CN107777738A - A kind of preparation method for being used to improve wastewater from chemical industry material - Google Patents

A kind of preparation method for being used to improve wastewater from chemical industry material Download PDF

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Publication number
CN107777738A
CN107777738A CN201610763630.3A CN201610763630A CN107777738A CN 107777738 A CN107777738 A CN 107777738A CN 201610763630 A CN201610763630 A CN 201610763630A CN 107777738 A CN107777738 A CN 107777738A
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CN
China
Prior art keywords
parts
sulfate
chemical industry
tannin
polyacrylamide
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Pending
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CN201610763630.3A
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Chinese (zh)
Inventor
陈小勇
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Jiangsu Jihua Chemical Co Ltd
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Jiangsu Jihua Chemical Co Ltd
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Priority to CN201610763630.3A priority Critical patent/CN107777738A/en
Publication of CN107777738A publication Critical patent/CN107777738A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The present invention discloses a kind of preparation method for being used to improve wastewater from chemical industry material, including certain herbaceous plants with big flowers aldehyde, sodium carboxymethylcellulose, polyacrylamide, tannin, calcium oxide, ion exchange resin, oyster shell powder, nanosized SiO_2, aluminium polychloride, aluminum sulfate, nanometer calcium sulfate, titanate coupling agent, zinc sulfate and ferric sulfate, above-mentioned each composition is well mixed by a certain percentage.A kind of preparation method for being used to improve wastewater from chemical industry material provided by the invention, for improving the material of wastewater from chemical industry, can improve the acid-base value of waste water, absorb heavy metal ion, while strong to suspended material capacity of decomposition, safe and efficient.

Description

A kind of preparation method for being used to improve wastewater from chemical industry material
Technical field
The present invention relates to a kind of preparation method of wastewater from chemical industry material, more particularly to one kind to be used to improve wastewater from chemical industry material Preparation method.
Background technology
Wastewater from chemical industry is exactly the technique waste water, cooling water, discarded washings, equipment and place given off in Chemical Manufacture The waste water such as flushing water.If these waste water discharge without processing, the heterogeneity of water body and different degrees of dirt can be caused Dye, so as to endanger the health of the mankind, influences the production of industrial or agricultural.Wastewater from chemical industry typically has the characteristics that:(1) water-quality constituents Complexity, accessory substance is more, and reaction raw materials are often solvent material or the compound of cyclic structure, add the intractability of waste water; (2) Pollutants in Wastewater content is high, and this is due to that a large amount of solvents that raw material reaction not exclusively and in raw material or production uses are situated between Matter is entered caused by waste water system;(3) poisonous and harmful substance is more, many of Fine Chemistry Wastewater organic pollution pair Microorganism is poisonous and hazardous.(4) bio-refractory material is more, and for B/C than low, biodegradability is poor;(5) chroma in waste water is high.Institute To need a kind of material that can effectively handle wastewater from chemical industry.
The content of the invention
The purpose of the present invention is overcome the deficiencies in the prior art, there is provided a kind of making side for being used to improve wastewater from chemical industry material Method.
Technical scheme is as follows:The present invention provides a kind of preparation method for being used to improve wastewater from chemical industry material, bag Include certain herbaceous plants with big flowers aldehyde, sodium carboxymethylcellulose, polyacrylamide, tannin, calcium oxide, ion exchange resin, oyster shell powder, nanosized SiO_2 , aluminium polychloride, aluminum sulfate, nanometer calcium sulfate, titanate coupling agent, zinc sulfate and ferric sulfate, by above-mentioned each composition by certain Ratio is well mixed.
Currently preferred, the certain herbaceous plants with big flowers aldehyde is 6-11 parts, and the sodium carboxymethylcellulose is 5-9 parts, the polyacrylamide Amine is 2-6 parts, and the tannin is 3-8 parts, and the calcium oxide is 2-6 parts, and the ion exchange resin is 5-9 parts, the oyster Shell powder is 5-8 parts, and the nanosized SiO_2 is 1-5 parts, and the aluminium polychloride is 5-10 parts, and the aluminum sulfate is 4-7 parts, The nanometer calcium sulfate is 2-6 parts, and the titanate coupling agent is 1-4 parts, and the zinc sulfate is 4-9 parts and the ferric sulfate is 6-10 parts.
Currently preferred, the certain herbaceous plants with big flowers aldehyde is 6 parts, and the sodium carboxymethylcellulose is 5 parts, and the polyacrylamide is 2 Part, the tannin is 3 parts, and the calcium oxide is 2 parts, and the ion exchange resin is 5 parts, and the oyster shell powder is 5 parts, institute Nanosized SiO_2 is stated as 1 part, the aluminium polychloride is 5 parts, and the aluminum sulfate is 4 parts, and the nanometer calcium sulfate is 2 parts, described Titanate coupling agent is 1 part, and the zinc sulfate is 4 parts and the ferric sulfate is 6 parts.
Currently preferred, the certain herbaceous plants with big flowers aldehyde is 8 parts, and the sodium carboxymethylcellulose is 7 parts, and the polyacrylamide is 4 Part, the tannin is 5 parts, and the calcium oxide is 4 parts, and the ion exchange resin is 7 parts, and the oyster shell powder is 6 parts, institute Nanosized SiO_2 is stated as 3 parts, the aluminium polychloride is 8 parts, and the aluminum sulfate is 5 parts, and the nanometer calcium sulfate is 4 parts, described Titanate coupling agent is 3 parts, and the zinc sulfate is 6 parts and the ferric sulfate is 8 parts.
Currently preferred, the certain herbaceous plants with big flowers aldehyde is 11 parts, and the sodium carboxymethylcellulose is 9 parts, and the polyacrylamide is 6 Part, the tannin is 8 parts, and the calcium oxide is 6 parts, and the ion exchange resin is 9 parts, and the oyster shell powder is 8 parts, institute Nanosized SiO_2 is stated as 5 parts, the aluminium polychloride is 10 parts, and the aluminum sulfate is 7 parts, and the nanometer calcium sulfate is 6 parts, institute Titanate coupling agent is stated as 4 parts, the zinc sulfate is 9 parts and the ferric sulfate is 10 parts.
Beneficial effects of the present invention are as follows:
Using such scheme, a kind of preparation method for being used to improve wastewater from chemical industry material provided by the invention, for improving chemical industry The material of waste water, the acid-base value of waste water can be improved, absorb heavy metal ion, while, safety strong to suspended material capacity of decomposition Efficiently.
Brief description of the drawings
Fig. 1 is a kind of flow chart for being used to improve the preparation method of wastewater from chemical industry material of the present invention.
Embodiment
Below in conjunction with the drawings and specific embodiments, the present invention is described in detail.
Referring to Fig. 1, the present invention provides a kind of preparation method for being used to improve wastewater from chemical industry material, including certain herbaceous plants with big flowers aldehyde, carboxylic first Base sodium cellulosate, polyacrylamide, tannin, calcium oxide, ion exchange resin, oyster shell powder, nanosized SiO_2, polyaluminium Aluminium, aluminum sulfate, nanometer calcium sulfate, titanate coupling agent, zinc sulfate and ferric sulfate, above-mentioned each composition is mixed by a certain percentage It is even.
The certain herbaceous plants with big flowers aldehyde is 6-11 parts, and the sodium carboxymethylcellulose is 5-9 parts, and the polyacrylamide is 2-6 parts, described Tannin is 3-8 parts, and the calcium oxide is 2-6 parts, and the ion exchange resin is 5-9 parts, and the oyster shell powder is 5-8 parts, The nanosized SiO_2 is 1-5 parts, and the aluminium polychloride is 5-10 parts, and the aluminum sulfate is 4-7 parts, the nanometer calcium sulfate For 2-6 parts, the titanate coupling agent is 1-4 parts, and the zinc sulfate is 4-9 parts and the ferric sulfate is 6-10 parts.
Embodiment one:
The certain herbaceous plants with big flowers aldehyde is 6 parts, and the sodium carboxymethylcellulose is 5 parts, and the polyacrylamide is 2 parts, and the tannin is 3 parts, The calcium oxide is 2 parts, and the ion exchange resin is 5 parts, and the oyster shell powder is 5 parts, and the nanosized SiO_2 is 1 part, The aluminium polychloride is 5 parts, and the aluminum sulfate is 4 parts, and the nanometer calcium sulfate is 2 parts, and the titanate coupling agent is 1 Part, the zinc sulfate is 4 parts and the ferric sulfate is 6 parts.
Embodiment two:
The certain herbaceous plants with big flowers aldehyde is 8 parts, and the sodium carboxymethylcellulose is 7 parts, and the polyacrylamide is 4 parts, and the tannin is 5 parts, The calcium oxide is 4 parts, and the ion exchange resin is 7 parts, and the oyster shell powder is 6 parts, and the nanosized SiO_2 is 3 parts, The aluminium polychloride is 8 parts, and the aluminum sulfate is 5 parts, and the nanometer calcium sulfate is 4 parts, and the titanate coupling agent is 3 Part, the zinc sulfate is 6 parts and the ferric sulfate is 8 parts.
Embodiment three:
The certain herbaceous plants with big flowers aldehyde is 11 parts, and the sodium carboxymethylcellulose is 9 parts, and the polyacrylamide is 6 parts, and the tannin is 8 parts, The calcium oxide is 6 parts, and the ion exchange resin is 9 parts, and the oyster shell powder is 8 parts, and the nanosized SiO_2 is 5 parts, The aluminium polychloride is 10 parts, and the aluminum sulfate is 7 parts, and the nanometer calcium sulfate is 6 parts, and the titanate coupling agent is 4 Part, the zinc sulfate is 9 parts and the ferric sulfate is 10 parts.
Using such scheme, a kind of preparation method for being used to improve wastewater from chemical industry material provided by the invention, for improving The material of wastewater from chemical industry, the acid-base value of waste water can be improved, absorb heavy metal ion, at the same it is strong to suspended material capacity of decomposition, It is safe and efficient.
These are only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and All any modification, equivalent and improvement made within principle etc., should be included in the scope of the protection.

Claims (5)

1. a kind of be used to improve the preparation method of wastewater from chemical industry material, it is characterised in that including certain herbaceous plants with big flowers aldehyde, sodium carboxymethylcellulose, Polyacrylamide, tannin, calcium oxide, ion exchange resin, oyster shell powder, nanosized SiO_2, aluminium polychloride, aluminum sulfate, receive Rice calcium sulfate, titanate coupling agent, zinc sulfate and ferric sulfate, above-mentioned each composition is well mixed by a certain percentage.
2. petrochemical industry emulsifying process water deoiling method according to claim 1, it is characterised in that the certain herbaceous plants with big flowers aldehyde is 6-11 Part, the sodium carboxymethylcellulose is 5-9 parts, and the polyacrylamide is 2-6 parts, and the tannin is 3-8 parts, the calcium oxide For 2-6 parts, the ion exchange resin is 5-9 parts, and the oyster shell powder is 5-8 parts, and the nanosized SiO_2 is 1-5 parts, institute It is 5-10 parts to state aluminium polychloride, and the aluminum sulfate is 4-7 parts, and the nanometer calcium sulfate is 2-6 parts, the titanate coupling agent For 1-4 parts, the zinc sulfate is 4-9 parts and the ferric sulfate is 6-10 parts.
3. petrochemical industry emulsifying process water deoiling method according to claim 2, it is characterised in that the certain herbaceous plants with big flowers aldehyde is 6 parts, The sodium carboxymethylcellulose is 5 parts, and the polyacrylamide is 2 parts, and the tannin is 3 parts, and the calcium oxide is 2 parts, institute Ion exchange resin is stated as 5 parts, the oyster shell powder is 5 parts, and the nanosized SiO_2 is 1 part, and the aluminium polychloride is 5 Part, the aluminum sulfate is 4 parts, and the nanometer calcium sulfate is 2 parts, and the titanate coupling agent is 1 part, and the zinc sulfate is 4 parts It it is 6 parts with the ferric sulfate.
4. petrochemical industry emulsifying process water deoiling method according to claim 2, it is characterised in that the certain herbaceous plants with big flowers aldehyde is 8 parts, The sodium carboxymethylcellulose is 7 parts, and the polyacrylamide is 4 parts, and the tannin is 5 parts, and the calcium oxide is 4 parts, institute Ion exchange resin is stated as 7 parts, the oyster shell powder is 6 parts, and the nanosized SiO_2 is 3 parts, and the aluminium polychloride is 8 Part, the aluminum sulfate is 5 parts, and the nanometer calcium sulfate is 4 parts, and the titanate coupling agent is 3 parts, and the zinc sulfate is 6 parts It it is 8 parts with the ferric sulfate.
5. petrochemical industry emulsifying process water deoiling method according to claim 2, it is characterised in that the certain herbaceous plants with big flowers aldehyde is 11 Part, the sodium carboxymethylcellulose is 9 parts, and the polyacrylamide is 6 parts, and the tannin is 8 parts, and the calcium oxide is 6 parts, The ion exchange resin is 9 parts, and the oyster shell powder is 8 parts, and the nanosized SiO_2 is 5 parts, and the aluminium polychloride is 10 parts, the aluminum sulfate is 7 parts, and the nanometer calcium sulfate is 6 parts, and the titanate coupling agent is 4 parts, and the zinc sulfate is 9 Part and the ferric sulfate are 10 parts.
CN201610763630.3A 2016-08-30 2016-08-30 A kind of preparation method for being used to improve wastewater from chemical industry material Pending CN107777738A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112174280A (en) * 2019-07-05 2021-01-05 林团员 Sewage treatment flocculant and preparation method thereof
CN116813057A (en) * 2023-05-29 2023-09-29 深圳市三理智光科技有限公司 Liquid alkali for treating acidic sewage, preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103771548A (en) * 2014-01-16 2014-05-07 江苏集贤绿色化学科技研究院有限公司 Chemical industry wastewater purifying agent and preparation method thereof
CN104326546A (en) * 2014-10-22 2015-02-04 青岛拓联信息技术有限公司 Material for improving chemical wastewater
CN104528869A (en) * 2014-12-31 2015-04-22 桂林市世环废气处理设备有限公司 Waste water treating agent
CN105603196A (en) * 2016-03-14 2016-05-25 云南博曦环保设备有限公司 Method for conducting resource treatment on non-ferrous metal hydrometallurgical waste water

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103771548A (en) * 2014-01-16 2014-05-07 江苏集贤绿色化学科技研究院有限公司 Chemical industry wastewater purifying agent and preparation method thereof
CN104326546A (en) * 2014-10-22 2015-02-04 青岛拓联信息技术有限公司 Material for improving chemical wastewater
CN104528869A (en) * 2014-12-31 2015-04-22 桂林市世环废气处理设备有限公司 Waste water treating agent
CN105603196A (en) * 2016-03-14 2016-05-25 云南博曦环保设备有限公司 Method for conducting resource treatment on non-ferrous metal hydrometallurgical waste water

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112174280A (en) * 2019-07-05 2021-01-05 林团员 Sewage treatment flocculant and preparation method thereof
CN116813057A (en) * 2023-05-29 2023-09-29 深圳市三理智光科技有限公司 Liquid alkali for treating acidic sewage, preparation method and application thereof

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