CN107793784A - A kind of packaging material with environmental-protecting performance and preparation method thereof - Google Patents
A kind of packaging material with environmental-protecting performance and preparation method thereof Download PDFInfo
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- CN107793784A CN107793784A CN201610788385.1A CN201610788385A CN107793784A CN 107793784 A CN107793784 A CN 107793784A CN 201610788385 A CN201610788385 A CN 201610788385A CN 107793784 A CN107793784 A CN 107793784A
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- packaging material
- protecting performance
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Packages (AREA)
- Wrappers (AREA)
Abstract
The invention discloses a kind of packaging material with environmental-protecting performance, the raw material of following parts by weight is included：5 15 parts of sodium methyl silicate, 2 10 parts of polycaprolactone, 5 15 parts of molybdenum carbide, 5 15 parts of hexadienoic acid, 5 15 parts of molybdenum carbide, 25 parts of hyaluronic acid, 5 15 parts of zirconium carbide, 25 parts of zinc oxide, 8 20 parts of antioxidant, 10 25 parts of glycerine, 15 30 parts of cerium oxide, 10 30 parts of polyester fiber, 2 10 parts of milk of lime, 5 10 parts of Cellulose nanocrystal, 5 15 parts of viscose rayon, 5 10 parts of heat stabilizer, 5 20 parts of lubricant, 5 15 parts of soda, 20 35 parts of resin, 5 25 parts of polypropylene, 58 parts of quartz sand；Also disclose the preparation method of this kind of environmental-friendpacking packing material.
Description
Technical field
The present invention relates to field of packaging material, more particularly to a kind of packaging material and its preparation with environmental-protecting performance
Method.
Background technology
Packaging material refers to meet product packaging for manufacturing packing container, packing and decorating, packages printing, packed and transported etc.
Material used in it is required that, it is fine that it had both included metal, plastics, glass, ceramics, paper, bamboo sheet, wild mushroom class, natural fiber, chemistry
The main packaging material such as dimension, composite, include the auxiliary materials such as coating, adhesive, strapping, decoration, printing material again.
However, with the industrialized development of society, the packaging material that all trades and professions needs are related to is multifarious, and species is numerous
It is more, while the demand of corresponding packaging material is steeply risen.But embody its value in industrial society in packaging material
While, it is many drawbacks of also occur simultaneously, frequency of use and durability be not high, and the not degradable, gas that is volatilized is to ring
Border is harmful to, and reclaim mechanism lacks or non-recovery is worth etc..Therefore, a kind of bag with better performance and environmental sound is developed
Package material just seems particularly necessary.
The content of the invention
In order to solve the above technical problems, the present invention provides a kind of improved packaging material with environmental-protecting performance and its accordingly
Preparation method.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of packaging material with environmental-protecting performance, it is characterised in that include sodium methyl silicate 5-15 parts, polycaprolactone 2-10
Part, molybdenum carbide 5-15 parts, hexadienoic acid 5-15 parts, molybdenum carbide 5-15 parts, hyaluronic acid 2-5 parts, zirconium carbide 5-15 parts, zinc oxide
2-5 parts, antioxidant 8-20 parts, glycerine 10-25 parts, cerium oxide 15-30 parts, polyester fiber 10-30 parts, milk of lime 2-10 parts,
Cellulose nanocrystal 5-10 parts, viscose rayon 5-15 parts, heat stabilizer 5-10 parts, lubricant 5-20 parts, soda 5-15 parts, resin
20-35 parts, polypropylene 5-25 parts, quartz sand 5-8 parts.
Described antioxidant be Butylated Hydroxytoluene, butylated hydroxy anisole, dibutyl hydroxy toluene, propylgallate,
One or more in TBHQ, dilauryl thiodipropionate and benzoic acid.
Described heat stabilizer is lead sulfate tribasic, dibasic lead stearate, dibasic lead phosphite, tin dilaurate two
In butyl tin, dibutyitin maleate, dibutyl tin maleate, laurate, stearic acid, organic aliphatic acid and salicylic acid
It is one or more of.
The preparation method of the described packaging material with environmental-protecting performance, it is characterised in that comprise the following steps：
（1）Weigh sodium methyl silicate 5-15 parts, polycaprolactone 2-10 parts, molybdenum carbide 5-15 parts, hexadienoic acid 5-15 parts, molybdenum carbide
5-15 parts, hyaluronic acid 2-5 parts, zirconium carbide 5-15 parts, zinc oxide 2-5 parts, glycerine 10-25 parts, cerium oxide 15-30 parts, polyester
Fiber 10-30 parts, milk of lime 2-10 parts, Cellulose nanocrystal 5-10 parts, viscose rayon 5-15 parts, lubricant 5-20 parts, soda
5-15 parts, resin 20-35 parts, polypropylene 5-25 parts, quartz sand 5-8 parts, it is well mixed；
（2）Said components are added in rotor mixer and stirred, mixing speed is 100 revs/min, while is slowly added to anti-oxidant
Agent 8-20 parts and heat stabilizer 5-10 parts；
（3）After all components add, for heating rotor mixer to 200 DEG C, mixing speed is 500 revs/min, persistently stirs 60
Minute；
（4）Material magma obtained above is extruded；
（5）The material that extruding obtains is cooled down, then draws high plastotype, as finished product.
The step（5）In, the material that extruding obtains is cooled down, is cooled to room temperature.
The step（5）In, drawing high plastotype needs to be heated to 80-120 DEG C of progress.
Compared with prior art, its advantage is the present invention：
（1）The packaging material that the present invention obtains is transparent with sodium methyl silicate, polycaprolactone, molybdenum carbide, hexadienoic acid, molybdenum carbide
Matter acid, zirconium carbide, zinc oxide, glycerine, cerium oxide, polyester fiber, milk of lime, Cellulose nanocrystal, viscose rayon, lubricant,
Soda, resin, polypropylene, quartz sand are primary raw material, add antioxidant and heat stabilizer, are aided with high-temperature stirring, magma is squeezed
The techniques such as pressure, cooling plastotype so that the packaging material durability being prepared is high, environmentally safe, the simple ring of manufacture craft
Protect.
（2）The antioxidant used in the present invention stated is Butylated Hydroxytoluene, butylated hydroxy anisole, butylated hydroxy-a
One or more in benzene, propylgallate, TBHQ, dilauryl thiodipropionate and benzoic acid；Institute
The heat stabilizer used be lead sulfate tribasic, dibasic lead stearate, dibasic lead phosphite, dibutyl tin laurate,
One kind in dibutyitin maleate, dibutyl tin maleate, laurate, stearic acid, organic aliphatic acid and salicylic acid or
It is several, it is environment friendly and pollution-free industrial additive.
（3）The packaging material of the present invention, its raw material economics are easy to get, and preparation technology is concise, the pollution of manufacturing process industrial discharge
Thing is few, suitable for large-scale industrial production.
Embodiment
The technical scheme of invention is described in detail with reference to specific embodiment.
Embodiment
（1）Weigh 5 parts of sodium methyl silicate, 2 parts of polycaprolactone, 5 parts of molybdenum carbide, 5 parts of hexadienoic acid, 5 parts of molybdenum carbide is transparent
2 parts of matter acid, 5 parts of zirconium carbide, 2 parts of zinc oxide, 10 parts of glycerine, 15 parts of cerium oxide, 10 parts of polyester fiber, 2 parts of milk of lime, cellulose
Nanocrystalline 5 parts, 5 parts of viscose rayon, 5 parts of lubricant, 5 parts of soda, 20 parts of resin, 5 parts of polypropylene, 5 parts of quartz sand, mixing is
It is even；
（2）Said components are added in rotor mixer and stirred, mixing speed is 100 revs/min, while is slowly added to fourth hydroxyl first
5 parts of 8 parts of benzene and lead sulfate tribasic；
（3）After all components add, for heating rotor mixer to 200 DEG C, mixing speed is 500 revs/min, persistently stirs 60
Minute；
（4）Material magma obtained above is extruded；
（5）The material that extruding obtains is cooled down, room temperature is cooled to, plastotype, as finished product is then drawn high under the conditions of 80 DEG C.
The durable performance test of obtained packaging material and the influence evaluating result to environment are as shown in table 1.
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair
The equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, it is included within the scope of the present invention.
Claims (6)
1. a kind of packaging material with environmental-protecting performance, it is characterised in that include the raw material of following parts by weight：Sodium methyl silicate 5-
15 parts, polycaprolactone 2-10 parts, molybdenum carbide 5-15 parts, hexadienoic acid 5-15 parts, molybdenum carbide 5-15 parts, hyaluronic acid 2-5 parts, carbon
Change zirconium 5-15 parts, zinc oxide 2-5 parts, antioxidant 8-20 parts, glycerine 10-25 parts, cerium oxide 15-30 parts, polyester fiber 10-30
Part, milk of lime 2-10 parts, Cellulose nanocrystal 5-10 parts, viscose rayon 5-15 parts, heat stabilizer 5-10 parts, lubricant 5-20
Part, soda 5-15 parts, resin 20-35 parts, polypropylene 5-25 parts, quartz sand 5-8 parts.
2. the packaging material according to claim 1 with environmental-protecting performance, it is characterised in that described antioxidant is fourth
Hydroxy toluene, butylated hydroxy anisole, dibutyl hydroxy toluene, propylgallate, TBHQ, thio-2 acid two
One or more in lauryl and benzoic acid.
3. the packaging material according to claim 1 with environmental-protecting performance, it is characterised in that described heat stabilizer is three
Alkali lead sulfate, dibasic lead stearate, dibasic lead phosphite, dibutyl tin laurate, dibutyitin maleate, suitable fourth
One or more in enedioic acid dibutyl tin, laurate, stearic acid, organic aliphatic acid and salicylic acid.
4. according to the preparation method of any described packaging material with environmental-protecting performance of claims 1 to 3, it is characterised in that
Comprise the following steps：
（1）Weigh sodium methyl silicate 5-15 parts, polycaprolactone 2-10 parts, molybdenum carbide 5-15 parts, hexadienoic acid 5-15 parts, molybdenum carbide
5-15 parts, hyaluronic acid 2-5 parts, zirconium carbide 5-15 parts, zinc oxide 2-5 parts, glycerine 10-25 parts, cerium oxide 15-30 parts, polyester
Fiber 10-30 parts, milk of lime 2-10 parts, Cellulose nanocrystal 5-10 parts, viscose rayon 5-15 parts, lubricant 5-20 parts, soda
5-15 parts, resin 20-35 parts, polypropylene 5-25 parts, quartz sand 5-8 parts, it is well mixed；
（2）Said components are added in rotor mixer and stirred, mixing speed is 100 revs/min, while is slowly added to anti-oxidant
Agent 8-20 parts and heat stabilizer 5-10 parts；
（3）After all components add, for heating rotor mixer to 200 DEG C, mixing speed is 500 revs/min, persistently stirs 60
Minute；
（4）Material magma obtained above is extruded；
（5）The material that extruding obtains is cooled down, then draws high plastotype, as finished product.
5. the preparation method of the packaging material according to claim 4 with environmental-protecting performance, it is characterised in that the step
（5）In, the material that extruding obtains is cooled down, is cooled to room temperature.
6. the preparation method of the packaging material according to claim 4 with environmental-protecting performance, it is characterised in that the step
（5）In, drawing high plastotype needs to be heated to 80-120 DEG C of progress.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610788385.1A CN107793784A (en) | 2016-08-31 | 2016-08-31 | A kind of packaging material with environmental-protecting performance and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610788385.1A CN107793784A (en) | 2016-08-31 | 2016-08-31 | A kind of packaging material with environmental-protecting performance and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107793784A true CN107793784A (en) | 2018-03-13 |
Family
ID=61527808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610788385.1A Withdrawn CN107793784A (en) | 2016-08-31 | 2016-08-31 | A kind of packaging material with environmental-protecting performance and preparation method thereof |
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| Country | Link |
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| CN (1) | CN107793784A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114456557A (en) * | 2022-01-21 | 2022-05-10 | 金旸（厦门）新材料科技有限公司 | Plant fiber-imitated degradable polyester composite material and preparation method thereof |
-
2016
- 2016-08-31 CN CN201610788385.1A patent/CN107793784A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114456557A (en) * | 2022-01-21 | 2022-05-10 | 金旸（厦门）新材料科技有限公司 | Plant fiber-imitated degradable polyester composite material and preparation method thereof |
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Application publication date: 20180313 |
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