CN107759103A - Can the refined card glass of tempering and its processing method - Google Patents
Can the refined card glass of tempering and its processing method Download PDFInfo
- Publication number
- CN107759103A CN107759103A CN201711167087.1A CN201711167087A CN107759103A CN 107759103 A CN107759103 A CN 107759103A CN 201711167087 A CN201711167087 A CN 201711167087A CN 107759103 A CN107759103 A CN 107759103A
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- Prior art keywords
- tempering
- refined
- card
- glass
- coating
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B27/00—Tempering or quenching glass products
- C03B27/012—Tempering or quenching glass products by heat treatment, e.g. for crystallisation; Heat treatment of glass products before tempering by cooling
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/0005—Other surface treatment of glass not in the form of fibres or filaments by irradiation
- C03C23/006—Other surface treatment of glass not in the form of fibres or filaments by irradiation by plasma or corona discharge
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/0075—Cleaning of glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/445—Organic continuous phases
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/118—Deposition methods from solutions or suspensions by roller-coating
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/31—Pre-treatment
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/32—After-treatment
Abstract
The invention discloses one kind can the refined card glass of tempering and its processing method, belong to glass technology field.It is disclosed by the invention can the refined card glass of tempering include glassy layer, the plate face of the glassy layer side is provided with can the refined card glass coating of tempering.Can the refined card glass coating of tempering by it is transparent can tempering coating liquid be formulated as film forming matter and the refined card coating of high temperature resistant.The refined card coating hardness treated by tempering is high, scratch-resistant, can monolithic use, will not aoxidize, durable in use, hydrophile function is lasting.The present invention also provide it is above-mentioned can the refined card glass of tempering processing method.
Description
Technical field
The invention belongs to glass technology field, and in particular to one kind can the refined card glass of tempering and its processing method.
Background technology
Refined card glass pattern is rich in color changeable, and artistic decoration is very strong, is greatly enriched the life of people, is got over
To be applied to the fields such as house ornamentation, furniture, building decoration more.But as one kind of glass, same generally existing defect, i.e.,
Not tempering, non-refractory, the mechanical strength and thermal shock resistance of glass are bad, and fragment is easily formed sharp on broken rear glass
Knife-like wedge angle, causes personal injury.Therefore there is very big potential safety hazard in refined card glass.
The refined card coating hardness of refined card glass is inadequate in the prior art, and not scratch resistance is, it is necessary to careful care；By workmen's skill
Art is horizontal and site operation environment influences, and is also easy to produce mould defect, influences attractive in appearance.
The content of the invention
In order to solve the above technical problems, the present invention provide one kind can tempering coating liquid, and with comprising it is described can tempering plate
Film liquid can the refined card glass of tempering made from the refined card glass coating of tempering.After tempering is treated can the refined card glass of tempering
Coating hardness is high, scratch-resistant, can monolithic use, will not aoxidize, durable in use, hydrophile function is lasting.
The present invention solves technical scheme used by above-mentioned technical problem：
On the one hand, the present invention provide one kind can tempering coating liquid, by weight percentage, include following component：
The glass resin is the organic-silicone prepolymer of 5~50mpas of viscosity, light transmittance higher than 90%.
The hydroxy silicon oil is the poly- diformazan for the silanol end-blocking that hydroxy radical content is 2%~4%, viscosity is 20~40mpas
Radical siloxane.
The polyether modified silicon oil molecular weight is 2000~6000.
The organic silicon sol SiO2Content is 20~40%, and average grain diameter be 50~100nm, dicyandiamide solution be methanol,
In isopropanol, ethylene glycol, propylene glycol monomethyl ether, butanone, methylisobutylketone, the one or more of the tert-butyl alcohol, ethyl acetate.
The titanate esters are positive isopropyl titanate, positive butyl titanate, metatitanic acid n-propyl, purity titanium tetraethoxide, triethanolamine titanium
One or more in hydrochlorate, Diethanolamine titanate.
The solvent is methanol, ethanol, ethylene glycol, isopropanol, n-butanol, the tert-butyl alcohol, ethyl acetate, vinegar ester butyl ester, fourth
One or more in ketone, methylisobutylketone, the tert-butyl alcohol, ethyl acetate.
On the other hand, the present invention provide one kind can the refined card glass of tempering, including glassy layer (1), the glassy layer side
Plate face be provided with can the refined card glass coating (2) of tempering, it is described can the refined card glass coating (2) of tempering by weight, comprising above-mentioned
Can 1 part of tempering coating liquid, 0.1~0.5 part of the refined card coating of high temperature resistant.
The refined card coating of high temperature resistant is resistant to more than 700 DEG C of high temperature.
It is described can refined card glass coating (2) Kun of tempering be coated on glassy layer (1), it is described can the refined card glass coating (2) of tempering
Film thickness monitoring at 1000~2500 nanometers.
It is of the present invention can the refined card glass of tempering process to obtain by the following method：
1) original sheet glass cleans, and Surface Treatment with Plasma, destatics；
2) roller coat can the refined card glass coating of tempering；
3) mould shapes to form pattern, UV optical soliton interactions；
4) heat cure；
5) after solidifying, promote annealing furnace to carry out tempering, can obtain a kind of lasting refined card of hydrophile function after cooling
Glass.
Preferably, it is described can the refined card glass coating of tempering film thickness monitoring at 1000~2500 nanometers.
It is highly preferred that it is described can the refined card glass coating of tempering film thickness monitoring at 2000 nanometers.
The present invention has advantages below compared with prior art：
1st, the refined card glass coating after tempering is handled, combines together with glass, and hardness is high, scratch-resistant, can monolithic make
With, will not aoxidize, durable in use, hydrophile function is lasting, almost with the glass same life-span, it is unabiding to solve hydrophile function
Problem.
2nd, the refined card glass coating after tempering is handled, bending strength is bigger 3~5 times than undressed, heat endurance
Improve, 200~250 DEG C of the temperature difference sudden turn of events can be subjected to, the particle without sharp corners is formed when crushing, to human injury's very little, is
Widely used safety-type refined card glass can be carried out.
3rd, the present invention announce can the refined card glass of tempering can carry out hot bending processing, be widely used in building glass and decoration glass
Glass.
Brief description of the drawings
Fig. 1 can the refined card glass schematic diagram of tempering, 1 simple glass original piece or glassy layer, 2 can the refined card glass coating of tempering.
Embodiment
With reference to specific embodiment, the present invention will be further described.It should be understood that within the scope of the present invention, it is of the invention
It can be mutually combined between above-mentioned each technical characteristic and each technical characteristic specifically described in below (eg embodiment), so as to
Form new or preferable technical scheme.As space is limited, no longer tire out one by one herein and state.
The refined card coating of high temperature resistant of the present invention is as it is known by the man skilled in the art, for applied to preparing refined card glass
Refined card coating, the refined card coating that more than 700 DEG C of preferred heatproof.
It is of the present invention can the refined card glass structure of tempering as shown in figure 1,1 is simple glass original piece or glassy layer, 2 is can
The refined card glass coating of tempering.Wherein, the thickness of simple glass original piece can be but not limited to 4mm~15mm.
The present invention can the refined card coating of tempering by adding inorganic Ludox, brought for whole coating system preferably hard
Degree, heat-resisting quantity and wear-resisting scratch-resisting wiping property.The addition of metatitanic acid fat and zirconic acid compound makes coating liquid after hardening and glass
It is clear coat after glass tempering, ensure that the transparency of film plating layer.Also, the hydrolysis of inorganic Ludox and titanate esters and zirconates
Thing reacts in the pyroprocess of glass tempering with substrate of glass, so as to realize the high rigidity of coating, high temperature resistant, wear-resisting
It is anti-scratch.
The present invention can the refined card coating of tempering pass through hydroxy silicon oil and polyether modified silicon oil added in system so that coating
Do not ftractureed in solidification and toughening process, ensure that the continuity and integrality of the pattern after coating tempering.Hydroxy silicon oil
All there is preferable temperature tolerance with polyether modified silicon oil, the work of connection inorganic matter bridge is played during plated film curing of coatings
With being slowly ashed with the rising of temperature in toughening process, ensure that the continuous and integrality of inorganic matter film forming, and be ashed
Remaining silica can turn into the bridge of other inorganic constituents connection afterwards, ensure that the aesthetic after coating tempering.
The present invention can the refined card coating of tempering by using organic solvent combination, coating liquid can be made after roller coat, formed
The smooth coating of Self-leveling, it is uneven to solve the problems, such as that coating easily occurs.
It is of the present invention can the refined card glass of tempering process to obtain by the following method：
1) original sheet glass cleans, and Surface Treatment with Plasma, destatics；
2) roller coat can the refined card glass coating of tempering；
3) mould shapes to form pattern, UV optical soliton interactions；
4) heat cure；
5) after solidifying, promote annealing furnace to carry out tempering, can obtain a kind of lasting refined card of hydrophile function after cooling
Glass.
Preferably, it is described can the refined card glass coating of tempering film thickness monitoring at 1000~2500 nanometers.
It is highly preferred that it is described can the refined card glass coating of tempering film thickness monitoring at 2000 nanometers.
Embodiment 1
Can tempering plated film formula of liquid 1：
By weight percentage, each component content：
Wherein,
Glass resin is viscosity 15mpas, and light transmittance is higher than 90% organic-silicone prepolymer.
Hydroxy silicon oil is that hydroxy radical content is 2%~4%, the polydimethylsiloxanes that the silanol that viscosity is 20mpas blocks
Alkane.
Polyether modified silicon oil molecular weight is 2000.
Organic silicon sol is SiO2Content is 20%, and average grain diameter 50nm, dicyandiamide solution is methanol.
Embodiment 2
Can tempering plated film formula of liquid 2：
By weight percentage, each component content：
The glass resin is viscosity 25mpas, and light transmittance is higher than 90% organic-silicone prepolymer.
The hydroxy silicon oil is that hydroxy radical content is 2%~4%, the poly dimethyl silicon that the silanol that viscosity is 20mpas blocks
Oxygen alkane.
The polyether modified silicon oil molecular weight is 3000.
The organic silicon sol is SiO2Content is 20%, average grain diameter 60nm, and dicyandiamide solution is isopropanol and tertiary fourth
Alcohol.
Embodiment 3
Can tempering plated film formula of liquid 3：
By weight percentage, each component content：
Wherein, glass resin is viscosity 30mpas, and light transmittance is higher than 90% organic-silicone prepolymer；
Hydroxy silicon oil is that hydroxy radical content is 2%~4%, the polydimethylsiloxanes that the silanol that viscosity is 30mpas blocks
Alkane；
Polyether modified silicon oil molecular weight is 3500；
Organic silicon sol is SiO2Content is 30%, average grain diameter 60nm, and dicyandiamide solution is isopropanol and methanol.
Embodiment 4
Can tempering plated film formula of liquid 4：
By weight percentage, each component content：
Wherein, glass resin is viscosity 40mpas, and light transmittance is higher than 90% organic-silicone prepolymer；
Hydroxy silicon oil is that hydroxy radical content is 2%~4%, the polydimethylsiloxanes that the silanol that viscosity is 30mpas blocks
Alkane；
Polyether modified silicon oil molecular weight is 4000；
Organic silicon sol is SiO2Content is 30%, average grain diameter 60nm, and dicyandiamide solution is isopropanol and methanol.
Embodiment 5
Can tempering plated film formula of liquid 5：
By weight percentage, each component content：
Wherein, glass resin is viscosity 40mpas, and light transmittance is higher than 90% organic-silicone prepolymer；
Hydroxy silicon oil is that hydroxy radical content is 2%~4%, the polydimethylsiloxanes that the silanol that viscosity is 40mpas blocks
Alkane；
Polyether modified silicon oil molecular weight is 5000；
Organic silicon sol is SiO2Content is 30%, average grain diameter 80nm, and dicyandiamide solution is isopropanol and ethyl acetate.
Embodiment 6
Can tempering plated film formula of liquid 6：
By weight percentage, each component content：
Wherein glass resin is viscosity 50mpas, and light transmittance is higher than 90% organic-silicone prepolymer；
Hydroxy silicon oil is that hydroxy radical content is 2%~4%, the polydimethylsiloxanes that the silanol that viscosity is 40mpas blocks
Alkane；
Polyether modified silicon oil molecular weight is 6000；
Organic silicon sol is SiO2Content is 40%, average grain diameter 100nm, and dicyandiamide solution is isopropanol and acetic acid second
Ester.
Embodiment 7-10 can the refined card glass coating formula (by weight) of tempering
Embodiment 11 can the refined card glass processing method of tempering
1) original sheet glass cleans, and Surface Treatment with Plasma, destatics；
2) described in roller coat embodiment 7-10 can the refined card glass coating of tempering, film thickness monitoring is at 2000 nanometers；
3) mould shapes to form pattern, UV optical soliton interactions；
4) 150 DEG C of -180 DEG C of heat cure 15-20 minutes；
5) after solidifying, annealing furnace is promoted to carry out tempering, cooling；
6) 65 DEG C of normal temperature is cooled to, glass frame bottom sheet, obtains a kind of lasting refined card glass of hydrophile function.
In step 1), because glass surface has mould proof powder, running water and underground water have substantial amounts of alkaline matter etc. in addition
Impurity, thus need to reuse purified water after running water cleaning, pure water is cleaned automatically, then high temperature and high speed drying again；It is high
Warm drying at a high speed uses 360 degree of dryings of twice wind up and down.Destatic and carried out in ten thousand grades of toilets, destatic processing
It is that influenceing roller coat effect makes coating irregular because being also easy to produce electrostatic in glass course of conveying.In step 2), it is transparent can tempering
The thickness control of refined card glass coating liquid roller coat is at 200~2000 nanometers；Heat cure refers in 150~180 DEG C of 15-20 points of heat cures
Clock.
Comparative example 1
A kind of glass can the refined card coating formula of tempering, its each component and content and the component in embodiment 7 and content phase
Together, its difference is not containing titanate.
Comparative example 2
A kind of glass can the refined card coating formula of tempering, its each component and content and the component in embodiment 8 and content phase
Together, its difference is not containing zirconates.
Comparative example 3
A kind of glass can the refined card coating formula of tempering, its each component and content and the component in embodiment 9 and content phase
Together, its difference is not containing organic silicon sol.
Comparative example 4
A kind of glass can the refined card coating formula of tempering, its each component and content and the component in embodiment 9 and content phase
Together, its difference is not containing titanate esters, zirconates and organic silicon sol.
, respectively can steel by glass disclosed in embodiment 7~10 and comparative example 1~4 in order to evaluate the hardness of coating exactly
Change refined card coating according to method disclosed in embodiment 11 be processed into tempering shaping refined card glass tested.
In order to more accurately evaluate the hardness of coating, roller coat thickness is 2000 nanometers, and heat cure condition is 170 DEG C of heat
Solidification 20 minutes.
Using Mitsubishi pencil, hardness test is carried out according to GB/T6739-1996 standards；RCA paper tape abrasion tests are adopted
Tested with 175g counterweights, set Rubbing number as 200-400 times, model is removed in friction end, with 10 times of amplification sem observation models
Coating condition.Test result contrast such as table 1 below：
It can be seen that by the test result of table 1：
Contrasted between embodiment 7 to 10 and comparative example 1 to 3 and comparative example 4, find organic silicon sol, titanate esters and
The addition of zirconates has obvious help to the coating hardness after tempering and wearability.
Film tempering is easily caused it can be seen from embodiment 7 to 10 when inorganic composition is more in formula to be cracked；
Illustrate that organic component and the appropriate ratio of inorganic composition play crucial effect to the wearability and film forming of tempering coating.
Embodiment 7,8 includes (coating liquid) of titanate esters and zirconates it can be seen from embodiment 7,8 and comparative example 1,2
Its wearability significantly increases after coating tempering.
Above content is only presently preferred embodiments of the present invention, for one of ordinary skill in the art, according to the present invention
Thinking, part can be changed in specific embodiment mode and its application, this specification content should not be construed as
Limitation of the present invention.
Claims (10)
1. one kind can tempering coating liquid, it is characterised in that by weight percentage, includes following component：
2. according to claim 1 can tempering coating liquid, it is characterised in that the glass resin is 5~50mpa of viscosity
S, light transmittance is higher than 90% organic-silicone prepolymer.
3. according to claim 1 can tempering coating liquid, it is characterised in that the hydroxy silicon oil is that hydroxy radical content is 2%
~4%, the dimethyl silicone polymer that the silanol that viscosity is 20~40mpas blocks.
4. according to claim 1 can tempering coating liquid, it is characterised in that the polyether modified silicon oil molecular weight is 2000
~6000.
5. according to claim 1 can tempering coating liquid, it is characterised in that the organic silicon sol SiO2Content be 20~
40%, average grain diameter is 50~100nm, and dicyandiamide solution is methanol, isopropanol, ethylene glycol, propylene glycol monomethyl ether, butanone, methyl
In isobutyl ketone, the one or more of the tert-butyl alcohol, ethyl acetate.
6. according to claim 1 can tempering coating liquid, it is characterised in that the titanate esters are positive isopropyl titanate, just
One or more in butyl titanate, metatitanic acid n-propyl, purity titanium tetraethoxide, triethanolamine titanate, Diethanolamine titanate.
7. according to claim 1 can tempering coating liquid, it is characterised in that the solvent be methanol, ethanol, ethylene glycol,
One in isopropanol, n-butanol, the tert-butyl alcohol, ethyl acetate, vinegar ester butyl ester, butanone, methylisobutylketone, the tert-butyl alcohol, ethyl acetate
Kind is a variety of.
8. one kind can the refined card glass of tempering, it is characterised in that including glassy layer (1), the plate face of the glassy layer side is provided with
Can the refined card glass coating (2) of tempering, it is described can the refined card glass coating (2) of tempering by weight, include claim 1~7 times
Meaning one described in can 1 part of tempering coating liquid, 0.1~0.5 part of the refined card coating of high temperature resistant.
9. according to claim 8 can the refined card glass of tempering, it is characterised in that the refined card coating of high temperature resistant is resistant to 700
High temperature more than DEG C.
10. according to claim 8-9 any one can the refined card glass of tempering, it is characterised in that it is described can the refined card of tempering
Glass coating (2) Kun is coated on glassy layer (1), it is described can the refined card glass coating (2) of tempering film thickness monitoring 1000~2500
Nanometer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711167087.1A CN107759103A (en) | 2017-11-21 | 2017-11-21 | Can the refined card glass of tempering and its processing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711167087.1A CN107759103A (en) | 2017-11-21 | 2017-11-21 | Can the refined card glass of tempering and its processing method |
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| Publication Number | Publication Date |
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| CN107759103A true CN107759103A (en) | 2018-03-06 |
Family
ID=61280268
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| CN201711167087.1A Withdrawn CN107759103A (en) | 2017-11-21 | 2017-11-21 | Can the refined card glass of tempering and its processing method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108751733A (en) * | 2018-05-31 | 2018-11-06 | 厦门大学 | A kind of hollow safety glass and preparation method thereof of silicon dioxide gel enhancing |
-
2017
- 2017-11-21 CN CN201711167087.1A patent/CN107759103A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108751733A (en) * | 2018-05-31 | 2018-11-06 | 厦门大学 | A kind of hollow safety glass and preparation method thereof of silicon dioxide gel enhancing |
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Application publication date: 20180306 |