CN107761372A - A kind of textile long acting antibiotic treatment fluid and preparation method thereof - Google Patents
A kind of textile long acting antibiotic treatment fluid and preparation method thereof Download PDFInfo
- Publication number
- CN107761372A CN107761372A CN201710879296.2A CN201710879296A CN107761372A CN 107761372 A CN107761372 A CN 107761372A CN 201710879296 A CN201710879296 A CN 201710879296A CN 107761372 A CN107761372 A CN 107761372A
- Authority
- CN
- China
- Prior art keywords
- treatment fluid
- long acting
- antibiotic treatment
- textile
- acting antibiotic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004753 textile Substances 0.000 title claims abstract description 69
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 41
- 239000012530 fluid Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims description 36
- 239000002994 raw material Substances 0.000 claims abstract description 65
- 239000002270 dispersing agent Substances 0.000 claims abstract description 42
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 41
- 229940064004 antiseptic throat preparations Drugs 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 238000002156 mixing Methods 0.000 claims abstract description 25
- 239000008367 deionised water Substances 0.000 claims abstract description 19
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 19
- 239000000853 adhesive Substances 0.000 claims abstract description 16
- 230000001070 adhesive effect Effects 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000007822 coupling agent Substances 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims description 63
- -1 isopropyl methyl Chemical group 0.000 claims description 54
- 239000000243 solution Substances 0.000 claims description 44
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 35
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 29
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 28
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 28
- 239000011230 binding agent Substances 0.000 claims description 27
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 25
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 24
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 23
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 20
- 239000007864 aqueous solution Substances 0.000 claims description 18
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 17
- 229920000728 polyester Polymers 0.000 claims description 16
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 15
- OVSQVDMCBVZWGM-QSOFNFLRSA-N quercetin 3-O-beta-D-glucopyranoside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=C(C=2C=C(O)C(O)=CC=2)OC2=CC(O)=CC(O)=C2C1=O OVSQVDMCBVZWGM-QSOFNFLRSA-N 0.000 claims description 15
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 14
- OVSQVDMCBVZWGM-IDRAQACASA-N Hirsutrin Natural products O([C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1)C1=C(c2cc(O)c(O)cc2)Oc2c(c(O)cc(O)c2)C1=O OVSQVDMCBVZWGM-IDRAQACASA-N 0.000 claims description 14
- FVQOMEDMFUMIMO-UHFFFAOYSA-N Hyperosid Natural products OC1C(O)C(O)C(CO)OC1OC1C(=O)C2=C(O)C=C(O)C=C2OC1C1=CC=C(O)C(O)=C1 FVQOMEDMFUMIMO-UHFFFAOYSA-N 0.000 claims description 14
- GXMWXESSGGEWEM-UHFFFAOYSA-N isoquercitrin Natural products OCC(O)C1OC(OC2C(Oc3cc(O)cc(O)c3C2=O)c4ccc(O)c(O)c4)C(O)C1O GXMWXESSGGEWEM-UHFFFAOYSA-N 0.000 claims description 14
- 229920006391 phthalonitrile polymer Polymers 0.000 claims description 14
- 239000000725 suspension Substances 0.000 claims description 14
- WHMDPDGBKYUEMW-UHFFFAOYSA-N pyridine-2-thiol Chemical compound SC1=CC=CC=N1 WHMDPDGBKYUEMW-UHFFFAOYSA-N 0.000 claims description 13
- 238000010792 warming Methods 0.000 claims description 13
- 229960000448 lactic acid Drugs 0.000 claims description 11
- LIGCDBBRWWUYEW-UHFFFAOYSA-N 2-(dihydroxyamino)butanoic acid Chemical compound CCC(N(O)O)C(O)=O LIGCDBBRWWUYEW-UHFFFAOYSA-N 0.000 claims description 10
- JBFHTYHTHYHCDJ-UHFFFAOYSA-N gamma-caprolactone Chemical compound CCC1CCC(=O)O1 JBFHTYHTHYHCDJ-UHFFFAOYSA-N 0.000 claims description 10
- MDNWOSOZYLHTCG-UHFFFAOYSA-N Dichlorophen Chemical compound OC1=CC=C(Cl)C=C1CC1=CC(Cl)=CC=C1O MDNWOSOZYLHTCG-UHFFFAOYSA-N 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 claims description 7
- 150000002989 phenols Chemical class 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- NCKMMSIFQUPKCK-UHFFFAOYSA-N 2-benzyl-4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1CC1=CC=CC=C1 NCKMMSIFQUPKCK-UHFFFAOYSA-N 0.000 claims description 2
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims description 2
- 229950010627 clorofene Drugs 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 229960003500 triclosan Drugs 0.000 claims description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- 238000002242 deionisation method Methods 0.000 claims 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 1
- 229920000742 Cotton Polymers 0.000 abstract description 17
- 210000004209 hair Anatomy 0.000 abstract description 13
- 230000000845 anti-microbial effect Effects 0.000 abstract description 10
- 241000894006 Bacteria Species 0.000 abstract description 9
- 150000001875 compounds Chemical class 0.000 abstract description 8
- 230000036541 health Effects 0.000 abstract description 5
- 230000002045 lasting effect Effects 0.000 abstract description 5
- 230000009286 beneficial effect Effects 0.000 abstract description 4
- 238000003912 environmental pollution Methods 0.000 abstract description 4
- 231100000957 no side effect Toxicity 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 3
- 230000007407 health benefit Effects 0.000 abstract description 3
- 238000000746 purification Methods 0.000 abstract description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 34
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 29
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 24
- 229910052757 nitrogen Inorganic materials 0.000 description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 16
- 239000000047 product Substances 0.000 description 15
- 238000012360 testing method Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 8
- 230000000844 anti-bacterial effect Effects 0.000 description 8
- 239000012065 filter cake Substances 0.000 description 8
- 239000003999 initiator Substances 0.000 description 8
- 241000191940 Staphylococcus Species 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 150000002576 ketones Chemical class 0.000 description 7
- 239000003242 anti bacterial agent Substances 0.000 description 6
- 244000000010 microbial pathogen Species 0.000 description 6
- ZSAIDYISADJCTG-UHFFFAOYSA-N CC(CCCCCCC)P(CCCCCCCC)CCCCCCCC Chemical compound CC(CCCCCCC)P(CCCCCCCC)CCCCCCCC ZSAIDYISADJCTG-UHFFFAOYSA-N 0.000 description 5
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 5
- 239000004471 Glycine Substances 0.000 description 5
- 238000005660 chlorination reaction Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 4
- RJQXTJLFIWVMTO-TYNCELHUSA-N Methicillin Chemical compound COC1=CC=CC(OC)=C1C(=O)N[C@@H]1C(=O)N2[C@@H](C(O)=O)C(C)(C)S[C@@H]21 RJQXTJLFIWVMTO-TYNCELHUSA-N 0.000 description 4
- 235000019270 ammonium chloride Nutrition 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 229960003085 meticillin Drugs 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 3
- 241000222122 Candida albicans Species 0.000 description 3
- 206010059866 Drug resistance Diseases 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 3
- 229940095731 candida albicans Drugs 0.000 description 3
- 210000000170 cell membrane Anatomy 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000004513 sizing Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000003138 coordinated effect Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229920000747 poly(lactic acid) Polymers 0.000 description 2
- 239000004626 polylactic acid Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- FFWJHVGUAKWTKW-UHFFFAOYSA-N pyridine-3-thiol Chemical class SC1=CC=CN=C1 FFWJHVGUAKWTKW-UHFFFAOYSA-N 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- OQHXZZGZASQSOB-UHFFFAOYSA-N 3,4,5,6-tetrachlorobenzene-1,2-dicarbonitrile Chemical compound ClC1=C(Cl)C(Cl)=C(C#N)C(C#N)=C1Cl OQHXZZGZASQSOB-UHFFFAOYSA-N 0.000 description 1
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- SUBDBMMJDZJVOS-UHFFFAOYSA-N 5-methoxy-2-{[(4-methoxy-3,5-dimethylpyridin-2-yl)methyl]sulfinyl}-1H-benzimidazole Chemical compound N=1C2=CC(OC)=CC=C2NC=1S(=O)CC1=NC=C(C)C(OC)=C1C SUBDBMMJDZJVOS-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- 101710088194 Dehydrogenase Proteins 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- CYDRXTMLKJDRQH-UHFFFAOYSA-N benzododecinium Chemical compound CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 CYDRXTMLKJDRQH-UHFFFAOYSA-N 0.000 description 1
- 238000005842 biochemical reaction Methods 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 150000002338 glycosides Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- NFIDBGJMFKNGGQ-UHFFFAOYSA-N isopropylmethylphenol Natural products CC(C)CC1=CC=CC=C1O NFIDBGJMFKNGGQ-UHFFFAOYSA-N 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000011278 mitosis Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000012946 outsourcing Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012956 testing procedure Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
- D06M13/156—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring containing halogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/345—Nitriles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/38—Polyurethanes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of textile long acting antibiotic treatment fluid, the composition of raw materials of the textile long acting antibiotic treatment fluid is by weight percentage：Deionized water 84 97.5%, Unined RM antiseptics 0.5 3.5%, adhesive 1.5 11.5%, dispersant 0.25 0.5% and coupling agent 0.25 0.5%.The antimicrobial treatment solution of the present invention uses multiple compounds, with hair, cotton and blending textile product are compound has good adhesiveness, it is added on hair, cotton and blending textile product surface, resist common germ so that hair, cotton and blending textile product have, suppress resistance venereal bacteria, high-efficient and lasting, play environment purification, eliminate peculiar smell, self-cleaning health care, it is free from environmental pollution and have no side effect to human body, obtain more health benefits beneficial to people.
Description
Technical field
The invention belongs to feature field of new materials, and in particular to it is anti-that one kind make it that hair, cotton and blending textile product have
Common germ, suppress resistance venereal bacteria, high-efficient and lasting, at the free from environmental pollution and textile long acting antibiotic that has no side effect to human body
Manage liquid and preparation method thereof.
Background technology
All kinds of hairs, cotton and blending textile product are with the development of the society, frequency of use more and more higher, and species is also increasingly
It is more.But these products do not have bacteria resistance function, are also easy to produce peculiar smell, easily grow or breed various harmful bacterias, mould, virus etc.
Microorganism, turn into a public propagation source, the health care belt to people carrys out larger puzzlement.
In view of above-mentioned factor, in recent years, the antibiotic property scientific research to hair, cotton and blending textile product both at home and abroad gradually increases
More, it is mainly obtained by adding the method for a small amount of antiseptic.Through searching document, current antiseptic is broadly divided into list by structure
One inorganic, organic and natural three big series.
Inorganic antiseptic be using metal ions such as silver, copper, zinc as antiseptic, it is non-with porous, inorganics such as phosphate, bentonites
Metal material is made for carrier, has that heat resistance is strong, but its is expensive, environmental protection shortcoming, product not wash resistant, it is long-term use of and
Touching the product containing metal ions such as silver, copper, zinc can adversely affect to the liver of human body.
Organic antibacterial agent includes quaternary ammonium salts, imidazoles, pyridines, organic metal class etc., although sterilization speed is fast, antibacterial
Significant effect, but drug resistance is also easy to produce, heat endurance is poor, and Durability of antimicrobial effect is short, and toxicity is larger, new so as to bring
Healthy hidden danger.
By comparison, natural antibacterial agent is extracted from plant, animal or biology, and its wide material sources, cost is low, has peace
Atoxic, nutritive and health protection components enrich, the advantages that being not likely to produce drug resistance and be environmentally friendly, therefore its application and research are increasingly
It is valued by people.But natural antibacterial agent is typically to extract to form from a kind of plant, animal or biology, antimicrobial component list
One, antibacterial range is narrow, the problems such as reunion, scattered uneven be present, and antimicrobial component easily separates out in use, and antibacterial effect is not
Can persistently, also easy product germ is to its resistance to the action of a drug, germ such as methicillin-resistant gold of these antiseptics to drug resistance
Yellow staphylococcus are without effect.
The content of the invention
The present invention is directed to above-mentioned technical problem, and it is anti-general that present invention offer one kind make it that hair, cotton and blending textile product have
Common fault bacterium, suppress resistance venereal bacteria, high-efficient and lasting, textile long acting antibiotic that is free from environmental pollution and having no side effect to human body is handled
Liquid and preparation method thereof, the antimicrobial treatment solution use multiple compounds, with hair, cotton and blending textile product it is compound have it is good
Adhesiveness, be added on hair, cotton and blending textile product surface so that hair, cotton and blending textile product have resist common germ,
Suppress resistance venereal bacteria, high-efficient and lasting, play environment purification, eliminate peculiar smell, self-cleaning health care, it is free from environmental pollution and to human body without pair
Effect, more health benefits are obtained beneficial to people.
To achieve these goals, the present invention uses following technical scheme：
One of technical problems to be solved by the invention are to provide a kind of textile long acting antibiotic treatment fluid.
The invention discloses a kind of textile long acting antibiotic treatment fluid, the raw material of the textile long acting antibiotic treatment fluid is matched somebody with somebody
Side is by weight percentage：Deionized water 84-97.5%, Unined RM antiseptic 0.5-3.5%, adhesive 1.5-
11.5%, dispersant 0.25-0.5% and coupling agent 0.25-0.5%.
Preferably, the Unined RM antiseptics are counted including 10-15 parts phenols, 1-3 part isoquercitrins in parts by weight
Glycosides, 2-4 parts N, N- dihydroxyethylglycin, 3-5 parts mercaptopyridine, 5-8 part dodecylbenzyls dimethyl ammonium, 0.3-10
Part dispersant, 0.56-22 parts acrylic acid and the tetrachloro phthalonitrile of 10-15 parts 2,4,5,6-.
The Antibacterial Mechanism of organic antibacterial agent is mainly combined or and mercapto with the anion of pathogenic microorganism cell membrane surface
Base reaction suppresses the breeding of pathogenic microorganism with this so as to destroy the structure of protein or influence the synthesis of biomembrane.Typically
The mechanism of action of organic antibacterial agent is summarized as in fact：1. act on the protease or other biological activity thing needed for biochemical reaction
Matter；2. act on hereditary material DNA or other hereditary particle structures；3. act on biofilm system or cell membrane.
And the present invention is acted on from each material coordinated, pathogenic microorganism of the absorption with negative electrical charge, microorganism is destroyed
Cell membrane mechanism, makes content leak, and can suppress the effect such as pathogen oxidizing ferment, dehydrogenase；Also it can remove pathogenic microorganism film
In lipid material and make protein denaturation；Also pathogenic microorganism mitosis process is may interfere with, suppresses the formation of spindle, shadow
Ring pathogenic microorganism fission process.
Preferably, the phenols is one kind in isopropyl methyl phenol, triclosan, antiphen, clorofene, chloreresol
Or several composition.
Preferably, the preparation method of the Unined RM antiseptics is：
(1) by load weighted phenols, isoquercitrin, N, N- dihydroxyethylglycins, mercaptopyridine, dodecylbenzyl
Dimethyl ammonium and 2,4,5,6- tetrachloro phthalonitriles form uniform suspension in mixed at room temperature；
(2) dispersant is added in the suspension obtained to step (1), 10-12 hours is mixed, then adds acrylic acid, is mixed
2-5 minutes are closed, obtain the Unined RM antiseptics.
Preferably, the dispersant is Sodium Polyacrylate.
In some embodiments of the invention, the dispersant Sodium Polyacrylate uses commercially available Sodium Polyacrylate, i.e. A11
Non-ionic dispersing agent.
In some embodiments of the invention, the preparation process of the dispersant Sodium Polyacrylate is：
By acrylic acid and isopropanol with mass ratio 1:(0.9-1.2) is mixed, and obtains mixed liquor A；By ammonium persulfate and go from
Sub- water is with solid-to-liquid ratio 1：(20-25) (g/mL) is well mixed, obtains mixed liquid B；By n- dodecyl mereaptan, isopropanol and deionized water
With mass ratio 1：(22-25)：7 is well mixed, obtains mixed liquor C, wherein n- dodecyl mereaptan, acrylic acid, ammonium persulfate quality
Than for 1：(20-25):1；Mixed liquor C is heated to 80-85 DEG C, while mixed liquor A is added dropwise with 5-8 μ L/s rate of addition and mixed
Close liquid B；After charging, 2.5-3 hours are reacted in 80-85 DEG C；After reaction terminates, reaction solution is cooled to 40-45 DEG C, uses matter
Measure the sodium hydrate aqueous solution that fraction is 25-30% and adjust the pH value of reaction solution to 7-8；Reaction solution is evaporated under reduced pressure, removed
Isopropyl alcohol and water, obtain the dispersant Sodium Polyacrylate.
In some embodiments of the invention, the preparation process of the dispersant Sodium Polyacrylate is：
(1) n- dodecyl mereaptan, the chlorination of methyl trioctylphosphine are added sequentially in reaction vessel by with acetone, described positive 12
Mercaptan, methyl trioctylphosphine chlorination are pressed and the mass ratio of acetone is 1：0.07:(3.2-3.5), nitrogen is passed through, while makes reaction system
Temperature remains 2-5 DEG C, and 2-3 minutes are stirred with 150-200 revs/min of rotating speed；Add the hydrogen-oxygen that mass fraction is 40-50%
The mass ratio of change sodium water solution, sodium hydrate aqueous solution and n- dodecyl mereaptan is (0.4-0.5):1, with 150-200 revs/min
Rotating speed stirs 15-20 minutes；Then the acetone soln for the carbon disulfide that addition mass fraction is 25-30%, the third of carbon disulfide
The mass ratio of ketone solution and n- dodecyl mereaptan is (1.3-1.4):1,5-10 minutes are stirred with 150-200 revs/min of rotating speed；With
Chloroform and mass fraction are added for 40-50% sodium hydrate aqueous solution successively afterwards, chloroform, sodium hydrate aqueous solution and positive ten
The mass ratio that the mass ratio of two mercaptan is is (0.8-0.9)：2:1, it is small with 150-200 revs/min of rotating speed stirring reaction 12-18
When；React after terminating, addition deionized water, the mass ratio of deionized water and n- dodecyl mereaptan is (30-40):1, after mixing, add
Enter the hydrochloric acid that mass fraction is 35-37%, the volume ratio of hydrochloric acid and deionized water is 1：(20-25), with 150-200 revs/min
Rotating speed stirring 20-25 minutes；Nitrogen is passed through, removes acetone；Using 80-100 mesh filter-cloth filterings, filter cake is collected；By filter cake in
50-60 DEG C, 8-10 hours are dried under conditions of vacuum 0.06-0.08MPa, obtain the chain-transferring agent；
(2) acrylic acid, initiator A IBN, the tert-butyl alcohol and chain-transferring agent are added in reaction vessel, wherein acrylic acid, initiation
Agent AIBN, the tert-butyl alcohol and chain-transferring agent mass ratio are 1：0.002：(1.8-1.9)：0.4, it is passed through nitrogen, 10-15 points of mixing
Clock；Reaction solution is then warming up to 75-80 DEG C, reacts 7-8 hours；Reaction solution is evaporated under reduced pressure, removes the tert-butyl alcohol, is obtained described
Dispersant Sodium Polyacrylate.
The dispersant Sodium Polyacrylate molecular weight that the present invention obtains is low, and range of molecular weight distributions is narrow, can effectively subtract
Few material is reunited, and improves dispersion effect.
Preferably, described adhesive is polyacrylic binder, aqueous polyurethane adhesive, lactyl polyester binder
In one or more mixtures.
The preparation process of the lactyl polyester binder is：DL-LACTIC ACID, 6-caprolactone and pungent are added in reaction vessel
The mass ratio of sour stannous, wherein DL-LACTIC ACID, 6-caprolactone and stannous octoate is (90-94)：(6-10)：0.1, in 400-600
Rev/min mixing speed under stirring be warming up to 120-140 DEG C, react 2-8 hours；Reaction solution is warming up to 160-180 DEG C, gathered
Close 4-8 hours；After polymerization terminates, reaction solution is cooled to room temperature, adds the volume ratio of chloroform, reaction solution and chloroform
For 1：(0.6-0.8), 5-10 minutes are stirred with 200-300 revs/min of rotating speed；Then methanol is added, methanol and reaction solution
Volume ratio is (5-6)：1,10-15 minutes are stirred with 200-300 revs/min of rotating speed, have precipitation to produce；With 1000-2000 turn/
The rotating speed centrifugation 10-15 minutes of minute, supernatant is abandoned, obtains bottom solid；By bottom solid in 50-60 DEG C, vacuum 0.08-
6-10 hours are dried under conditions of 0.09MPa, obtain the lactyl polyester binder.
PLA obtains because of its good biocompatibility and Bioabsorbable in terms of medical treatment with degradation material
It is widely applied.The present invention is improved using 6-caprolactone as the stiffness with poly lactic acid polymerized monomer, segment, submissive
Property be improved, their copolymer is used for adhesive used for textiles, not only with excellent bond properties, and can biology drop
Solution, it is environmentally friendly.
Inventor has found by experiment, when the mixture that adhesive is polyacrylic binder and lactyl polyester binder
When, bonding effect is more excellent.Preferably, described adhesive is the mixing of polyacrylic binder and lactyl polyester binder
Thing, the wherein mass ratio of polyacrylic binder and lactyl polyester binder are 1：(3-5).
The two of the technical problems to be solved by the invention are to provide a kind of preparation method of textile long acting antibiotic treatment fluid.
The preparation method of the textile long acting antibiotic treatment fluid comprises the following steps：Each raw material is weighed by formula；By original
In material input high-speed mixer, 10-12 hours are stirred with 100-200 revs/min of rotating speed in 25-35 DEG C, obtain the weaving
Product long acting antibiotic treatment fluid.
Beneficial effects of the present invention：The antimicrobial treatment solution of the present invention uses multiple compounds, weaves and produces with hair, cotton and blending
Product are compound to have good adhesiveness, is added on hair, cotton and blending textile product surface so that hair, cotton and blending weaving production
Product, which have, to be resisted common germ, suppresses resistance venereal bacteria, high-efficient and lasting, is played environment purification, is eliminated peculiar smell, self-cleaning health care, not dirty
Contaminate environment and have no side effect to human body, obtain more health benefits beneficial to people, the present invention uses multiple compounds, Mei Zhonghua
Coordinated effect between the different functional groups of compound, plays a part of anti-common germ, suppresses resistance venereal bacteria, get rid of simultaneously
The not water-fastness of natural antibacterial agent is abandoned, it is toxic to wait side effect.
Embodiment
Each raw material introduction in embodiment：
Polyacrylic binder, purchased from Jiangyin Fine Chemical Works.
A11 non-ionic dispersing agents, purchased from Foshan City Shuande head of district's sky trade Co., Ltd, specific composition is polyacrylic acid
Sodium.
Coupling agent, purchased from Zhengzhou City Jinshui District Jia Xuan chemical industry firm, model KH570.
Antiphen, No. CAS：97-23-4, purchased from Hubei giant dragon hall medication chemistry Co., Ltd.
Isoquercitrin, No. CAS：21637-25-2, purchased from Nanjing Duo Long bio tech ltd.
N, N- dihydroxyethylglycin, CAS：150-25-4, purchased from Shanghai Nuo Yuan Industrial Co., Ltd.s.
3- mercaptopyridines, CAS：16133-26-9, purchased from Shanghai Nuo He Chemical Industry Science Co., Ltd.
Dodecyl benzyl dimethyl ammonium chloride, CAS：139-07-1, purchased from Shanghai Losec Chemical Co., Ltd..
Acrylic acid, purchased from subfamily power Chemical Industry Science Co., Ltd of BOE.
2,4,5,6- tetrachloro phthalonitriles, No. CAS：1897-45-6, purchased from Wuhan Yi Tai Science and Technology Ltd.s Shanghai point
Company.
Isopropanol, No. CAS：67-63-0, purchased from this hundred full chemistries (Shanghai) Co., Ltd..
Ammonium persulfate, No. CAS：7727-54-0, purchased from this hundred full chemistries (Shanghai) Co., Ltd..
N- dodecyl mereaptan, No. CAS：112-55-0, purchased from Rui Pu new materials Co., Ltd of Liyang City.
Methyl tricapryl ammonium chloride, No. CAS：5137-55-3, purchased from Chengdu Hua Xia chemical reagent Co., Ltd.
Acetone, No. CAS：67-64-1.
Carbon disulfide, No. CAS：75-15-0, purchased from lark prestige Science and Technology Ltd..
Initiator A IBN, No. CAS：78-67-1, purchased from azodiisobutyronitrile lark prestige Science and Technology Ltd..
The tert-butyl alcohol, No. CAS：75-65-0, hundred million bio tech ltd are praised purchased from Zhuhai.
DL-LACTIC ACID, No. CAS：598-82-3, purchased from Nanjing Kang Manlin chemical industry Industrial Co., Ltd..
6-caprolactone, No. CAS：502-44-3, hundred million bio tech ltd are praised purchased from Zhuhai.
Stannous octoate, No. CAS：301-10-0, purchased from Nantong chemical products Co., Ltd of Hao Thailands.
Chloroform, No. CAS：67-66-3, purchased from Shanghai Nuo Yuan Industrial Co., Ltd.s.
Below by embodiment, the present invention will be further described.
In the present invention, if not refering in particular to, all devices and raw material are commercially available or the industry is conventional, following
Method in embodiment, it is this area conventional method unless otherwise instructed.
The specific preparation process of the Unined RM antiseptics used in embodiment 1-3 for：
The Unined RM antiseptics are counted including 15 parts of antiphens, 3 parts of isoquercitrin, 4 parts of N, N- dihydroxies in parts by weight
Base ethyl glycine, 5 parts of mercaptopyridines, 8 parts of dodecylbenzyl dimethyl ammoniums, 10 parts of A11 non-ionic dispersing agents, 22 parts
Acrylic acid and 15 part 2,4,5,6- tetrachloro phthalonitriles.
The preparation method of the Unined RM antiseptics is：
(1) by load weighted antiphen, isoquercitrin, N, N- dihydroxyethylglycins, mercaptopyridine, dodecyl benzyl
Base dimethyl ammonium and 2,4,5,6- tetrachloro phthalonitriles mix at room temperature, form unit for uniform suspension；
(2) A11 non-ionic dispersing agents are added in the suspension obtained to step (1), with 500 in homogenizer
Rev/min rotating speed be stirred 12 hours after, add acrylic acid, continue to be stirred 5 minutes with 500 revs/min of rotating speed,
Obtain the Unined RM antiseptics.
Treatment fluid is tested：
Embodiment 1
Raw material：Water：97.5wt%, Unined RM antiseptics：0.5wt%, polyacrylic binder：1.5wt%, A11 are non-
Ionic dispersant：0.25wt%, coupling agent：0.25wt%.
The preparation method of the textile long acting antibiotic treatment fluid is：Each raw material is weighed by formula；Raw material is put at a high speed
In mixer, stirred 10 hours with 200 revs/min of rotating speed in 30 DEG C, obtain the textile long acting antibiotic treatment fluid.
Embodiment 2
Raw material：Water：84wt%, Unined RM antiseptics:3.5wt%, polyacrylic binder：11.5wt%, A11 are non-
Ionic dispersant：0.5wt%, coupling agent：0.5wt%.
The preparation method of the textile long acting antibiotic treatment fluid is：Each raw material is weighed by formula；Raw material is put at a high speed
In mixer, stirred 10 hours with 200 revs/min of rotating speed in 30 DEG C, obtain the textile long acting antibiotic treatment fluid.
Embodiment 3
Raw material：Water：90wt%, Unined RM antiseptics:2wt%, polyacrylic binder：7.3wt%, A11 nonionic
Type dispersant 0.4wt%, coupling agent：0.3wt%.
The preparation method of the textile long acting antibiotic treatment fluid is：Each raw material is weighed by formula；Raw material is put at a high speed
In mixer, stirred 10 hours with 200 revs/min of rotating speed in 30 DEG C, obtain the textile long acting antibiotic treatment fluid.
The long acting antibiotic performance of embodiment 1-2 textile long acting antibiotic treatment fluid is tested：
Material：
Textile long acting antibiotic treatment fluid
Textile 1：Wool Overcoat of baby (100% wool), it is commercially available.
Textile 2：Pure cotton Overcoat of baby (100% combed cotton), it is commercially available.
Textile 3：Blending upper garment of children clothes (80% combed cotton, 17% terylene, 3% spandex), it is commercially available.
Machine：Antibacterial textile process for producing line, including wash, soak, spin-drying device, drying plant device.
Step：
The textile of outsourcing is put into antimicrobial treatment production line, adds the treatment fluid produced according to embodiment, the place
The weight ratio for managing liquid and textile is 10：1；Then stirred 30 minutes with 60 revs/min of mixing speed at room temperature；Again will place
Reason liquid bleeds off standby；After the textile of moistening dries at a high speed in spin dryer tube, it is put into dryer and is heated to 120 DEG C of drying 1
Hour, it is stand-by.
Textile 1, textile 2, the textile 3 handled by the antimicrobial treatment solution of embodiment 1 is denoted as sample 1, sample
2, sample 3.
Textile 1, textile 2, the textile 3 handled by the antimicrobial treatment solution of embodiment 2 is denoted as sample 4, sample
5, sample 6.
Antibacterial test
Antibacterial test is carried out according to FZ/T73023-2006 standards.The strain of experiment is Escherichia coli (ATCC25922), resistance to
Methicillin golden yellow staphylococcus (ATCC43300), golden yellow staphylococcus (ATCC6538), Candida albicans (ATCC10231).
Washing by soaking is tested
By the textile samples that antimicrobial treatment solution obtained above is handled according to FZ/T73023 standard wash, but wash
Number is 50 times required in 100 times rather than standard.Obtained textile carries out antibacterial test.
The embodiment 1 of table 1. processing textile print wash 100 times after bacteriostasis rate (%)
| Experimental strain | Sample 1 | Sample 2 | Sample 3 |
| Escherichia coli | 96.1 | 98.9 | 97.2 |
| Golden yellow staphylococcus | 99.3 | 99.2 | 98.3 |
| Candida albicans | 96.7 | 98.6 | 90.2 |
| Methicillin-resistant staphylococcus staphylococcus | 99.8 | 99.2 | 99.1 |
As it can be seen from table 1 the bacteriostasis rate after washing 100 times of the textile after the processing of embodiment 1 is above 70%, explanation
The present invention has the bacteriostasis of practicality.
The embodiment 2 of table 2. processing textile print wash 100 times after bacteriostasis rate (%)
| Experimental strain | Sample 4 | Sample 5 | Sample 6 |
| Escherichia coli | 99.9 | 99.9 | 98.5 |
| Golden yellow staphylococcus | 99.8 | 99.3 | 99.2 |
| Candida albicans | 98.9 | 99.1 | 95.1 |
| Methicillin-resistant staphylococcus staphylococcus | 98.4 | 99.7 | 93.4 |
From table 2 it can be seen that the bacteriostasis rate after washing 100 times of the textile after the processing of embodiment 2 is above 70%, explanation
The present invention has the bacteriostasis of practicality.
Embodiment 4
Raw material：Water：97.5wt%, Unined RM antiseptics：0.5wt%, polyacrylic binder：1.5wt%, disperse
Agent Sodium Polyacrylate：0.25wt%, coupling agent：0.25wt%.
The preparation method of the textile long acting antibiotic treatment fluid is：Each raw material is weighed by formula；Raw material is put at a high speed
In mixer, stirred 10 hours with 200 revs/min of rotating speed in 30 DEG C, obtain the textile long acting antibiotic treatment fluid.
Wherein the specific preparation process for the Unined RM antiseptics that embodiment 4 uses for：
The Unined RM antiseptics are counted including 15 parts of antiphens, 3 parts of isoquercitrin, 4 parts of N, N- dihydroxies in parts by weight
Base ethyl glycine, 5 parts of mercaptopyridines, 8 parts of dodecylbenzyl dimethyl ammoniums, 10 parts of dispersant Sodium Polyacrylates, 22 parts
Acrylic acid and 15 part 2,4,5,6- tetrachloro phthalonitriles.
The preparation method of the Unined RM antiseptics is：
(1) by load weighted antiphen, isoquercitrin, N, N- dihydroxyethylglycins, mercaptopyridine, dodecyl benzyl
Base dimethyl ammonium and 2,4,5,6- tetrachloro phthalonitriles mix at room temperature, form unit for uniform suspension；
(2) in the suspension obtained to step (1) add dispersant Sodium Polyacrylate, in homogenizer with 500 turns/
After the rotating speed of minute is stirred 12 hours, acrylic acid is added, continues to be stirred 5 minutes with 500 revs/min of rotating speed, obtains
To the Unined RM antiseptics.
The preparation process of the dispersant Sodium Polyacrylate is：By acrylic acid and isopropanol with mass ratio 1:1 mixing, is obtained
Mixed liquor A；By ammonium persulfate and deionized water with solid-to-liquid ratio 1：25 (g/mL) are well mixed, obtain mixed liquid B；By positive 12 sulphur
Alcohol, isopropanol and deionized water are with mass ratio 1：25：7 is well mixed, obtains mixed liquor C, wherein n- dodecyl mereaptan, acrylic acid,
The mass ratio of ammonium persulfate is 1：22:1；Mixed liquor C is heated to 85 DEG C, while mixed liquor A is added dropwise with 8 μ L/s rate of addition
And mixed liquid B；After charging, reacted 3 hours in 85 DEG C；After reaction terminates, reaction solution is cooled to 40 DEG C, uses mass fraction
The pH value of reaction solution is adjusted to 7 for 30% sodium hydrate aqueous solution；Reaction solution is evaporated under reduced pressure, removes isopropyl alcohol and water,
Obtain the dispersant Sodium Polyacrylate.
Embodiment 5
Raw material：Water：97.5wt%, Unined RM antiseptics：0.5wt%, polyacrylic binder：1.5wt%, disperse
Agent Sodium Polyacrylate：0.25wt%, coupling agent：0.25wt%.
The preparation method of the textile long acting antibiotic treatment fluid is：Each raw material is weighed by formula；Raw material is put at a high speed
In mixer, stirred 10 hours with 200 revs/min of rotating speed in 30 DEG C, obtain the textile long acting antibiotic treatment fluid.
Wherein the specific preparation process for the Unined RM antiseptics that embodiment 5 uses for：
The Unined RM antiseptics are counted including 15 parts of antiphens, 3 parts of isoquercitrin, 4 parts of N, N- dihydroxies in parts by weight
Base ethyl glycine, 5 parts of mercaptopyridines, 8 parts of dodecylbenzyl dimethyl ammoniums, 10 parts of dispersant Sodium Polyacrylates, 22 parts
Acrylic acid and 15 part 2,4,5,6- tetrachloro phthalonitriles.
The preparation method of the Unined RM antiseptics is：
(1) by load weighted antiphen, isoquercitrin, N, N- dihydroxyethylglycins, mercaptopyridine, dodecyl benzyl
Base dimethyl ammonium and 2,4,5,6- tetrachloro phthalonitriles mix at room temperature, form unit for uniform suspension；
(2) in the suspension obtained to step (1) add dispersant Sodium Polyacrylate, in homogenizer with 500 turns/
After the rotating speed of minute is stirred 12 hours, acrylic acid is added, continues to be stirred 5 minutes with 500 revs/min of rotating speed, obtains
To the Unined RM antiseptics.
The preparation process of the dispersant Sodium Polyacrylate is：(1) by n- dodecyl mereaptan, methyl tricapryl ammonium chloride and third
Ketone is added sequentially in reaction vessel, and the n- dodecyl mereaptan, methyl trioctylphosphine chlorination are pressed and the mass ratio of acetone is 1：0.07：
3.5, nitrogen is passed through, while temperature of reaction system is remained 5 DEG C, stirred 3 minutes with 180 revs/min of rotating speed；Add quality
Fraction is 40% sodium hydrate aqueous solution, and the mass ratio of sodium hydrate aqueous solution and n- dodecyl mereaptan is 0.4:1, with 180 turns/
The rotating speed of minute stirs 20 minutes；Then the acetone soln for the carbon disulfide that addition mass fraction is 25%, the third of carbon disulfide
The mass ratio of ketone solution and n- dodecyl mereaptan is 1.4:1, stirred 10 minutes with 180 revs/min of rotating speed；Then successively by chloroform
With the sodium hydrate aqueous solution addition that mass fraction is 40%, the mass ratio of chloroform, sodium hydrate aqueous solution and n- dodecyl mereaptan
For 0.9：2:1, with 180 revs/min of rotating speed stirring reaction 16 hours；Reaction terminate after, add deionized water, deionized water and
The mass ratio of n- dodecyl mereaptan is 30:1, after mixing, add the volume of the hydrochloric acid that mass fraction is 36%, hydrochloric acid and deionized water
Than for 1：20, stirred 25 minutes with 180 revs/min of rotating speed；Nitrogen is passed through, makes acetone volatilization totally；Using 80 mesh filter cloth mistakes
Filter, collect filter cake；Filter cake is dried 8 hours under conditions of 55 DEG C, vacuum 0.07MPa, obtains chain-transferring agent；(2) by third
Olefin(e) acid, initiator A IBN, the tert-butyl alcohol and chain-transferring agent are added in reaction vessel, wherein acrylic acid, initiator A IBN, the tert-butyl alcohol and
The mass ratio of chain-transferring agent is 1：0.002：1.8：0.4, nitrogen is passed through, is mixed 15 minutes；Reaction solution is then warming up to 80 DEG C,
Reaction 7 hours；Reaction solution is evaporated under reduced pressure, the tert-butyl alcohol is removed, obtains the dispersant Sodium Polyacrylate.
The dispersive property of the dispersant of embodiment 1,4 and 5 is measured：A diameter of 6 μm of glass fibres (are purchased from and appointed
The emerging glass fibre factory in Qiu Shi Yongxings), the section that length is 5cm is cut into, be put into beater (has purchased from Xianyang Tai Site testing equipments
Limit company, model PL4-00) in 10-20 minutes are beaten with 500 revs/min of rotating speed, glass fibre is cut off rapidly in wadding
Solid fraction, it is dried 8 hours in 60 DEG C, it is stand-by；200mL water, 4g glass fibres and 0.4g dispersants (are purchased from good fortune with agitator
Hai Te Machinery Co., Ltd.s of Jian Sheng Nan'ans) it is scattered 10 minutes with 200 revs/min of rotating speed, the sedimentation time is then determined, simultaneously
Observe the state of dispersion liquid.
Specific test result is shown in Table 3.
The dispersive property test result table of table 3.
Embodiment 6
Raw material：Water：97.5wt%, Unined RM antiseptics：0.5wt%, lactyl polyester binder：1.5wt%, point
Powder Sodium Polyacrylate：0.25wt%, coupling agent：0.25wt%.
The preparation method of the textile long acting antibiotic treatment fluid is：Each raw material is weighed by formula；Raw material is put at a high speed
In mixer, stirred 10 hours with 200 revs/min of rotating speed in 30 DEG C, obtain the textile long acting antibiotic treatment fluid.
Wherein the specific preparation process for the Unined RM antiseptics that embodiment 6 uses for：
The Unined RM antiseptics are counted including 15 parts of antiphens, 3 parts of isoquercitrin, 4 parts of N, N- dihydroxies in parts by weight
Base ethyl glycine, 5 parts of mercaptopyridines, 8 parts of dodecylbenzyl dimethyl ammoniums, 10 parts of dispersant Sodium Polyacrylates, 22 parts
Acrylic acid and 15 part 2,4,5,6- tetrachloro phthalonitriles.
The preparation method of the Unined RM antiseptics is：
(1) by load weighted antiphen, isoquercitrin, N, N- dihydroxyethylglycins, mercaptopyridine, dodecyl benzyl
Base dimethyl ammonium and 2,4,5,6- tetrachloro phthalonitriles mix at room temperature, form unit for uniform suspension；
(2) in the suspension obtained to step (1) add dispersant Sodium Polyacrylate, in homogenizer with 500 turns/
After the rotating speed of minute is stirred 12 hours, acrylic acid is added, continues to be stirred 5 minutes with 500 revs/min of rotating speed, obtains
To the Unined RM antiseptics.
The preparation process of the dispersant Sodium Polyacrylate is：(1) by n- dodecyl mereaptan, methyl tricapryl ammonium chloride and third
Ketone is added sequentially in reaction vessel, and the n- dodecyl mereaptan, methyl trioctylphosphine chlorination are pressed and the mass ratio of acetone is 1：0.07：
3.5, nitrogen is passed through, while temperature of reaction system is remained 5 DEG C, stirred 3 minutes with 180 revs/min of rotating speed；Add quality
Fraction is 40% sodium hydrate aqueous solution, and the mass ratio of sodium hydrate aqueous solution and n- dodecyl mereaptan is 0.4:1, with 180 turns/
The rotating speed of minute stirs 20 minutes；Then the acetone soln for the carbon disulfide that addition mass fraction is 25%, the third of carbon disulfide
The mass ratio of ketone solution and n- dodecyl mereaptan is 1.4:1, stirred 10 minutes with 180 revs/min of rotating speed；Then successively by chloroform
With the sodium hydrate aqueous solution addition that mass fraction is 40%, the mass ratio of chloroform, sodium hydrate aqueous solution and n- dodecyl mereaptan
For 0.9：2:1, with 180 revs/min of rotating speed stirring reaction 16 hours；Reaction terminate after, add deionized water, deionized water and
The mass ratio of n- dodecyl mereaptan is 30:1, after mixing, add the volume of the hydrochloric acid that mass fraction is 36%, hydrochloric acid and deionized water
Than for 1：20, stirred 25 minutes with 180 revs/min of rotating speed；Nitrogen is passed through, makes acetone volatilization totally；Using 80 mesh filter cloth mistakes
Filter, collect filter cake；Filter cake is dried 8 hours under conditions of 55 DEG C, vacuum 0.07MPa, obtains the chain-transferring agent；(2)
Acrylic acid, initiator A IBN, the tert-butyl alcohol and chain-transferring agent are added in reaction vessel, wherein acrylic acid, initiator A IBN, tertiary fourth
The mass ratio of alcohol and chain-transferring agent is 1：0.002：1.8：0.4, nitrogen is passed through, is mixed 15 minutes；Then reaction solution is warming up to
80 DEG C, react 7 hours；Reaction solution is evaporated under reduced pressure, the tert-butyl alcohol is removed, obtains the dispersant Sodium Polyacrylate.
The preparation process of the lactyl polyester binder is：DL-LACTIC ACID, 6-caprolactone and pungent are added in reaction vessel
The mass ratio of sour stannous, wherein DL-LACTIC ACID, 6-caprolactone and stannous octoate is 90：10：0.1, in 500 revs/min of stirring speed
The lower stirring of degree is warming up to 120 DEG C, reacts 3 hours, with the moisture in elimination reaction system；Reaction solution is warming up to 160 DEG C, polymerization
8 hours；After reaction terminates, reaction solution is cooled to room temperature, adds chloroform, the volume ratio of reaction solution and chloroform is 1：
0.8, stirred 5 minutes with 300 revs/min of rotating speed；Then methanol is added, the volume ratio of methanol and reaction solution is 6：1, with 200-
300 revs/min of rotating speed stirring 10-15 minutes, there is precipitation to produce；Centrifuged 15 minutes with 1000 revs/min of rotating speed, abandon supernatant
Liquid, obtain bottom solid；Bottom solid is dried 10 hours under conditions of 55 DEG C, vacuum 0.08MPa, obtains the lactic acid
Base polyester binder.
Embodiment 7
Raw material：Water：97.5wt%, Unined RM antiseptics：0.5wt%, adhesive：1.5wt%, dispersant polypropylene
Sour sodium：0.25wt%, coupling agent：0.25wt%.
Described adhesive is the mixture of polyacrylic binder and lactyl polyester binder, wherein polyacrylic adhesive
The mass ratio of agent and lactyl polyester binder is 1：3.
The preparation method of the textile long acting antibiotic treatment fluid is：Each raw material is weighed by formula；Raw material is put at a high speed
In mixer, stirred 10 hours with 200 revs/min of rotating speed in 30 DEG C, obtain the textile long acting antibiotic treatment fluid.
Wherein the specific preparation process for the Unined RM antiseptics that embodiment 7 uses for：
The Unined RM antiseptics are counted including 15 parts of antiphens, 3 parts of isoquercitrin, 4 parts of N, N- dihydroxies in parts by weight
Base ethyl glycine, 5 parts of mercaptopyridines, 8 parts of dodecylbenzyl dimethyl ammoniums, 10 parts of dispersant Sodium Polyacrylates, 22 parts
Acrylic acid and 15 part 2,4,5,6- tetrachloro phthalonitriles.
The preparation method of the Unined RM antiseptics is：
(1) by load weighted antiphen, isoquercitrin, N, N- dihydroxyethylglycins, mercaptopyridine, dodecyl benzyl
Base dimethyl ammonium and 2,4,5,6- tetrachloro phthalonitriles mix at room temperature, form unit for uniform suspension；
(2) in the suspension obtained to step (1) add dispersant Sodium Polyacrylate, in homogenizer with 500 turns/
After the rotating speed of minute is stirred 12 hours, acrylic acid is added, continues to be stirred 5 minutes with 500 revs/min of rotating speed, obtains
To the Unined RM antiseptics.
The preparation process of the dispersant Sodium Polyacrylate is：(1) by n- dodecyl mereaptan, methyl tricapryl ammonium chloride and third
Ketone is added sequentially in reaction vessel, and the n- dodecyl mereaptan, methyl trioctylphosphine chlorination are pressed and the mass ratio of acetone is 1：0.07：
3.5, nitrogen is passed through, while temperature of reaction system is remained 5 DEG C, stirred 3 minutes with 180 revs/min of rotating speed；Add quality
Fraction is 40% sodium hydrate aqueous solution, and the mass ratio of sodium hydrate aqueous solution and n- dodecyl mereaptan is 0.4:1, with 180 turns/
The rotating speed of minute stirs 20 minutes；Then the acetone soln for the carbon disulfide that addition mass fraction is 25%, the third of carbon disulfide
The mass ratio of ketone solution and n- dodecyl mereaptan is 1.4:1, stirred 10 minutes with 180 revs/min of rotating speed；Then successively by chloroform
With the sodium hydrate aqueous solution addition that mass fraction is 40%, the mass ratio of chloroform, sodium hydrate aqueous solution and n- dodecyl mereaptan
For 0.9：2:1, with 180 revs/min of rotating speed stirring reaction 16 hours；Reaction terminate after, add deionized water, deionized water and
The mass ratio of n- dodecyl mereaptan is 30:1, after mixing, add the volume of the hydrochloric acid that mass fraction is 36%, hydrochloric acid and deionized water
Than for 1：20, stirred 25 minutes with 180 revs/min of rotating speed；Nitrogen is passed through, makes acetone volatilization totally；Using 80 mesh filter cloth mistakes
Filter, collect filter cake；Filter cake is dried 8 hours under conditions of 55 DEG C, vacuum 0.07MPa, obtains the chain-transferring agent；(2)
Acrylic acid, initiator A IBN, the tert-butyl alcohol and chain-transferring agent are added in reaction vessel, wherein acrylic acid, initiator A IBN, tertiary fourth
The mass ratio of alcohol and chain-transferring agent is 1：0.002：1.8：0.4, nitrogen is passed through, is mixed 15 minutes；Then reaction solution is warming up to
80 DEG C, react 7 hours；Reaction solution is evaporated under reduced pressure, the tert-butyl alcohol is removed, obtains the dispersant Sodium Polyacrylate.
The preparation process of the lactyl polyester binder is：DL-LACTIC ACID, 6-caprolactone and pungent are added in reaction vessel
The mass ratio of sour stannous, wherein DL-LACTIC ACID, 6-caprolactone and stannous octoate is 90：10：0.1, in 500 revs/min of stirring speed
The lower stirring of degree is warming up to 120 DEG C, reacts 3 hours, with the moisture in elimination reaction system；Reaction solution is warming up to 160 DEG C, polymerization
8 hours；After reaction terminates, reaction solution is cooled to room temperature, adds chloroform, the volume ratio of reaction solution and chloroform is 1：
0.8, stirred 5 minutes with 300 revs/min of rotating speed；Then methanol is added, the volume ratio of methanol and reaction solution is 6：1, with 200-
300 revs/min of rotating speed stirring 10-15 minutes, there is precipitation to produce；Centrifuged 15 minutes with 1000 revs/min of rotating speed, abandon supernatant
Liquid, obtain bottom solid；Bottom solid is dried 10 hours under conditions of 55 DEG C, vacuum 0.08MPa, obtains the lactic acid
Base polyester binder.
The bond properties of embodiment 5-7 adhesive is measured, specific testing procedure is as follows：
(1) slurry is configured：25g adhesives are weighed, add 100mL distilled water, are mixed 10 minutes, are warming up to 95 DEG C, insulation 1
Hour, obtain slurry；
(2) the pure cotton rove being wound on metal frame is impregnated 5 (purchased from Weifang profit Photar Textile Co., Ltd.) in slurries
Minute, by rove framework take out hang airing, then by light sizing rove bar cut collect it is standby；
(3) 24 hours are balanced after light sizing rove bar is dried, in the environment of 20 DEG C of temperature, relative humidity 65%, then
Using universal testing machine (being purchased from Shanghai Zhu Jin Analytical Instrument Co., Ltd, model zwick) test light sizing rove bar
Maximum strength and work to break.
Test condition：Draw speed is 50mm/min, and sample chuck distance is 100mm, 20 DEG C of test temperature, relative humidity
65%, each embodiment tests 20 samples.After rejecting abnormalities value, its average value is taken as test result.
Specific test result is shown in Table 4.
Table 4：Bond properties test result table
| Maximum strength (N) | Work to break (J) | |
| Embodiment 5 | 58.3 | 0.215 |
| Embodiment 6 | 66.2 | 0.279 |
| Embodiment 7 | 72.8 | 0.302 |
It is described above, simply one embodiment of the invention, not the invention is made any formal
Limitation, on the basis of the technical scheme of the invention is not departed from, made simple modification, equivalent variations or modification, falls
Enter the protection domain of the invention.
Claims (9)
- A kind of 1. textile long acting antibiotic treatment fluid, it is characterised in that the composition of raw materials of the textile long acting antibiotic treatment fluid It is by weight percentage：Deionized water 84-97.5%, Unined RM antiseptic 0.5-3.5%, adhesive 1.5-11.5%, Dispersant 0.25-0.5% and coupling agent 0.25-0.5%.
- 2. textile long acting antibiotic treatment fluid according to claim 1, it is characterised in that the Unined RM antiseptics Meter includes 10-15 parts phenols, 1-3 parts isoquercitrin, 2-4 parts N, N- dihydroxyethylglycin, 3-5 part sulfydryls in parts by weight Pyridine, 5-8 part dodecylbenzyls dimethyl ammonium, 0.3-10 parts dispersant, 0.56-22 parts acrylic acid and 10-15 parts 2,4, 5,6- tetrachloro phthalonitriles.
- 3. textile long acting antibiotic treatment fluid according to claim 2, it is characterised in that the phenols is isopropyl methyl One or more of compositions in phenol, triclosan, antiphen, clorofene, chloreresol.
- 4. textile long acting antibiotic treatment fluid according to claim 2, it is characterised in that the Unined RM antiseptics Preparation method be：(1) by load weighted phenols, isoquercitrin, N, N- dihydroxyethylglycins, mercaptopyridine, dodecylbenzyl diformazan Base ammonium salt and 2,4,5,6- tetrachloro phthalonitriles form uniform suspension in mixed at room temperature；(2) dispersant is added in the suspension obtained to step (1), mixes 10-12 hours, then adds acrylic acid, mixes 2-5 Minute, obtain the Unined RM antiseptics.
- 5. textile long acting antibiotic treatment fluid according to claim 1, it is characterised in that the dispersant is polyacrylic acid Sodium.
- 6. textile long acting antibiotic treatment fluid according to claim 5, it is characterised in that the preparation of the Sodium Polyacrylate Process is：By acrylic acid and isopropanol with mass ratio 1:(0.9-1.2) is mixed, and obtains mixed liquor A；By ammonium persulfate and deionization Water is with solid-to-liquid ratio 1：(20-25) (g/mL) is well mixed, obtains mixed liquid B；By n- dodecyl mereaptan, isopropanol and deionized water with Mass ratio 1：(22-25)：7 is well mixed, obtains mixed liquor C, wherein n- dodecyl mereaptan, acrylic acid, ammonium persulfate mass ratio For 1：(20-25):1；Mixed liquor C is heated to 80-85 DEG C, while mixed liquor A and mixing are added dropwise with 5-8 μ L/s rate of addition Liquid B；After charging, 2.5-3 hours are reacted in 80-85 DEG C；After reaction terminates, reaction solution is cooled to 40-45 DEG C, uses quality The sodium hydrate aqueous solution that fraction is 25-30% adjusts the pH value of reaction solution to 7-8；Reaction solution is evaporated under reduced pressure, removed different Third alcohol and water, obtain the dispersant Sodium Polyacrylate.
- 7. textile long acting antibiotic treatment fluid according to claim 1, it is characterised in that described adhesive is polyacrylic acid One or more mixtures in adhesive, aqueous polyurethane adhesive, lactyl polyester binder.
- 8. textile long acting antibiotic treatment fluid according to claim 7, it is characterised in that the lactyl polyester binder Preparation process be：DL-LACTIC ACID, 6-caprolactone and stannous octoate, wherein DL-LACTIC ACID, 6-caprolactone are added in reaction vessel Mass ratio with stannous octoate is (90-94)：(6-10)：0.1, stir and be warming up under 400-600 revs/min of mixing speed 120-140 DEG C, react 2-8 hours；Reaction solution is warming up to 160-180 DEG C, polymerize 4-8 hours；After polymerization terminates, by reaction solution It is cooled to room temperature, adds chloroform, the volume ratio of reaction solution and chloroform is 1：(0.6-0.8), with 200-300 revs/min The rotating speed stirring 5-10 minutes of clock；Then methanol is added, the volume ratio of methanol and reaction solution is (5-6)：1, with 200-300 turn/ The rotating speed stirring 10-15 minutes of minute, there is precipitation to produce；10-15 minutes are centrifuged with 1000-2000 revs/min of rotating speed, abandoned Clear liquid, obtain bottom solid；Bottom solid is dried into 6-10 hours under conditions of 50-60 DEG C, vacuum 0.08-0.09MPa, Obtain the lactyl polyester binder.
- 9. prepare the method for the textile long acting antibiotic treatment fluid as any one of claim 1-8, it is characterised in that bag Include following steps：Each raw material is weighed by formula；Raw material is put into high-speed mixer, in 25-35 DEG C with 100-200 revs/min Rotating speed stirring 10-12 hours, obtain the textile long acting antibiotic treatment fluid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710879296.2A CN107761372B (en) | 2017-09-26 | 2017-09-26 | Long-acting antibacterial treatment fluid for textiles and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710879296.2A CN107761372B (en) | 2017-09-26 | 2017-09-26 | Long-acting antibacterial treatment fluid for textiles and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107761372A true CN107761372A (en) | 2018-03-06 |
| CN107761372B CN107761372B (en) | 2022-09-06 |
Family
ID=61266531
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710879296.2A Active CN107761372B (en) | 2017-09-26 | 2017-09-26 | Long-acting antibacterial treatment fluid for textiles and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107761372B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109457466A (en) * | 2018-11-15 | 2019-03-12 | 李宁 | Functionalized carbon nano-tube and its application in antistatic antibiotic fabric finishing liquor |
| CN109468844A (en) * | 2018-11-15 | 2019-03-15 | 李宁 | Antibacterial fabric and its production technology |
| CN113622188A (en) * | 2021-08-12 | 2021-11-09 | 杭州纵纬针纺有限公司 | Deodorizing knitted fabric and manufacturing method thereof |
| CN113929606A (en) * | 2021-09-23 | 2022-01-14 | 武汉海翎化学工业有限公司 | Trithioester chain transfer agent, low-molecular-weight sodium polyacrylate obtained by using same, application and preparation |
| CN114763674A (en) * | 2021-05-27 | 2022-07-19 | 吉林省手足堂生物科技有限公司 | Antibacterial and deodorant sock and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102094323A (en) * | 2009-12-11 | 2011-06-15 | 国家纳米技术与工程研究院 | Composite antibacterial textile finishing agent and application thereof |
-
2017
- 2017-09-26 CN CN201710879296.2A patent/CN107761372B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102094323A (en) * | 2009-12-11 | 2011-06-15 | 国家纳米技术与工程研究院 | Composite antibacterial textile finishing agent and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| 伍天荣: "《纺织应用化学与实验》", 31 August 2003, 中国纺织出版社 * |
| 潘才元: "《高分子化学》", 31 July 2012, 中国科学技术大学出版社 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109457466A (en) * | 2018-11-15 | 2019-03-12 | 李宁 | Functionalized carbon nano-tube and its application in antistatic antibiotic fabric finishing liquor |
| CN109468844A (en) * | 2018-11-15 | 2019-03-15 | 李宁 | Antibacterial fabric and its production technology |
| CN109457466B (en) * | 2018-11-15 | 2021-06-08 | 浪达网络科技(浙江)有限公司 | Functionalized carbon nanotube and application thereof in antistatic and antibacterial fabric finishing liquid |
| CN114763674A (en) * | 2021-05-27 | 2022-07-19 | 吉林省手足堂生物科技有限公司 | Antibacterial and deodorant sock and application thereof |
| CN114763674B (en) * | 2021-05-27 | 2023-07-14 | 河南浩川生物科技有限公司 | Antibacterial deodorizing sock and application thereof |
| CN113622188A (en) * | 2021-08-12 | 2021-11-09 | 杭州纵纬针纺有限公司 | Deodorizing knitted fabric and manufacturing method thereof |
| CN113929606A (en) * | 2021-09-23 | 2022-01-14 | 武汉海翎化学工业有限公司 | Trithioester chain transfer agent, low-molecular-weight sodium polyacrylate obtained by using same, application and preparation |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107761372B (en) | 2022-09-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107761372A (en) | A kind of textile long acting antibiotic treatment fluid and preparation method thereof | |
| Zhou et al. | Bioactive and UV protective silk materials containing baicalin—The multifunctional plant extract from Scutellaria baicalensis Georgi | |
| Jothi | Experimental study on antimicrobial activity of cotton fabric treated with aloe gel extract from Aloe vera plant for controlling the Staphylococcus aureus (bacterium) | |
| CN106222777B (en) | A kind of preparation method of the mosquito repellent viscose rayon containing wormwood extract | |
| CN105854853B (en) | A kind of preparation method of antibacterial metal organic backbone composite nano fiber | |
| Teli et al. | Modified bamboo rayon–copper nanoparticle composites as antibacterial textiles | |
| DE60305172T2 (en) | ANTIMICROBIAL YARN WITH NANOSILIC PARTICLES AND METHOD FOR THE PRODUCTION THEREOF | |
| Khurshid et al. | Assessment of eco-friendly natural antimicrobial textile finish extracted from aloe vera and neem plants | |
| CN107326470B (en) | A kind of processing method of the lasting modified polyester fiber of antibacterial | |
| KR101159123B1 (en) | Method for producing natural pigment composition containing phytoncide and chitosan | |
| CN102337669A (en) | Method for processing antibacterial wool fiber | |
| Jafary et al. | Antibacterial property of cellulose fabric finished by allicin-conjugated nanocellulose | |
| WO2012059944A2 (en) | Blue coloured aqueous dispersion of silver nanoparticles a process for preparation and compositions thereof | |
| WO2008131720A1 (en) | Method for the production of a bioactive cellulose fiber with a high degree of brightness | |
| CN111280178A (en) | Multicolor graphene antibacterial liquid and preparation method and application thereof | |
| CN113337903A (en) | Antiviral polypropylene non-woven fabric and preparation method thereof | |
| CN111962177A (en) | Antibacterial polyester fiber and preparation method and application thereof | |
| CN105442307B (en) | A kind of preparation method of loading nano silvery anti-bacterial fibre | |
| Li et al. | Screening ionic liquids by the COSMO-RS method for the preparation of antibacterial cellulose fibers | |
| CN101130607A (en) | Polyvinyl alcohol polymer compound film and method for preparing the same | |
| CN102493014A (en) | Epsilon-polylysine and polyvinyl alcohol composite biological antibacterial fiber and preparation method thereof | |
| ITMI20080792A1 (en) | METHOD FOR THE FUNCTIONALIZATION OF NATURAL OR SYNTHETIC FIBERS WITH SILVER NANOPARTICLES | |
| CN106012510B (en) | Have anti-bacterial fibre, antibacterial textile of washability and preparation method thereof | |
| CN109137490A (en) | A kind of antibacterial modified method of cotton fiber | |
| Syed et al. | Eco-friendly antimicrobial finishing of cotton fabrics using bioactive agents from novel Melia azedarachayan berries extract and their performance after subsequent washings |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20220817 Address after: No. 1914, New Century Avenue, Linjiang Industrial Park, Linjiang street, Qiantang District, Hangzhou, Zhejiang 310000 Applicant after: Hangzhou Daoxian Intelligent Technology Co.,Ltd. Address before: 322000 Xuefeng West Road, Beiyuan street, Yiwu, Jinhua, Zhejiang, 968 Applicant before: ZHEJIANG UNINED TECHNOLOGY CO.,LTD. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: No. 1914, New Century Avenue, Linjiang Industrial Park, Linjiang street, Qiantang District, Hangzhou, Zhejiang 310000 Patentee after: Ruyu Deshui (Hangzhou) Soft Decoration Customization Co.,Ltd. Country or region after: China Address before: No. 1914, New Century Avenue, Linjiang Industrial Park, Linjiang street, Qiantang District, Hangzhou, Zhejiang 310000 Patentee before: Hangzhou Daoxian Intelligent Technology Co.,Ltd. Country or region before: China |