CN107746477A - A kind of manufacture method of carbon nanometer tire tread containing all-steel cord and products thereof - Google Patents

A kind of manufacture method of carbon nanometer tire tread containing all-steel cord and products thereof Download PDF

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Publication number
CN107746477A
CN107746477A CN201710780447.9A CN201710780447A CN107746477A CN 107746477 A CN107746477 A CN 107746477A CN 201710780447 A CN201710780447 A CN 201710780447A CN 107746477 A CN107746477 A CN 107746477A
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carbon nanometer
tire tread
steel cord
tread
carbon
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CN201710780447.9A
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徐俊士
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SHANGHAI LVREN ECOLOGICAL ECONOMIC ENVIRONMENTAL PROTECTION RESEARCH INSTITUTE
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SHANGHAI LVREN ECOLOGICAL ECONOMIC ENVIRONMENTAL PROTECTION RESEARCH INSTITUTE
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Priority to CN201710780447.9A priority Critical patent/CN107746477A/en
Publication of CN107746477A publication Critical patent/CN107746477A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2307/00Characterised by the use of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/001Conductive additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/004Additives being defined by their length
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/80Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
    • Y02T10/86Optimisation of rolling resistance, e.g. weight reduction 

Abstract

The invention provides a kind of manufacture method of carbon nanometer tire tread containing all-steel cord and products thereof.Wherein, manufacture method includes:Short carbon nanometer tube is first made;Then it is rubber master batches, cracking black carbon, the short carbon nanometer tube is admixed together, banburying processing, carbon tube mother material is made;Carbon tube mother material, natural rubber, butadiene rubber, vulcanized rubber powder, ZnO, sulphur, vulcanization accelerator are mixed, banburying processing, tread mix is made;Obtained tread mix is put into tire tread vulcanizing machine together with all-steel cord, the carbon nanometer tire tread for containing all-steel cord is made.The tire tread is by tread band(5)Formed with casing play;Casing play is made up of quadriply belt beam layer:Transition zone(1), working lining(2), working lining(3), protective layer(4).The tire tread can reduce the delamination between belt and carcass, belt and tyre surface, can improve the contact area of tire and the stability of manipulation, reduce further the rolling resistance of tire.

Description

A kind of manufacture method of carbon nanometer tire tread containing all-steel cord and products thereof
Technical field
The invention belongs to full steel wire heavy load radial tire (TBR) manufacturing technology field, and in particular to one kind contains steel wire Manufacture method of carbon nanometer tire tread of cord and products thereof.
Background technology
At present, it is increasing with full steel wire heavy load radial tire (TBR) application amount, it is replaced the useless mesh wheel to get off Tire is also being continuously increased, and only tread contour polishes among these and carcass is undamaged, can apply traditional presulfurization bar shaped tire What face remanufactured only accounts for 5% or so, and crown belt steel wire is ground with or is damaged, carcass is intact still the useless of value Old tire then accounts for more than 40%, and the part junked tire can not remanufacture using bar shaped tyre surface, or be broken and rubber powder is made, or Burned and refine oil by local method, or abandoned is stacked everywhere, for rubber sources in short supply by serious waste, environment is heavily polluted destruction. Therefore, full steel wire heavy load radial tire is improved to remanufacture rate, carry out tire resources circulation recycling and environmental protection gesture must OK.For junked tire in addition to using bar shaped tyre surface reproducing method, have on present society still has certain depth using the decorative pattern cut off Old tire top remanufactured, but the old tire top cut off tries to gain hidden danger there is serious uneasiness and for example cuts off it in old tire top The either sidewall explosion or tyre bead explosion in using process (rotating at a high speed) of preceding old tire, can all make crown not take charge of degree Ground is damaged and phenomena such as light or heavy delamination or impaired steel belt occurs, in addition when cutting off old tire top due to checking not In place, the problems such as still being broken by thorn there is belt hand hay cutter silk department, these all severely impact the peace for remanufacturing tire Full performance.Therefore, old tire top cannot be used for tire and remanufacture.
In addition, CNT has excellent mechanical property, conduction, heat conductivility, thus it is considered as that polymer matrix is answered The preferable mechanics of condensation material strengthens and function modified material, using composite material exhibits made of CNT go out good strength, Elasticity and fatigue resistance, if applied on new tire tread, can greatly improve the overall performance of tire.
The content of the invention
Technical scheme provided by the present invention aims to solve the problem that above-mentioned technical problem present in prior art, and inventor is entering Go after substantial amounts of further investigation, designed and manufactured a kind of carbon nanometer tire tread containing all-steel cord so that used Performance after the tire of the tyre surface remanufactures is unaffected, or even improves the comprehensive of the tire after remanufacturing to a certain extent Close performance.
Technical scheme provided by the present invention includes:
First aspect, there is provided a kind of manufacture method of the carbon nanometer tire tread containing all-steel cord, including following step Suddenly:
S1:First CNT is added in rubber polymer melt and stirred to form carbon nano tube paste, then, uses material Pump is injected into the lapping device of two ceramic millstones with Line Contacts, is fully ground, and CNT is evenly spread to rubber In xanthan polymer melt, while by CNT under the shearing strength between layers effect in mechanical friction and rubber polymer melt Block;Polymer is removed, short carbon nanometer tube is made;
S2:Rubber master batches, cracking black carbon, the short carbon nanometer tube is admixed together, and banburying is carried out in banbury Processing, carbon tube mother material is made;
S3:The carbon tube mother material, natural rubber, butadiene rubber, vulcanized rubber powder, ZnO, sulphur, vulcanization accelerator are mixed To together, and banburying processing is carried out in banbury, tread mix is made;Then, by obtained tread mix and steel wire curtain Line is put into tire tread vulcanizing machine together, and through mould molding, the carbon nanometer tire tread containing all-steel cord is made.
Preferably, in above-mentioned manufacture method, the direction of rotation of described two ceramic millstones on the contrary, and rotary speed be 4500~5000rpm.
Preferably, in above-mentioned manufacture method, the rotary speed of described two ceramic millstones is 4800rpm.
Preferably, in above-mentioned manufacture method, the length of the short carbon nanometer tube is 50nm~5 μm.
Preferably, the proportion by weight that feeds intake in the S3 of above-mentioned manufacture method includes:
In addition, the second aspect of the present invention additionally provides a kind of carbon nanometer tire tread containing all-steel cord, it is by this Manufacture method described in invention first aspect is made.
Preferably, the above-mentioned carbon nanometer tire tread containing all-steel cord is the annular of closure, also, it is by tread band Formed with casing play;Wherein, the external annular surface of tread band has tread groove, and its inner ring surface can be with the crown phase after polishing It coincide;In addition, the casing play is made up of quadriply belt beam layer, from the direction away from the tread band to being close to the tread rubber The direction of layer inner side includes successively:Transition zone (i.e. first layer belt), working lining (i.e. second layer belt), working lining are (i.e. Third layer belt), protective layer (i.e. quadriply belt beam layer).Wherein, second layer belt and third layer belt cross arrangement.
It is further preferred that in the carbon nanometer tire tread containing all-steel cord, the cord bias angle of the transition zone Spend for 25~30 degree, and it is made up of high tenacity steel cord or conventional strength steel silk cord.
It is further preferred that in the carbon nanometer tire tread containing all-steel cord, the second layer belt with The third layer belt --- the cord angle of i.e. two layers working lining is 25~30 degree, and they are by high strength steel Silk cord or conventional strength steel silk cord are made;Also, the cord of the cord angle of the protective layer and two layers of working lining Angle is identical.
It is further preferred that in the carbon nanometer tire tread containing all-steel cord, the width of the quadriply belt beam layer Degree relation is:Described in third layer belt (working lining) > described in transition zone > described in second layer belt (working lining) > Protective layer.In other words, the width G T.GT.GT of the width G T.GT.GT third layer belts of the width G T.GT.GT first layer belts of second layer belt The width of quadriply belt beam layer.Wherein, the maximum working lining of width --- i.e. the width of second layer belt is that tread surface is wide The 80-90% of degree.In alternative technologies scheme, the width of each layer can be also set in the following order:The width of first layer belt Spend the width of the width G T.GT.GT quadriply belt beam layers of the width G T.GT.GT third layer belts of > second layer belts.
What deserves to be explained is compared with prior art, technical scheme provided by the present invention have following technical advantage with Beneficial effect:
Carbon tube mother material composite is applied in tire tread by the present invention, effectively reduces tire drag and changes It has been apt to braking distance (fuel-economizing 5% can be realized by contrasting existing carbon black tire), and the tyre surface has good antistatic property, Electric conductivity is superior, and wearability improves 30%, is successfully realized application of the CNT in tire tread glue;It is same with this When, the present invention using the tire that remanufactures of tyre surface with all-steel cord, can reduce belt and carcass, belt and tyre surface it Between delamination, can improve tire contact area and manipulation stability, reduce further the rolling resistance of tire.
In summary, manufacture method provided by the present invention, and contain steel wire curtain according to obtained by the manufacture method The carbon nanometer tire tread of line, there are excellent application value and wide market prospects.
Brief description of the drawings
Fig. 1 is disperses in the S1 of the manufacture method described in one embodiment of the present of invention, grinding technics schematic diagram.
Fig. 2 is the structural representation of the carbon nanometer tire tread containing all-steel cord described in one embodiment of the present of invention Figure;Wherein:1- transition zones, 2- working linings, 3- working linings, 4- protective layers, 5- tread bands.
Embodiment
With reference to embodiment, the present invention is further elaborated, but the present invention is not limited to following embodiment party Formula.
First aspect, there is provided a kind of manufacture method of the carbon nanometer tire tread containing all-steel cord, including following step Suddenly:
S1:Stirred as shown in figure 1, first CNT is added in rubber polymer melt to form carbon nano tube paste, Then, it is injected into the lapping device of two ceramic millstones with Line Contacts, is fully ground using material pump, removes polymer, Short carbon nanometer tube is made;
S2:Rubber master batches, cracking black carbon, the short carbon nanometer tube is admixed together, and banburying is carried out in banbury Processing, carbon tube mother material is made;
S3:The carbon tube mother material, natural rubber, butadiene rubber, vulcanized rubber powder, ZnO, sulphur, vulcanization accelerator are mixed To together, and banburying processing is carried out in banbury, tread mix is made;Then, by obtained tread mix and steel wire curtain Line is put into tire tread vulcanizing machine together, and through mould molding, the carbon nanometer tire tread containing all-steel cord is made.
In a preferred embodiment, described two ceramic millstones direction of rotation on the contrary, and rotary speed be 4500~ 5000rpm。
In a preferred embodiment, the length of the short carbon nanometer tube is 50nm~5 μm.
In a preferred embodiment, the proportion by weight that feeds intake in S3 includes:
Second aspect, there is provided a kind of carbon nanometer tire tread containing all-steel cord, it is as the system described in first aspect The method of making is made.
As shown in Fig. 2 in a preferred embodiment, the carbon nanometer tire tread containing all-steel cord is by tread rubber Layer 5 forms with casing play;Wherein, the casing play is made up of quadriply belt beam layer, from the direction away from the tread band to tight Paste the direction on the inside of the tread band includes successively:Transition zone 1, working lining 2, working lining 3, protective layer 4.
In a further preferred embodiment, the cord angle of the transition zone 1 is 25~30 degree, and it is by high-strength Degree all-steel cord or conventional strength steel silk cord are made.
In a further preferred embodiment, the cord angle of the working lining 2,3 is 25~30 degree, and they It is made by high tenacity steel cord or conventional strength steel silk cord;Also, the cord angle of the protective layer 4 and the work The cord angle of layer 2,3 is identical.
In a further preferred embodiment, the wide association of the quadriply belt beam layer is:The > institutes of working lining 2 State protective layer 4 described in the > of working lining 3 described in the > of transition zone 1.
Embodiment 1
S1:First CNT is added in rubber polymer melt and stirred to form carbon nano tube paste, then, uses material Pump is injected into the lapping device of two ceramic millstones with Line Contacts, is fully ground, wherein, described two ceramic millstones Direction of rotation is on the contrary, and rotary speed is 4500rpm;Polymer is removed, it is 50nm~5 μm short carbon nanometer tube that length, which is made,;
S2:Rubber master batches, cracking black carbon, the short carbon nanometer tube is admixed together, and banburying is carried out in banbury Processing, carbon tube mother material is made;
S3:The carbon tube mother material, natural rubber, butadiene rubber, vulcanized rubber powder, ZnO, sulphur, vulcanization accelerator are mixed To together, and banburying processing is carried out in banbury, tread mix is made;Then, by obtained tread mix and steel wire curtain Line is put into tire tread vulcanizing machine together, and through mould molding, the carbon nanometer tire tread containing all-steel cord is made;Its In, the proportion by weight that feeds intake is:
Embodiment 2
S1:First CNT is added in rubber polymer melt and stirred to form carbon nano tube paste, then, uses material Pump is injected into the lapping device of two ceramic millstones with Line Contacts, is fully ground, wherein, described two ceramic millstones Direction of rotation is on the contrary, and rotary speed is 4800rpm;Polymer is removed, it is 50nm~5 μm short carbon nanometer tube that length, which is made,;
S2:Rubber master batches, cracking black carbon, the short carbon nanometer tube is admixed together, and banburying is carried out in banbury Processing, carbon tube mother material is made;
S3:The carbon tube mother material, natural rubber, butadiene rubber, vulcanized rubber powder, ZnO, sulphur, vulcanization accelerator are mixed To together, and banburying processing is carried out in banbury, tread mix is made;Then, by obtained tread mix and steel wire curtain Line is put into tire tread vulcanizing machine together, and through mould molding, the carbon nanometer tire tread containing all-steel cord is made;Its In, the proportion by weight that feeds intake is:
Embodiment 3
S1:First CNT is added in rubber polymer melt and stirred to form carbon nano tube paste, then, uses material Pump is injected into the lapping device of two ceramic millstones with Line Contacts, is fully ground, wherein, described two ceramic millstones Direction of rotation is on the contrary, and rotary speed is 5000rpm;Polymer is removed, it is 50nm~5 μm short carbon nanometer tube that length, which is made,;
S2:Rubber master batches, cracking black carbon, the short carbon nanometer tube is admixed together, and banburying is carried out in banbury Processing, carbon tube mother material is made;
S3:The carbon tube mother material, natural rubber, butadiene rubber, vulcanized rubber powder, ZnO, sulphur, vulcanization accelerator are mixed To together, and banburying processing is carried out in banbury, tread mix is made;Then, by obtained tread mix and steel wire curtain Line is put into tire tread vulcanizing machine together, and through mould molding, the carbon nanometer tire tread containing all-steel cord is made;Its In, the proportion by weight that feeds intake is:
Embodiment 4
S1:First CNT is added in rubber polymer melt and stirred to form carbon nano tube paste, then, uses material Pump is injected into the lapping device of two ceramic millstones with Line Contacts, is fully ground, wherein, described two ceramic millstones Direction of rotation is on the contrary, and rotary speed is 4800rpm;Polymer is removed, it is 50nm~5 μm short carbon nanometer tube that length, which is made,;
S2:Rubber master batches, cracking black carbon, the short carbon nanometer tube is admixed together, and banburying is carried out in banbury Processing, carbon tube mother material is made;
S3:The carbon tube mother material, natural rubber, butadiene rubber, vulcanized rubber powder, ZnO, sulphur, vulcanization accelerator are mixed To together, and banburying processing is carried out in banbury, tread mix is made;Then, by obtained tread mix and steel wire curtain Line is put into tire tread vulcanizing machine together, and through mould molding, the carbon nanometer tire tread containing all-steel cord is made;Its In, the proportion by weight that feeds intake is:
In addition, inventor according to the performance of tire tread made from the step in above example 1~4 also to being surveyed Examination, it is as a result as shown in table 1 below:
The testing performance index result of the tire tread of table 1
Further, inventor is also to the load-carrying according to tire tread made from the step in above example 1~4 Automobile conventional section radial has carried out coherent detection, and its testing conditions is:Wheel rim 8.25 is tested, examines speed 70KM/ H, 35-41 DEG C of environment temperature, test air pressure 830Kpa, test load 3000KG;Also, the result of above-mentioned detection such as table 2 below institute Show:
The truck conventional section radial testing result of table 2
As can be seen here, the tire manufactured using the carbon nanometer tire tread of the present invention containing all-steel cord, is being passed through Cross and remanufacture the indices of the reconstruction tire obtained after tire technique and be up to state standards, even more than brand-new tire; Tested and found by heat transfer coefficient, compared with other new tires, reconstruction tire heat transfer coefficient under 60 degree and 80 degree of situation Improve 25%;In addition, in road test, the crown surface temperature and groove bottom temperature of the reconstruction tire substantially reduce, Tire wear improves more than 30%, and actual travel mileage can reach more than 200,000 kilometers, and manufacturing cost is relatively low.
In a word, the tire reproduced by the carbon nanometer tire tread of the present invention containing all-steel cord, due to using Carbon nanomaterial, the wear-resisting and heat dispersion of tire are effectively improved;And the skeleton structure with cord can be reduced in tyre surface Delamination between belt and carcass, belt and tyre surface, the contact area and control stability of tire are improved, reduces tire Rolling resistance, uneven wear is reduced, therefore, it is used suitable for middle-long distance apart from big cargo dead-weight Automobile Transportation, and suitable in height Fast highway uses.
The specific embodiment of the present invention is described in detail above, but it is intended only as example, it is of the invention and unlimited It is formed on particular embodiments described above.To those skilled in the art, it is any to the equivalent modifications that carry out of the present invention and Substitute also all among scope of the invention.Therefore, the impartial conversion made without departing from the spirit and scope of the invention and Modification, all should be contained within the scope of the invention.

Claims (10)

1. a kind of manufacture method of the carbon nanometer tire tread containing all-steel cord, it is characterised in that comprise the following steps:
S1:First CNT is added in rubber polymer melt and stirred to form carbon nano tube paste, then, uses material infusion Enter into the lapping device of two ceramic millstones with Line Contacts, be fully ground, remove polymer,
Short carbon nanometer tube is made;
S2:Rubber master batches, cracking black carbon, the short carbon nanometer tube is admixed together, and banburying processing is carried out in banbury, Carbon tube mother material is made;
S3:The carbon tube mother material, natural rubber, butadiene rubber, vulcanized rubber powder, ZnO, sulphur, vulcanization accelerator are mixed into one Rise, and banburying processing is carried out in banbury, tread mix is made;Then, by obtained tread mix and all-steel cord one Rise and put into tire tread vulcanizing machine, and through mould molding, the carbon nanometer tire tread containing all-steel cord is made.
2. manufacture method according to claim 1, it is characterised in that the direction of rotation of described two ceramic millstones on the contrary, And rotary speed is 4500 ~ 5000 rpm.
3. manufacture method according to claim 1, it is characterised in that the rotary speed of described two ceramic millstones is 4800 rpm。
4. manufacture method according to claim 1, it is characterised in that the length of the short carbon nanometer tube is 50nm ~ 5 μm.
5. manufacture method according to claim 1, it is characterised in that the proportion by weight that feeds intake in S3 includes:
Carbon tube mother material 10 ~ 15
Natural rubber 75 ~ 80
Butadiene rubber 18 ~ 22
Vulcanized rubber powder 48 ~ 51
ZnO 1.2~1.5
Sulphur 1.5 ~ 2
Vulcanization accelerator 1.3 ~ 1.6.
A kind of 6. carbon nanometer tire tread containing all-steel cord, it is characterised in that the carbon nanometer wheel containing all-steel cord Tire tread is made as the manufacture method any one of according to claim 1 ~ 5.
7. the carbon nanometer tire tread according to claim 6 containing all-steel cord, it is characterised in that it is by tread band (5)Formed with casing play;Wherein, the casing play is made up of quadriply belt beam layer, from the direction away from the tread band to tight Paste the direction on the inside of the tread band includes successively:Transition zone(1), working lining(2), working lining(3), protective layer(4).
8. the carbon nanometer tire tread according to claim 7 containing all-steel cord, it is characterised in that the transition zone (1)Cord angle be 25~30 degree, and it is made up of high tenacity steel cord or conventional strength steel silk cord.
9. the carbon nanometer tire tread according to claim 7 containing all-steel cord, it is characterised in that the working lining (2)、(3)Cord angle be 25~30 degree, and they are made by high tenacity steel cord or conventional strength steel silk cord; Also, the protective layer(4)Cord angle and the working lining(2)、(3)Cord angle it is identical.
10. the carbon nanometer tire tread according to claim 7 containing all-steel cord, it is characterised in that the quadriply belt The wide association of beam layer is:The working lining(2)Transition zone described in >(1)Working lining described in >(3)Protective layer described in >(4).
CN201710780447.9A 2017-09-01 2017-09-01 A kind of manufacture method of carbon nanometer tire tread containing all-steel cord and products thereof Pending CN107746477A (en)

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CN110643080A (en) * 2019-09-04 2020-01-03 芜湖集拓实心胎有限公司 Low themogenesis engineering solid tire

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