CN107759974A - A kind of sepiolite fire-retarding epoxy resin composite material - Google Patents
A kind of sepiolite fire-retarding epoxy resin composite material Download PDFInfo
- Publication number
- CN107759974A CN107759974A CN201610683286.7A CN201610683286A CN107759974A CN 107759974 A CN107759974 A CN 107759974A CN 201610683286 A CN201610683286 A CN 201610683286A CN 107759974 A CN107759974 A CN 107759974A
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- China
- Prior art keywords
- parts
- epoxy resin
- sepiolite
- fire
- composite material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2275—Ferroso-ferric oxide (Fe3O4)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses a kind of sepiolite fire-retarding epoxy resin composite material, it is made from the following raw materials in parts by weight：Epoxy resin, sepiolite, N methyl pyrrolidones, BYK301, maleic anhydride, cobalt naphthenate, isopropyl stearic acid oxygen base aluminum acid ester, ferroso-ferric oxide, nano silicon, suitable quantity of water.Beneficial effects of the present invention：Have the advantages that flame retardant effect is excellent, elongation percentage is high, tensile strength is big, fracture elongation is high and viscosity is small, adhesive strength is good.
Description
Technical field
The present invention relates to a kind of composite, more particularly to a kind of sepiolite fire-retarding epoxy resin composite material.
Background technology
Epoxy resin is to refer to the organic compound containing two or more active epoxide groups in molecule, and they can
Reaction is crosslinked with polytype curing agent and forms insoluble, the insoluble high polymer with three-dimensional network structure.Have
It is excellent be electrically insulated, machinery, bonding, resistance to chemical corrosion and good physics, chemical property, be used as lamination material, viscous extensively
Agent, coating etc. are tied, is increasingly taken seriously in fields such as steamer, automobile, Aero-Space.
At present, epoxy resin shows many problems by the matrix as composite, as hardness is low, poor insulativity, by
Thermal softening, easily layering, the shortcomings of mass-and heat-transfer is difficult, smell is big, are, it is necessary to improve the preparation technology of epoxy resin.
The content of the invention
It is an object of the invention to overcome the above-mentioned deficiency in the presence of prior art, there is provided a kind of sepiolite flame retardant epoxy
Resin composite materials.
In order to realize foregoing invention purpose, the invention provides following technical scheme：
A kind of sepiolite fire-retarding epoxy resin composite material, is made from the following raw materials in parts by weight：Epoxy resin 10-20 parts, sea
Afrodite 20-35 parts, 1-METHYLPYRROLIDONE 10-15 parts, BYK301 1-2 parts, maleic anhydride 10-13 parts, cobalt naphthenate 0.5-1
It is part, isopropyl stearic acid oxygen base aluminum acid ester 1-3 parts, ferroso-ferric oxide 0.1-0.5 parts, nano silicon 5-8 parts, appropriate
Water.
Preferably, it is made from the following raw materials in parts by weight：16 parts of epoxy resin, 31 parts of sepiolite, 1-METHYLPYRROLIDONE
12 parts, 1.2 parts of BYK301,11 parts of maleic anhydride, 0.8 part of cobalt naphthenate, 1.6 parts of isopropyl stearic acid oxygen base aluminum acid ester, four
0.4 part of Fe 3 O, 6 parts of nano silicon, suitable quantity of water.
Compared with prior art, beneficial effects of the present invention：With flame retardant effect is excellent, elongation percentage is high, tensile strength is big, disconnected
Split the advantages that elongation percentage is high and viscosity is small, adhesive strength is good.
Embodiment
With reference to test example and embodiment, the present invention is described in further detail.But this should not be understood
Following embodiment is only limitted to for the scope of the above-mentioned theme of the present invention, it is all that this is belonged to based on the technology that present invention is realized
The scope of invention.
Embodiment 1：
A kind of sepiolite fire-retarding epoxy resin composite material, is made from the following raw materials in parts by weight：10 parts of epoxy resin, Hai Pao
20 parts of stone, 10 parts of 1-METHYLPYRROLIDONE, 1 part of BYK301,10 parts of maleic anhydride, 0.5 part of cobalt naphthenate, isopropyl distearyl
1 part of acyloxy Aluminate, 0.1 part of ferroso-ferric oxide, 5 parts of nano silicon, suitable quantity of water.
Embodiment 2：
A kind of sepiolite fire-retarding epoxy resin composite material, is made from the following raw materials in parts by weight：20 parts of epoxy resin, sepiolite
35 parts, 15 parts of 1-METHYLPYRROLIDONE, 2 parts of BYK301,13 parts of maleic anhydride, 1 part of cobalt naphthenate, isopropyl distearyl acyl-oxygen
3 parts of base Aluminate, 0.5 part of ferroso-ferric oxide, 8 parts of nano silicon, suitable quantity of water.
Embodiment 3：
A kind of sepiolite fire-retarding epoxy resin composite material, is made from the following raw materials in parts by weight：16 parts of epoxy resin, sepiolite
31 parts, 12 parts of 1-METHYLPYRROLIDONE, 1.2 parts of BYK301,11 parts of maleic anhydride, 0.8 part of cobalt naphthenate, isopropyl distearyl
1.6 parts of acyloxy Aluminate, 0.4 part of ferroso-ferric oxide, 6 parts of nano silicon, suitable quantity of water.
Claims (2)
1. a kind of sepiolite fire-retarding epoxy resin composite material, it is characterised in that be made from the following raw materials in parts by weight：Epoxy
Resin 10-20 parts, sepiolite 20-35 parts, 1-METHYLPYRROLIDONE 10-15 parts, BYK301 1-2 parts, maleic anhydride 10-13 parts,
Cobalt naphthenate 0.5-1 parts, isopropyl stearic acid oxygen base aluminum acid ester 1-3 parts, ferroso-ferric oxide 0.1-0.5 parts, nanometer titanium dioxide
Silicon 5-8 parts, suitable quantity of water.
2. sepiolite fire-retarding epoxy resin composite material according to claim 1, it is characterised in that by following parts by weight
Raw material be made：16 parts of epoxy resin, 31 parts of sepiolite, 12 parts of 1-METHYLPYRROLIDONE, 1.2 parts of BYK301, maleic anhydride 11
Part, 0.8 part of cobalt naphthenate, 1.6 parts of isopropyl stearic acid oxygen base aluminum acid ester, 0.4 part of ferroso-ferric oxide, nano silicon 6
Part, suitable quantity of water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610683286.7A CN107759974A (en) | 2016-08-18 | 2016-08-18 | A kind of sepiolite fire-retarding epoxy resin composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610683286.7A CN107759974A (en) | 2016-08-18 | 2016-08-18 | A kind of sepiolite fire-retarding epoxy resin composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107759974A true CN107759974A (en) | 2018-03-06 |
Family
ID=61261423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610683286.7A Withdrawn CN107759974A (en) | 2016-08-18 | 2016-08-18 | A kind of sepiolite fire-retarding epoxy resin composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107759974A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115353718A (en) * | 2022-09-22 | 2022-11-18 | 湖南亿润新材料科技有限公司 | High-flame-retardant high-temperature-resistant epoxy resin composite board and preparation method thereof |
-
2016
- 2016-08-18 CN CN201610683286.7A patent/CN107759974A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115353718A (en) * | 2022-09-22 | 2022-11-18 | 湖南亿润新材料科技有限公司 | High-flame-retardant high-temperature-resistant epoxy resin composite board and preparation method thereof |
| CN115353718B (en) * | 2022-09-22 | 2024-01-26 | 湖南亿润新材料科技有限公司 | High-flame-retardance high-temperature-resistant epoxy resin composite board and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180306 |