CN107793892A - A kind of photocuring waterborne anti-fouling coatings - Google Patents

A kind of photocuring waterborne anti-fouling coatings Download PDF

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Publication number
CN107793892A
CN107793892A CN201711173562.6A CN201711173562A CN107793892A CN 107793892 A CN107793892 A CN 107793892A CN 201711173562 A CN201711173562 A CN 201711173562A CN 107793892 A CN107793892 A CN 107793892A
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CN
China
Prior art keywords
parts
fouling coatings
waterborne anti
rosin
defoamer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711173562.6A
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Chinese (zh)
Inventor
黄波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu Nashuo Technology Co Ltd
Original Assignee
Chengdu Nashuo Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chengdu Nashuo Technology Co Ltd filed Critical Chengdu Nashuo Technology Co Ltd
Priority to CN201711173562.6A priority Critical patent/CN107793892A/en
Publication of CN107793892A publication Critical patent/CN107793892A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The present invention provides a kind of photocuring waterborne anti-fouling coatings, and its raw material is calculated as by weight:30 ~ 45 parts of bisphenol-a epoxy acrylate, 25 ~ 38 parts of aqueous epoxy resins, 20 ~ 25 parts of hydroxyethyl methacrylate, 14 ~ 20 parts of acrylic emulsion, 8 ~ 12 parts of basic zinc carbonate, 2 ~ 5 parts of rosin, 2 ~ 4 parts of talcum powder, 2 ~ 3 parts of light trigger, 1 ~ 3 part of defoamer, 1 ~ 3 part of thickener, 1 ~ 3 part of coalescents, 70 parts of water.The photocuring waterborne anti-fouling coatings of the present invention, antifouling capacity is strong, and use range is extensive, can effectively prevent destruction of the various pollution sources to dope layer.

Description

A kind of photocuring waterborne anti-fouling coatings
Technical field
The present invention relates to paint field, and in particular to a kind of photocuring waterborne anti-fouling coatings.
Technical background
Paint, in general, it can exactly be coated in coated article body surface face and the continuous film of firm attachment can be formed Material, whether traditional coating products using natural materials as raw material, or in modern development to synthesize chemical products For the coating products of raw material, organic chemical industry's macromolecular material is belonged to, the film formed belongs to high-molecular compound type, presses The classification for the chemical products passed through according to the modern times, coating belong to fine chemical product, and modern coating is progressively turning into a kind of more Functional engineering material, it is an important industry in chemical industry.In daily, coating use is frequently subjected to respectively in product The destruction of kind pollution sources, the high coating products of a soil resistance can extend the service life of coating, improve the quality of product.
The content of the invention
The technical problems to be solved by the invention are:A kind of photocuring waterborne anti-fouling coatings are provided, antifouling capacity is strong, uses It is in extensive range, it can effectively prevent destruction of the various pollution sources to dope layer.In order to solve the above technical problems, the invention provides with Lower technical scheme:
A kind of photocuring waterborne anti-fouling coatings, its raw material are calculated as by weight:It is 30 ~ 45 parts of bisphenol-a epoxy acrylate, water-based 25 ~ 38 parts of epoxy resin, 20 ~ 25 parts of hydroxyethyl methacrylate, 14 ~ 20 parts of acrylic emulsion, 8 ~ 12 parts of basic zinc carbonate, pine Fragrant 2 ~ 5 parts, 2 ~ 4 parts of talcum powder, 2 ~ 3 parts of light trigger, 1 ~ 3 part of defoamer, 1 ~ 3 part of thickener, 1 ~ 3 part of coalescents, water 70 Part.
As preferred:Its raw material is calculated as by weight:36 parts of bisphenol-a epoxy acrylate, 28 parts of aqueous epoxy resins, 23 parts of hydroxyethyl methacrylate, 18 parts of acrylic emulsion, 9 parts of basic zinc carbonate, 3 parts of rosin, 3 parts of talcum powder, light trigger 2 Part, 2 parts of defoamer, 2 parts of thickener, 2 parts of coalescents, 70 parts of water.
Preferably, in the rosin rosin acid Han Liang≤85%.
Preferably, the mass ratio of the defoamer, thickener and coalescents is 2:1:1.
Compared with prior art, the present invention program has beneficial effect:The photocuring waterborne anti-fouling coatings collocation of the present invention Scientific and reasonable, raw material economics, antifouling capacity is strong, can effectively prevent destruction of the various pollution sources to dope layer, and use range is extensive.
Embodiment
The present invention is described in further detail below by specific embodiment.
Embodiment 1:A kind of photocuring waterborne anti-fouling coatings, its raw material are calculated as by weight:Bisphenol-a epoxy acrylate 30 parts, 38 parts of aqueous epoxy resins, 25 parts of hydroxyethyl methacrylate, 20 parts of acrylic emulsion, 8 parts of basic zinc carbonate, rosin 5 Part, 4 parts of talcum powder, 2 parts of light trigger, 2 parts of defoamer, 1 part of thickener, 1 part of coalescents, 70 parts of water.
Han Liang≤85% of rosin acid in the rosin.
The mass ratio of the defoamer, thickener and coalescents is 2:1:1.
Embodiment 2:A kind of photocuring waterborne anti-fouling coatings, its raw material are calculated as by weight:Bisphenol-a epoxy acrylate 45 parts, 25 parts of aqueous epoxy resins, 20 parts of hydroxyethyl methacrylate, 20 parts of acrylic emulsion, 12 parts of basic zinc carbonate, rosin 2 parts, 2 parts of talcum powder, 3 parts of light trigger, 3 parts of defoamer, 1 part of thickener, 3 parts of coalescents, 70 parts of water.
Han Liang≤85% of rosin acid in the rosin.
Embodiment 3:A kind of photocuring waterborne anti-fouling coatings, its raw material are calculated as by weight:Bisphenol-a epoxy acrylate 36 parts, 28 parts of aqueous epoxy resins, 23 parts of hydroxyethyl methacrylate, 18 parts of acrylic emulsion, 9 parts of basic zinc carbonate, rosin 3 Part, 3 parts of talcum powder, 2 parts of light trigger, 2 parts of defoamer, 2 parts of thickener, 2 parts of coalescents, 70 parts of water.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the skill of this area For art personnel, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made any repaiies Change, equivalent substitution, improvement etc., should be included in the scope of the protection.

Claims (4)

1. a kind of photocuring waterborne anti-fouling coatings, it is characterised in that its raw material is calculated as by weight:Bisphenol type epoxy acrylic acid 30 ~ 45 parts of ester, 25 ~ 38 parts of aqueous epoxy resins, 20 ~ 25 parts of hydroxyethyl methacrylate, 14 ~ 20 parts of acrylic emulsion, alkali formula 8 ~ 12 parts of zinc carbonate, 2 ~ 5 parts of rosin, 2 ~ 4 parts of talcum powder, 2 ~ 3 parts of light trigger, 1 ~ 3 part of defoamer, 1 ~ 3 part of thickener, film forming 1 ~ 3 part of auxiliary agent, 70 parts of water.
2. photocuring waterborne anti-fouling coatings as claimed in claim 1, it is characterised in that its raw material is calculated as by weight:Bisphenol-A 36 parts of type epoxy acrylate, 28 parts of aqueous epoxy resins, 23 parts of hydroxyethyl methacrylate, 18 parts of acrylic emulsion, alkali formula 9 parts of zinc carbonate, 3 parts of rosin, 3 parts of talcum powder, 2 parts of light trigger, 2 parts of defoamer, 2 parts of thickener, 2 parts of coalescents, water 70 Part.
3. photocuring waterborne anti-fouling coatings as claimed in claim 1, it is characterised in that Han Liang of rosin acid in the rosin≤ 85%。
4. photocuring waterborne anti-fouling coatings as claimed in claim 1, it is characterised in that the defoamer, thickener and film forming The mass ratio of auxiliary agent is 2:1:1.
CN201711173562.6A 2017-11-22 2017-11-22 A kind of photocuring waterborne anti-fouling coatings Withdrawn CN107793892A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711173562.6A CN107793892A (en) 2017-11-22 2017-11-22 A kind of photocuring waterborne anti-fouling coatings

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711173562.6A CN107793892A (en) 2017-11-22 2017-11-22 A kind of photocuring waterborne anti-fouling coatings

Publications (1)

Publication Number Publication Date
CN107793892A true CN107793892A (en) 2018-03-13

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711173562.6A Withdrawn CN107793892A (en) 2017-11-22 2017-11-22 A kind of photocuring waterborne anti-fouling coatings

Country Status (1)

Country Link
CN (1) CN107793892A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114736547A (en) * 2022-04-21 2022-07-12 兰建情 Photocuring water-based paint and emulsifying machine for producing same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114736547A (en) * 2022-04-21 2022-07-12 兰建情 Photocuring water-based paint and emulsifying machine for producing same

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WW01 Invention patent application withdrawn after publication

Application publication date: 20180313

WW01 Invention patent application withdrawn after publication