CN107747243A - A kind of anti-static plastic rope and preparation method - Google Patents
A kind of anti-static plastic rope and preparation method Download PDFInfo
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- CN107747243A CN107747243A CN201710792296.9A CN201710792296A CN107747243A CN 107747243 A CN107747243 A CN 107747243A CN 201710792296 A CN201710792296 A CN 201710792296A CN 107747243 A CN107747243 A CN 107747243A
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-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/02—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2401/00—Aspects related to the problem to be solved or advantage
- D07B2401/20—Aspects related to the problem to be solved or advantage related to ropes or cables
- D07B2401/202—Environmental resistance
- D07B2401/203—Low temperature resistance
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2401/00—Aspects related to the problem to be solved or advantage
- D07B2401/20—Aspects related to the problem to be solved or advantage related to ropes or cables
- D07B2401/2055—Improving load capacity
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Ropes Or Cables (AREA)
Abstract
The present invention discloses a kind of anti-static plastic rope and preparation method, and each raw material weight percentage is：Modified polypropene 50% 65%, composite epoxy resin 11% 18%, string cellulose fiber 10% 16%, antistatic additive 6% 13%, magnesium stearate 0.5% 1.3%, calcium oxalate 0.2% 0.6%, plasticizer 3% 6%, foaming agent 1% 2.8%.The modified polypropene of synthesis, there is good low-temperature flexibility, be resistant to 25 DEG C of low-temperature impact, obtained plastic ties transparency is high, and shock resistance greatly improves；Antistatic additive is with the addition of in modified polypropene, will be mixed in antistatic additive in plastic ties so that plastic ties have long-term antistatic protection effect；Synthetic plastic rope is twisted thread using multiply, ensure that strength and toughness, the service life length of rope, and simple production process, efficiency high, cost are low.
Description
Technical field
The present invention relates to field of rope, and in particular to a kind of anti-static plastic rope and preparation method.
Background technology
In life and production, the generation of electrostatic is inevitable, if caused electrostatic is not released in time, just
May accumulate, the electric field that electrostatic charge is formed plays the role of electric field force to surrounding, can attract the dust of surrounding, fiber,
Pollutant etc., serious electrostatic can also produce spark discharge, cause the accidents such as fire, blast to produce.Such as：Contact combustible material
When, common chemical fibre cable can produce electrostatic spark because of friction, easily cause an explosion accident；In electronics industry, electrostatic can cause electronics
Component is damaged, Quality Down, or even is scrapped；Electrostatic can be produced in liquid petroleum product storage and transport process, the liquid with electrostatic
After oil product enters container (such as oil tank), raise liquid level electrostatic potential, when now carrying out sampling the operations such as thermometric inspection water, meeting
Static discharge is induced, so as to cause fire incident.Therefore in inflammable and explosive and colliery petroleum industry, using with electrostatic-proof function
Fibrecord plastic ties be to ensure personal safety the important means with product quality.
Scribble antistatic coating outside some ropes, but this antistatic coating be exposed to the sun, rain erosion and use
Wearing causes coating failure, and antistatic external coating service life is short.
A kind of thermoplastic resin of prepared by polypropylene is by propylene polymerization, is the main component of synthetic plastic rope, poly- third
The crystallinity of alkene is high, compound with regular structure, thus has excellent mechanical property, with good dielectric properties and high-frequency insulation and
Do not influenceed by humidity, the organic solvent such as common acid, alkali does not almost work to it, but becomes fragile during low temperature, not wear-resisting, easily old
Change.
The content of the invention
It is an object of the invention to provide a kind of anti-static plastic rope and preparation method, will be mixed in antistatic additive modified poly-
In propylene so that plastic ties have long-term antistatic protection effect, simple production process, efficiency high.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of anti-static plastic rope, each raw material weight percentage are：Modified polypropene 50%-65%, composite epoxy resin
11%-18%, string cellulose fiber 10%-16%, antistatic additive 6%-13%, magnesium stearate 0.5%-1.3%, calcium oxalate
0.2%-0.6%, plasticizer 3%-6%, foaming agent 1%-2.8%.
Further, described modified polypropene is to be copolymerized with propylene monomer, cyclopentene monomer in the presence of catalyst
Arrive.
Further, described propylene monomer, the weight ratio of cyclopentene monomer are 7:2.5-3.3.
Further, described catalyst is levulinic ketone group ruthenous chloride, is a kind of improved Ziegler-Natta catalysis
Agent, the addition of levulinic ketone group ruthenous chloride are the 0.02%-0.05% of the total addition of each raw material of modified polypropene.
Further, described composite epoxy resin is bisphenol epoxy, phosphine epoxide epoxy resin and nano titanium oxide
In ball mill, stirring, after insulation, add 2,5,6- trimethyl benzimidazoles and continue to stir, complex loop oxygen tree is produced after filtering
Fat；Bisphenol epoxy, phosphine epoxide epoxy resin, nano titanium oxide, the mass ratio of 2,5,6- trimethyl benzimidazoles are 3:
3:2:0.3-0.6。
Further, described antistatic additive is ethyoxyl lauryl amine, ethyoxyl Stearyl Amine, ethylene glycol monostearate
One or more in ester, pentaerythritol stearate.
Further, described plasticizer is one kind in epoxy aliphatic acid methyl ester, terephthalic acids diethylester；Described foaming
Agent is lauryl sodium sulfate, the mixture of sodium sulfate of polyethenoxy ether of fatty alcohol, lauryl sodium sulfate, fatty alcohol polyoxy second
The weight ratio of alkene ether sodium sulfate is 1.5:2-3.
A kind of preparation method of anti-static plastic rope, it is characterised in that：Specifically include following steps：
(1) each raw material prepared by weight proportion is added to multiple screw extruder, by preheating, melting, plastifying, counting
Melting extrusion plastic optical fibre after amount, spinneret process；
(2) plastic optical fibre of melting extrusion is put into tank and cooled down, obtain plastic monofilament fiber；
(3) the plastic monofilament fiber after cooling is put into drafting machine and carries out drawing-off, be introduced into forming press-roller shape afterwards；
(4) by plastic monofilament fiber and be one plastic strip, take plastic strip to be twisted by twisting machine afterwards, twist with the fingers
Line machine driving belt is elastic consistent, and plastic strip is knitted in advance on full-automatic pre- loom after being twisted by twisting machine, twist direction, is moulded
Material rope, anti-static plastic rope, winding finally is made by steam forming machine thermal finalization in the plastic ties after twisting.
Further, the preheating temperature described in step (1) is 185 DEG C~200 DEG C, and melt temperature is 230 DEG C -265 DEG C；Step
(2) chilling temperature described in is 18 DEG C~35 DEG C；Drawing temperature described in step (3) is 90 DEG C~120 DEG C, drafting multiple 15-
22 times.
Further, described in step (4) and the plastic monofilament number of fiber that is plastic strip be 5-15 roots, the number of share of stock of twisting
For 5-12 stocks；Described twist direction mode is two parts of the identical number of share of stock plastic strip in area, and portion is S twist directions, and another is Z twist directions；Institute
The steam shaping temperature stated is 105 DEG C -132 DEG C, pressure 0.09-0.15Mpa.
Beneficial effects of the present invention：
Compared with prior art, the modified polypropene that the present invention synthesizes, has good low-temperature flexibility, is resistant to -25 DEG C
Low-temperature impact, obtained plastic ties transparency is high, and shock resistance greatly improves；It with the addition of in modified polypropene antistatic
Agent, it will be mixed in antistatic additive in plastic ties so that plastic ties have long-term antistatic protection effect；Synthetic plastic rope uses
Multiply is twisted thread, and ensure that strength and toughness, the service life length of rope, and simple production process, efficiency high, cost are low.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example only part of the embodiment of the present invention, rather than whole embodiments.It is common based on the embodiment in the present invention, this area
All other embodiment that technical staff is obtained under the premise of creative work is not made, belong to the model that the present invention protects
Enclose.
Embodiment 1
1st, the preparation of raw material
(1) preparation of modified polypropene
70kg propylene monomers, 25kg cyclopentene monomer and 19kg levulinic ketone group ruthenous chlorides is weighed to be put into reactor,
120 DEG C of copolyreaction 4h, that is, obtain modified polypropene；
(2) preparation of composite epoxy resin
30kg bisphenol epoxies, 30kg phosphine epoxides epoxy resin, 20kg nano titanium oxides is weighed to add in ball mill,
Using ethanol as medium, 2h is stirred at 85 DEG C, is incubated, is subsequently added into the trimethyl benzimidazoles of 0.6kg 2,5,6- and continues to stir
0.5h, composite epoxy resin is produced after filtering.
2nd, the preparation of anti-static plastic rope
(1) by modified polypropene 50kg, composite epoxy resin 18kg, string cellulose fiber 13.3kg, ethyoxyl 12
Alkylamine 6kg, magnesium stearate 1.3kg, calcium oxalate 0.6kg, epoxy aliphatic acid methyl ester 3kg, lauryl sodium sulfate 1.2kg, fat
Fat alcohol polyethenoxy ether sodium sulfate 2.4kg is added to multiple screw extruder, and the preheating temperature of multiple screw extruder is 185 DEG C, melts temperature
Spend for 230 DEG C, by preheating, melting, plastifying, measuring, melting extrusion plastic optical fibre after spinneret process；
(2) plastic optical fibre of melting extrusion is put into tank and cooled down, chilling temperature is 18 DEG C, obtains plastic monofilament fibre
Dimension；
(3) the plastic monofilament fiber after cooling is put into drafting machine and carries out drawing-off, drawing temperature is 90 DEG C, is drafting multiple
15 times, it is introduced into forming press-roller shapes afterwards；
(4) by 5 plastic monofilament fibers and be one plastic strip, 12 strands of plastic strips are taken to be carried out by twisting machine afterwards
Twisting, twisting machine driving belt is elastic consistent, and plastic strip is knitted in advance on full-automatic pre- loom after being twisted by twisting machine, 6 strands
For S twist directions, 6 strands are Z twist directions, obtain plastic ties, are finally 105 DEG C by steam shaping temperature by the plastic ties after twisting, pressure
Power is 0.09Mpa steam forming machine thermal finalization, and anti-static plastic rope, winding is made.
Embodiment 2
1st, the preparation of raw material
(1) preparation of modified polypropene
70kg propylene monomers, 33kg cyclopentene monomer and 50kg levulinic ketone group ruthenous chlorides is weighed to be put into reactor,
140 DEG C of copolyreaction 4h, that is, obtain modified polypropene；
(2) preparation of composite epoxy resin
30kg bisphenol epoxies, 30kg phosphine epoxides epoxy resin, 20kg nano titanium oxides is weighed to add in ball mill,
Using ethanol as medium, 2h is stirred at 122 DEG C, is incubated, is subsequently added into the trimethyl benzimidazoles of 0.3kg 2,5,6- and continues to stir
0.5h, composite epoxy resin is produced after filtering.
2nd, the preparation of anti-static plastic rope
(1) by modified polypropene 65kg, composite epoxy resin 11kg, string cellulose fiber 10kg, ethyoxyl stearic acid
Amine 3.3kg, ethylene glycol monostearate 5kg, magnesium stearate 0.5kg, calcium oxalate 0.2kg, terephthalic acids diethylester 4kg, 12
Sodium alkyl sulfate 0.3kg, sodium sulfate of polyethenoxy ether of fatty alcohol 0.7kg are added to multiple screw extruder, the preheating of multiple screw extruder
Temperature is 200 DEG C, and melt temperature is 265 DEG C, and by preheating, melting, plastifying, measuring, after spinneret process, melting extrusion plastics are fine
Dimension；
(2) plastic optical fibre of melting extrusion is put into tank and cooled down, chilling temperature is 35 DEG C, obtains plastic monofilament fibre
Dimension；
(3) the plastic monofilament fiber after cooling is put into drafting machine and carries out drawing-off, drawing temperature is 120 DEG C, is drawing-off times
22 times of number, is introduced into forming press-roller shapes afterwards；
(4) by 15 plastic monofilament fibers and be one plastic strip, 6 strands of plastic strips are taken to be carried out by twisting machine afterwards
Twisting, twisting machine driving belt is elastic consistent, and plastic strip is knitted in advance on full-automatic pre- loom after being twisted by twisting machine, 3 strands
For S twist directions, 3 strands are Z twist directions, obtain plastic ties, are finally 132 DEG C by steam shaping temperature by the plastic ties after twisting, pressure
Power is 0.15Mpa steam forming machine thermal finalization, and anti-static plastic rope, winding is made.
Embodiment 3
1st, the preparation of raw material
(1) preparation of modified polypropene
74kg propylene monomers, 31kg cyclopentene monomer and 23kg levulinic ketone group ruthenous chlorides is weighed to be put into reactor,
140 DEG C of copolyreaction 4h, that is, obtain modified polypropene；
(2) preparation of composite epoxy resin
30kg bisphenol epoxies, 30kg phosphine epoxides epoxy resin, 20kg nano titanium oxides is weighed to add in ball mill,
Using ethanol as medium, 2h is stirred at 105 DEG C, is incubated, is subsequently added into the trimethyl benzimidazoles of 0.4kg 2,5,6- and continues to stir
0.5h, composite epoxy resin is produced after filtering.
2nd, the preparation of anti-static plastic rope
(1) by modified polypropene 53kg, composite epoxy resin 12kg, string cellulose fiber 15.3kg, ethyoxyl 12
Alkylamine 2.2kg, ethyoxyl Stearyl Amine 3.5kg, ethylene glycol monostearate 1.5kg, pentaerythritol stearate 4.5kg,
Magnesium stearate 0.6kg, calcium oxalate 0.3kg, terephthalic acids diethylester 6kg, lauryl sodium sulfate 0.45kg, fatty alcohol polyoxy second
Alkene ether sodium sulfate 0.75kg is added to multiple screw extruder, and the preheating temperature of multiple screw extruder is 196 DEG C, and melt temperature is 258 DEG C,
By preheating, melting, plastifying, measuring, melting extrusion plastic optical fibre after spinneret process；
(2) plastic optical fibre of melting extrusion is put into tank and cooled down, chilling temperature is 25 DEG C, obtains plastic monofilament fibre
Dimension；
(3) the plastic monofilament fiber after cooling is put into drafting machine and carries out drawing-off, drawing temperature is 112 DEG C, is drawing-off times
21 times of number, is introduced into forming press-roller shapes afterwards；
(4) by 11 plastic monofilament fibers and be one plastic strip, 8 strands of plastic strips are taken to be carried out by twisting machine afterwards
Twisting, twisting machine driving belt is elastic consistent, and plastic strip is knitted in advance on full-automatic pre- loom after being twisted by twisting machine, 4 strands
For S twist directions, 4 strands are Z twist directions, obtain plastic ties, are finally 122 DEG C by steam shaping temperature by the plastic ties after twisting, pressure
Power is 0.13Mpa steam forming machine thermal finalization, and anti-static plastic rope, winding is made.
Above content is only to design example and explanation of the invention, affiliated those skilled in the art
Various modifications or supplement are made to described specific embodiment or is substituted using similar mode, without departing from invention
Design or surmount scope defined in the claims, protection scope of the present invention all should be belonged to.
Claims (10)
- A kind of 1. anti-static plastic rope, it is characterised in that：Each raw material weight percentage is：It is modified polypropene 50%-65%, compound Epoxy resin 11%-18%, string cellulose fiber 10%-16%, antistatic additive 6%-13%, magnesium stearate 0.5%- 1.3%th, calcium oxalate 0.2%-0.6%, plasticizer 3%-6%, foaming agent 1%-2.8%.
- A kind of 2. anti-static plastic rope according to claim 1, it is characterised in that：Described modified polypropene is with propylene Monomer, cyclopentene monomer are copolymerized in the presence of catalyst and obtained.
- A kind of 3. anti-static plastic rope according to claim 2, it is characterised in that：Described propylene monomer, cyclopentene list The weight ratio of body is 7:2.5-3.3.
- A kind of 4. anti-static plastic rope according to claim 2, it is characterised in that：Described catalyst is levulinic ketone group Ruthenous chloride, it is a kind of improved Ziegler-Natta catalyst, the addition of levulinic ketone group ruthenous chloride is modified poly- third The 0.02%-0.05% of the total addition of each raw material of alkene.
- A kind of 5. anti-static plastic rope according to claim 1, it is characterised in that：Described composite epoxy resin is bis-phenol Epoxy resin, phosphine epoxide epoxy resin and nano titanium oxide are in ball mill, stirring, after insulation, add 2,5,6- trimethyls Benzimidazole continues to stir, and composite epoxy resin is produced after filtering；Bisphenol epoxy, phosphine epoxide epoxy resin, nano-silica Change titanium, the mass ratio of 2,5,6- trimethyl benzimidazoles is 3:3:2:0.3-0.6.
- A kind of 6. anti-static plastic rope according to claim 1, it is characterised in that：Described antistatic additive is ethyoxyl ten One or more in dialkylamine, ethyoxyl Stearyl Amine, ethylene glycol monostearate, pentaerythritol stearate.
- A kind of 7. anti-static plastic rope according to claim 1, it is characterised in that：Described plasticizer is epoxyfatty acid One kind in methyl esters, terephthalic acids diethylester；Described foaming agent is lauryl sodium sulfate, AEO sulfuric acid The mixture of sodium, lauryl sodium sulfate, the weight of sodium sulfate of polyethenoxy ether of fatty alcohol ratio are 1.5:2-3.
- A kind of 8. preparation method of anti-static plastic rope, it is characterised in that：Specifically include following steps：(1) each raw material prepared by weight proportion is added to multiple screw extruder, by preheating, melting, plastifying, measuring, spraying Melting extrusion plastic optical fibre after wire process；(2) plastic optical fibre of melting extrusion is put into tank and cooled down, obtain plastic monofilament fiber；(3) the plastic monofilament fiber after cooling is put into drafting machine and carries out drawing-off, be introduced into forming press-roller shape afterwards；(4) by plastic monofilament fiber and be one plastic strip, plastic strip is taken to be twisted by twisting machine afterwards, twisting machine Driving belt is elastic consistent, and plastic strip is knitted in advance on full-automatic pre- loom after being twisted by twisting machine, twist direction, obtains plastics Rope, anti-static plastic rope, winding finally is made by steam forming machine thermal finalization in the plastic ties after twisting.
- A kind of 9. preparation method of anti-static plastic rope according to claim 8, it is characterised in that：Described in step (1) Preheating temperature is 185 DEG C~200 DEG C, and melt temperature is 230 DEG C -265 DEG C；Chilling temperature described in step (2) is 18 DEG C~35 ℃；Drawing temperature described in step (3) is 90 DEG C~120 DEG C, 15-22 times of drafting multiple.
- A kind of 10. preparation method of anti-static plastic rope according to claim 8, it is characterised in that：Described in step (4) And be that the plastic monofilament number of fiber of plastic strip is 5-15 roots, the number of share of stock of twisting is 5-12 stocks；Described twist direction mode is area Identical two parts of number of share of stock plastic strip, portion is S twist directions, and another is Z twist directions；Described steam shaping temperature is 105 DEG C -132 DEG C, pressure 0.09-0.15Mpa.
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| CN201710792296.9A CN107747243A (en) | 2017-09-05 | 2017-09-05 | A kind of anti-static plastic rope and preparation method |
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| CN201710792296.9A CN107747243A (en) | 2017-09-05 | 2017-09-05 | A kind of anti-static plastic rope and preparation method |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108707330A (en) * | 2018-04-17 | 2018-10-26 | 句容沣润塑料制品有限公司 | A kind of anti-static plastic and preparation method thereof |
| CN108841192A (en) * | 2018-04-17 | 2018-11-20 | 句容沣润塑料制品有限公司 | A kind of anti-static plastic filler and preparation method thereof |
| CN111021112A (en) * | 2019-12-25 | 2020-04-17 | 界首市宏利塑料有限公司 | Reusable straw bundling rope convenient to bind and loosen |
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| JPH0748743A (en) * | 1993-08-05 | 1995-02-21 | Toyobo Co Ltd | Conjugate fiber material |
| CN101463165A (en) * | 2009-01-09 | 2009-06-24 | 咸阳石油钢管钢绳有限责任公司 | Special material for compact wire rope core and preparation of rope core |
| CN101994266A (en) * | 2009-08-10 | 2011-03-30 | 中国水产科学研究院东海水产研究所 | Method for processing medium-size mixed rope for fishing with warning function |
| CN102432948A (en) * | 2011-11-28 | 2012-05-02 | 成都盛尔嘉科技有限公司 | Antistatic resin |
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2017
- 2017-09-05 CN CN201710792296.9A patent/CN107747243A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0748743A (en) * | 1993-08-05 | 1995-02-21 | Toyobo Co Ltd | Conjugate fiber material |
| CN101463165A (en) * | 2009-01-09 | 2009-06-24 | 咸阳石油钢管钢绳有限责任公司 | Special material for compact wire rope core and preparation of rope core |
| CN101994266A (en) * | 2009-08-10 | 2011-03-30 | 中国水产科学研究院东海水产研究所 | Method for processing medium-size mixed rope for fishing with warning function |
| CN102432948A (en) * | 2011-11-28 | 2012-05-02 | 成都盛尔嘉科技有限公司 | Antistatic resin |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108707330A (en) * | 2018-04-17 | 2018-10-26 | 句容沣润塑料制品有限公司 | A kind of anti-static plastic and preparation method thereof |
| CN108841192A (en) * | 2018-04-17 | 2018-11-20 | 句容沣润塑料制品有限公司 | A kind of anti-static plastic filler and preparation method thereof |
| CN111021112A (en) * | 2019-12-25 | 2020-04-17 | 界首市宏利塑料有限公司 | Reusable straw bundling rope convenient to bind and loosen |
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