CN107778994A - A kind of water-based color shifting ink of ceramics and preparation method thereof - Google Patents
A kind of water-based color shifting ink of ceramics and preparation method thereof Download PDFInfo
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- CN107778994A CN107778994A CN201711295568.0A CN201711295568A CN107778994A CN 107778994 A CN107778994 A CN 107778994A CN 201711295568 A CN201711295568 A CN 201711295568A CN 107778994 A CN107778994 A CN 107778994A
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- water
- color shifting
- weight
- based color
- ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of water-based color shifting ink of ceramics, include the component of following percentage by weight：Change colour aqueous emulsion 35 45, water-based ink 10 18, sodium cellulosate liquid 30 40, glycerine 7 12, defoamer 36, aqueous infiltrating agent 0.5 0.8.The present invention is made ink have organic environmental-protection speciality, is more met environmental requirement using organic substances such as sodium cellulosate, glycerine.
Description
Technical field
The present invention relates to ceramic product technical field, is specifically a kind of water-based color shifting ink of ceramics and preparation method thereof.
Background technology
Ceramic printing is that different printing plates is made with different plate and technique, with special ceramic paint and different viscous
Ramming material is rolled into printing-ink, is directly printed onto on ceramics, or is printed on special paper, is then transferred on ceramics and is roasted through high temperature
Burn till the technology for ceramic product.
Existing ceramic printing ink is actually synthetic ink, has theme synthetic resin and two component inks to form transfer paste
Marble paper ink and ceramic ink belong to such.Mainly it is made up of toner and solvent, toner is to colour mineral matter, solvent polyphyly lead
Borosilicate glass body, the two is processed further that solid solution or suspension body pigment is made.
In order to increase that ceramic product is attractive in appearance and artistic effect etc., there is the color shifting ink using colour-changing agent as matrix, due to
The defects of existing in terms of selection, preparation technology in link stuff so that the thermochromatic inks of preparation do not meet environmental requirement, life
Production cost is higher, and adhesive force and crocking resistance are poor.
The content of the invention
It is an object of the invention to provide a kind of water-based color shifting ink of ceramics and preparation method thereof, to solve above-mentioned background skill
The problem of being proposed in art.
To achieve the above object, the present invention provides following technical scheme：
A kind of water-based color shifting ink of ceramics, include the component of following percentage by weight：Change colour aqueous emulsion 35-45, water-based oil
Black 10-18, sodium cellulosate liquid 30-40, glycerine 7-12, defoamer 3-6, aqueous infiltrating agent 0.5-0.8.
As the further scheme of the present invention：A kind of water-based color shifting ink of ceramics also includes the binder of 1-2 parts by weight.
As the further scheme of the present invention：A kind of water-based color shifting ink of ceramics also includes the anti-corrosion of 2.5-8.5 parts by weight
Agent.
As the further scheme of the present invention：It is oily, 45-55 parts by weight that the water-based ink includes 5-10 parts by weight of soybean
The water-base resin oil of rosin, 25-40 parts by weight, the dimethyl amine of 2-4 parts by weight, which is dissolved in suitable quantity of water, to be formed.
As the further scheme of the present invention：The defoamer is preferably tributyl phosphate.
As the further scheme of the present invention：The sodium cellulosate liquid is preferably the carboxymethyl cellulose of 1.5% weight concentration
Plain sodium.
As the further scheme of the present invention：The preservative is preferably the amic acid of 1.5% weight concentration.
A kind of preparation method of the water-based color shifting ink of ceramics, comprises the following steps：
S1, water-based ink, glycerine, defoamer, aqueous infiltrating agent, binder are mixed into sodium cellulosate solution, fully stirred
Mix scattered, in 75-100r/min, mixing time at least 30min, whipping temp controls at 35-40 DEG C the control of agitator rotating speed, quiet
Put cooling；
S2, addition discoloration aqueous emulsion, 30min is sufficiently stirred, the scattered grinding of grinder, bag filter are put into after cool drying
Dress, disperse in process of lapping that pH value can be surveyed, and add pH adjusting agent on a small quantity and be adjusted, pH value is reached requirement.
Compared with prior art, the beneficial effects of the invention are as follows：The present invention uses the organic substances such as sodium cellulosate, glycerine,
Make ink that there is organic environmental-protection speciality, more meet environmental requirement.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only part of the embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belong to the model that the present invention protects
Enclose.
Embodiment one, in the embodiment of the present invention, a kind of water-based color shifting ink of ceramics, include the group of following percentage by weight
Part：Change colour aqueous emulsion 35-45, water-based ink 10-18, sodium cellulosate liquid 30-40, glycerine 7-12, defoamer 3-6, aqueous infiltrating
Agent 0.5-0.8.
A kind of water-based color shifting ink of ceramics also includes the binder of 1-2 parts by weight.
A kind of water-based color shifting ink of ceramics also includes the preservative of 2.5-8.5 parts by weight.
The water-based ink include 5-10 parts by weight of soybean oil, the rosin of 45-55 parts by weight, 25-40 parts by weight it is water-based
Resinon, the dimethyl amine of 2-4 parts by weight, which is dissolved in suitable quantity of water, to be formed.
The defoamer is preferably tributyl phosphate.
The sodium cellulosate liquid is preferably the sodium carboxymethylcellulose of 1.5% weight concentration.
The preservative is preferably the amic acid of 1.5% weight concentration.
A kind of preparation method of the water-based color shifting ink of ceramics, comprises the following steps：
S1, water-based ink, glycerine, defoamer, aqueous infiltrating agent, binder are mixed into sodium cellulosate solution, fully stirred
Mix scattered, in 75-100r/min, mixing time at least 30min, whipping temp controls at 35-40 DEG C the control of agitator rotating speed, quiet
Put cooling；
S2, addition discoloration aqueous emulsion, 30min is sufficiently stirred, the scattered grinding of grinder, bag filter are put into after cool drying
Dress, disperse in process of lapping that pH value can be surveyed, and add pH adjusting agent on a small quantity and be adjusted, pH value is reached requirement.
Embodiment two, a kind of water-based color shifting ink of ceramics, include the component of following percentage by weight：Change colour aqueous emulsion 20-
30, thermal discoloration reversible color pigment 20-25, water-based ink, 20-30, sodium cellulosate liquid 30-40, glycerine 7-12, defoamer 3-6,
Aqueous infiltrating agent 0.5-0.8, in the present embodiment, increase water-based ink content, reduce discoloration aqueous emulsion dosage, and be equipped with thermal discoloration
Reversible color pigment, make ink while there is phototropic and thermochromic effect.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It is appreciated that other embodiment.
Claims (8)
- A kind of 1. water-based color shifting ink of ceramics, it is characterised in that：Include the component of following percentage by weight：Change colour aqueous emulsion 35- 45, water-based ink 10-18, sodium cellulosate liquid 30-40, glycerine 7-12, defoamer 3-6, aqueous infiltrating agent 0.5-0.8.
- A kind of 2. water-based color shifting ink of ceramics according to claim 1, it is characterised in that：A kind of water-based color shifting ink of ceramics Also include the binder of 1-2 parts by weight.
- A kind of 3. water-based color shifting ink of ceramics according to claim 1, it is characterised in that：A kind of water-based color shifting ink of ceramics Also include the preservative of 2.5-8.5 parts by weight.
- A kind of 4. water-based color shifting ink of ceramics according to claim 1, it is characterised in that：The water-based ink includes 5-10 The water-base resin oil of parts by weight of soybean oil, the rosin of 45-55 parts by weight, 25-40 parts by weight, the dimethyl amine of 2-4 parts by weight It is dissolved in suitable quantity of water and forms.
- A kind of 5. water-based color shifting ink of ceramics according to claim 1, it is characterised in that：The defoamer is preferably phosphoric acid Tributyl.
- A kind of 6. water-based color shifting ink of ceramics according to claim 1, it is characterised in that：The sodium cellulosate liquid is preferably The sodium carboxymethylcellulose of 1.5% weight concentration.
- A kind of 7. water-based color shifting ink of ceramics according to claim 3, it is characterised in that：The preservative is preferably The amic acid of 1.5% weight concentration.
- A kind of 8. preparation method of water-based color shifting ink of ceramics according to claim 1, it is characterised in that：Including following step Suddenly：S1, water-based ink, glycerine, defoamer, aqueous infiltrating agent, binder are mixed into sodium cellulosate solution, are sufficiently stirred point Dissipate, the control of agitator rotating speed is controlled at 35-40 DEG C in 75-100r/min, mixing time at least 30min, whipping temp, is stood cold But；S2, addition discoloration aqueous emulsion, 30min is sufficiently stirred, the scattered grinding of grinder is put into after cool drying, is filtered and packaged, point PH value can be surveyed by dissipating in process of lapping, and is added pH adjusting agent on a small quantity and be adjusted, and pH value is reached requirement.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711295568.0A CN107778994A (en) | 2017-12-08 | 2017-12-08 | A kind of water-based color shifting ink of ceramics and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711295568.0A CN107778994A (en) | 2017-12-08 | 2017-12-08 | A kind of water-based color shifting ink of ceramics and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107778994A true CN107778994A (en) | 2018-03-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711295568.0A Pending CN107778994A (en) | 2017-12-08 | 2017-12-08 | A kind of water-based color shifting ink of ceramics and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008084042A1 (en) * | 2007-01-12 | 2008-07-17 | Lamberti Spa | Ceramic inks and ceramic colours vehicles based on aqueous emulsions |
| US20110269885A1 (en) * | 2010-04-28 | 2011-11-03 | Canon Kabushiki Kaisha | Transfer ink jet recording aqueous ink |
| CN102295861A (en) * | 2010-06-25 | 2011-12-28 | 深圳市顾康力化工有限公司 | Water-based ceramic ink |
| CN102516844A (en) * | 2011-12-05 | 2012-06-27 | 义乌市伟航水性油墨有限公司 | Paper water color ink |
| CN104497710A (en) * | 2014-11-25 | 2015-04-08 | 苏州中亚油墨有限公司 | New thermochromic ink |
-
2017
- 2017-12-08 CN CN201711295568.0A patent/CN107778994A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008084042A1 (en) * | 2007-01-12 | 2008-07-17 | Lamberti Spa | Ceramic inks and ceramic colours vehicles based on aqueous emulsions |
| US20110269885A1 (en) * | 2010-04-28 | 2011-11-03 | Canon Kabushiki Kaisha | Transfer ink jet recording aqueous ink |
| CN102295861A (en) * | 2010-06-25 | 2011-12-28 | 深圳市顾康力化工有限公司 | Water-based ceramic ink |
| CN102516844A (en) * | 2011-12-05 | 2012-06-27 | 义乌市伟航水性油墨有限公司 | Paper water color ink |
| CN104497710A (en) * | 2014-11-25 | 2015-04-08 | 苏州中亚油墨有限公司 | New thermochromic ink |
Non-Patent Citations (2)
| Title |
|---|
| 中国防伪行业协会组: "《中国防伪战略 中国防伪战略高层研讨会论文集》", 31 August 1997, 中国标准出版社 * |
| 夏征农等: "《大辞海 第37卷 材料科学卷》", 31 December 2015, 上海辞书出版社 * |
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| PB01 | Publication | ||
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Application publication date: 20180309 |