CN107747216A - A kind of preparation method of high tenacity basalt fibre - Google Patents
A kind of preparation method of high tenacity basalt fibre Download PDFInfo
- Publication number
- CN107747216A CN107747216A CN201711035940.4A CN201711035940A CN107747216A CN 107747216 A CN107747216 A CN 107747216A CN 201711035940 A CN201711035940 A CN 201711035940A CN 107747216 A CN107747216 A CN 107747216A
- Authority
- CN
- China
- Prior art keywords
- parts
- high tenacity
- basalt fibre
- fiber
- basalt
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
The invention discloses a kind of preparation method of high tenacity basalt fibre, it comprises the following steps：（1）By basalt ore melt drawing；（2）Fiber after drawing is soaked into 1 ~ 2h in acetic acid；（3）Silane coupler is added into soak, adds kaolin, quartz；（4）Wire drawing again；（5）To new fiber surface plated nickel layer；（6）By the fiber after the completion of plating containing nano silicon, silane coupler ethanol solution in soak 1 ~ 2h, take out, drying, that is, obtain the high tenacity basalt fibre.The present invention forms the protective layer of high tenacity on basalt fibre surface, can effectively reduce the fragility of basalt fibre, improve its toughness and chemism.
Description
Technical field
The present invention relates to the technical field of basalt fibre.
Background technology
Basalt fibre, it is to draw the continuous fiber formed by basalt building stones, is that a kind of novel inorganic environment-friendly and green is high
Performance fibers material.Its intensity is high, and electric insulation, corrosion-resistant, heat-resisting quantity is excellent, fibre reinforced composites, friction material,
The many aspects such as shipbuilding materials, heat-barrier material, automobile industry, petroleum industry, high temperature filtration fabric and protection field obtain
It is widely applied.
The content of the invention
It is an object of the invention to propose a kind of preparation method of treated basalt fiber, so as to get basalt fibre tool
There are higher toughness and chemism.
Technical scheme is as follows：
A kind of preparation method of high tenacity basalt fibre, it comprises the following steps：
（1）By the broken removal of impurities of basalt ore feed powder, after being heated to 1400 DEG C~1600 DEG C meltings, drawn by bushing as fibre
Tie up shape；
（2）Fiber after drawing is soaked into 1 ~ 2h in acetic acid；
（3）Silane coupler is added into soak, kaolin is added after stirring, quartz, is stirred, in the pasty state；
（4）Pastel is pulled out by fibrillation shape, Cheng Xin fiber, baking；
（5）To the fiber surface plated nickel layer after baking；
（6）By the fiber after the completion of plating containing nano silicon, silane coupler ethanol solution in soak 1 ~ 2h, take
Go out, dry, that is, obtain the high tenacity basalt fibre.
Preferably：The high tenacity basalt fibre is in parts by mass, it is characterised in that：The high tenacity basalt is fine
In parts by mass, 100 parts of basalt ore, 5 ~ 10 parts of kaolin is quartzy 5 ~ 10 parts, 3 ~ 7 parts of nano silicon, nickel metal for dimension
3 ~ 8 parts, 1 ~ 6 part of silane coupler.
It is also preferred that：The high tenacity basalt fibre in parts by mass, including following raw material：Basalt ore
100 parts, 5 parts of kaolin, 8 parts of quartz, 5 parts of nano silicon, 5 parts of nickel metal, 3 parts of silane coupler.
The present invention can form the protective layer of multiple high tenacity on basalt fibre surface, can effectively reduce basalt fibre
Fragility, its toughness is improved, it is not easy brittle failure when by external force collision, while be remarkably improved its chemism.
Embodiment
A kind of preparation method of high tenacity basalt fibre, it comprises the following steps：
（1）By the broken removal of impurities of basalt ore feed powder, after being heated to 1400 DEG C~1600 DEG C meltings, drawn by bushing as fibre
Tie up shape；
（2）Fiber after drawing is soaked into 1 ~ 2h in acetic acid；
（3）Silane coupler is added into soak, kaolin is added after stirring, quartz, is stirred, in the pasty state；
（4）Pastel is pulled out by fibrillation shape, Cheng Xin fiber, baking；
（5）To the fiber surface plated nickel layer after baking；
（6）By the fiber after the completion of plating containing nano silicon, silane coupler ethanol solution in soak 1 ~ 2h, take
Go out, dry, that is, obtain the high tenacity basalt fibre.
Wherein：
Preferably：The high tenacity basalt fibre is in parts by mass, it is characterised in that：The high tenacity basalt fibre is pressed
Mass parts meter, 100 parts of basalt ore, 5 ~ 10 parts of kaolin, 5 ~ 10 parts of quartz, 3 ~ 7 parts of nano silicon, nickel metal 3 ~ 8
Part, 1 ~ 6 part of silane coupler.
It is also preferred that：The high tenacity basalt fibre in parts by mass, including following raw material：Basalt ore
100 parts, 5 parts of kaolin, 8 parts of quartz, 5 parts of nano silicon, 5 parts of nickel metal, 3 parts of silane coupler.
Claims (3)
- A kind of 1. preparation method of high tenacity basalt fibre, it is characterised in that：Comprise the following steps：（1）By the broken removal of impurities of basalt ore feed powder, after being heated to 1400 DEG C~1600 DEG C meltings, drawn by bushing as fibre Tie up shape；（2）Fiber after drawing is soaked into 1 ~ 2h in acetic acid；（3）Silane coupler is added into soak, kaolin is added after stirring, quartz, is stirred, in the pasty state；（4）Pastel is pulled out by fibrillation shape, Cheng Xin fiber, baking；（5）To the fiber surface plated nickel layer after baking；（6）By the fiber after the completion of plating containing nano silicon, silane coupler ethanol solution in soak 1 ~ 2h, take Go out, dry, that is, obtain the high tenacity basalt fibre.
- 2. the preparation method of high tenacity basalt fibre according to claim 1, it is characterised in that：The high tenacity Black Warrior Rock fiber is in parts by mass, it is characterised in that：In parts by mass, 100 parts of basalt ore is high for the high tenacity basalt fibre 5 ~ 10 parts of ridge soil, 5 ~ 10 parts of quartz, 3 ~ 7 parts of nano silicon, 3 ~ 8 parts of nickel metal, 1 ~ 6 part of silane coupler.
- 3. the preparation method of high tenacity basalt fibre according to claim 1, it is characterised in that：The high tenacity Black Warrior Rock fiber in parts by mass, including following raw material：100 parts of basalt ore, 5 parts of kaolin, 8 parts of quartz, nano silicon 5 Part, 5 parts of nickel metal, 3 parts of silane coupler.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711035940.4A CN107747216A (en) | 2017-10-30 | 2017-10-30 | A kind of preparation method of high tenacity basalt fibre |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711035940.4A CN107747216A (en) | 2017-10-30 | 2017-10-30 | A kind of preparation method of high tenacity basalt fibre |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107747216A true CN107747216A (en) | 2018-03-02 |
Family
ID=61253746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711035940.4A Withdrawn CN107747216A (en) | 2017-10-30 | 2017-10-30 | A kind of preparation method of high tenacity basalt fibre |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107747216A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110747558A (en) * | 2019-10-10 | 2020-02-04 | 浙江石金玄武岩纤维股份有限公司 | Basalt fiber sewing thread for heat-insulation board and preparation method thereof |
| CN114059051A (en) * | 2021-10-22 | 2022-02-18 | 北京科技大学 | Method for metallizing surface of basalt fiber material |
| DE102021101494A1 (en) | 2021-01-25 | 2022-07-28 | Fibrecoat Gmbh | Co-filament, roving, yarn, semi-finished product, use of a co-filament and method of making a co-filament |
-
2017
- 2017-10-30 CN CN201711035940.4A patent/CN107747216A/en not_active Withdrawn
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110747558A (en) * | 2019-10-10 | 2020-02-04 | 浙江石金玄武岩纤维股份有限公司 | Basalt fiber sewing thread for heat-insulation board and preparation method thereof |
| CN110747558B (en) * | 2019-10-10 | 2021-06-18 | 浙江石金玄武岩纤维股份有限公司 | Basalt fiber sewing thread for heat-insulation board and preparation method thereof |
| DE102021101494A1 (en) | 2021-01-25 | 2022-07-28 | Fibrecoat Gmbh | Co-filament, roving, yarn, semi-finished product, use of a co-filament and method of making a co-filament |
| CN114059051A (en) * | 2021-10-22 | 2022-02-18 | 北京科技大学 | Method for metallizing surface of basalt fiber material |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180302 |
|
| WW01 | Invention patent application withdrawn after publication |