CN107747046A - Steel Bar and its production method are built containing V, Ti microalloy - Google Patents

Steel Bar and its production method are built containing V, Ti microalloy Download PDF

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Publication number
CN107747046A
CN107747046A CN201711242339.2A CN201711242339A CN107747046A CN 107747046 A CN107747046 A CN 107747046A CN 201711242339 A CN201711242339 A CN 201711242339A CN 107747046 A CN107747046 A CN 107747046A
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steel
microalloy
production method
steel bar
bar
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邓通武
刘明
郭跃华
冉准
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Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
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Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The invention belongs to field of steel metallurgy, and in particular to one kind is containing V, Ti microalloy building Steel Bar and its production method.The problems such as alloy of vanadium nitride nitrogen content is low, species is few is prepared selected by nitrogen-containing alloy steel for existing, the invention provides one kind containing V, Ti microalloy building Steel Bar and its production method.The constituent of the bar is:By weight percentage, C:0.15%~0.30%, Si:0.30%~1.00%, Mn:0.60%~1.30%, N:0.0060%~0.0180%, P≤0.040%, S≤0.040%, V:0.010%~0.100%, Ti:0.010%~0.030%, surplus is Fe and inevitable impurity.The key of its preparation method is that after stove chain-wales feed core-spun yarn containing N, adjustment N to suitable level.The inventive method is simple to operate, and nitrogen recovery rate is high and stably, moreover it is possible to effectively reduces production cost, is worth of widely use.

Description

Steel Bar and its production method are built containing V, Ti microalloy
Technical field
The invention belongs to field of steel metallurgy, and in particular to one kind is containing V, Ti microalloy building Steel Bar and its producer Method.
Background technology
Micro alloyed steel is primarily referred to as adding certain either micro element of minimal amount in steel with regard to that can significantly improve performance Steel, particularly improve steel intensity index.It is either micro- mainly generally to add minimal amount for micro alloyed steel under the conditions of prior art Measure vanadium, niobium and titanium and obtain.The mechanism of action of microalloying is:After vanadium, niobium and titanium as trace element add molten steel, with steel Carbon and nitrogen in liquid combine, and form carbon, nitrogen compound particle, i.e. V (C, N), Nb (C, N) and Ti (C, N) particle, these particles There is certain precipitation strength and crystal grain refinement, can significantly improve the intensity of steel.
It will thus be seen that the effect of actually micro alloyed steel vanadium, niobium and titanium is inseparable with nitrogen, but generally Using converter smelting steel, residual nitrogen content is in the range of 0.0030%~0.065%, using electric furnace smelting steel, residual nitrogen content In the range of 0.050%~0.085%, in most cases.The effect of vanadium, niobium and titanium is such as given full play to, is to have to volume It is outer to add what nitrogen be realized.
Early stage increases nitrogen in micro alloyed steel, is realized by the nitridation class alloy of addition 3%~6%, but due to It is nitrogenous very low to nitrogenize class alloy, causes alloy addition big, and recovery rate is unstable, is gradually closed by the higher vanadium nitride of nitrogen content Jin Dynasty is replaced.At present almost it is difficult to reuse 3%~6% nitridation class alloy in the production of micro alloyed steel, almost all use is Containing vanadium and nitrogen content and high alloy of vanadium nitride.Alloy of vanadium nitride mainly has tri- trades mark of VN12, VN14 and VN16.General feelings The ratio of three trade mark nitrogen and vanadium is substantially stationary under condition, respectively 12:78(N:V);14:78(N:V);16:78(N: V), i.e. the ratio of nitrogen and vanadium is up to the 16 of VN16:78, i.e., containing 16% N in alloy, contain 78% vanadium.Alloy of vanadium nitride Although not only containing vanadium and nitrogen content but also high, for micro-alloying technology route different in micro alloyed steel, particularly compound micro- conjunction Jin Gang, such as V-Ti-N, even V-Ti-Nb-N, and it is unable to meet demand.
The content of the invention
The problems such as alloy of vanadium nitride nitrogen content is low, species is few is prepared selected by nitrogen-containing alloy steel for existing, and the present invention carries A kind of new method for preparing nitrogen-containing alloy is supplied.This method accurately controls nitrogen content by the way of nitrogenous core-spun yarn is added, Nitrogen recovery rate is high.
The present invention solve above-mentioned technical problem technical scheme be:There is provided it is a kind of containing V, Ti microalloy building Steel Bar and its Production method.
The present invention provides a kind of V, Ti microalloy that contains and builds Steel Bar, and its chemical composition is:By weight percentage, C: 0.15%~0.30%, Si:0.30%~1.00%, Mn:0.60%~1.30%, N:0.0060%~0.0180%, P≤ 0.040%th, S≤0.040%, V:0.010%~0.100%, Ti:0.010%~0.030%, surplus is for Fe and unavoidably Impurity.
Present invention also offers a kind of production method of the above-mentioned building Steel Bar containing V, Ti microalloy, comprise the following steps:
It is blast-melted that steel billet is made through converter smelting, continuous casting;Steel billet is heated, continous way rolling bar production line is rolled into Pole or Ribbed Bar is made in material, cooling;Core-spun yarn adjustment N, heating steel billet temperature are fed in the ladle of chain-wales wherein after stove Degree control is 950~1220 DEG C, and soaking temperature control is 1000~1200 DEG C, heating and 90~120min of soaking total time;Institute Stating steel billet composition is:By weight percentage, C:0.15%~0.30%, Si:0.30%~1.00%, Mn:0.60%~ 1.30%th, N:0.0060%~0.0180%, P≤0.040%, S≤0.040%, V:0.010%~0.100%, Ti: 0.010%~0.030%, surplus is Fe and inevitable impurity.
Further, the production method of the above-mentioned building Steel Bar containing V, Ti microalloy, comprises the following steps:
A, converter smelting
Molten iron and steel scrap are added in converter, C is taken off using Converter Oxigen Blowing, is smelted, treat molten steel C content for 0.05%~ 0.15%, P content≤0.025%, S content≤0.035%, tap during liquid steel temperature >=1650 DEG C;
Tap 1/3-2/3 when, add FeSi, FeMn, FeTi alloy and carburant, FeV or VN, control C be 0.15%~ 0.30%th, Si be 0.30%~1.00%, Mn be 0.60%~1.30%, V be 0.010%~0.100%, Ti 0.010% ~0.030%;
B, core-spun yarn is fed
It is transferred to ladle after tapping, ladle is reached after stove after chain-wales, and inert gas is blown into ladle, adds cored containing N Line, it is 0.0060%~0.0180% to control N content in molten steel;
C, continuous casting
It is 20~50 DEG C to control the degree of superheat wrapped in conticaster, and the steel billet section that molten steel is casting continuously to form is 150mm × 150mm ~200mm × 200mm square billet, is air-cooled to room temperature;
D, heating steel billet and rolling
Billet heating temperature control is 950~1220 DEG C, and soaking temperature control is 1000~1200 DEG C, and heating and soaking are total Time is 90~120min, and pole or Ribbed Bar are rolled into using continous way rolling bar production line.
Wherein, in the production method of the above-mentioned building Steel Bar containing V, Ti microalloy, molten iron described in step a requires S contents ≤ 0.060%.
Wherein, in the production method of the above-mentioned building Steel Bar containing V, Ti microalloy, FeSi and FeMn alloys described in step a With FeSiMn alloy replacings.
Wherein, in the production method of the above-mentioned building Steel Bar containing V, Ti microalloy, the inert gas described in step b is argon One kind in gas or nitrogen.
Wherein, in the production method of the above-mentioned building Steel Bar containing V, Ti microalloy, inert gas is blown into described in step b Time >=2min.
Wherein, in the production method of the above-mentioned building Steel Bar containing V, Ti microalloy, step b out-station temperatures are higher than the liquid phase of steel 60~90 DEG C of line temperature.
Wherein, in the production method of the above-mentioned building Steel Bar containing V, Ti microalloy, pole or Ribbed Bar described in step d Specification be
Beneficial effects of the present invention are:
The present invention builds Steel Bar by designing a kind of microalloy containing V, Ti, and alloying component V is added in steel: 0.010%~0.100% and Ti:0.010%~0.030%, then coordinate using the side that the core-spun yarn containing N is fed after converter smelting Formula is adjusted steel grade N content, rolled using rolling bar production line, and it is high that a kind of intensity height, nitrogen recovery rate can finally be prepared Microalloy builds Steel Bar.The inventive method is simple to operate, and nitrogen recovery rate is high and stably, moreover it is possible to production cost is effectively reduced, It is worth of widely use.
Embodiment
It is containing V, Ti microalloy building Steel Bar, its chemical composition the invention provides one kind:By weight percentage, C: 0.15%~0.30%, Si:0.30%~1.00%, Mn:0.60%~1.30%, N:0.0060%~0.0180%, P≤ 0.040%th, S≤0.040%, V:0.010%~0.100%, Ti:0.010%~0.030%, surplus is for Fe and unavoidably Impurity.
When the Ti that the present invention adds 0.010%~0.100% V and 0.010%~0.030% is to ensure steel Imitate performance.When generally using converter smelting steel, residual nitrogen content in final finished steel 0.0030%~ In the range of 0.0065%, using electric furnace smelting steel, residual nitrogen content is then in the range of 0.0050%~0.0085%.With in steel N content raises, ageing to be deteriorated therewith, and V and 0.010% that is of the invention then using addition 0.010%~0.100%~ 0.030% Ti modes, to ensure the ageing of steel, while the solution strengthening effect of nitrogen can also be given full play to, so as to improve The intensity of steel, reduce the cost of alloy of steel.
In addition, in above-mentioned chemical composition, because the nitrogen content in molten steel is higher than residual nitrogen content in usual steel, the addition of titanium It is more prone to form V (C, N) particles and Ti (C, N) particle, so as to promote V, Ti precipitation, can more fully plays vanadium ,, can on the premise of equal mechanical property to improve the comprehensive mechanical property of steel with the precipitation strength and Grain Refinement Effect of niobium Reduce the usage amount of vanadium and titanium.
Present invention also offers a kind of production method of the building Steel Bar containing V, Ti microalloy, comprise the following steps:
A, converter smelting
Molten iron and steel scrap are added first in converter, it is desirable to which the molten iron S contents of addition are not more than 0.060%, molten iron and useless After steel adds converter, C function is taken off using Converter Oxigen Blowing, molten iron and steel scrap are just smelt molten steel, arrived when molten steel composition just refines 0.05%~0.15% C, P are no more than 0.025%, S is not more than 0.035%, and tap when tapping temperature is not less than 1650 DEG C Into ladle;
The FeSi alloys containing Si elements, the FeMn alloys containing Mn elements are added in tapping process, and contains V element Alloy and alloy and carburant containing Ti elements, the carburant be C powder or anthracite, control C 0.15%~ In the range of 0.30%, Si is controlled in the range of 0.30%~1.00%, and Mn is in the range of 0.60%~1.30% for control, controls V In the range of 0.010%~0.100%, Ti is in the range of 0.010%~0.100% for control;It is initially added into tapping 1/3 FeSi, FeMn and FeV or VN alloys and FeTi, tapping to when 2/3 to add;
In the addition of above-mentioned alloy, also FeSi and FeMn alloys can be replaced using the FeSiMn alloys containing Si and Mn;
B, inert gas is blown into after Converter and feeds core-spun yarn
After the completion of tapping, steel ladle immediately accesses pipeline, and the molten steel into ladle is blown into inert gas, the inertia being blown into Gas can be argon gas or nitrogen, be blown into the time of inert gas and should be not less than 2min;Regulation inert gas is blown into Time is that all kinds of alloys that can make addition in order to ensure that molten steel has enough circulation time fully melt and not less than 2min It is even;
The inert gas time is blown into more than after 2min, sampling carries out N content detection, and the side of line feeding is used according to assay Method add core-spun yarn containing N, the core-spun yarn containing N predominantly alloy containing N, such as SiN, control molten steel in N content 0.0060% In the range of~0.0180%;If relatively stable can not sample of N content control carries out N content detection in molten steel after stove, directly feed Enter core-spun yarn;
Before feeding core-spun yarn, steel ladle need to connect the pipeline for being blown into inert gas again, and after the inert gas being blown into The core-spun yarn containing N can be fed, inert gas can be argon gas or nitrogen, and inert gas is blown into after the completion of line feeding Time also needs to extend more than 2min, to ensure the uniformity of N element in molten steel, and controls outbound liquid steel temperature;
Thermometric is carried out before outbound, it is ensured that out-station temperature is higher than 60~90 DEG C of the liquidus temperature of steel;
C, it is casting continuously to form steel billet
It is 20~50 DEG C to control the degree of superheat wrapped in conticaster, and the temperature is by outbound temperature after above-mentioned converter tapping and stove Degree controls to realize;
The steel billet section that molten steel is casting continuously to form be 150mm × 150mm~200mm × 200mm square billet, less than 150mm × 150mm square billet section is small to be unfavorable for working continuously for bof process, and the square billet section more than 200mm × 200mm can then extend Heat time during follow-up rolling steel billet;
The steel billet that molten steel is casting continuously to form, naturally cools to room temperature in atmosphere;
D, heating steel billet and rolling
Heating requirements total heat time of steel billet is 90~120min, and heating furnace maximum heating temperature is 1220 DEG C, highest Soaking temperature is 1200 DEG C, and steel billet goes out the temperature control of heating furnace in the range of 1000~1200 DEG C;
Final finished specification isPole, or have and defined in GB 1499.2 Ribbed Bar external formWith Ribbed Bar for building, can be entered using continous way rolling bar production line Row rolling.
Explanation will be further explained to the embodiment of the present invention by embodiment below, but do not indicated that this The protection domain of invention is limited in described in embodiment in scope.
Embodiment 1 is prepared containing V, Ti microalloy building Steel Bar with the inventive method
Certain steel plant is on 120 tons of (actual tap is in the range of 120~140 tons) bof processes of nominal capacity using this Inventive technique produces Ribbed Bar for building, and production technology is to be blown into inert gas+feeding core-spun yarn → 6 after converter smelting → stove The stream billet caster of machine 6 is cast into 150mm × 150mm steel billets → heating steel billet → continous way rolling bar production line and is rolled intoRibbed Bar.
120 tons of molten iron and 20 tons of steel scraps are added first in converter, the molten iron S contents of addition are 0.051%.Molten iron and useless After steel adds converter, C function is taken off using Converter Oxigen Blowing, molten iron and steel scrap are just smelt molten steel, arrived when molten steel composition just refines 0.10% C, 0.025% P, 0.024% S, tapping is into ladle when temperature is 1684 DEG C, and now actual tap is 132 tons (about 5% raw material is burnt in converter steelmaking process).In tapping process into molten steel add FeSi, FeMn, FeV, FeTi alloys and anthracite carry out Si, Mn, V, Ti and C element alloying, wherein Si contents are 74% in the FeSi alloys added, Mn contents are that V content is that Ti contents are 40% in 78%, FeTi alloys in 82%, FeV alloys in FeMn alloys, solid in anthracite C is determined for 92%, controls in molten steel that Si contents are 0.30%, Mn contents are 0.60%, V content 0.011%, Ti contents are 0.012%th, C content 0.15%.
After molten steel arrival stove after chain-wales, steel ladle immediately accesses pipeline, and the molten steel into ladle is blown into nitrogen, is blown into nitrogen Core-spun yarn containing N is added using the method for line feeding after gas 4min, it is 0.0063% to control N content in molten steel.
Continue to carry out thermometric after being blown into nitrogen 2min after having fed core-spun yarn, according to temperature-measuring results determine continue the nitrogen flushing time with Liquid steel temperature is adjusted, thermometric is carried out again before outbound, it is outbound when liquid steel temperature is 1570 DEG C, and molten steel is sent to conticaster and entered Row casting.
150mm × 150mm strands are cast on 6 machines 6 stream billet caster, tundish temperature is 1544 DEG C during continuous casting, The liquidus temperature of steel is 1515 DEG C, bag sampling analysis molten steel chemical constituent is 0.15% in conticaster C, 0.33% Si, 0.61% Mn, 0.03% Cr, 0.011% V, 0.010% Ti, 0.035% P, 0.019% S, 0.0068% N, remaining is Fe and inevitable other impurity.Casting blank stacking naturally cools to room temperature.
Deliver to continous way production line of bar after slab cooling to be heated, rolled, rolling specs areIt is with ribbing Reinforcing bar.Slab heating temperature is 1217 DEG C, and soaking temperature is 1187 DEG C, and total heat time, which reaches to come out of the stove after 95min, to be rolled, Finishing temperature is 952 DEG C, and natural air cooling is carried out after upper cold bed, is finally collected, bundling.
The mechanical properties test result of steel is:ReL (Rp0.2) is 351MPa, tensile strength 465MPa, elongation are 37.1%th, maximum, force percentage of total elongation is 17.8%, and 180 DEG C of clod washes are qualified.The tissue of steel is ferrite+pearlite.
Embodiment 2 is prepared containing V, Ti microalloy building Steel Bar with the inventive method
Certain steel plant is on 120 tons of (actual tap is in the range of 120~140 tons) bof processes of nominal capacity using this Inventive technique produces Ribbed Bar for building, and production technology is to be blown into inert gas+feeding core-spun yarn → 6 after converter smelting → stove The stream billet caster of machine 6 is cast into 200mm × 200mm steel billets → heating steel billet → continous way rolling bar production line and is rolled intoRibbed Bar.
120 tons of molten iron and 20 tons of steel scraps are added first in converter, the molten iron S contents of addition are 0.047%.Molten iron and useless After steel adds converter, C function is taken off using Converter Oxigen Blowing, molten iron and steel scrap are just smelt molten steel, arrived when molten steel composition just refines 0.08% C, 0.023% P, 0.027% S, tapping is into ladle when temperature is 1662 DEG C, and now actual tap is 136 tons (about 5% raw material is burnt in converter steelmaking process).In tapping process into molten steel add FeSi, FeMn, FeV, FeTi alloys and anthracite carry out Si, Mn, V, Ti and C element alloying, wherein Si contents are 74% in the FeSi alloys added, Mn contents are that V content is that Ti contents are 40% in 78%, FeTi alloys in 82%, FeV alloys in FeMn alloys, solid in anthracite C is determined for 92%, controls in molten steel that Si contents are 0.95%, Mn contents are 1.26%, V content 0.097%, Ti contents are 0.029%th, C content 0.30%.
After molten steel arrival stove after chain-wales, steel ladle immediately accesses pipeline, and the molten steel into ladle is blown into nitrogen, is blown into nitrogen Core-spun yarn containing N is added using the method for line feeding after gas 4min, it is 0.0171% to control N content in molten steel.
Continue to carry out thermometric after being blown into nitrogen 2min after having fed core-spun yarn, according to temperature-measuring results determine continue the nitrogen flushing time with Liquid steel temperature is adjusted, thermometric is carried out again before outbound, it is outbound when liquid steel temperature is 1569 DEG C, and molten steel is sent to conticaster and entered Row casting.
200mm × 200mm strands are cast on 6 machines 6 stream billet caster, tundish temperature is 1532 DEG C during continuous casting, The liquidus temperature of steel is 1495 DEG C, bag sampling analysis molten steel chemical constituent is 0.30% in conticaster C, 0.98% Si, 1.28% Mn, 0.03% Cr, 0.096% V, 0.029% Ti, 0.031% P, 0.022% S, 0.0177% N, remaining is Fe and inevitable other impurity.Casting blank stacking naturally cools to room temperature.
Deliver to continous way production line of bar after slab cooling to be heated, rolled, rolling specs areIt is with ribbing Reinforcing bar.Slab heating temperature is 1030 DEG C, and soaking temperature is 1006 DEG C, and total heat time, which reaches to come out of the stove after 95min, to be rolled, Finishing temperature is 884 DEG C, and natural air cooling is carried out after upper cold bed, is finally collected, bundling.
The mechanical properties test result of steel is:ReL (Rp0.2) is 519MPa, tensile strength 689MPa, elongation are 16.2%th, maximum, force percentage of total elongation is 10.9%, and 180 DEG C of clod washes are qualified.The tissue of steel is ferrite+pearlite.
Embodiment 3 is prepared containing V, Ti microalloy building Steel Bar with the inventive method
Certain steel plant is on 120 tons of (actual tap is in the range of 120~140 tons) bof processes of nominal capacity using this Inventive technique produces Ribbed Bar for building, and production technology is to be blown into inert gas+feeding core-spun yarn → 6 after converter smelting → stove The stream billet caster of machine 6 is cast into 200mm × 200mm steel billets → heating steel billet → continous way rolling bar production line and is rolled intoRibbed Bar.
120 tons of molten iron and 20 tons of steel scraps are added first in converter, it is 0.055% that the molten iron S contents of addition, which are less than,.Molten iron After adding converter with steel scrap, C function is taken off using Converter Oxigen Blowing, molten iron and steel scrap are just smelt molten steel, when molten steel composition just refines C, 0.018% P, 0.025% S to 0.06%, tapping is into ladle when temperature is 1683 DEG C, and now actual tap is 133 tons (about 5% raw material is burnt in converter steelmaking process).In tapping process into molten steel add FeSi, FeMn, FeV, FeTi alloys and anthracite carry out Si, Mn, V, Ti and C element alloying, wherein Si contents are 74% in the FeSi alloys added, Mn contents are that V content is that Ti contents are 40% in 78%, FeTi alloys in 82%, FeV alloys in FeMn alloys, solid in anthracite C is determined for 92%, controls in molten steel that Si contents are 0.52%, Mn contents are 0.97%, V content 0.053%, Ti contents are 0.021%th, C content 0.22%.
After molten steel arrival stove after chain-wales, steel ladle immediately accesses pipeline, and the molten steel into ladle is blown into nitrogen, is blown into nitrogen Core-spun yarn containing N is added using the method for line feeding after gas 4min, it is 0.0114% to control N content in molten steel.
Continue to carry out thermometric after being blown into nitrogen 2min after having fed core-spun yarn, according to temperature-measuring results determine continue the nitrogen flushing time with Liquid steel temperature is adjusted, thermometric is carried out again before outbound, it is outbound when liquid steel temperature is 1667 DEG C, and molten steel is sent to conticaster and entered Row casting.
200mm × 200mm strands are cast on 6 machines 6 stream billet caster, tundish temperature is 1537 DEG C during continuous casting, The liquidus temperature of steel is 1510 DEG C, bag sampling analysis molten steel chemical constituent is 0.22% in conticaster C, 0.55% Si, 0.96% Mn, 0.03% Cr, 0.053% V, 0.020% Ti, 0.025% P, 0.021% S, 0.0117% N, remaining is Fe and inevitable other impurity.Casting blank stacking naturally cools to room temperature.
Deliver to continous way production line of bar after slab cooling to be heated, rolled, rolling specs areIt is with ribbing Reinforcing bar.Slab heating temperature is 1128 DEG C, and soaking temperature is 1106 DEG C, and total heat time, which reaches to come out of the stove after 95min, to be rolled, Finishing temperature is 903 DEG C, and natural air cooling is carried out after upper cold bed, is finally collected, bundling.
The mechanical properties test result of steel is:ReL (Rp0.2) is 434MPa, tensile strength 570, elongation are 21.9%th, maximum, force percentage of total elongation is 15.2%, and 180 DEG C of clod washes are qualified.The tissue of steel is ferrite+pearlite.

Claims (9)

1. containing V, Ti microalloy building Steel Bar, it is characterised in that chemical composition is:By weight percentage, C:0.15%~ 0.30%th, Si:0.30%~1.00%, Mn:0.60%~1.30%, N:0.0060%~0.0180%, P≤0.040%, S ≤ 0.040%, V:0.010%~0.100%, Ti:0.010%~0.030%, surplus is Fe and inevitable impurity.
2. the production method of the building Steel Bar containing V, Ti microalloy described in claim 1, it is characterised in that including following step Suddenly:
It is blast-melted that steel billet is made through converter smelting, continuous casting;Steel billet is heated, the rolling of continous way rolling bar production line is become a useful person, Pole or Ribbed Bar is made in cooling;Core-spun yarn adjustment N, billet heating temperature control are fed in the ladle of chain-wales wherein after stove 950~1220 DEG C are made as, soaking temperature control is 1000~1200 DEG C, heating and 90~120min of soaking total time;The steel Base composition is:By weight percentage, C:0.15%~0.30%, Si:0.30%~1.00%, Mn:0.60%~1.30%, N:0.0060%~0.0180%, P≤0.040%, S≤0.040%, V:0.010%~0.100%, Ti:0.010%~ 0.030%, surplus is Fe and inevitable impurity.
3. the production method of the building Steel Bar according to claim 2 containing V, Ti microalloy, it is characterised in that including following Step:
A, converter smelting
Molten iron and steel scrap are added in converter, C is taken off using Converter Oxigen Blowing, is smelted, treat molten steel C content for 0.05%~ 0.15%, P content≤0.025%, S content≤0.035%, tap during liquid steel temperature >=1650 DEG C;
Tap 1/3-2/3 when, add FeSi, FeMn, FeTi alloy and carburant, FeV or VN, control C be 0.15%~ 0.30%th, Si be 0.30%~1.00%, Mn be 0.60%~1.30%, V be 0.010%~0.100%, Ti 0.010% ~0.030%;
B, core-spun yarn is fed
It is transferred to ladle after tapping, ladle is reached after stove after chain-wales, and inert gas is blown into ladle, adds core-spun yarn containing N, is controlled N content is 0.0060%~0.0180% in molten steel processed;
C, continuous casting
It is 20~50 DEG C to control the degree of superheat wrapped in conticaster, the steel billet section that molten steel is casting continuously to form be 150mm × 150mm~ 200mm × 200mm square billet, is air-cooled to room temperature;
D, heating steel billet and rolling
Billet heating temperature control is 950~1220 DEG C, and soaking temperature control is 1000~1200 DEG C, heating and soaking total time For 90~120min, pole or Ribbed Bar are rolled into using continous way rolling bar production line.
4. the production method of the building Steel Bar according to claim 3 containing V, Ti microalloy, it is characterised in that:In step a The molten iron requires S content≤0.060%.
5. the production method of the building Steel Bar according to claim 3 containing V, Ti microalloy, it is characterised in that:In step a FeSi the and FeMn alloys FeSiMn alloy replacings.
6. the production method of the building Steel Bar according to claim 3 containing V, Ti microalloy, it is characterised in that:In step b Described inert gas is one kind in argon gas or nitrogen.
7. the production method of the building Steel Bar according to claim 3 containing V, Ti microalloy, it is characterised in that:In step b Time >=the 2min for being blown into inert gas.
8. the production method of the building Steel Bar according to claim 3 containing V, Ti microalloy, it is characterised in that:Step b goes out Temperature of standing is higher than 60~90 DEG C of the liquidus temperature of steel.
9. the production method of the building Steel Bar according to claim 3 containing V, Ti microalloy, it is characterised in that:In step d The specification of the pole or Ribbed Bar is
CN201711242339.2A 2017-11-30 2017-11-30 Steel Bar and its production method are built containing V, Ti microalloy Pending CN107747046A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107955915A (en) * 2017-11-30 2018-04-24 攀钢集团攀枝花钢铁研究院有限公司 Steel bar and its LF stove production methods are built containing V, Ti microalloy
CN110846568A (en) * 2019-10-16 2020-02-28 邯郸钢铁集团有限责任公司 400 MPa-level straight reinforcing steel bar and production method thereof
CN111172459A (en) * 2020-01-19 2020-05-19 江苏省沙钢钢铁研究院有限公司 HRB600E vanadium-titanium microalloyed high-strength anti-seismic hot-rolled steel bar
CN114293096A (en) * 2021-11-17 2022-04-08 攀钢集团攀枝花钢铁研究院有限公司 500 MPa-grade vanadium-titanium micro-alloying hot-rolled steel bar and production method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102383039A (en) * 2011-11-10 2012-03-21 长沙东鑫环保材料有限责任公司 Microalloy HRB500E steel bar containing chrome and nitrogen and production method thereof
CN104694850A (en) * 2015-03-12 2015-06-10 东北大学 Thick steel plate with excellent rack arrest property and preparation method of thick steel plate
CN104928595A (en) * 2015-07-07 2015-09-23 南京钢铁股份有限公司 Band steel with good cold forming performance and for automobile structure and production process thereof
CN105463159A (en) * 2015-12-24 2016-04-06 马鞍山中科冶金材料科技有限公司 Multi-element nitralloy cored wire and application method thereof in reinforcing treatment technique of Q620D steel
CN106756566A (en) * 2017-01-17 2017-05-31 浙江富钢金属制品有限公司 A kind of Aldecor transmission rod and its manufacture method
CN107955915A (en) * 2017-11-30 2018-04-24 攀钢集团攀枝花钢铁研究院有限公司 Steel bar and its LF stove production methods are built containing V, Ti microalloy

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102383039A (en) * 2011-11-10 2012-03-21 长沙东鑫环保材料有限责任公司 Microalloy HRB500E steel bar containing chrome and nitrogen and production method thereof
CN104694850A (en) * 2015-03-12 2015-06-10 东北大学 Thick steel plate with excellent rack arrest property and preparation method of thick steel plate
CN104928595A (en) * 2015-07-07 2015-09-23 南京钢铁股份有限公司 Band steel with good cold forming performance and for automobile structure and production process thereof
CN105463159A (en) * 2015-12-24 2016-04-06 马鞍山中科冶金材料科技有限公司 Multi-element nitralloy cored wire and application method thereof in reinforcing treatment technique of Q620D steel
CN106756566A (en) * 2017-01-17 2017-05-31 浙江富钢金属制品有限公司 A kind of Aldecor transmission rod and its manufacture method
CN107955915A (en) * 2017-11-30 2018-04-24 攀钢集团攀枝花钢铁研究院有限公司 Steel bar and its LF stove production methods are built containing V, Ti microalloy

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
黄志勇等: "《第十八届(2014年)全国炼钢学术会议论文集S05:炉外精炼》", 31 May 2015 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107955915A (en) * 2017-11-30 2018-04-24 攀钢集团攀枝花钢铁研究院有限公司 Steel bar and its LF stove production methods are built containing V, Ti microalloy
CN110846568A (en) * 2019-10-16 2020-02-28 邯郸钢铁集团有限责任公司 400 MPa-level straight reinforcing steel bar and production method thereof
CN111172459A (en) * 2020-01-19 2020-05-19 江苏省沙钢钢铁研究院有限公司 HRB600E vanadium-titanium microalloyed high-strength anti-seismic hot-rolled steel bar
CN114293096A (en) * 2021-11-17 2022-04-08 攀钢集团攀枝花钢铁研究院有限公司 500 MPa-grade vanadium-titanium micro-alloying hot-rolled steel bar and production method thereof

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Application publication date: 20180302