CN107793892A - A kind of photocuring waterborne anti-fouling coatings - Google Patents
A kind of photocuring waterborne anti-fouling coatings Download PDFInfo
- Publication number
- CN107793892A CN107793892A CN201711173562.6A CN201711173562A CN107793892A CN 107793892 A CN107793892 A CN 107793892A CN 201711173562 A CN201711173562 A CN 201711173562A CN 107793892 A CN107793892 A CN 107793892A
- Authority
- CN
- China
- Prior art keywords
- parts
- fouling coatings
- waterborne anti
- rosin
- defoamer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention provides a kind of photocuring waterborne anti-fouling coatings, and its raw material is calculated as by weight:30 ~ 45 parts of bisphenol-a epoxy acrylate, 25 ~ 38 parts of aqueous epoxy resins, 20 ~ 25 parts of hydroxyethyl methacrylate, 14 ~ 20 parts of acrylic emulsion, 8 ~ 12 parts of basic zinc carbonate, 2 ~ 5 parts of rosin, 2 ~ 4 parts of talcum powder, 2 ~ 3 parts of light trigger, 1 ~ 3 part of defoamer, 1 ~ 3 part of thickener, 1 ~ 3 part of coalescents, 70 parts of water.The photocuring waterborne anti-fouling coatings of the present invention, antifouling capacity is strong, and use range is extensive, can effectively prevent destruction of the various pollution sources to dope layer.
Description
Technical field
The present invention relates to paint field, and in particular to a kind of photocuring waterborne anti-fouling coatings.
Technical background
Paint, in general, it can exactly be coated in coated article body surface face and the continuous film of firm attachment can be formed
Material, whether traditional coating products using natural materials as raw material, or in modern development to synthesize chemical products
For the coating products of raw material, organic chemical industry's macromolecular material is belonged to, the film formed belongs to high-molecular compound type, presses
The classification for the chemical products passed through according to the modern times, coating belong to fine chemical product, and modern coating is progressively turning into a kind of more
Functional engineering material, it is an important industry in chemical industry.In daily, coating use is frequently subjected to respectively in product
The destruction of kind pollution sources, the high coating products of a soil resistance can extend the service life of coating, improve the quality of product.
The content of the invention
The technical problems to be solved by the invention are:A kind of photocuring waterborne anti-fouling coatings are provided, antifouling capacity is strong, uses
It is in extensive range, it can effectively prevent destruction of the various pollution sources to dope layer.In order to solve the above technical problems, the invention provides with
Lower technical scheme:
A kind of photocuring waterborne anti-fouling coatings, its raw material are calculated as by weight:It is 30 ~ 45 parts of bisphenol-a epoxy acrylate, water-based
25 ~ 38 parts of epoxy resin, 20 ~ 25 parts of hydroxyethyl methacrylate, 14 ~ 20 parts of acrylic emulsion, 8 ~ 12 parts of basic zinc carbonate, pine
Fragrant 2 ~ 5 parts, 2 ~ 4 parts of talcum powder, 2 ~ 3 parts of light trigger, 1 ~ 3 part of defoamer, 1 ~ 3 part of thickener, 1 ~ 3 part of coalescents, water 70
Part.
As preferred:Its raw material is calculated as by weight:36 parts of bisphenol-a epoxy acrylate, 28 parts of aqueous epoxy resins,
23 parts of hydroxyethyl methacrylate, 18 parts of acrylic emulsion, 9 parts of basic zinc carbonate, 3 parts of rosin, 3 parts of talcum powder, light trigger 2
Part, 2 parts of defoamer, 2 parts of thickener, 2 parts of coalescents, 70 parts of water.
Preferably, in the rosin rosin acid Han Liang≤85%.
Preferably, the mass ratio of the defoamer, thickener and coalescents is 2:1:1.
Compared with prior art, the present invention program has beneficial effect:The photocuring waterborne anti-fouling coatings collocation of the present invention
Scientific and reasonable, raw material economics, antifouling capacity is strong, can effectively prevent destruction of the various pollution sources to dope layer, and use range is extensive.
Embodiment
The present invention is described in further detail below by specific embodiment.
Embodiment 1:A kind of photocuring waterborne anti-fouling coatings, its raw material are calculated as by weight:Bisphenol-a epoxy acrylate
30 parts, 38 parts of aqueous epoxy resins, 25 parts of hydroxyethyl methacrylate, 20 parts of acrylic emulsion, 8 parts of basic zinc carbonate, rosin 5
Part, 4 parts of talcum powder, 2 parts of light trigger, 2 parts of defoamer, 1 part of thickener, 1 part of coalescents, 70 parts of water.
Han Liang≤85% of rosin acid in the rosin.
The mass ratio of the defoamer, thickener and coalescents is 2:1:1.
Embodiment 2:A kind of photocuring waterborne anti-fouling coatings, its raw material are calculated as by weight:Bisphenol-a epoxy acrylate
45 parts, 25 parts of aqueous epoxy resins, 20 parts of hydroxyethyl methacrylate, 20 parts of acrylic emulsion, 12 parts of basic zinc carbonate, rosin
2 parts, 2 parts of talcum powder, 3 parts of light trigger, 3 parts of defoamer, 1 part of thickener, 3 parts of coalescents, 70 parts of water.
Han Liang≤85% of rosin acid in the rosin.
Embodiment 3:A kind of photocuring waterborne anti-fouling coatings, its raw material are calculated as by weight:Bisphenol-a epoxy acrylate
36 parts, 28 parts of aqueous epoxy resins, 23 parts of hydroxyethyl methacrylate, 18 parts of acrylic emulsion, 9 parts of basic zinc carbonate, rosin 3
Part, 3 parts of talcum powder, 2 parts of light trigger, 2 parts of defoamer, 2 parts of thickener, 2 parts of coalescents, 70 parts of water.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made any repaiies
Change, equivalent substitution, improvement etc., should be included in the scope of the protection.
Claims (4)
1. a kind of photocuring waterborne anti-fouling coatings, it is characterised in that its raw material is calculated as by weight:Bisphenol type epoxy acrylic acid
30 ~ 45 parts of ester, 25 ~ 38 parts of aqueous epoxy resins, 20 ~ 25 parts of hydroxyethyl methacrylate, 14 ~ 20 parts of acrylic emulsion, alkali formula
8 ~ 12 parts of zinc carbonate, 2 ~ 5 parts of rosin, 2 ~ 4 parts of talcum powder, 2 ~ 3 parts of light trigger, 1 ~ 3 part of defoamer, 1 ~ 3 part of thickener, film forming
1 ~ 3 part of auxiliary agent, 70 parts of water.
2. photocuring waterborne anti-fouling coatings as claimed in claim 1, it is characterised in that its raw material is calculated as by weight:Bisphenol-A
36 parts of type epoxy acrylate, 28 parts of aqueous epoxy resins, 23 parts of hydroxyethyl methacrylate, 18 parts of acrylic emulsion, alkali formula
9 parts of zinc carbonate, 3 parts of rosin, 3 parts of talcum powder, 2 parts of light trigger, 2 parts of defoamer, 2 parts of thickener, 2 parts of coalescents, water 70
Part.
3. photocuring waterborne anti-fouling coatings as claimed in claim 1, it is characterised in that Han Liang of rosin acid in the rosin≤
85%。
4. photocuring waterborne anti-fouling coatings as claimed in claim 1, it is characterised in that the defoamer, thickener and film forming
The mass ratio of auxiliary agent is 2:1:1.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201711173562.6A CN107793892A (en) | 2017-11-22 | 2017-11-22 | A kind of photocuring waterborne anti-fouling coatings |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201711173562.6A CN107793892A (en) | 2017-11-22 | 2017-11-22 | A kind of photocuring waterborne anti-fouling coatings |
Publications (1)
Publication Number | Publication Date |
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CN107793892A true CN107793892A (en) | 2018-03-13 |
Family
ID=61535409
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201711173562.6A Withdrawn CN107793892A (en) | 2017-11-22 | 2017-11-22 | A kind of photocuring waterborne anti-fouling coatings |
Country Status (1)
Country | Link |
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CN (1) | CN107793892A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114736547A (en) * | 2022-04-21 | 2022-07-12 | 兰建情 | Photocuring water-based paint and emulsifying machine for producing same |
-
2017
- 2017-11-22 CN CN201711173562.6A patent/CN107793892A/en not_active Withdrawn
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114736547A (en) * | 2022-04-21 | 2022-07-12 | 兰建情 | Photocuring water-based paint and emulsifying machine for producing same |
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Legal Events
Date | Code | Title | Description |
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PB01 | Publication | ||
PB01 | Publication | ||
WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180313 |
|
WW01 | Invention patent application withdrawn after publication |