CN107747240A - A kind of antistatic dyestuff of Anti-fade for the printing and dyeing of pig hair - Google Patents
A kind of antistatic dyestuff of Anti-fade for the printing and dyeing of pig hair Download PDFInfo
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- CN107747240A CN107747240A CN201710976853.2A CN201710976853A CN107747240A CN 107747240 A CN107747240 A CN 107747240A CN 201710976853 A CN201710976853 A CN 201710976853A CN 107747240 A CN107747240 A CN 107747240A
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
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- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
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- D06P1/655—Compounds containing ammonium groups
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Abstract
The invention discloses a kind of antistatic dyestuff of Anti-fade for the printing and dyeing of pig hair, its raw material includes perfluoroalkyl acrylate, fluorinated acrylate emulsion, AEO, N, N dimethylethanolamines, melamine phosphate, sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, Cocoamidopropyl betaine, vinyl pyrrolidone polymer, triethanolamine oleate, dimethyl silicone polymer, methylcellulose, nano zine oxide, nano titanium oxide, diatomite, sodium carbonate, isopropanol, propane diols, Anti-fade modified additive and antistatic modified filler.The dyestuff of the present invention is used for the printing and dyeing of pig hair, has excellent Anti-fade antistatic property.
Description
Technical field
The present invention relates to the technical field of dyestuff, more particularly to a kind of antistatic dyestuff of Anti-fade for the printing and dyeing of pig hair.
Background technology
Pig hair, refers to be attached to the fur with pig, and pig hair is mainly used for brushing for making, can also be used to extract ammonia
Base acid, also there is pig writing brush with soft material.Pig hair needs progress pig hair to be handled when in use, the dye that the processing of pig hair uses in the prior art
Material, its Anti-fade and antistatic property can not meet the needs of in actual production process, be printed so needing out a kind of pig hair that is used for badly
The antistatic dyestuff of Anti-fade of dye solves the problems of the prior art.
The content of the invention
To solve technical problem present in background technology, it is quiet that the present invention proposes that a kind of Anti-fade for the printing and dyeing of pig hair resists
Electric dyestuff, there is excellent Anti-fade antistatic property.
A kind of antistatic dyestuff of Anti-fade for the printing and dyeing of pig hair proposed by the present invention, its raw material include by weight：Entirely
Fluoroalkyl 40-50 parts, fluorinated acrylate emulsion 15-25 parts, AEO 1-4 parts, N, N- diformazans
Ethylethanolamine 6-12 parts, melamine phosphate 4-8 parts, sodium sulfate of polyethenoxy ether of fatty alcohol 2-5 parts, isomery alcohol polyoxyethylene
Ether 3-6 parts, Cocoamidopropyl betaine 1-3 parts, vinyl pyrrolidone polymer 1-4 parts, triethanolamine oleate 2-5 parts,
Dimethyl silicone polymer 2-4 parts, methylcellulose 3-6 parts, nano zine oxide 2-6 parts, nano titanium oxide 2-5 parts, diatomite
1-6 parts, sodium carbonate 3-6 parts, isopropanol 1-3 parts, propane diols 3-5 parts, Anti-fade modified additive 10-20 parts, antistatic modified fill out
Expect 5-25 parts.
Preferably, the raw material of Anti-fade modified additive includes by weight：Paraffin 5-15 parts, dewatering nano silica are molten
Liquid 4-8 parts, octamethylcy-clotetrasiloxane 3-9 parts, silane resin acceptor kh-550 2-8 parts, emulsifying agent AEO-03 1-5 parts, emulsification
Agent TX-10 4-8 parts, odium stearate 2-5 parts, DTAC 3-6 parts, water 5-15 parts, oxidized wax 5-15 parts,
Oleic acid 4-9 parts, hexamethylene diamine 3-9 parts.
Preferably, Anti-fade modified additive is prepared by following technique：Paraffin is heated in water-bath makes its thawing, so
Dewatering nano silicon dioxde solution is added afterwards, is disperseed, is cooled to room temperature and obtains material a；Octamethylcy-clotetrasiloxane, silane is even
Connection agent KH-550, emulsifying agent AEO-03 and emulsifying agent TX-10, which are well mixed, obtains material b；By odium stearate, dodecyl front three
Ammonium chloride and water are well mixed, and heating, the process of heating does not stop to stir, and are then instilled in material a, are heated up, and insulation, are cooled to
Room temperature obtains material c；Oxidized wax and oleic acid are well mixed, heated up under the protection of nitrogen, stirs after point fusing, then adds
Hexamethylene diamine and material c, heat up, insulation, after the substantially all discharge of water, terminating reaction, cooling, be cooled to room temperature and obtain Anti-fade
Modified additive.
Preferably, Anti-fade modified additive is prepared by following technique：Paraffin is heated into 80-90 DEG C in water-bath makes
It melts, and then adds dewatering nano silicon dioxde solution, disperses 20-40min in 9000-12000r/min, be cooled to room temperature
Obtain material a；Octamethylcy-clotetrasiloxane, silane resin acceptor kh-550, emulsifying agent AEO-03 and emulsifying agent TX-10 are mixed equal
It is even to obtain material b；Odium stearate, DTAC and water are well mixed, are warming up to 70-80 DEG C, heating
Process does not stop to stir, and then instills in material a, is warming up to 80-90 DEG C, is incubated 3-5h, is cooled to room temperature and obtains material c；By oxygen
Change wax and oleic acid is well mixed, 90-110 DEG C is warming up under the protection of nitrogen, stir 15-25min after point fusing, then add
Hexamethylene diamine and material c, 140-160 DEG C is warming up to, is incubated 3-5h, rise temperature is incubated 2-4h to 180-200 DEG C, treated water base
After the discharge of this whole, terminating reaction, 150-170 DEG C is cooled to, is cooled to room temperature and obtains Anti-fade modified additive.
Preferably, the raw material of antistatic modified filler includes by weight：CNT 15-25 parts, concentrated nitric acid 2-5 parts,
Phenyltriethoxysilane 1-5 parts, diethyl triethoxysilane 3-6 parts, tetraethoxysilane 4-8 parts, n-butanol 3-9
Part, dimethylbenzene 2-5 parts, epoxy resin E-20 1-5 parts, butyl titanate 4-8 parts, styrene 3-9 parts, cumyl peroxide 2-5
Part, chloroform 1-5 parts, concentrated sulfuric acid 4-9 parts.
Preferably, antistatic modified filler is prepared by following technique：CNT and concentrated nitric acid are well mixed, so
After flow back, then filtered, washed to neutrality with filter membrane, be then placed in baking oven dry, be cooled to room temperature and obtain material A；By one
Phenyl triethoxysilane, diethyl triethoxysilane and tetraethoxysilane are well mixed, and are heated up, and insulation, are then dehydrated,
It is cooled to room temperature and obtains material B；N-butanol, dimethylbenzene and epoxy resin E-20 are well mixed and obtain material b, then by material
A and material B are well mixed, and are subsequently added into butyl titanate and are well mixed, and are heated up, and insulation, are cooled to room temperature and are obtained material C；In nitrogen
Under gas atmosphere, material C, styrene and cumyl peroxide are well mixed, heated up, insulation, is then cooled to room temperature, is extracted
Drying is filtered afterwards, chloroform is subsequently added into and is well mixed, is stirred, and is added the concentrated sulfuric acid and is well mixed, heat up, be incubated, dilute, filters,
Drying, is cooled to grinding at room temperature and obtains antistatic modified filler into powder.
Preferably, antistatic modified filler is prepared by following technique：CNT and concentrated nitric acid are well mixed, so
After be placed in 55-65 DEG C backflow 1-3h, then with aperture be 0.1-0.3 μm miillpore filter filter, wash to neutrality, be then placed in
10-14h is dried in 1100-1130 DEG C of baking oven, room temperature is cooled to and obtains material A；By phenyltriethoxysilane, diethyl three
Ethoxysilane and tetraethoxysilane are well mixed, and are warming up to 85-95 DEG C, are incubated 20-40min, then de- in 100-120 DEG C
Water, it is cooled to room temperature and obtains material B；N-butanol, dimethylbenzene and epoxy resin E-20 are well mixed and obtain material b, then will
Material A and material B are well mixed, and are subsequently added into butyl titanate and are well mixed, and are warming up to 170-180 DEG C, are incubated 1-3h, are cooled to
Room temperature obtains material C；Under nitrogen atmosphere, material C, styrene and cumyl peroxide are well mixed, are warming up to 130-
150 DEG C, 5-7h is incubated, is then cooled to room temperature, drying is filtered after extracting 20-26h, is subsequently added into chloroform and is well mixed, in
350-550r/min rotating speeds stir 10-14h, add the concentrated sulfuric acid and are well mixed, are warming up to 35-45 DEG C, are incubated 8-10h, dilution, take out
Filter, drying, is cooled to grinding at room temperature and obtains antistatic modified filler into powder.
A kind of antistatic dyestuff of Anti-fade for the printing and dyeing of pig hair of the present invention, its raw material include perfluoroalkyl acrylic
Ester, fluorinated acrylate emulsion, AEO, N, N- dimethylethanolamines, melamine phosphate, poly alkyl alcohol
Oxygen ethene ether sodium sulfate, isomeric alcohol polyethenoxy ether, Cocoamidopropyl betaine, vinyl pyrrolidone polymer, oleic acid
Triethanolamine, dimethyl silicone polymer, methylcellulose, nano zine oxide, nano titanium oxide, diatomite, sodium carbonate, isopropyl
Alcohol, propane diols, Anti-fade modified additive and antistatic modified filler, it is with perfluoroalkyl acrylate and fluorinated acrylate breast
Liquid is as major ingredient, with AEO, N, N- dimethylethanolamines, melamine phosphate, aliphatic alcohol polyethenoxy
Ether sodium sulfate, isomeric alcohol polyethenoxy ether, Cocoamidopropyl betaine, vinyl pyrrolidone polymer, oleic acid triethanolamine
Amine and dimethyl silicone polymer strengthen as major ingredient expects, with methylcellulose, nano zine oxide, nano titanium oxide, diatomite
It is filler with sodium carbonate, using isopropanol, propane diols, Anti-fade modified additive and antistatic modified filler as strengthening helping agent, passes through
Major ingredient, major ingredient enhancing material, filler and strengthening helping agent coordinate, the obtained dyestuff for being used for the printing and dyeing of pig hair have excellent Anti-fade and
Antistatic auxiliary.Wherein, Anti-fade modified additive is prepared by following technique：Paraffin is heated in water-bath makes its thawing,
Then dewatering nano silicon dioxde solution is added, is disperseed, is cooled to room temperature and obtains material a；By octamethylcy-clotetrasiloxane, silane
Coupling agent KH-550, emulsifying agent AEO-03 and emulsifying agent TX-10, which are well mixed, obtains material b；By odium stearate, dodecyl three
Ammonio methacrylate and water are well mixed, and heating, the process of heating does not stop to stir, and are then instilled in material a, are heated up, and are incubated, cooling
Material c is obtained to room temperature；Oxidized wax and oleic acid are well mixed, heated up under the protection of nitrogen, is stirred after point fusing, Ran Houjia
Enter hexamethylene diamine and material c, heat up, insulation, after the substantially all discharge of water, terminating reaction, cooling, be cooled to room temperature and obtain anticreep
Color modified additive, apply in the pig hair printing dye of the present invention, effectively increase the Anti-fade performance of dyestuff.Wherein, resist quiet
Electric modified filler is prepared by following technique：CNT and concentrated nitric acid are well mixed, are then refluxed for, is then taken out with filter membrane
Filter, is washed to neutrality, is then placed in baking oven and is dried, is cooled to room temperature and obtains material A；By phenyltriethoxysilane, two
Ethyl triethoxysilane and tetraethoxysilane are well mixed, and are heated up, and insulation, are then dehydrated, are cooled to room temperature and obtain material
B；N-butanol, dimethylbenzene and epoxy resin E-20 are well mixed and obtain material b, is then well mixed material A and material B,
It is subsequently added into butyl titanate to be well mixed, heats up, insulation, is cooled to room temperature and obtains material C；Under nitrogen atmosphere, by material C,
Styrene and cumyl peroxide are well mixed, and are heated up, and insulation, are then cooled to room temperature, and drying is filtered after extraction, are then added
Enter chloroform to be well mixed, stir, add the concentrated sulfuric acid and be well mixed, heat up, be incubated, dilute, filter, drying, be cooled to room temperature and grind
Clay into power to obtain antistatic modified filler, apply to the pig hair printing dye of the present invention, effectively increase dyestuff of the present invention
Antistatic property.The dyestuff of the present invention is used for the printing and dyeing of pig hair, has excellent Anti-fade antistatic property.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
Embodiment 1
A kind of antistatic dyestuff of Anti-fade for the printing and dyeing of pig hair proposed by the present invention, its raw material include by weight：Entirely
45 parts of fluoroalkyl, 20 parts of fluorinated acrylate emulsion, 2.5 parts of AEO, N, N- dimethyl ethanols
9 parts of amine, 6 parts of melamine phosphate, 3.5 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 4.5 parts of isomeric alcohol polyethenoxy ether, coconut palm
2 parts of oleamide CAB, 2.5 parts of vinyl pyrrolidone polymer, 3.5 parts of triethanolamine oleate, polydimethylsiloxanes
3 parts of alkane, 4.5 parts of methylcellulose, 4 parts of nano zine oxide, 3.5 parts of nano titanium oxide, 3.5 parts of diatomite, sodium carbonate 4.5
Part, 2 parts of isopropanol, 4 parts of propane diols, 15 parts of Anti-fade modified additive, 15 parts of antistatic modified filler.
Anti-fade modified additive is prepared by following technique：10 parts of paraffin are heated to 85 DEG C in water-bath by weight
Make its thawing, then add 6 parts of dewatering nano silicon dioxde solutions, disperse 30min in 10500r/min, be cooled to room temperature and obtain
Material a；By 6 parts of octamethylcy-clotetrasiloxanes, 5 parts of silane resin acceptor kh-550s, 3 parts of emulsifying agent AEO-03 and 6 parts of emulsifying agent TX-
10 well mixed obtain material b；3.5 parts of odium stearate, 4.5 parts of DTACs and 10 parts of water are mixed equal
It is even, 75 DEG C are warming up to, the process of heating does not stop to stir, and then instills in material a, is warming up to 85 DEG C, is incubated 4h, is cooled to room temperature
Obtain material c；10 parts of oxidized wax and 6.5 parts of oleic acid are well mixed, 100 DEG C are warming up under the protection of nitrogen, after point fusing
20min is stirred, then adds 6 parts of hexamethylene diamines and material c, is warming up to 150 DEG C, is incubated 4h, rise temperature is incubated to 190 DEG C
3h, after the substantially all discharge of water, terminating reaction, 160 DEG C are cooled to, are cooled to room temperature and obtain Anti-fade modified additive.
Antistatic modified filler is prepared by following technique：By weight by 20 parts of CNTs and 3.5 parts of concentrated nitric acids
It is well mixed, 30 DEG C of backflow 2h are subsequently placed in, is then filtered with the miillpore filter that aperture is 0.2 μm, is washed to neutrality, then put
12h is dried in 1120 DEG C of baking ovens, room temperature is cooled to and obtains material A；By 3 parts of phenyltriethoxysilanes, 4.5 parts of diethyl
Triethoxysilane and 6 parts of tetraethoxysilanes are well mixed, and are warming up to 90 DEG C, are incubated 30min, cold then in 110 DEG C of dehydrations
But material B is obtained to room temperature；6 parts of n-butanols, 3.5 parts of dimethylbenzene and 3 parts of epoxy resin E-20 are well mixed and obtain material b,
Then material A and material B are well mixed, are subsequently added into 6 parts of butyl titanates and are well mixed, be warming up to 175 DEG C, be incubated 2h, it is cold
But material C is obtained to room temperature；Under nitrogen atmosphere, material C, 6 parts of styrene and 3.5 parts of cumyl peroxides are mixed equal
It is even, 140 DEG C are warming up to, is incubated 6h, is then cooled to room temperature, drying is filtered after extracting 23h, it is equal to be subsequently added into 3 parts of chloroform mixing
It is even, 12h is stirred in 450r/min rotating speeds, 6.5 parts of concentrated sulfuric acids is added and is well mixed, be warming up to 40 DEG C, be incubated 9h, dilute, filter,
Drying, is cooled to grinding at room temperature and obtains antistatic modified filler into powder.
Embodiment 2
A kind of antistatic dyestuff of Anti-fade for the printing and dyeing of pig hair proposed by the present invention, its raw material include by weight：Entirely
40 parts of fluoroalkyl, 25 parts of fluorinated acrylate emulsion, 1 part of AEO, N, N- dimethylethanolamines
12 parts, 4 parts of melamine phosphate, 5 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 3 parts of isomeric alcohol polyethenoxy ether, coconut oleoyl amine
3 parts of CAB, 1 part of vinyl pyrrolidone polymer, 5 parts of triethanolamine oleate, 2 parts of dimethyl silicone polymer, methyl
6 parts of cellulose, 2 parts of nano zine oxide, 5 parts of nano titanium oxide, 1 part of diatomite, 6 parts of sodium carbonate, 1 part of isopropanol, propane diols 5
Part, 10 parts of Anti-fade modified additive, 25 parts of antistatic modified filler.
Anti-fade modified additive is prepared by following technique：5 parts of paraffin are heated to 90 DEG C in water-bath by weight
Make its thawing, then add 4 parts of dewatering nano silicon dioxde solutions, disperse 20min in 12000r/min, be cooled to room temperature and obtain
Material a；By 9 parts of octamethylcy-clotetrasiloxanes, 2 parts of silane resin acceptor kh-550s, 5 parts of emulsifying agent AEO-03 and 4 parts of emulsifying agent TX-
10 well mixed obtain material b；5 parts of odium stearate, 3 parts of DTACs and 15 parts of water are well mixed, risen
Temperature to 70 DEG C, do not stop to stir by the process of heating, then instills in material a, is warming up to 90 DEG C, is incubated 3h, is cooled to room temperature and obtains
Material c；15 parts of oxidized wax and 4 parts of oleic acid are well mixed, 110 DEG C are warming up under the protection of nitrogen, are stirred after point fusing
15min, 9 parts of hexamethylene diamines and material c are then added, be warming up to 140 DEG C, be incubated 5h, rise temperature is incubated 4h to 180 DEG C, treated
After the substantially all discharge of water, terminating reaction, 150 DEG C are cooled to, are cooled to room temperature and obtain Anti-fade modified additive.
Antistatic modified filler is prepared by following technique：15 parts of CNTs and 5 parts of concentrated nitric acids are mixed by weight
Close uniformly, be subsequently placed in 55 DEG C of backflow 3h, then filtered with the miillpore filter that aperture is 0.1 μm, wash to neutrality, be then placed in
10h is dried in 1130 DEG C of baking ovens, room temperature is cooled to and obtains material A；By 5 parts of phenyltriethoxysilanes, 3 parts of second of diethyl three
TMOS and 8 parts of tetraethoxysilanes are well mixed, and are warming up to 85 DEG C, are incubated 40min, then in 100 DEG C of dehydrations, are cooled to
Room temperature obtains material B；9 parts of n-butanols, 2 parts of dimethylbenzene and 5 parts of epoxy resin E-20 are well mixed and obtain material b, then will
Material A and material B are well mixed, and are subsequently added into 4 parts of butyl titanates and are well mixed, and are warming up to 180 DEG C, are incubated 1h, are cooled to room
Temperature obtains material C；Under nitrogen atmosphere, material C, 9 parts of styrene and 2 parts of cumyl peroxides are well mixed, are warming up to
150 DEG C, 5h is incubated, is then cooled to room temperature, drying is filtered after extracting 26h, is subsequently added into 1 part of chloroform and is well mixed, in 550r/
Min rotating speeds stir 10h, add 9 parts of concentrated sulfuric acids and are well mixed, be warming up to 35 DEG C, be incubated 10h, dilute, filter, drying, are cooled to
Grinding at room temperature obtains antistatic modified filler into powder.
Embodiment 3
A kind of antistatic dyestuff of Anti-fade for the printing and dyeing of pig hair proposed by the present invention, its raw material include by weight：Entirely
50 parts of fluoroalkyl, 15 parts of fluorinated acrylate emulsion, 4 parts of AEO, N, N- dimethylethanolamines 6
Part, 8 parts of melamine phosphate, 2 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 6 parts of isomeric alcohol polyethenoxy ether, coconut oleoyl amine third
1 part of base glycine betaine, 4 parts of vinyl pyrrolidone polymer, 2 parts of triethanolamine oleate, 4 parts of dimethyl silicone polymer, methyl are fine
3 parts of dimension element, 6 parts of nano zine oxide, 2 parts of nano titanium oxide, 6 parts of diatomite, 3 parts of sodium carbonate, 3 parts of isopropanol, propane diols 3
Part, 20 parts of Anti-fade modified additive, 5 parts of antistatic modified filler.
Anti-fade modified additive is prepared by following technique：15 parts of paraffin are heated to 80 DEG C in water-bath by weight
Make its thawing, then add 8 parts of dewatering nano silicon dioxde solutions, disperse 40min in 9000r/min, be cooled to room temperature and obtain
Material a；By 3 parts of octamethylcy-clotetrasiloxanes, 8 parts of silane resin acceptor kh-550s, 1 part of emulsifying agent AEO-03 and 8 parts of emulsifying agent TX-
10 well mixed obtain material b；2 parts of odium stearate, 6 parts of DTACs and 5 parts of water are well mixed, heated up
To 80 DEG C, the process of heating does not stop to stir, and then instills in material a, is warming up to 80 DEG C, is incubated 5h, is cooled to room temperature and obtains thing
Expect c；5 parts of oxidized wax and 9 parts of oleic acid are well mixed, 90 DEG C are warming up under the protection of nitrogen, 25min is stirred after point fusing,
Then 3 parts of hexamethylene diamines and material c are added, is warming up to 160 DEG C, is incubated 3h, rise temperature is incubated 2h to 200 DEG C, treats water base
All after discharge, terminating reaction, 170 DEG C are cooled to, are cooled to room temperature and obtain Anti-fade modified additive.
Antistatic modified filler is prepared by following technique：25 parts of CNTs and 2 parts of concentrated nitric acids are mixed by weight
Close uniformly, be subsequently placed in 65 DEG C of backflow 1h, then filtered with the miillpore filter that aperture is 0.3 μm, wash to neutrality, be then placed in
14h is dried in 1100 DEG C of baking ovens, room temperature is cooled to and obtains material A；By 1 part of phenyltriethoxysilane, 6 parts of second of diethyl three
TMOS and 4 parts of tetraethoxysilanes are well mixed, and are warming up to 95 DEG C, are incubated 20min, then in 120 DEG C of dehydrations, are cooled to
Room temperature obtains material B；3 parts of n-butanols, 5 parts of dimethylbenzene and 1 part of epoxy resin E-20 are well mixed and obtain material b, then will
Material A and material B are well mixed, and are subsequently added into 8 parts of butyl titanates and are well mixed, and are warming up to 170 DEG C, are incubated 3h, are cooled to room
Temperature obtains material C；Under nitrogen atmosphere, material C, 3 parts of styrene and 5 parts of cumyl peroxides are well mixed, are warming up to
130 DEG C, 7h is incubated, is then cooled to room temperature, drying is filtered after extracting 20h, is subsequently added into 5 parts of chloroforms and is well mixed, in 350r/
Min rotating speeds stir 14h, add 4 parts of concentrated sulfuric acids and are well mixed, be warming up to 45 DEG C, be incubated 8h, dilute, filter, drying, are cooled to
Grinding at room temperature obtains antistatic modified filler into powder.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of antistatic dyestuff of Anti-fade for the printing and dyeing of pig hair, it is characterised in that its raw material includes by weight：Perfluor alkane
Base acrylate 40-50 parts, fluorinated acrylate emulsion 15-25 parts, AEO 1-4 parts, N, N- dimethyl second
Hydramine 6-12 parts, melamine phosphate 4-8 parts, sodium sulfate of polyethenoxy ether of fatty alcohol 2-5 parts, isomeric alcohol polyethenoxy ether 3-
6 parts, Cocoamidopropyl betaine 1-3 parts, vinyl pyrrolidone polymer 1-4 parts, triethanolamine oleate 2-5 parts, poly- two
Methylsiloxane 2-4 parts, methylcellulose 3-6 parts, nano zine oxide 2-6 parts, nano titanium oxide 2-5 parts, diatomite 1-6
Part, sodium carbonate 3-6 parts, isopropanol 1-3 parts, propane diols 3-5 parts, Anti-fade modified additive 10-20 parts, antistatic modified filler 5-
25 parts.
2. the Anti-fade antistatic dyestuff according to claim 1 for the printing and dyeing of pig hair, it is characterised in that Anti-fade is modified
The raw material of auxiliary agent includes by weight：Paraffin 5-15 parts, dewatering nano silicon dioxde solution 4-8 parts, octamethylcy-clotetrasiloxane
3-9 parts, silane resin acceptor kh-550 2-8 parts, emulsifying agent AEO-03 1-5 parts, emulsifying agent TX-10 4-8 parts, odium stearate 2-5
Part, DTAC 3-6 parts, water 5-15 parts, oxidized wax 5-15 parts, oleic acid 4-9 parts, hexamethylene diamine 3-9 parts.
3. the Anti-fade antistatic dyestuff according to claim 1 or 2 for the printing and dyeing of pig hair, it is characterised in that Anti-fade
Modified additive is prepared by following technique：Paraffin is heated in water-bath makes its thawing, then adds dewatering nano titanium dioxide
Silicon solution, disperse, be cooled to room temperature and obtain material a；By octamethylcy-clotetrasiloxane, silane resin acceptor kh-550, emulsifying agent
AEO-03 and emulsifying agent TX-10 is well mixed to obtain material b；Odium stearate, DTAC and water are mixed
Uniformly, heat up, the process of heating does not stop to stir, and then instills in material a, heats up, and insulation, is cooled to room temperature and obtains material c；Will
Oxidized wax and oleic acid are well mixed, and are heated up under the protection of nitrogen, are stirred after point fusing, are then added hexamethylene diamine and material c, risen
Temperature, insulation, after the substantially all discharge of water, terminating reaction, cooling, it is cooled to room temperature and obtains Anti-fade modified additive.
4. the antistatic dyestuff of Anti-fade for being used for the printing and dyeing of pig hair according to claim any one of 1-3, it is characterised in that anti-
Decolouring modified additive is prepared by following technique：Paraffin is heated into 80-90 DEG C in water-bath makes its thawing, then adds and dredges
Water nanosilica solution, disperse 20-40min in 9000-12000r/min, be cooled to room temperature and obtain material a；By prestox
Cyclotetrasiloxane, silane resin acceptor kh-550, emulsifying agent AEO-03 and emulsifying agent TX-10 are well mixed to obtain material b；By tristearin
Sour sodium, DTAC and water are well mixed, and are warming up to 70-80 DEG C, the process of heating does not stop to stir, and then drips
Enter in material a, be warming up to 80-90 DEG C, be incubated 3-5h, be cooled to room temperature and obtain material c；Oxidized wax and oleic acid are well mixed,
90-110 DEG C is warming up under the protection of nitrogen, 15-25min is stirred after point fusing, then adds hexamethylene diamine and material c, heating
To 140-160 DEG C, 3-5h is incubated, rise temperature is incubated 2-4h to 180-200 DEG C, after the substantially all discharge of water, terminates anti-
Should, 150-170 DEG C is cooled to, room temperature is cooled to and obtains Anti-fade modified additive.
5. the antistatic dyestuff of Anti-fade for being used for the printing and dyeing of pig hair according to claim any one of 1-4, it is characterised in that anti-
The raw material of electrostatic modified filler includes by weight：CNT 15-25 parts, concentrated nitric acid 2-5 parts, phenyltriethoxysilane
1-5 parts, diethyl triethoxysilane 3-6 parts, tetraethoxysilane 4-8 parts, n-butanol 3-9 parts, dimethylbenzene 2-5 parts, epoxy
Resin E-20 1-5 parts, butyl titanate 4-8 parts, styrene 3-9 parts, cumyl peroxide 2-5 parts, chloroform 1-5 parts, the concentrated sulfuric acid
4-9 parts.
6. the antistatic dyestuff of Anti-fade for being used for the printing and dyeing of pig hair according to claim any one of 1-5, it is characterised in that anti-
Electrostatic modified filler is prepared by following technique：CNT and concentrated nitric acid are well mixed, are then refluxed for, then uses filter membrane
Filter, wash to neutrality, be then placed in baking oven and dry, be cooled to room temperature and obtain material A；By phenyltriethoxysilane,
Diethyl triethoxysilane and tetraethoxysilane are well mixed, and are heated up, and insulation, are then dehydrated, are cooled to room temperature and obtain thing
Expect B；N-butanol, dimethylbenzene and epoxy resin E-20 are well mixed and obtain material b, is then mixed material A and material B equal
It is even, it is subsequently added into butyl titanate and is well mixed, heat up, insulation, is cooled to room temperature and obtains material C；Under nitrogen atmosphere, by material
C, styrene and cumyl peroxide are well mixed, and are heated up, and insulation, are then cooled to room temperature, drying are filtered after extraction, then
Add chloroform to be well mixed, stir, add the concentrated sulfuric acid and be well mixed, heat up, be incubated, dilute, filter, drying, be cooled to room temperature
Grind into powder obtains antistatic modified filler.
7. the antistatic dyestuff of Anti-fade for being used for the printing and dyeing of pig hair according to claim any one of 1-6, it is characterised in that anti-
Electrostatic modified filler is prepared by following technique：CNT and concentrated nitric acid are well mixed, are subsequently placed in 55-65 DEG C of backflow
1-3h, then filtered with the miillpore filter that aperture is 0.1-0.3 μm, wash to neutrality, be then placed in 1100-1130 DEG C of baking oven
10-14h is dried, room temperature is cooled to and obtains material A；By phenyltriethoxysilane, diethyl triethoxysilane and tetrem
TMOS is well mixed, and is warming up to 85-95 DEG C, is incubated 20-40min, then in 100-120 DEG C of dehydration, is cooled to room temperature and is obtained
To material B；N-butanol, dimethylbenzene and epoxy resin E-20 are well mixed and obtain material b, then mixes material A and material B
Uniformly, it is subsequently added into butyl titanate to be well mixed, is warming up to 170-180 DEG C, is incubated 1-3h, is cooled to room temperature and obtains material C；In
Under nitrogen atmosphere, material C, styrene and cumyl peroxide are well mixed, are warming up to 130-150 DEG C, 5-7h is incubated, connects
And be cooled to room temperature, filter drying after extracting 20-26h, be subsequently added into chloroform and be well mixed, stirred in 350-550r/min rotating speeds
10-14h, add the concentrated sulfuric acid and be well mixed, be warming up to 35-45 DEG C, be incubated 8-10h, dilute, filter, drying, be cooled to room temperature and grind
Clay into power to obtain antistatic modified filler.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710976853.2A CN107747240A (en) | 2017-10-19 | 2017-10-19 | A kind of antistatic dyestuff of Anti-fade for the printing and dyeing of pig hair |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710976853.2A CN107747240A (en) | 2017-10-19 | 2017-10-19 | A kind of antistatic dyestuff of Anti-fade for the printing and dyeing of pig hair |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106398548A (en) * | 2016-08-27 | 2017-02-15 | 安徽天瞳智能科技有限公司 | Acid and alkali resistant low-yellowing composite material |
| CN106634568A (en) * | 2016-12-05 | 2017-05-10 | 天长市优信电器设备有限公司 | Antistatic coating of aluminum charger shell and preparation method thereof |
| CN106867378A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of tack oil resistant wallpaper high and preparation method thereof |
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2017
- 2017-10-19 CN CN201710976853.2A patent/CN107747240A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106398548A (en) * | 2016-08-27 | 2017-02-15 | 安徽天瞳智能科技有限公司 | Acid and alkali resistant low-yellowing composite material |
| CN106634568A (en) * | 2016-12-05 | 2017-05-10 | 天长市优信电器设备有限公司 | Antistatic coating of aluminum charger shell and preparation method thereof |
| CN106867378A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of tack oil resistant wallpaper high and preparation method thereof |
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