the first ball milling material, obtains mixed once material after being well mixed, mixed once material then is carried out into secondary ball milling, obtained Second ball milling material;
Wherein, described in S12 during a ball milling, ball milling is carried out according to following mass ratio:First proportioning material:Abrading-ball:Water= 1.2:3:0.7, Ball-milling Time 21h, then sieved with 325 mesh mesh screens, its screen over-size is 0.2%, during the secondary ball milling, is pressed Ball milling, mixed once material are carried out according to following mass ratio:Abrading-ball:Water=1.2:2.5:0.9, Ball-milling Time 2h;
S13, dehydration:
Second ball milling material obtained by step 2 is dehydrated, material must be dehydrated;
Wherein, the water content of gained dehydration material is 24%;
S14, vacuum pugging:
Dehydration material obtained by step 3 is placed in pugging in vacuum deairing machine, obtains pugging material;
It is S15, old:
Pugging material progress obtained by step 4 is old, obtain high feldspathic ceramic body material.
The method for preparing ceramic with described high feldspathic ceramic body material, comprises the following steps:
S21, shaping:
Ceramic molding blank is made in high feldspathic ceramic body material obtained by step S15;
S22, glazing:
Glazing is carried out to ceramic molding blank obtained by step S21, obtains glazing ceramic body;
S23, firing:
Glazing ceramic body obtained by step S22 is fired, high feldspathic ceramics are obtained after cooling.
Wherein, in step S23 sintering procedures, 1210 DEG C, when being then incubated first are warming up to 1.8 DEG C/min heating rate Between 70 minutes, produce high feldspathic ceramics after finally cooling down and prepare ceramic.
Embodiment 6
High feldspathic ceramic body material, it is characterised in that including base-material and additive, the quality of the base-material and additive Than for:100:4, wherein, the base-material includes following component in percentage by weight:Potassium feldspar 30%, albite 18%, Longyan kaolin 20%, lithium feldspar 11%, Guangxi white clay 18%, calcination of talc 3%, amount to 100%.
Wherein, the additive includes following component in percentage by weight:Transparent agent 45% is viscosified, glass mutually increases Stick 55%, the thickening transparent agent is boron frit, and the glass phase tackifier are white carbon.
The preparation method of described high feldspathic ceramic body material, comprises the following steps:
S11, stock:
The potassium feldspar, albite, lithium feldspar, calcination of talc and Guangxi white clay are mixed according to the quality proportioning It is even, the first proportioning material is obtained, Longyan kaolin and additive are well mixed according to the quality proportioning, obtains the second proportioning material;
S12, ball milling:
First proportioning material obtained by step 1 is subjected to a ball milling, the first ball milling material is obtained, then second obtained by step 1 Proportioning material is added in the first ball milling material, obtains mixed once material after being well mixed, mixed once material then is carried out into secondary ball milling, obtained Second ball milling material;
Wherein, described in S12 during a ball milling, ball milling is carried out according to following mass ratio:First proportioning material:Abrading-ball:Water= 1.2:3:0.7, Ball-milling Time 20h, then sieved with 325 mesh mesh screens, its screen over-size is 0.2%, during the secondary ball milling, is pressed Ball milling is carried out according to following mass ratio:Mixed once material:Abrading-ball:Water=1.2:2.5:0.9, Ball-milling Time 3h;
S13, dehydration:
Second ball milling material obtained by step 2 is dehydrated, material must be dehydrated;
Wherein, the water content of gained dehydration material is 24%;
S14, vacuum pugging:
Dehydration material obtained by step 3 is placed in pugging in vacuum deairing machine, obtains pugging material;
It is S15, old:
Pugging material progress obtained by step 4 is old, obtain high feldspathic ceramic body material.
The method for preparing ceramic with described high feldspathic ceramic body material, comprises the following steps:
S21, shaping:
Ceramic molding blank is made in high feldspathic ceramic body material obtained by step S15;
S22, glazing:
Glazing is carried out to ceramic molding blank obtained by step S21, obtains glazing ceramic body;
S23, firing:
Glazing ceramic body obtained by step S22 is fired, high feldspathic ceramics are obtained after cooling.
Wherein, in step S23 sintering procedures, 1190 DEG C, when being then incubated first are warming up to 1.8 DEG C/min heating rate Between 80 minutes, produce high feldspathic ceramics after finally cooling down and prepare ceramic.
The high feldspathic ceramic of the gained of the embodiment of the present invention 1 to 6 is subjected to performance detection, testing result such as following table:
It was found from the data obtained of table 1, with the present invention high feldspathic ceramic body material prepare high feldspar ceramics product, its Rupture strength performance is strong, and whiteness is high, and thermal stability is strong.
It should be understood by those skilled in the art that the present invention is not limited to the above embodiments, above-described embodiment and explanation Merely illustrating the principles of the invention described in book, without departing from the spirit and scope of the present invention, the present invention also have Various changes and modifications, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention By appended claims and its equivalent thereof.

Claims (9)

1. high feldspathic ceramic body material, it is characterised in that including base-material and additive, the mass ratio of the base-material and additive For:100:3 ~ 8, wherein, the base-material includes following component in percentage by weight:Potassium feldspar 30 ~ 40%, albite 15 ~ 28%, Longyan kaolin 15~25%, lithium feldspar 5~15%, Guangxi white clay 18~25%, calcination of talc 1 ~ 5%, add up to 100%.
2. high feldspathic ceramic body material according to claim 1, it is characterised in that the additive is anti-reflection to viscosify Agent.
3. high feldspathic ceramic body material according to claim 1, it is characterised in that the additive is included according to weight The following component of percentages:Viscosify transparent agent 40 ~ 50%, glass phase tackifier 50 ~ 60%, total amount 100%.
4. high feldspathic ceramic body material according to claim 3, it is characterised in that the thickening transparent agent melts for boron Block, the glass phase tackifier are white carbon.
5. the preparation method of the high feldspathic ceramic body material described in Claims 1-4 any one, it is characterised in that including Following steps:
S11, stock:
The potassium feldspar, albite, lithium feldspar, calcination of talc and Guangxi white clay are well mixed according to the quality proportioning, obtained First proportioning material, Longyan kaolin and additive are well mixed according to the quality proportioning, obtain the second proportioning material;
S12, ball milling:
First proportioning material obtained by step 1 is subjected to a ball milling, the first ball milling material is obtained, is then matched obtained by step 1 second Material is added in the first ball milling material, obtains mixed once material after being well mixed, mixed once material finally is carried out into secondary ball milling, obtains second Ball milling material;
S13, dehydration:
Second ball milling material obtained by step 2 is dehydrated, material must be dehydrated;
S14, vacuum pugging:
Dehydration material obtained by step 3 is placed in pugging in vacuum deairing machine, obtains pugging material;
It is S15, old:
Pugging material progress obtained by step 4 is old, obtain high feldspathic ceramic body material.
6. the preparation method of high feldspathic ceramic body material according to claim 5, it is characterised in that described in step S12 During ball milling, ball milling, the first proportioning material are carried out according to following mass ratio:Abrading-ball:Water=1 ~ 1.2:3:0.7, Ball-milling Time 20 ~ 22h, then sieved with 300 ~ 350 mesh mesh screens, its screen over-size is 0.1 ~ 0.3%, during the secondary ball milling, according to following mass ratio Carry out ball milling, mixed once material:Abrading-ball:Water=1 ~ 1.2:2.5:0.9, Ball-milling Time is 2 ~ 3h.
7. the preparation method of high feldspathic ceramic body material according to claim 5, it is characterised in that obtained by step S13 The water content of dehydration material is 23 ~ 26%.
8. the method for preparing ceramic with the high feldspathic ceramic body material described in claim 1, it is characterised in that including such as Lower step:
S21, shaping:
Ceramic molding blank is made in high feldspathic ceramic body material obtained by step S15;
S22, glazing:
Glazing is carried out to ceramic molding blank obtained by step S21, obtains glazing ceramic body;
S23, firing:
Glazing ceramic body obtained by step S22 is fired, high feldspathic ceramics are obtained after cooling.
9. the method for preparing ceramic with high feldspathic ceramic body material described in claim 8, it is characterised in that step In S23 sintering procedures, 1180 ~ 1220 DEG C first are warming up to 1 ~ 2 DEG C/min heating rate, then soaking time 40 ~ 60 minutes, Finally cool down and produce high feldspathic ceramics and prepare ceramic.
CN201711052699.6A 2017-11-01 2017-11-01 High feldspathic ceramic body material and preparation method thereof, the method for preparing with it ceramic Pending CN107805047A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711052699.6A CN107805047A (en) 2017-11-01 2017-11-01 High feldspathic ceramic body material and preparation method thereof, the method for preparing with it ceramic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711052699.6A CN107805047A (en) 2017-11-01 2017-11-01 High feldspathic ceramic body material and preparation method thereof, the method for preparing with it ceramic

Publications (1)

Publication Number Publication Date
CN107805047A true CN107805047A (en) 2018-03-16

Family

ID=61582336

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711052699.6A Pending CN107805047A (en) 2017-11-01 2017-11-01 High feldspathic ceramic body material and preparation method thereof, the method for preparing with it ceramic

Country Status (1)

Country Link
CN (1) CN107805047A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108409288A (en) * 2018-04-04 2018-08-17 醴陵益新陶瓷有限公司 Hard-paste ceramic material and the method for preparing ceramic product using it
CN113213906A (en) * 2021-05-28 2021-08-06 醴陵千汇实业有限公司 Processing method of feldspar porcelain blank material

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102674804A (en) * 2012-06-06 2012-09-19 景德镇陶瓷学院 Reinforcing porcelain blank suitable for Longquan green glaze and preparation method of product thereof
JP5083971B2 (en) * 2008-03-11 2012-11-28 三重県 Composition for low-temperature fired porcelain and method for producing low-temperature fired porcelain
CN103951380A (en) * 2014-04-02 2014-07-30 景德镇陶瓷学院 High-whiteness high-transparency reinforced porcelain and its preparation method
CN107056249A (en) * 2017-04-25 2017-08-18 福建德化五洲陶瓷股份有限公司 High-performance ceramic whiteware base substrate and preparation method thereof
CN107226689A (en) * 2017-07-25 2017-10-03 合肥达户电线电缆科技有限公司 A kind of preparation method of novel environment friendly ceramic tile

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5083971B2 (en) * 2008-03-11 2012-11-28 三重県 Composition for low-temperature fired porcelain and method for producing low-temperature fired porcelain
CN102674804A (en) * 2012-06-06 2012-09-19 景德镇陶瓷学院 Reinforcing porcelain blank suitable for Longquan green glaze and preparation method of product thereof
CN103951380A (en) * 2014-04-02 2014-07-30 景德镇陶瓷学院 High-whiteness high-transparency reinforced porcelain and its preparation method
CN107056249A (en) * 2017-04-25 2017-08-18 福建德化五洲陶瓷股份有限公司 High-performance ceramic whiteware base substrate and preparation method thereof
CN107226689A (en) * 2017-07-25 2017-10-03 合肥达户电线电缆科技有限公司 A kind of preparation method of novel environment friendly ceramic tile

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108409288A (en) * 2018-04-04 2018-08-17 醴陵益新陶瓷有限公司 Hard-paste ceramic material and the method for preparing ceramic product using it
CN113213906A (en) * 2021-05-28 2021-08-06 醴陵千汇实业有限公司 Processing method of feldspar porcelain blank material

Similar Documents

Publication Publication Date Title
CN107188530B (en) A kind of preparation method of low-cost and high-performance low expansion ceramic blank and its ceramic product
CN109095775B (en) Transparent glaze suitable for high-strength white porcelain and preparation method thereof
CN101979359B (en) Ultra-low temperature sintered ceramic tiles and preparation method thereof
CN104496438B (en) A kind of quartz sand ore mine tailing or silica sand ore deposit mine tailing base high-strength ceramic plate and preparation method thereof
CN104692808A (en) Additive and method for lowering ceramic firing temperature
CN109516779B (en) Medium-temperature crack glaze household porcelain and preparation method thereof
CN110526694B (en) Marble ceramic tile blank with adjustable thermal expansion coefficient and preparation method thereof
CN103753410A (en) Low-temperature metal ceramic blinder grinding wheel and production method thereof
CN105884200B (en) A method of manufacturing devitrified glass ceramics composite material using industrial fly ash and vitrifying slag
CN105218170B (en) A kind of high-hardness, wearable exempts to polish iron microcrystalline glass in series ceramic clad plate and preparation method thereof
CN105669161A (en) Method of reductive firing of ceramic at medium temperature (1190-1260 DEG C)
CN104211443A (en) Energy-saving and environmental-friendly ceramic transparent glaze and preparation method thereof
CN106396649B (en) A kind of high quartz-ceramics and preparation method thereof
CN105503148A (en) Preparation method of high-strength magnesium Longquan celadon billet, glaze and product
CN106380176A (en) High-plasticity daily heat-resistant ceramic and preparation method thereof
CN111892389A (en) Multi-element composite flux low-temperature sintered marble ceramic tile blank and preparation method thereof
CN107805047A (en) High feldspathic ceramic body material and preparation method thereof, the method for preparing with it ceramic
CN106746656B (en) Low-temperature fast-firing matte glaze and preparation method thereof
CN113800770A (en) Intermediate-temperature double-layer transmutation fancy glaze and manufacturing method thereof
CN111675534B (en) Heat-resistant porcelain with high thermal shock resistance
CN103193515A (en) One-process fast-fired transparent microcrystalline brick and production process thereof
CN102924046B (en) Ceramic vetrified tile and blank and preparation method thereof
CN101811827A (en) Glass ceramic raw material prepared by utilizing scrapped glass ceramic and method for producing glass ceramic products by utilizing same
CN102924090B (en) Vitrified ceramic tile blank and vitrified ceramic tile preparation method thereof
CN109111117A (en) A kind of red glaze of pottery using flyash

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180316

RJ01 Rejection of invention patent application after publication