CN107793997A - Water-resistant cigarette adhesive - Google Patents
Water-resistant cigarette adhesive Download PDFInfo
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- CN107793997A CN107793997A CN201711146533.0A CN201711146533A CN107793997A CN 107793997 A CN107793997 A CN 107793997A CN 201711146533 A CN201711146533 A CN 201711146533A CN 107793997 A CN107793997 A CN 107793997A
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- water
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- resistant type
- dispersant
- essential oil
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 45
- 239000000853 adhesive Substances 0.000 title abstract description 11
- 230000001070 adhesive effect Effects 0.000 title abstract description 9
- 239000000654 additive Substances 0.000 claims abstract description 35
- 230000000996 additive effect Effects 0.000 claims abstract description 35
- 239000002270 dispersing agent Substances 0.000 claims abstract description 29
- 239000000341 volatile oil Substances 0.000 claims abstract description 27
- 238000007599 discharging Methods 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 239000003292 glue Substances 0.000 claims description 40
- 235000007164 Oryza sativa Nutrition 0.000 claims description 23
- 239000004568 cement Substances 0.000 claims description 23
- 235000009566 rice Nutrition 0.000 claims description 23
- 239000001913 cellulose Substances 0.000 claims description 20
- 229920002678 cellulose Polymers 0.000 claims description 20
- 238000004880 explosion Methods 0.000 claims description 18
- 239000012188 paraffin wax Substances 0.000 claims description 14
- 239000013530 defoamer Substances 0.000 claims description 13
- 239000002028 Biomass Substances 0.000 claims description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 11
- 239000011285 coke tar Substances 0.000 claims description 10
- 238000003763 carbonization Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000012184 mineral wax Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical group CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 6
- 239000010668 rosemary oil Substances 0.000 claims description 6
- 229940058206 rosemary oil Drugs 0.000 claims description 6
- 240000008042 Zea mays Species 0.000 claims description 5
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 235000009973 maize Nutrition 0.000 claims description 5
- 239000010902 straw Substances 0.000 claims description 5
- 238000007654 immersion Methods 0.000 claims description 4
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 241000205585 Aquilegia canadensis Species 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 239000010656 jasmine oil Substances 0.000 claims description 3
- -1 polypropylene glycerol Polymers 0.000 claims description 3
- 150000004291 polyenes Chemical class 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000002244 precipitate Substances 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 229920002545 silicone oil Polymers 0.000 claims 1
- 238000003756 stirring Methods 0.000 abstract description 3
- 229920000715 Mucilage Polymers 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 1
- 238000005303 weighing Methods 0.000 abstract 1
- 241000209094 Oryza Species 0.000 description 19
- 239000007789 gas Substances 0.000 description 14
- 239000000047 product Substances 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 7
- 229920002472 Starch Polymers 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000008107 starch Substances 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- 229920000083 poly(allylamine) Polymers 0.000 description 4
- 229920002689 polyvinyl acetate Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 241000208125 Nicotiana Species 0.000 description 3
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- 239000010903 husk Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 238000010025 steaming Methods 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000007799 cork Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 235000019505 tobacco product Nutrition 0.000 description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000011895 specific detection Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J197/00—Adhesives based on lignin-containing materials
- C09J197/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a water-resistant cigarette adhesive, and belongs to the technical field of adhesives. Weighing 60-80 parts of modified mucilage, 5-8 parts of essential oil, 12-15 parts of mixed additive, 4-7 parts of dispersing agent, 3-5 parts of defoaming agent and 15-25 parts of water in sequence, stirring and mixing the essential oil and the mixed additive at the temperature of 50-60 ℃ and the rotating speed of 260-300 r/min, then adding the modified mucilage, the dispersing agent, the defoaming agent and the water into the mixture of the essential oil and the mixed additive in sequence, stirring and mixing at the temperature of 60-75 ℃ and the rotating speed of 250-280 r/min, cooling, discharging, and obtaining the water-resistant cigarette adhesive. The water-resistant cigarette adhesive prepared by the technical scheme of the invention has the characteristics of moderate viscosity, good fluidity and obviously improved water resistance compared with the traditional cigarette adhesive.
Description
Technical field
The invention discloses a kind of water-resistant type cigarette glue, belong to field of adhesive technology.
Background technology
One tobacco product is made up of tens kinds of smoking materials, except key components such as pipe tobacco, flavouring essence for tobacco and cork papers
Outside, it is also one of auxiliary material for can not be ignored in tobacco product to be bonded filter stick, cigarette paper, cork paper and packing box with adhesive.Cigarette
Glue includes connecing mouth glue（Dosage relative maximum）, filter stick glue, middle seam glue, applique glue, capsule package glue and large packaging glue etc. it is several big
Type, it is generally used for the manufacture of filter rod, the rolling of cigarette paper, the tipping of filter tip, capsule packaging, barrel packaging, aureate pullcord glue
Connect, the technique such as joint sealing and labelling.The prerequisite main performance of cigarette glue is：1. be free of organic solvent, nontoxic, free from extraneous odour and
It is pollution-free；2. there is suitable viscosity and good stability（Such as storage stability, mechanical stability）；3. it is fast to be bonded speed
The uniform bonding of spraying is smooth etc..This has required cigarette glue modest viscosity, and viscosity is too high, influences its mobility；Viscosity is too low,
Influence its plybonding effect.
Cigarette glue is in polyvinyl acetate（PVAc）Grow up on the basis of emulsion.The cigarette glue having been developed that at present
Mainly emulsion glue, except PVAc emulsions, also vinyl acetate-ethylene copolymerization emulsions（VAE）, the price of this 2 kinds of emulsion glues is high,
Security is low, the quality and mouthfeel of the gases affect discharged during burning to cigarette.The PVAc emulsions of one pack system are in cigarette industry
The defects of certain, such as water resistance, cold resistance, stability difference in be present.Simultaneously as its glass transition temperature is higher, just
Viscosity is low, and cigarette feel is bad after doing, and is not applied for high-speed cigarette machine.In order to improve its performance, people are carried out to it
Modified, although modified emulsion glue performance increases, but cost also improves therewith.In recent years, as people's environmental protection is anticipated
The enhancing of knowledge, starch also enter the sight of people therewith.Starch is green product, is widely used renewable natural polymer
Material, it is harmless.Researcher makes starch adhesive by carrying out the method for modifying such as physics, chemistry, biology to starch
Performance is greatly improved.But the problem of traditional starch type cigarette glue solid content is low, poor water resistance, which is still it, promotes and answers
Obstacle.
Therefore, the shortcomings that how improving conventional roll smoked sheet poor fluidity and poor water resistance, to obtain more high combination property
Cigarette glue, it is that it is promoted and is applied to broader field, meets industrial production demand urgent problem to be solved.
The content of the invention
The present invention solves the technical problem of：For conventional roll smoked sheet mobility is bad and the shortcomings that poor water resistance,
Provide a kind of water-resistant type cigarette glue.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of water-resistant type cigarette glue, is made up of the raw material of following parts by weight：
Modified 60~80 parts of rubber cement
5~8 parts of essential oil
12~15 parts of additive package
4~7 parts of dispersant
3~5 parts of defoamer
15~25 parts of water
The preparation method of the modified rubber cement is：
Rice hull cellulose is added and steamed in quick-fried tank, stream explosion process, discharging, gas explosion rice hull cellulose is obtained, by gas explosion rice hull cellulose and polyene
Propylamine in mass ratio 3：1~4：1 mixing, and the water of 2~5 times of gas explosion rice hull cellulose quality is added, after being stirred, use hydroxide
Sodium solution adjusts pH to 10.5~11.8, constant temperature immersion, obtains modified rubber cement；
The preparation method of the additive package is：
Maize straw is moved into retort, charing process, discharging, obtain carbonization residue, carbonization residue is moved into centrifuge, centrifuged
After separation, precipitate, filtering, obtain biomass coke tar, biomass coke tar is moved into destilling tower, take the distillation that temperature is 180~220 DEG C
Component, obtain additive；By paraffin and additive in mass ratio 10：1~13：1 mixing, after being stirred, obtains additive package；
The preparation method of the water-resistant type cigarette glue is：
（1）Formed by raw material and weigh each component；
（2）Essential oil and additive package are stirred, and sequentially add modified rubber cement, dispersant, defoamer and water, heating is stirred
Mixing is mixed, is cooled, discharging, produces water-resistant type cigarette glue.
The essential oil is Rosemary Oil, any one in honeysuckle essential oil or refined jasmine oil.
The dispersant is dispersant NNO, any one in Dispersant MF or dispersant 5040.
The defoamer is propane diols, any one in dimethicone or polypropylene glycerol aether.
The paraffin is mineral wax mixture of the carbon number between 20~24.
The beneficial effects of the invention are as follows：
（1）The present invention is when preparing cigarette glue using modified rubber cement, and first, the rice hull cellulose through gas explosion processing in modified rubber cement is again
After base extraction, lignin and cellulosic sections degraded in rice hull cellulose, and crosslink, so that modified rubber cement has
Viscosity, and due to being alkalescence by modified rubber cement, cigarette paper can be activated to a certain extent after being contacted with cigarette paper, make cigarette
Paper activity improves, so that the initial bonding strength of product improves, secondly as modified rubber cement is in alkalescence, and the titanium dioxide in rice hull cellulose
Silicon can be partly dissolved, and form silicate, and contain polyallylamine in modified rubber cement, can be in cigarette after absorbing carbon dioxide
Cross-linked network is formed in colloid system, so as to which silicate is fixed in system, makes the mobile performance of product improve, water resistance carries
It is high；
（2）The present invention adds additive package when preparing cigarette glue, on the one hand, contains less biomass in additive package
The cut of higher temperature in tar, after heating in cigarette glue system, the initial bonding strength of product can be improved, while make the resistance to of product
It is water-based to be improved；On the other hand, paraffin is contained in additive package, after being added in cigarette glue system, due to paraffin
Mobility is higher during thawing, can improve the mobility of product, be easy to coat, and because paraffin has hydrophobicity, simultaneously
With certain adhesion strength, so that the water resistance and initial bonding strength of product are improved.
Embodiment
Rice hull cellulose is moved into and steamed in quick-fried tank, and vapor is passed through with 45~60mL/min speed to steaming in quick-fried tank, until tank
Interior pressure is 2.2~2.6MPa, and after pressurize handles 12~18min, moment opens tank bottom valve, discharging, obtains gas explosion rice hull cellulose,
By gas explosion rice hull cellulose and polyallylamine in mass ratio 3：1~4：1 is mixed in beaker, and gas explosion rice husk fibre is added into beaker
The water of 2~5 times of quality is tieed up, is 45~55 DEG C in temperature, under conditions of rotating speed is 280~300r/min, it is stirred 10~
After 15min, the sodium hydroxide solution of mass fraction 3~7% is added into beaker, adjusts material pH to 10.5~11.8 in beaker,
Under conditions of temperature is 40~50 DEG C, constant temperature soaks 5~8h, obtains modified rubber cement；Maize straw is moved into retort, with 45
~60 DEG C/h heating rate is warming up to 500~600 DEG C, insulation 2~3h of charing, discharging, obtains carbonization residue, carbonization residue is moved
Enter centrifugal separator, after the speed that rotating speed is 7000~9000r/min centrifuges 10~15min, natural sedimentation 60~
80min, filtering, obtains filtrate, produces biomass coke tar, biomass coke tar is moved into destilling tower fractionation, it is 180~220 to take temperature
Distillation component under conditions of DEG C, obtains additive；By paraffin and additive in mass ratio 10：1~13：1 is mixed in reactor,
It is 45~60 DEG C in temperature, under conditions of rotating speed is 200~240r/min, is stirred 45~60min, obtains additive package；
Count in parts by weight and weigh 60~80 parts of modified rubber cements successively, 5~8 parts of essential oils, 12~15 parts of additive packages, 4~7 parts scattered
Agent, 3~5 parts of defoamers and 15~25 parts of water, in temperature it is 50~60 DEG C by essential oil and additive package, rotating speed is 260~
15~25min is stirred under conditions of 300r/min, then adds be modified into the mixture of essential oil and additive package successively
Rubber cement, dispersant, defoamer and water, temperature are continued at as 60~75 DEG C, rotating speed stirs mixed under conditions of being 250~280r/min
35~55min is closed, 32~36 DEG C is cooled to, discharging, produces water-resistant type cigarette glue.The essential oil is Rosemary Oil, honeysuckle
Any one in essential oil or refined jasmine oil.The dispersant is dispersant NNO, any one in Dispersant MF or dispersant 5040
Kind.The defoamer is propane diols, any one in dimethicone or polypropylene glycerol aether.The paraffin is carbon number
Mineral wax mixture between 20~24.
Example 1
Rice hull cellulose is moved into and steamed in quick-fried tank, and vapor is passed through with 60mL/min speed to steaming in quick-fried tank, until tank internal pressure
Power is 2.6MPa, and after pressurize handles 18min, moment opens tank bottom valve, discharging, obtains gas explosion rice hull cellulose, and gas explosion rice husk is fine
Dimension and polyallylamine in mass ratio 4：1 is mixed in beaker, and the water of 5 times of gas explosion rice hull cellulose quality is added into beaker, in
Temperature is 55 DEG C, and under conditions of rotating speed is 300r/min, after being stirred 15min, the hydrogen of mass fraction 7% is added into beaker
Sodium hydroxide solution, material pH to 11.8 in beaker is adjusted, under conditions of temperature is 50 DEG C, constant temperature immersion 8h, obtain modified rubber cement；
Maize straw is moved into retort, 600 DEG C is warming up to 60 DEG C/h heating rate, insulation charing 3h, discharging, must carbonize residual
Slag, carbonization residue is moved into centrifugal separator, after the speed that rotating speed is 9000r/min centrifuges 15min, natural sedimentation
80min, filtering, obtains filtrate, produces biomass coke tar, and biomass coke tar is moved into destilling tower fractionation, takes the bar that temperature is 220 DEG C
Distillation component under part, obtains additive；By paraffin and additive in mass ratio 13：1 is mixed in reactor, in temperature be 60
DEG C, under conditions of rotating speed is 240r/min, 60min is stirred, obtains additive package；Count in parts by weight and weigh 80 parts successively
Modified rubber cement, 8 parts of essential oils, 15 parts of additive packages, 7 parts of dispersants, 5 parts of defoamers and 25 parts of water, by essential oil with mixing addition
Agent is 60 DEG C in temperature, and rotating speed is stirred 25min under conditions of being 300r/min, then successively to essential oil and additive package
Modified rubber cement, dispersant, defoamer and water are added in mixture, continues at temperature as 75 DEG C, rotating speed is 280r/min condition
Under be stirred 55min, be cooled to 36 DEG C, discharging, produce water-resistant type cigarette glue.The essential oil is Rosemary Oil.Described point
Powder is dispersant NNO.The defoamer is propane diols.The paraffin is mineral wax mixture of the carbon number between 24.
Example 2
Maize straw is moved into retort, 600 DEG C is warming up to 60 DEG C/h heating rate, insulation charing 3h, discharging, obtains charcoal
Change residue, carbonization residue is moved into centrifugal separator, it is naturally heavy after the speed that rotating speed is 9000r/min centrifuges 15min
Shallow lake 80min, filtering, obtains filtrate, produces biomass coke tar, biomass coke tar is moved into destilling tower fractionation, it is 220 DEG C to take temperature
Under the conditions of distillation component, obtain additive；By paraffin and additive in mass ratio 13：1 is mixed in reactor, in temperature be 60
DEG C, under conditions of rotating speed is 240r/min, 60min is stirred, obtains additive package；Count in parts by weight and weigh 8 parts successively
Essential oil, 15 parts of additive packages, 7 parts of dispersants, 5 parts of defoamers and 25 parts of water, by essential oil and additive package in temperature be 60
DEG C, rotating speed is stirred 25min under conditions of being 300r/min, then adds successively into the mixture of essential oil and additive package
Dispersant, defoamer and water, temperature are continued at as 75 DEG C, rotating speed is stirred 55min under conditions of being 280r/min, is cooled to
36 DEG C, discharging, produce water-resistant type cigarette glue.The essential oil is Rosemary Oil.The dispersant is dispersant NNO.It is described to disappear
Infusion is propane diols.The paraffin is mineral wax mixture of the carbon number between 24.
Example 3
Rice hull cellulose is moved into and steamed in quick-fried tank, and vapor is passed through with 60mL/min speed to steaming in quick-fried tank, until tank internal pressure
Power is 2.6MPa, and after pressurize handles 18min, moment opens tank bottom valve, discharging, obtains gas explosion rice hull cellulose, and gas explosion rice husk is fine
Dimension and polyallylamine in mass ratio 4：1 is mixed in beaker, and the water of 5 times of gas explosion rice hull cellulose quality is added into beaker, in
Temperature is 55 DEG C, and under conditions of rotating speed is 300r/min, after being stirred 15min, the hydrogen of mass fraction 7% is added into beaker
Sodium hydroxide solution, material pH to 11.8 in beaker is adjusted, under conditions of temperature is 50 DEG C, constant temperature immersion 8h, obtain modified rubber cement；
Count in parts by weight and weigh 80 parts of modified rubber cements, 8 parts of essential oils, 7 parts of dispersants, 5 parts of defoamers and 25 parts of water successively, by essential oil with
Modified rubber cement, dispersant, defoamer and water, it is 75 DEG C in temperature, rotating speed is stirred 55min under conditions of being 280r/min,
36 DEG C are cooled to, discharging, produces water-resistant type cigarette glue.The essential oil is Rosemary Oil.The dispersant is dispersant NNO.
The defoamer is propane diols.The paraffin is mineral wax mixture of the carbon number between 24.
Comparative example：
The water-resistant type cigarette glue of the gained of example 1 to 3 and comparative example product are subjected to performance detection, specific detection method is as follows：
1. mobility：Then temperature control is measured according to GB/T2794 standards to test specimen viscosity in (25 ± 0.5) DEG C；
2. water resistance：It is measured according to GB/T17657 standards, by pine bonded part（60±2）DEG C dry 30h, then by it
It is immersed in 25 DEG C of water, the record weld cracking time.
Specific testing result is as shown in table 1：
Table 1
| Detection project | Example 1 | Example 2 | Example 3 | Comparative example |
| Viscosity/mPas | 2031 | 2643 | 2287 | 1569 |
| Come unglued test specimen/min | 55 | 45 | 49 | 31 |
The water-resistant type cigarette glue modest viscosity prepared from the testing result of table 1, technical solution of the present invention, has good flowing
Property, and the characteristics of water resistance significantly improves compared with conventional roll smoked sheet, had broad prospects in the development that tobacco makes industry.
Claims (5)
1. a kind of water-resistant type cigarette glue, it is characterised in that be made up of the raw material of following parts by weight：
Modified 60~80 parts of rubber cement
5~8 parts of essential oil
12~15 parts of additive package
4~7 parts of dispersant
3~5 parts of defoamer
15~25 parts of water
The preparation method of the modified rubber cement is：
Rice hull cellulose is added and steamed in quick-fried tank, stream explosion process, discharging, gas explosion rice hull cellulose is obtained, by gas explosion rice hull cellulose and polyene
Propylamine in mass ratio 3：1~4：1 mixing, and the water of 2~5 times of gas explosion rice hull cellulose quality is added, after being stirred, use hydroxide
Sodium solution adjusts pH to 10.5~11.8, constant temperature immersion, obtains modified rubber cement；
The preparation method of the additive package is：
Maize straw is moved into retort, charing process, discharging, obtain carbonization residue, carbonization residue is moved into centrifuge, centrifuged
After separation, precipitate, filtering, obtain biomass coke tar, biomass coke tar is moved into destilling tower, take the distillation that temperature is 180~220 DEG C
Component, obtain additive；By paraffin and additive in mass ratio 10：1~13：1 mixing, after being stirred, obtains additive package；
The preparation method of the water-resistant type cigarette glue is：
（1）Formed by raw material and weigh each component；
（2）Essential oil and additive package are stirred, and sequentially add modified rubber cement, dispersant, defoamer and water, heating is stirred
Mixing is mixed, is cooled, discharging, produces water-resistant type cigarette glue.
A kind of 2. water-resistant type cigarette glue according to claim 1, it is characterised in that：The essential oil is Rosemary Oil, gold
Any one in honeysuckle flower essential oil or refined jasmine oil.
A kind of 3. water-resistant type cigarette glue according to claim 1, it is characterised in that：The dispersant is dispersant NNO, point
Any one in powder MF or dispersant 5040.
A kind of 4. water-resistant type cigarette glue according to claim 1, it is characterised in that：The defoamer is propane diols, diformazan
Any one in base silicone oil or polypropylene glycerol aether.
A kind of 5. water-resistant type cigarette glue according to claim 1, it is characterised in that：The paraffin be carbon number 20~
Mineral wax mixture between 24.
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| CN114410249A (en) * | 2022-02-16 | 2022-04-29 | 连云港昌瑞科技有限公司 | Preparation method of waterproof heat-resistant cigarette adhesive |
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| CN102162199A (en) * | 2011-05-03 | 2011-08-24 | 浙江农林大学 | Method for extracting lignin from raw grass |
| CN105505269A (en) * | 2016-01-06 | 2016-04-20 | 浙江农林大学 | Lignin adhesive production method through steam explosion conducted on gramineous plants |
| CN106279718A (en) * | 2016-08-08 | 2017-01-04 | 山东理工大学 | A kind of powder of straw method of modifying and the binder matrix containing modified straw powder |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102162199A (en) * | 2011-05-03 | 2011-08-24 | 浙江农林大学 | Method for extracting lignin from raw grass |
| CN105505269A (en) * | 2016-01-06 | 2016-04-20 | 浙江农林大学 | Lignin adhesive production method through steam explosion conducted on gramineous plants |
| CN106279718A (en) * | 2016-08-08 | 2017-01-04 | 山东理工大学 | A kind of powder of straw method of modifying and the binder matrix containing modified straw powder |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114410249A (en) * | 2022-02-16 | 2022-04-29 | 连云港昌瑞科技有限公司 | Preparation method of waterproof heat-resistant cigarette adhesive |
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