CN107771840A - A kind of chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation - Google Patents
A kind of chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation Download PDFInfo
- Publication number
- CN107771840A CN107771840A CN201610776385.XA CN201610776385A CN107771840A CN 107771840 A CN107771840 A CN 107771840A CN 201610776385 A CN201610776385 A CN 201610776385A CN 107771840 A CN107771840 A CN 107771840A
- Authority
- CN
- China
- Prior art keywords
- nicosulfuron
- fluorine cyanogen
- insect amide
- cyanogen insect
- chlorine fluorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A kind of chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation, by chlorine fluorine cyanogen insect amide by weight 5%~40%, nicosulfuron by weight 2 35%, remaining is formed for additive mixture.Preferably, the chlorine fluorine cyanogen insect amide and the proportioning of nicosulfuron are 4:1、2:1、1:1、1:2 or 1:4.Preferably, the auxiliary agent includes solvent, sticker and filler, the percentage by weight that wherein solvent accounts for the pesticidal preparations gross weight is 2~60.0%, the percentage by weight that sticker accounts for the pesticidal preparations gross weight is 5~60.0%, and the percentage by weight that filler accounts for the pesticidal preparations gross weight is 8~60.0%.The present invention expands insecticidal spectrum by the rational mixture between chlorine fluorine cyanogen insect amide and nicosulfuron, improves drug effect, reduces dosage, mitigates the pollution to environment, safe and efficient.
Description
Technical field
The present invention relates to a kind of pesticidal preparations, particularly a kind of chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation.
Background technology
Due to the long-term single insecticide depended on using a certain type, insect easily develops immunity to drugs, and causes chemistry to kill
The dosage of worm agent sharply increases, and not only increases production cost, and largely kills the natural enemy and pollution environment of insect, causes
The Rampant damage of insect.Chlorine fluorine cyanogen insect amide is that have excellent insecticidal activity, all effective to most of agricultural pests, dosage
It is low, degrade quickly in the environment, do not injure natural enemy and other non-target organisms, be a kind of outstanding biological insecticides, its shortcoming
It is unstable.Therefore, it is necessary to a kind of new pesticidal preparations.
The content of the invention
It is an object of the invention to provide a kind of chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation, passes through chlorine fluorine cyanogen worm
Rational mixture between acid amides and nicosulfuron, expand insecticidal spectrum, improve drug effect, reduce dosage, mitigate the pollution to environment,
It is safe and efficient.
The purpose of the present invention is achieved through the following technical solutions, a kind of chlorine fluorine cyanogen insect amide and nicosulfuron mixture agriculture
Medicine preparation, it is characterized in that, the pesticidal preparations are by chlorine fluorine cyanogen insect amide by weight 5%~40%, and nicosulfuron is by weight
2-35%, remaining is formed for additive mixture.
Preferably, the chlorine fluorine cyanogen insect amide and the proportioning of nicosulfuron are 4:1、2:1、1:1、1:2 or 1:4.
Preferably, the auxiliary agent includes solvent, sticker and filler, and wherein solvent accounts for the weight of the pesticidal preparations gross weight
It is 2~60.0% to measure percentage, and the percentage by weight that sticker accounts for the pesticidal preparations gross weight is 5~60.0%, and filler accounts for
The percentage by weight of the pesticidal preparations gross weight is 8~60.0%.
Preferably, the solvent be selected from benzene,toluene,xylene, methanol, ethanol, propyl alcohol, butanol, isobutanol, cyclohexanone,
In MEK, isophorone, pyrrolidones, N- methyl pyrrolidones, dimethylformamide, dimethyl sulfoxide, 2- pyrrolidones
Any one or two or more any composition.
Preferably, the sticker is selected from polyvinyl acetate, gelatin, polyvinyl alcohol, styrene-butadiene latex, Arabic gum, marine alga
Sour sodium, xanthans, sodium carboxymethylcellulose, carboxy-propyl cellulose sodium, polyethylene glycol, polyethylene glycol oxide, polyvinylpyrrolidone,
In polyacrylamide, soluble starch, dextrin, polyvinyl acetate, coumarone resin, Petropols, naphthalene resinox
Any one or two or more any composition；
Preferably, the filler is selected from diatomite, Concave-convex clay rod, bentonite, sepiolite, kaolin, clay, lightweight carbonic acid
Any one in calcium, sawdust powder, rice husk, tobacco powder, walnut parting, lignin or two or more any combination
Thing.
Compared with prior art, the invention has the advantages that：
First, after chlorine fluorine cyanogen insect amide and nicosulfuron mixture, the shortcomings that nicosulfuron can be overcome easily to produce resistance, it can open up
The use range of wide medicament, improve drug effect.Play the role of to the resistance management of insect important.
Second, after chlorine fluorine cyanogen insect amide and nicosulfuron mixture, many merits of botanical pesticide are not only maintained, and
And the dosage of mixture reduces, drug effect increases substantially, and development and application of the mixture to natural insecticide have great importance.
3rd, due to preparing the compatibility and reasonable mixture ratio of each material needed for the insecticides, can greatly mitigate to various
Insect
The toxic action of natural enemy, the pollution to ecological environment is small, is advantageous to protect person poultry safety.
Embodiment
Embodiment 1,50.0% chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation
Chlorine fluorine cyanogen insect amide 40.0, nicosulfuron 10.0, propyl alcohol 8.0, cyclohexanone 6.0, polyvinyl acetate 5.0, gelatin 5.0, pottery
Soil 8.0, diatomite 18.0；Pesticide active ingredient is added under stirring at normal temperature after binding agent, filler, solvent are mixed, into paste
Liquid and tinning.
Embodiment 2,30.0% chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation
Chlorine fluorine cyanogen insect amide 20.0, nicosulfuron 10.0, isobutanol 6.0, dimethylformamide 8.0,2-Pyrrolidone 2.0, gather
Ethylene glycol 10.0, precipitated calcium carbonate 30.0, sawdust powder 14.0；Added after binding agent, filler, solvent are mixed under stirring at normal temperature
Pesticide active ingredient, into cream liquid and tinning.
Embodiment 3,20.0% chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation
Chlorine fluorine cyanogen insect amide 10.0, nicosulfuron 10.0,2-Pyrrolidone 4.0, butanol 4.0, MEK 6.0, dextrin 0.2, gather
Vinyl acetate 5.0, coumarone resin 5.0, kaolin 55.8；Add after binding agent, filler, solvent are mixed under stirring at normal temperature
Enter pesticide active ingredient, into cream liquid and tinning.
Embodiment 4,30.0% chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation
Chlorine fluorine cyanogen insect amide 10.0, nicosulfuron 20.0, toluene 10.0, ethanol 4.0,2-Pyrrolidone 4.0, sodium alginate 8.0,
Xanthans 4.0, precipitated calcium carbonate 40.0；Will binding agent, filler, solvent mix after under stirring at normal temperature add agricultural chemicals effectively into
Point, into cream liquid and tinning.
Embodiment 5,50.0% chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation
Chlorine fluorine cyanogen insect amide 10.0, nicosulfuron 40.0, isophorone 2.0, MEK 4.0, sodium carboxymethylcellulose 0.5, sea
Algae element sodium 9.5, rice husk 5.0, tobacco powder 5.0, diatomite 24.0；Add after binding agent, filler, solvent are mixed under stirring at normal temperature
Enter pesticide active ingredient, into cream liquid and tinning.
Embodiment 6, chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation
Chlorine fluorine cyanogen insect amide 29.9, nicosulfuron 0.1,1-METHYLPYRROLIDONE 0.5, isobutanol 7.5, ethanol 0.5, gelatin 0.5,
Dextrin 0.5, coumarone resin 9.0, diatomite 0.5, kaolin 51.0；In stirring at normal temperature after binding agent, filler, solvent are mixed
Lower addition pesticide active ingredient, into cream liquid and tinning.
Embodiment 7, chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation
Chlorine fluorine cyanogen insect amide 0.1, nicosulfuron 29.9, propyl alcohol 2.0, dimethylformamide 0.5, cyclohexanone 7.5, Arabic gum
0.5, polyvinyl lactam 0.5, butadiene-styrene latex 8.0, clay 0.5, bentonite 50.5；Normal after binding agent, filler, solvent are mixed
Temperature stirring is lower to add pesticide active ingredient, into cream liquid and tinning.
Embodiment 8, indoor mixture synergism toxicity test
Each reagent agent is made into respective concentration respectively, draws the agricultural chemicals prepared from low concentration to high concentration with microsyringe,
Drip and rinse microsyringe with acetone between the pronotary of the instar larvae of anoplophora glabripennis 3, different agents, every drips 1 μ L,
Per concentration 30, while 5% acetone solution is set to do control treatment, 24h observation dead larvae numbers.Calculate LC50Value and toxicity regression side
Journey and co-toxicity coefficient.Co-toxicity coefficient is calculated using the abundant methods of Sun Yun.
The toxicity index that mixed toxicity index/theory in co-toxicity coefficient CTC=100 × actually is used with
When co-toxicity coefficient is significantly greater than 100, show there is synergistic effect；Close to 100, summation action is indicated；It is significantly less than
100, show there is antagonism.It is dense during each proportioning mixture of chlorine fluorine cyanogen insect amide and nicosulfuron is effectively lethal to anoplophora glabripennis
Spend LC50Value is sequentially（4:1、2:1、1:1、1:2 and 1:4）Respectively 52.89,24.59,39.93,30.15,25.41,23.60 and
22.25mg/mL；The co-toxicity coefficient of chlorine fluorine cyanogen insect amide and each proportioning mixture of nicosulfuron is sequentially（4:1、2:1、1:1、1:2 Hes
1:4）Respectively 129.68,139.64,149.29,166.25 and 132.18.Chlorine fluorine cyanogen insect amide is 4 with nicosulfuron proportioning:
1、2:1、1:1、1:2 and 1:4 have synergistic effect, wherein proportioning is 1:Synergistic effect is most obvious when 2.
Claims (6)
1. a kind of chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation, it is characterized in that, the pesticidal preparations are by chlorine fluorine cyanogen worm
Acid amides by weight 5%~40%, nicosulfuron 2-35% by weight, remaining is formed for additive mixture.
2. chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation according to claim 1, it is characterised in that the chlorine
The proportioning of fluorine cyanogen insect amide and nicosulfuron is 4:1、2:1、1:1、1:2 or 1:4.
3. chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation according to claim 1, it is characterised in that described
Auxiliary agent includes solvent, sticker and filler, and the percentage by weight that wherein solvent accounts for the pesticidal preparations gross weight is 2~60.0%,
The percentage by weight that sticker accounts for the pesticidal preparations gross weight is 5~60.0%, and filler accounts for the pesticidal preparations gross weight
Percentage by weight is 8~60.0%.
4. chlorine fluorine cyanogen insect amide according to claim 1 and nicosulfuron mixed insecticide preparation, it is characterised in that described molten
Agent is selected from benzene,toluene,xylene, methanol, ethanol, propyl alcohol, butanol, isobutanol, cyclohexanone, MEK, isophorone, pyrrolidines
In ketone, N- methyl pyrrolidones, dimethylformamide, dimethyl sulfoxide, 2- pyrrolidones any one or it is any two kinds or
Two or more compositions.
5. chlorine fluorine cyanogen insect amide according to claim 1 and nicosulfuron mixed insecticide preparation, it is characterised in that described viscous
Agent and be selected from polyvinyl acetate, gelatin, polyvinyl alcohol, styrene-butadiene latex, Arabic gum, sodium alginate, xanthans, carboxymethyl cellulose
Plain sodium, carboxy-propyl cellulose sodium, polyethylene glycol, polyethylene glycol oxide, polyvinylpyrrolidone, polyacrylamide, soluble starch,
In dextrin, polyvinyl acetate, coumarone resin, Petropols, naphthalene resinox any one or it is any two kinds or
Two or more compositions.
6. chlorine fluorine cyanogen insect amide according to claim 1 and nicosulfuron mixed insecticide preparation, it is characterised in that described to fill out
Material is selected from diatomite, Concave-convex clay rod, bentonite, sepiolite, kaolin, clay, precipitated calcium carbonate, sawdust powder, rice husk, cigarette
Any one in grass meal, walnut parting, lignin or two or more any composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610776385.XA CN107771840A (en) | 2016-08-31 | 2016-08-31 | A kind of chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610776385.XA CN107771840A (en) | 2016-08-31 | 2016-08-31 | A kind of chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107771840A true CN107771840A (en) | 2018-03-09 |
Family
ID=61450628
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610776385.XA Pending CN107771840A (en) | 2016-08-31 | 2016-08-31 | A kind of chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107771840A (en) |
-
2016
- 2016-08-31 CN CN201610776385.XA patent/CN107771840A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106550953A (en) | A kind of desinsection ointment containing Tolfenpyrad | |
| CN107788000A (en) | A kind of agricultural insecticide composition | |
| CN110313486A (en) | A kind of kasugarnycin and prochloraz nantokite mixed insecticide preparation | |
| CN107771840A (en) | A kind of chlorine fluorine cyanogen insect amide and nicosulfuron mixed insecticide preparation | |
| CN110402947A (en) | A kind of Hexythiazox and pyridalyl mixed insecticide preparation | |
| CN106550947A (en) | A kind of fipronil bisamide and Rynaxypyr mixed insecticide preparation | |
| CN106689180A (en) | Isoprocarb-containing insecticidal ointment | |
| CN107467034A (en) | A kind of shenqinmycin and Profenofos mixed insecticide preparation | |
| CN107771858A (en) | A kind of Jiean-peptide and chlorine sulphur grass amine mixed insecticide preparation | |
| CN108496984A (en) | A kind of Pesticidal combination containing indoxacarb and effective cypermethrin | |
| CN107467058A (en) | A kind of phonamiphos and kasugarnycin mixed insecticide preparation | |
| CN108496972A (en) | A kind of Spiromesifen and Rynaxypyr mixed insecticide preparation | |
| CN107788004A (en) | A kind of nicosulfuron and dinotefuran mixed pesticidal preparations | |
| CN109315408A (en) | A kind of Pesticidal combination containing prothioconazoles and chlortoluron | |
| CN107494594A (en) | A kind of desinsection ointment containing prochloraz nantokite and Aldicarb | |
| CN106376592A (en) | Rotenone and dichlorvos mixed pesticide preparation | |
| CN106689179A (en) | Pesticide composition | |
| CN108496988A (en) | A kind of Hostathion and propylene glycol alginate mixed insecticide preparation | |
| CN110313484A (en) | A kind of first dimension element and fluacrypyrim mixed insecticide preparation | |
| CN107787987A (en) | A kind of desinsection ointment containing pleocidin | |
| CN107787993A (en) | A kind of spiral shell worm ethyl ester and chlorine sulphur grass amine mixture desinsection ointment | |
| CN110402953A (en) | A kind of Fluoxastrobin and phonamiphos mixed insecticide preparation | |
| CN110402938A (en) | A kind of flufenzine and Tebuconazole mixed insecticide preparation | |
| CN110402941A (en) | A kind of pyrrole metsulfovax and trifluoro-benzene pyrimidine mixed insecticide preparation | |
| CN108651501A (en) | A kind of chlorfluazuron and fenpyroximate mixed insecticide preparation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180309 |
|
| WD01 | Invention patent application deemed withdrawn after publication |